CN105949919A - Abrasion-resisting insulation coating for power cable external coating and preparation method thereof - Google Patents
Abrasion-resisting insulation coating for power cable external coating and preparation method thereof Download PDFInfo
- Publication number
- CN105949919A CN105949919A CN201610579089.0A CN201610579089A CN105949919A CN 105949919 A CN105949919 A CN 105949919A CN 201610579089 A CN201610579089 A CN 201610579089A CN 105949919 A CN105949919 A CN 105949919A
- Authority
- CN
- China
- Prior art keywords
- parts
- power cable
- cable external
- nano
- abrasion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/26—Cellulose ethers
- C09D101/28—Alkyl ethers
- C09D101/284—Alkyl ethers with hydroxylated hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/22—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an abrasion-resisting insulation coating for a power cable external coating and a preparation method thereof. Nano silicon dioxide, nano titanium dioxide, modified castor alkyd polyester polyol, emulsified silicone oil, multi-walled carbon nanotubes, rubber powder, zinc silicate, zeolite powder, graphene, polyimide, hexafluorobutyl methacrylate-acrylate copolymer emulsion, organic silicone modified fluorocarbon resin, hydroxyethyl cellulose, acrylic acid, 2,4,6-tri(dimethyl aminomethyl) phenol and other materials are used as raw materials, and the abrasion-resisting, insulating and self-cleaning coating for the power cable external coating is prepared by adopting a distributing and mixing method.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of power cable external coating abrasion-proof insulating coating and preparation method thereof.
Background technology
Nanometer is the least unit of length metering, / 1000000th of a length of 1 millimeter of 1 nanometer, nanotechnology is in the length range of 1nm-100nm, direct composition various elements and the atom of material, atomic group, molecule, micel assemble there is the material of specific function or there is the high-quality precision and sophisticated technology of special performance products.Successfully nanotechnology can be applicable to the every field such as electronics, chemical industry, military affairs, and countries in the world are all in research and development.Nanotechnology (nano raw material) is applied in coating, mainly by the double vegetables mechanism of Folium Nelumbinis, improves resistance to water and the anti-fungi performance of coating.As coating, it is made up of multiple chemical composition, prepares through science, unique physical and chemical reaction, if formula and technique are unreasonable, even if adding some nanoscale raw materials, there will not be the biggest raising in quality.
Summary of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposes a kind of abrasion-proof insulating, it is possible to self-cleaning power cable external coating coating.
Technical scheme: a kind of power cable external coating abrasion-proof insulating coating of the present invention, including the component of following mass fraction:
nullNano silicon 10-20 part，Nano titanium oxide 5-20 part，Modified castor alkyd polyester polyhydric alcohol 15-30 part，Emulsified silicone oil 10-35 part，Multi-walled carbon nano-tubes 10-40 part，Rubber powder 10-40 part，Zinc silicate 25-40 part，Zeolite powder 25-60 part，Graphene 10-20 part，Polyimides 20-40 part，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-60 part，Organic-silicon-modified fluorocarbon resin 25-60 part，Hydroxyethyl cellulose 25-60 part，Acrylic acid 1-22 part，2,4,6-tri(dimethylaminomethyl)phenol 1-22 part，Dibutyl tin laurate 1-22 part，Styrene-acrylic emulsion 1-22 part，Sodium tripolyphosphate 1-22 part，Gas phase aluminium sesquioxide 1-22 part，Alumina silicate fibre 1-22 part，IPPP 1-22 part，Ammonium carbonate 1-22 part，Phenolic resin 1-22 part，Coagulator 1-22 part，Diluent 1-22 part，Iron powder 1-22 part，Ludox 1-22 part.
