CN105951206B - A kind of antistatic modified PBT fibers - Google Patents
A kind of antistatic modified PBT fibers Download PDFInfo
- Publication number
- CN105951206B CN105951206B CN201610483317.4A CN201610483317A CN105951206B CN 105951206 B CN105951206 B CN 105951206B CN 201610483317 A CN201610483317 A CN 201610483317A CN 105951206 B CN105951206 B CN 105951206B
- Authority
- CN
- China
- Prior art keywords
- parts
- graphene
- antistatic
- pbt fibers
- modified pbt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 33
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 5
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical group C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- -1 phenyl ester Chemical class 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000005119 centrifugation Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 206010054949 Metaplasia Diseases 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000015689 metaplastic ossification Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 description 7
- 239000000463 material Substances 0.000 description 4
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical group [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
Abstract
The present invention relates to fiber, and in particular to a kind of antistatic modified PBT fibers, are made of the component comprising following mass parts：45 50 parts of terephthalic acid (TPA), 34 43 parts of butanediol, 0.5 1 parts of catalyst, 8 12 parts of modified graphene, 38 parts of nano metal compound, 0.1 0.5 parts of antioxidant 1010,0.3 0.8 parts of stabilizer.The antistatic property, nontoxic, preferable heat resistance and washing fastness, performance that fiber prepared by the present invention has high-efficient and lasting are stablized, and can be adapted for a variety of application fields；Preparation method of the present invention is simple, easy to operate, easy to control, and cost is low, environmental protection, is adapted to the production of mass metaplasia.
Description
Technical field
The present invention relates to fiber, and in particular to a kind of antistatic modified PBT fibers.
Background technology
Polyester fiber has the characteristics that intensity is high, elasticity is good, wrinkle resistance is strong, wearability is good and excellent heat resistance.Cause
This, is a kind of ideal textile material no matter civilian and be industrially widely used.Polyester fiber is currently synthetic fibers
The kind that middle yield is maximum, purposes is most wide, due to its good mechanical performance and tensile property, be widely used dress ornament,
The field such as industry, good logical transport, ornament materials.But with the expansion of its application field, field is used in some special dimensions
Close, such as the ornament materials of military affairs, aviation, communications and transportation, public place of entertainment, hospital etc., fire fighting device etc., then need to reach certain
Antistatic requirement.Electrostatic hazard often results in heavy losses and disaster, can be because putting a production when the electrostatic of aggregation is higher than 500V
Light a fire flower, cause fire, higher than 8000V when can then produce shock phenomenon.Harm caused by electrostatic limits answering for polyester fiber
Use field.The technical method of general antistatic fibre has three kinds：The first covers antistatic place in fiber or fabric face
Manage agent；Second is that surfactant-based antistatic additive is added inside polyester；3rd is by adding conductive material inside polyester
Matter.
Since graphene is found for 2004, it causes the very big of scientific circles immediately as a kind of new carbon
Concern.Graphene has unique two-dimensional nanostructure, its electron transfer rate is high, electric conductivity is superior, thermal conductivity is high, is
The highest material of mechanical strength known and possesses the advantages that stable chemical performance translucency is good.Graphene is in lithium ion battery, super
The fields such as level capacitor, functional composite material, sensor, biological medicine, transparent conductive film, microelectronic component have very wide
General application prospect.Many can be improved by the mechanical property of polymer by adding a small amount of graphene in the polymer.In addition, phase
Than traditional anti-static composite material filler, graphene can obtain antistatic effect under relatively low content.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of antistatic modified PBT fibers.
The present invention adopts the following technical scheme that：
A kind of antistatic modified PBT fibers, are made of the component comprising following mass parts：
45-50 parts of terephthalic acid (TPA), 34-43 parts of butanediol, 0.5-1 parts of catalyst, 8-12 parts of modified graphene, nanogold
Belong to 3-8 parts of compound, 0.1-0.5 parts of antioxidant 1010,0.3-0.8 parts of stabilizer.
Specifically, the catalyst is tetraethyl titanate, four n-propyl of metatitanic acid, one kind in tetra-n-butyl titanate or several
Kind.