Further, including the component of following mass fraction:
nullNano silicon 10-15 part，Nano titanium oxide 5-15 part，Modified castor alkyd polyester polyhydric alcohol 15-25 part，Emulsified silicone oil 10-25 part，Multi-walled carbon nano-tubes 10-30 part，Rubber powder 10-20 part，Zinc silicate 25-30 part，Zeolite powder 25-40 part，Graphene 10-15 part，Polyimides 20-30 part，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-40 part，Organic-silicon-modified fluorocarbon resin 25-40 part，Hydroxyethyl cellulose 25-40 part，Acrylic acid 1-15 part，2,4,6-tri(dimethylaminomethyl)phenol 1-15 part，Dibutyl tin laurate 1-15 part，Styrene-acrylic emulsion 1-15 part，Sodium tripolyphosphate 1-15 part，Gas phase aluminium sesquioxide 1-15 part，Alumina silicate fibre 1-15 part，IPPP 1-15 part，Ammonium carbonate 1-15 part，Phenolic resin 1-15 part，Coagulator 1-15 part，Diluent 1-15 part，Iron powder 1-15 part，Ludox 1-15 part.
Further, including the component of following mass fraction:
nullNano silicon 12 parts，Nano titanium oxide 10 parts，Modified castor alkyd polyester polyhydric alcohol 20 parts，Emulsified silicone oil 15 parts，Multi-walled carbon nano-tubes 20 parts，Rubber powder 15 parts，Zinc silicate 27 parts，Zeolite powder 35 parts，Graphene 12 parts，Polyimides 25 parts，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 32 parts，Organic-silicon-modified fluorocarbon resin 30 parts，Hydroxyethyl cellulose 30 parts，12 parts of acrylic acid，2,4,6-tri(dimethylaminomethyl)phenol 12 parts，Dibutyl tin laurate 10 parts，Styrene-acrylic emulsion 12 parts，Sodium tripolyphosphate 12 parts，Gas phase aluminium sesquioxide 11 parts，Alumina silicate fibre 13 parts，IPPP 13 parts，Ammonium carbonate 10 parts，10 parts of phenolic resin，10 parts of coagulator，Diluent 10 parts，Iron powder 12 parts，Ludox 12 parts.
Further, the particle diameter of described multi-walled carbon nano-tubes is 20-80nm.
Further, the particle diameter of described nano silicon is 20-80nm.
Further, the particle diameter of described nano titanium oxide is 20-80nm.
Further, the particle diameter of described Graphene is 20-60nm.
The invention also discloses the preparation method of above-mentioned a kind of power cable external coating abrasion-proof insulating coating, comprise the steps:
(1) each component is weighed according to mass fraction proportioning；
(2) it is firstly added multi-walled carbon nano-tubes, Graphene, nano silicon, nano titanium oxide, zinc silicate, emulsified silicone oil, polyimides, rubber powder, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, modified castor alkyd polyester polyhydric alcohol and organic-silicon-modified fluorocarbon resin according to formula ratio, grinder ground and mixed 3-10min, add hydroxyethyl cellulose subsequently, stir 20-40min with homogenizer；
(3) add at 40-60 DEG C acrylic acid, 2,4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, phenolic resin, coagulator, diluent, iron powder and Ludox, and stir 40-50min, obtain this product.
Beneficial effect: beneficial effects of the present invention is as follows:
(1) CNT is used, zinc silicate, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, organic-silicon-modified fluorocarbon resin and hydroxyethyl cellulose are as the main component of anticorrosive paint, CNT is as the main component of anticorrosive paint, electric conductivity or salt spray resistance can not only be improved, coating layer thickness can also be reduced further simultaneously, increase the adhesive force to base material, promote wearability and the antiseptic property of this anticorrosive paint, and resin and the compound use of organic-silicon-modified fluorocarbon resin, the wear-resisting of this anticorrosive paint will be greatly enhanced, abrasion-proof insulating and the performance of acid and alkali-resistance；And inorganic material zeolite powder and Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, owing to self is for the reinforced effects of coating, make the anti-corrosive properties of this anticorrosive paint be greatly enhanced as main component.
(2) acrylic acid is selected, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, titanium dioxide, phenolic resin, coagulator, diluent, iron powder and Ludox are auxiliary element, not only make the wear-resisting of this anticorrosive paint, abrasion-proof insulating, acid-proof alkaline is improved, or obtaining this anticorrosive paint has preferable hydrophobic performance, and owing to the addition of solar selectively absorption function iron powder and Ludox combination, this anticorrosive paint is made to can be used in the electric power network outdoor case that solar energy is relevant.
(3) using nano silicon, nano titanium oxide and rubber powder as the main component of coating, it has preferable wearability, owing to titanium dioxide has photo-catalysis function so that this coating has self-cleaning function；Meanwhile, combine with inorganic nano material use by epoxide modified silicones, emulsified silicone oil, multi-walled carbon nano-tubes, improves for wear-resisting, the abrasion-proof insulating of coating and the performance of acid and alkali-resistance and plays toughening effect.
(4) in order to optimize the performance of coating further, have selected alumina silicate fibre, FeCuMnO3.5, ammonium hydrogen carbonate, acrylic acid, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, APP, chlorinated paraffin, IPPP, ethyl cellulose is as auxiliary element, not only make the wear-resisting of this coating, abrasion-proof insulating, acid-proof alkaline is improved, or obtaining this coating has preferable hydrophobic performance, and make this coating can be used in the power cable external coating that solar energy is relevant owing to the addition of solar selectively absorption function powder body FeCuMnO3.5.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
A kind of power cable external coating abrasion-proof insulating coating, including the component of following mass fraction:
nullNano silicon 10 parts，Nano titanium oxide 5 parts，Modified castor alkyd polyester polyhydric alcohol 15 parts，Emulsified silicone oil 10 parts，Multi-walled carbon nano-tubes 10 parts，Rubber powder 10 parts，Zinc silicate 25 parts，Zeolite powder 25 parts，Graphene 10 parts，Polyimides 20 parts，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25 parts，Organic-silicon-modified fluorocarbon resin 25 parts，Hydroxyethyl cellulose 25 parts，1 part of acrylic acid，2,4,6-tri(dimethylaminomethyl)phenol 1 part，Dibutyl tin laurate 1 part，Styrene-acrylic emulsion 3 parts，Sodium tripolyphosphate 2 parts，Gas phase aluminium sesquioxide 1 part，Alumina silicate fibre 5 parts，IPPP 5 parts，Ammonium carbonate 5 parts，5 parts of phenolic resin，2 parts of coagulator，Diluent 3 parts，Iron powder 4 parts，Ludox 2 parts.
The preparation method of above-mentioned a kind of power cable external coating abrasion-proof insulating coating, comprises the steps:
(1) each component is weighed according to mass fraction proportioning；
(2) it is firstly added multi-walled carbon nano-tubes, Graphene, nano silicon, nano titanium oxide, zinc silicate, emulsified silicone oil, polyimides, rubber powder, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, modified castor alkyd polyester polyhydric alcohol and organic-silicon-modified fluorocarbon resin according to formula ratio, grinder ground and mixed 3min, add hydroxyethyl cellulose subsequently, stir 20min with homogenizer；
(3) add at 40 DEG C acrylic acid, 2,4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, phenolic resin, coagulator, diluent, iron powder and Ludox, and stir 40min, obtain this product.