Specifically, the modified graphene is prepared as follows：1) graphene vulcanizes：Graphene is immersed into dense sulphur
In acid, 10-12h is heated at being 140-150 DEG C in temperature, taking-up distilled water filtration washing must vulcanize graphene 3-6 times；(2)
Vulcanization graphene is dissolved in anhydrous ethanol solvent, it is 3-5% to vulcanize the concentration in graphene absolute ethyl alcohol, and alcohol solvent pH is controlled
8.5-9 is made as, then adds Silane coupling agent KH550, reaction 3-5h is carried out at being 35-45 DEG C in temperature；(3) after the completion of reacting
It is centrifuged, carrying out vacuum drying to solid prepares modified graphene.
Specifically, the nano-metal-oxide is zinc oxide and zirconium oxide (1-3) in mass ratio：1 composition, particle diameter are
50-100nm。
Specifically, the stabilizer for triphenyl phosphite, Trimethyl phosphite, one kind in three certain herbaceous plants with big flowers ester of phosphorous acid or
It is several.
Beneficial effects of the present invention：
(1) modified graphene that the present invention adds has excellent electric conductivity, can effectively reduce the resistance of fiber surface
The ELECTRONIC SCREENING EFFECT IN of zinc oxide has preferable synergistic effect in rate, with metallic compound so that the antistatic property of fiber is high
Effect, persistently；And the addition of graphene can also improve the mechanical strength of fiber.
(2) fiber for preparing of the present invention is nontoxic, preferable heat resistance and washing fastness, performance are stablized, and can be adapted for more
Kind application field.
(3) preparation method of the present invention is simple, easy to operate, easy to control, and cost is low, environmental protection, is adapted to the production of mass metaplasia.
Embodiment
Presently in connection with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of antistatic modified PBT fibers, are made of the component comprising following mass parts：
45 parts of terephthalic acid (TPA), 43 parts of butanediol, 0.5 part of tetraethyl titanate, 8 parts of modified graphene, particle diameter 50-
The zinc oxide and zirconium oxide in mass ratio 1 of 100nm:3 parts of nano metal compound, 0.1 part of antioxidant 1010, the phosphorous of 1 composition
0.4 part of triphenyl phosphate ester.
Wherein, modified graphene is prepared as follows：1) graphene vulcanizes：Graphene is immersed in the concentrated sulfuric acid,
Temperature is to heat 10-12h at 140-150 DEG C, and taking-up distilled water filtration washing must vulcanize graphene 3-6 times；(2) stone will be vulcanized
Black alkene is dissolved in anhydrous ethanol solvent, and it is 3~5% to vulcanize the concentration in graphene absolute ethyl alcohol, and alcohol solvent pH controls are
8.5, Silane coupling agent KH550 is then added, reaction 3-5h is carried out at being 35-45 DEG C in temperature；(3) react after the completion of carry out from
The heart separates, and carries out vacuum drying to solid and prepares modified graphene.
A kind of preparation method of antistatic modified PBT fibers, includes the following steps：
(1) modified graphene, nano metal compound, butanediol are added in reaction kettle, in the case where temperature is 50-60 DEG C
Stir 0.5-1h；
(2) terephthalic acid (TPA), catalyst are added in the reaction kettle of step (1), rise system temperature to 200-220
DEG C, react 2-3h；
(3) antioxidant 1010, stabilizer are added, is then vacuumized, the quick temperature that raises is to 250-280 DEG C, polycondensation reaction
3-5h, when the viscosity of polymer is 0.6-0.9 scopes, i.e., reaction was completed obtains antistatic modified PBT polyester；
(4) the antistatic modified PBT polyester for obtaining step (3) passes through screw type spinning-drawing machine, is 250-270 DEG C in temperature
Melt spinning is carried out, after cooling, is oiled, 500-600m/min preliminary drafts, is stretched by 1000-1800m/min, ensures to lead
It is 2-3 to draw rate, and winding, processing temperature are 65-85 DEG C, obtain the controllable antistatic modified PBT fibers of even structure, fiber number.
Embodiment 2-5 is substantially the same manner as Example 1, difference such as table 1.
Table 1
By fibre property such as table 2 obtained by above-mentioned formula
Table 2
It is complete by above-mentioned description, relevant staff using the above-mentioned desirable embodiment according to the present invention as enlightenment
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to determines its technical scope according to right.
Claims (4)
- A kind of 1. antistatic modified PBT fibers, it is characterised in that：It is made of the component comprising following mass parts：Terephthalic acid (TPA) 45-50 parts, it is 34-43 parts of butanediol, 0.5-1 parts of catalyst, 8-12 parts of modified graphene, 3-8 parts of nano metal compound, anti- 1010 0.1-0.5 parts of oxygen agent, 0.3-0.8 parts of stabilizer；The modified graphene is prepared as follows：1）Graphene vulcanizes：Graphene is immersed in the concentrated sulfuric acid, is in temperature Heat 10-12h at 140-150 DEG C, taking-up distilled water filtration washing must vulcanize graphene 3-6 times；2）Graphene will be vulcanized It is dissolved in anhydrous ethanol solvent, it is 3-5wt% to vulcanize the concentration in graphene absolute ethyl alcohol, and alcohol solvent pH controls are 8.5-9, Then Silane coupling agent KH550 is added, reaction 3-5h is carried out at being 35-45 DEG C in temperature；3）Centrifugation point is carried out after the completion of reaction From carrying out being dried in vacuo to obtain modified graphene to solid；The nano-metal-oxide for zinc oxide and zirconium oxide in mass ratio（1-3）：1 composition.
- 2. as a kind of antistatic modified PBT fibers described in claim 1, it is characterised in that：The catalyst is metatitanic acid tetrem One or more in ester, four n-propyl of metatitanic acid, tetra-n-butyl titanate.
- 3. as a kind of antistatic modified PBT fibers described in claim 1, it is characterised in that：The zinc oxide and zirconium oxide Particle diameter is 50-100nm.
- 4. as a kind of antistatic modified PBT fibers described in claim 1, it is characterised in that：The stabilizer is phosphorous acid three One or more in phenyl ester, Trimethyl phosphite, three certain herbaceous plants with big flowers ester of phosphorous acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610483317.4A CN105951206B (en) | 2016-06-27 | 2016-06-27 | A kind of antistatic modified PBT fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610483317.4A CN105951206B (en) | 2016-06-27 | 2016-06-27 | A kind of antistatic modified PBT fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105951206A CN105951206A (en) | 2016-09-21 |
| CN105951206B true CN105951206B (en) | 2018-05-01 |
Family
ID=56904334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610483317.4A Active CN105951206B (en) | 2016-06-27 | 2016-06-27 | A kind of antistatic modified PBT fibers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105951206B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107338506A (en) * | 2017-08-07 | 2017-11-10 | 太仓荣文合成纤维有限公司 | A kind of Environmental-friendantistatic antistatic PBT fibers |
| CN107313127A (en) * | 2017-08-07 | 2017-11-03 | 太仓荣文合成纤维有限公司 | A kind of PBT bamboo charcoals elastic fibers |
| CN107523896B (en) * | 2017-08-28 | 2020-02-18 | 广州科技职业技术学院 | Graphene-polyester conductive polyester filament and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701369A (en) * | 2009-09-14 | 2010-05-05 | 吴江鹰翔万信化纤有限公司 | Antistatic polyester fibre |
| CN103910908A (en) * | 2014-04-02 | 2014-07-09 | 合肥杰事杰新材料股份有限公司 | Method for preparing modified graphene antistatic agent |
| CN104120505A (en) * | 2013-04-27 | 2014-10-29 | 上海杰事杰新材料(集团)股份有限公司 | Inflaming retarding modified PBT (Polybutylene Terephthalate) fiber and preparation method thereof |
| CN105331058A (en) * | 2015-11-17 | 2016-02-17 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing conductive polyester master batch with in-situ polymerization method |
| CN105670329A (en) * | 2016-04-05 | 2016-06-15 | 江苏宏远科技工程有限公司 | Preparation method of graphene-modified glass-fiber-reinforced composite material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130224452A1 (en) * | 2012-02-28 | 2013-08-29 | Indian Institute Of Technology Madras | Metal nanoparticle-graphene composites and methods for their preparation and use |