Embodiment 2
A kind of power cable external coating abrasion-proof insulating coating, including the component of following mass fraction:
nullNano silicon 20 parts，Nano titanium oxide 20 parts，Modified castor alkyd polyester polyhydric alcohol 30 parts，Emulsified silicone oil 35 parts，Multi-walled carbon nano-tubes 40 parts，Rubber powder 40 parts，Zinc silicate 40 parts，Zeolite powder 60 parts，Graphene 20 parts，Polyimides 40 parts，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 60 parts，Organic-silicon-modified fluorocarbon resin 60 parts，Hydroxyethyl cellulose 60 parts，20 parts of acrylic acid，2,4,6-tri(dimethylaminomethyl)phenol 22 parts，Dibutyl tin laurate 22 parts，Styrene-acrylic emulsion 20 parts，Sodium tripolyphosphate 15 parts，Gas phase aluminium sesquioxide 15 parts，Alumina silicate fibre 15 parts，IPPP 12 parts，Ammonium carbonate 12 parts，10 parts of phenolic resin，20 parts of coagulator，Diluent 18 parts，Iron powder 15 parts，Ludox 15 parts.
The preparation method of above-mentioned a kind of power cable external coating abrasion-proof insulating coating, comprises the steps:
(1) each component is weighed according to mass fraction proportioning；
(2) it is firstly added multi-walled carbon nano-tubes, Graphene, nano silicon, nano titanium oxide, zinc silicate, emulsified silicone oil, polyimides, rubber powder, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, modified castor alkyd polyester polyhydric alcohol and organic-silicon-modified fluorocarbon resin according to formula ratio, grinder ground and mixed 10min, add hydroxyethyl cellulose subsequently, stir 40min with homogenizer；
(3) add at 60 DEG C acrylic acid, 2,4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, phenolic resin, coagulator, diluent, iron powder and Ludox, and stir 50min, obtain this product.
Embodiment 3
A kind of power cable external coating abrasion-proof insulating coating, including the component of following mass fraction:
nullNano silicon 12 parts，Nano titanium oxide 10 parts，Modified castor alkyd polyester polyhydric alcohol 20 parts，Emulsified silicone oil 15 parts，Multi-walled carbon nano-tubes 20 parts，Rubber powder 15 parts，Zinc silicate 27 parts，Zeolite powder 35 parts，Graphene 12 parts，Polyimides 25 parts，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 32 parts，Organic-silicon-modified fluorocarbon resin 30 parts，Hydroxyethyl cellulose 30 parts，12 parts of acrylic acid，2,4,6-tri(dimethylaminomethyl)phenol 12 parts，Dibutyl tin laurate 10 parts，Styrene-acrylic emulsion 12 parts，Sodium tripolyphosphate 12 parts，Gas phase aluminium sesquioxide 11 parts，Alumina silicate fibre 13 parts，IPPP 13 parts，Ammonium carbonate 10 parts，10 parts of phenolic resin，10 parts of coagulator，Diluent 10 parts，Iron powder 12 parts，Ludox 12 parts.
The preparation method of above-mentioned a kind of power cable external coating abrasion-proof insulating coating, comprises the steps:
(1) each component is weighed according to mass fraction proportioning；
(2) it is firstly added multi-walled carbon nano-tubes, Graphene, nano silicon, nano titanium oxide, zinc silicate, emulsified silicone oil, polyimides, rubber powder, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, modified castor alkyd polyester polyhydric alcohol and organic-silicon-modified fluorocarbon resin according to formula ratio, grinder ground and mixed 6min, add hydroxyethyl cellulose subsequently, stir 30min with homogenizer；
(3) add at 50 DEG C acrylic acid, 2,4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, phenolic resin, coagulator, diluent, iron powder and Ludox, and stir 45min, obtain this product.
The above, it it is only presently preferred embodiments of the present invention, not the present invention is made any pro forma restriction, although the present invention is disclosed above with preferred embodiment, but it is not limited to the present invention, any those skilled in the art, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or is modified to the Equivalent embodiments of equivalent variations, in every case it is the content without departing from technical solution of the present invention, any simple modification above example made according to the technical spirit of the present invention, equivalent variations and modification, all still fall within the range of technical solution of the present invention.