-
2016
- 2016-06-27 CN CN201610483317.4A patent/CN105951206B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701369A (en) * | 2009-09-14 | 2010-05-05 | 吴江鹰翔万信化纤有限公司 | Antistatic polyester fibre |
| CN104120505A (en) * | 2013-04-27 | 2014-10-29 | 上海杰事杰新材料(集团)股份有限公司 | Inflaming retarding modified PBT (Polybutylene Terephthalate) fiber and preparation method thereof |
| CN103910908A (en) * | 2014-04-02 | 2014-07-09 | 合肥杰事杰新材料股份有限公司 | Method for preparing modified graphene antistatic agent |
| CN105331058A (en) * | 2015-11-17 | 2016-02-17 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing conductive polyester master batch with in-situ polymerization method |
| CN105670329A (en) * | 2016-04-05 | 2016-06-15 | 江苏宏远科技工程有限公司 | Preparation method of graphene-modified glass-fiber-reinforced composite material |
Non-Patent Citations (1)
| Title |
|---|
| 石墨烯改性环氧树脂/碳纤维复合材料拉伸性能的研究;陈建剑等;《化工新型材料》;20120915;第40卷(第9期);第63-65,71页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105951206A (en) | 2016-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105951206B (en) | A kind of antistatic modified PBT fibers | |
| CN105970340B (en) | A kind of preparation method of antistatic modified PBT fibers | |
| CN109778335B (en) | Modified polypropylene fiber and preparation method thereof | |
| CN107794591A (en) | A kind of preparation method and spinning process of the Anti-radiation polyester fiber based on mechanical stripping graphene | |
| JP2017535684A (en) | Polyester composite material, polyester composite fiber, production method and use thereof | |
| WO2023184665A1 (en) | Ultraviolet-aging-resistant tpu hot melt adhesive film and preparation method therefor | |
| CN107099089A (en) | A kind of graphene master batch with antistatic behaviour and its preparation method and application | |
| CN109943964B (en) | Ribbon and preparation method thereof | |
| CN106318135B (en) | A kind of antistatic bacteriostasis complex function stainless steel tube coating | |
| CN114086273A (en) | Graphene anti-ultraviolet anti-cutting high-stretch-resistance composite fiber and preparation method thereof | |
| KR101788634B1 (en) | Method for Producing Carbon NanoTube Fiber | |
| CN115850708B (en) | Preparation method and application of N-P-Si-containing caged polysilsesquioxane flame retardant | |
| CN105714399A (en) | Preparation method of light-colored CuI/PAN (polyacrylonitrile) composite conductive fiber | |
| CN109320779A (en) | A kind of fluorescent nano-fiber element film and preparation method thereof | |
| CN103046159A (en) | Manufacturing method of polyamide conductive fibres | |
| CN109553902B (en) | Transparent flame-retardant polyvinyl alcohol film and preparation method thereof | |
| CN108997547B (en) | Photoelectric active benzoxazine resin and preparation method thereof | |
| WO2018036017A1 (en) | Antistatic molding composition comprising conductive fiberglass, and method of preparing same | |
| CN104893260A (en) | Preparation method of PET composite for packaging tape | |
| CN117644702B (en) | High-performance plastic woven cloth and preparation thereof | |
| KR101566334B1 (en) | Epoxy resin composite materials containing cabon nanotube | |
| CN103013111A (en) | Method for preparing nitrogen and phosphorus-containing fire retardant | |
| CN104250394B (en) | A kind of modified polypropylene material and preparation method thereof | |
| Tang et al. | Scalable production of stretchable conductive fibers for textile electronics | |
| CN111453717A (en) | Efficient heat-resistant graphene film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240320 Address after: 211400 No. 112, Hebei New Area, Dayi Town, Yizheng City, Yangzhou City, Jiangsu Province Patentee after: Yizheng Shengda Textile Technology Co.,Ltd. Country or region after: Zhong Guo Address before: 211400 North side of Zhicheng Road, Industrial Park, Maji Town, Yizheng City, Yangzhou City, Jiangsu Province Patentee before: YIZHENG SHENGDA TEXTILE NEW MATERIAL Co.,Ltd. Country or region before: Zhong Guo |