Claims (8)
1. a power cable external coating abrasion-proof insulating coating, it is characterised in that: include the component of following mass fraction:
Nano silicon 10-20 part, nano titanium oxide 5-20 part, modified castor alkyd polyester polyhydric alcohol
null15-30 part，Emulsified silicone oil 10-35 part，Multi-walled carbon nano-tubes 10-40 part，Rubber powder 10-40 part，Zinc silicate 25-40 part，Zeolite powder 25-60 part，Graphene 10-20 part，Polyimides 20-40 part，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-60 part，Organic-silicon-modified fluorocarbon resin 25-60 part，Hydroxyethyl cellulose 25-60 part，Acrylic acid 1-22 part，2,4,6-tri(dimethylaminomethyl)phenol 1-22 part，Dibutyl tin laurate 1-22 part，Styrene-acrylic emulsion 1-22 part，Sodium tripolyphosphate 1-22 part，Gas phase aluminium sesquioxide 1-22 part，Alumina silicate fibre 1-22 part，IPPP 1-22 part，Ammonium carbonate 1-22 part，Phenolic resin 1-22 part，Coagulator 1-22 part，Diluent 1-22 part，Iron powder 1-22 part，Ludox 1-22 part.
A kind of power cable external coating abrasion-proof insulating coating the most according to claim 1, it is characterised in that: include the component of following mass fraction:
Nano silicon 10-15 part, nano titanium oxide 5-15 part, modified castor alkyd polyester polyhydric alcohol
null15-25 part，Emulsified silicone oil 10-25 part，Multi-walled carbon nano-tubes 10-30 part，Rubber powder 10-20 part，Zinc silicate 25-30 part，Zeolite powder 25-40 part，Graphene 10-15 part，Polyimides 20-30 part，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-40 part，Organic-silicon-modified fluorocarbon resin 25-40 part，Hydroxyethyl cellulose 25-40 part，Acrylic acid 1-15 part，2,4,6-tri(dimethylaminomethyl)phenol 1-15 part，Dibutyl tin laurate 1-15 part，Styrene-acrylic emulsion 1-15 part，Sodium tripolyphosphate 1-15 part，Gas phase aluminium sesquioxide 1-15 part，Alumina silicate fibre 1-15 part，IPPP 1-15 part，Ammonium carbonate 1-15 part，Phenolic resin 1-15 part，Coagulator 1-15 part，Diluent 1-15 part，Iron powder 1-15 part，Ludox 1-15 part.
A kind of power cable external coating abrasion-proof insulating coating the most according to claim 1, it is characterised in that: include the component of following mass fraction:
Nano silicon 12 parts, nano titanium oxide 10 parts, modified castor alkyd polyester polyhydric alcohol
null20 parts，Emulsified silicone oil 15 parts，Multi-walled carbon nano-tubes 20 parts，Rubber powder 15 parts，Zinc silicate 27 parts，Zeolite powder 35 parts，Graphene 12 parts，Polyimides 25 parts，Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 32 parts，Organic-silicon-modified fluorocarbon resin 30 parts，Hydroxyethyl cellulose 30 parts，12 parts of acrylic acid，2,4,6-tri(dimethylaminomethyl)phenol 12 parts，Dibutyl tin laurate 10 parts，Styrene-acrylic emulsion 12 parts，Sodium tripolyphosphate 12 parts，Gas phase aluminium sesquioxide 11 parts，Alumina silicate fibre 13 parts，IPPP 13 parts，Ammonium carbonate 10 parts，10 parts of phenolic resin，10 parts of coagulator，Diluent 10 parts，Iron powder 12 parts，Ludox 12 parts.
4. according to the arbitrary described a kind of power cable external coating abrasion-proof insulating coating of claim 1-3, it is characterised in that: the particle diameter of described multi-walled carbon nano-tubes is 20-80nm.
5. according to the arbitrary described a kind of power cable external coating abrasion-proof insulating coating of claim 1-3, it is characterised in that: the particle diameter of described nano silicon is 20-80nm.
6. according to the arbitrary described a kind of power cable external coating abrasion-proof insulating coating of claim 1-3, it is characterised in that: the particle diameter of described nano titanium oxide is 20-80nm.
7. according to the arbitrary described a kind of power cable external coating abrasion-proof insulating coating of claim 1-3, it is characterised in that: the particle diameter of described Graphene is 20-60nm.
8. according to the preparation method of the arbitrary described a kind of power cable external coating abrasion-proof insulating coating of claim 1-3, it is characterised in that: comprise the steps:
(1) each component is weighed according to mass fraction proportioning；
(2) it is firstly added multi-walled carbon nano-tubes, Graphene, nano silicon, nano titanium oxide, zinc silicate, emulsified silicone oil, polyimides, rubber powder, zeolite powder, Hexafluorobutyl mathacrylate-acrylate copolymer emulsion, modified castor alkyd polyester polyhydric alcohol and organic-silicon-modified fluorocarbon resin according to formula ratio, grinder ground and mixed 3-10min, add hydroxyethyl cellulose subsequently, stir 20-40min with homogenizer；
(3) add at 40-60 DEG C acrylic acid, 2,4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, styrene-acrylic emulsion, sodium tripolyphosphate, gas phase aluminium sesquioxide, alumina silicate fibre, IPPP, ammonium carbonate, phenolic resin, coagulator, diluent, iron powder and Ludox, and stir 40-50min, obtain this product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610579089.0A CN105949919A (en) | 2016-07-22 | 2016-07-22 | Abrasion-resisting insulation coating for power cable external coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610579089.0A CN105949919A (en) | 2016-07-22 | 2016-07-22 | Abrasion-resisting insulation coating for power cable external coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105949919A true CN105949919A (en) | 2016-09-21 |
Family
ID=56901085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610579089.0A Pending CN105949919A (en) | 2016-07-22 | 2016-07-22 | Abrasion-resisting insulation coating for power cable external coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105949919A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107216785A (en) * | 2017-08-08 | 2017-09-29 | 合肥安力电力工程有限公司 | It is a kind of for fire-resistant anticorrosion paint of power cable and preparation method thereof |
| CN107325697A (en) * | 2017-07-12 | 2017-11-07 | 合肥思博特软件开发有限公司 | It is a kind of for insulated paint of computer cable and preparation method thereof |
| CN107722825A (en) * | 2017-11-28 | 2018-02-23 | 南宁思飞电子科技有限公司 | A kind of coatings |
| CN109439125A (en) * | 2018-11-07 | 2019-03-08 | 长沙小如信息科技有限公司 | A kind of water-based acrylic resin anti-corrosive insulation coating and preparation method thereof |
| CN109679424A (en) * | 2018-11-21 | 2019-04-26 | 温州市东日建筑装饰工程有限公司 | A kind of underground space finishing wall finiss coating method and preparation method |
| CN110600167A (en) * | 2019-08-05 | 2019-12-20 | 东莞福川精密工业股份有限公司 | Special cable for high-flexibility robot and manufacturing process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230224A (en) * | 2008-02-27 | 2008-07-30 | 孟中 | Fluorosilicone rubber nano composite alloy three-proof paint and production method thereof |
| CN102993852A (en) * | 2012-10-31 | 2013-03-27 | 汪洋 | Novel nanometer self-cleaning fluorocarbon coating for exterior wall and preparation method thereof |
-
2016
- 2016-07-22 CN CN201610579089.0A patent/CN105949919A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230224A (en) * | 2008-02-27 | 2008-07-30 | 孟中 | Fluorosilicone rubber nano composite alloy three-proof paint and production method thereof |
| CN102993852A (en) * | 2012-10-31 | 2013-03-27 | 汪洋 | Novel nanometer self-cleaning fluorocarbon coating for exterior wall and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325697A (en) * | 2017-07-12 | 2017-11-07 | 合肥思博特软件开发有限公司 | It is a kind of for insulated paint of computer cable and preparation method thereof |
| CN107216785A (en) * | 2017-08-08 | 2017-09-29 | 合肥安力电力工程有限公司 | It is a kind of for fire-resistant anticorrosion paint of power cable and preparation method thereof |
| CN107722825A (en) * | 2017-11-28 | 2018-02-23 | 南宁思飞电子科技有限公司 | A kind of coatings |
| CN109439125A (en) * | 2018-11-07 | 2019-03-08 | 长沙小如信息科技有限公司 | A kind of water-based acrylic resin anti-corrosive insulation coating and preparation method thereof |
| CN109679424A (en) * | 2018-11-21 | 2019-04-26 | 温州市东日建筑装饰工程有限公司 | A kind of underground space finishing wall finiss coating method and preparation method |
| CN110600167A (en) * | 2019-08-05 | 2019-12-20 | 东莞福川精密工业股份有限公司 | Special cable for high-flexibility robot and manufacturing process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105949919A (en) | Abrasion-resisting insulation coating for power cable external coating and preparation method thereof | |
| CN105925100A (en) | Corrosion-resistant coating for outdoor power grid equipment and preparation method thereof | |
| CN105949854A (en) | Waterproof anti-aging coating for electric power and power grid outdoor equipment and preparation method thereof | |
| Liu et al. | Recent advances in the flame retardancy role of graphene and its derivatives in epoxy resin materials | |
| CN106398206B (en) | The preparation method of graphene oxide/polyaniline/titanium dioxide nanocomposite and polyaniline nano anticorrosive paint | |
| CN106675320A (en) | Graphene heat-conduction anticorrosion paint and preparation method thereof | |
| Jiang et al. | Graphene-coated ZnO tetrapod whiskers for thermally and electrically conductive epoxy composites | |
| CN104163928A (en) | Conductive heat-conductive graphene slurry and coating | |
| CN106046893A (en) | Waterproof anti-aging paint for outer coatings of power cables and preparation method of waterproof anti-aging paint | |
| Zhou et al. | MOF-derived strategy to obtain CuCoOx functionalized HO-BN: a novel design to enhance the toughness, fire safety and heat resistance of bismaleimide resin | |
| CN101275052A (en) | Corrosion-resistant electromagnetic screen coating and preparation thereof | |
| CN101633809A (en) | Water-soluble conducting polyaniline static-free damping paint and preparation method thereof | |
| CN109943127A (en) | A kind of thin graphene dispersed paste, preparation method and application | |
| Ding et al. | GO modified EPDM/paraffin shape-stabilized phase change materials with high elasticity and low leakage rate | |
| CN110240814A (en) | A kind of amphiphilic graphene oxide and preparation method thereof and the application in water paint | |
| CN105153874A (en) | High-adhesion wear-resistant waterborne electrostatic conducted anticorrosive coating | |
| TW201723052A (en) | Thermosetting resin compound and use thereof | |
| CN109722121A (en) | A kind of fire-proof and thermal-insulation coating material of fullerene modification and preparation method thereof | |
| WO2015015918A1 (en) | Electroconductive-film-forming composition and method for producing electroconductive film | |
| CN102732148B (en) | Urushiol silicon high temperature resistant liquid anti-corrosion paint | |
| Xu et al. | Effect of different ionic layered compounds decorated with zinc hydroxystannate on flame retardancy and smoke performance of epoxy resin | |
| Conejo et al. | Degradation behavior of carbon nanotubes/phenol-furfuryl alcohol multifunctional composites with aerospace application | |
| Jia et al. | Improved thermal conductivity of styrene acrylic resin with carbon nanotubes, graphene and boron nitride hybrid fillers | |
| CN104962169A (en) | High-temperature-resistant epoxy resin powder coating | |
| CN110791171A (en) | Composite nano material reinforced solvent type epoxy primer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160921 |