CN105949530A - Composite rubber material for shock absorbers - Google Patents

Composite rubber material for shock absorbers Download PDF

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Publication number
CN105949530A
CN105949530A CN201610477081.3A CN201610477081A CN105949530A CN 105949530 A CN105949530 A CN 105949530A CN 201610477081 A CN201610477081 A CN 201610477081A CN 105949530 A CN105949530 A CN 105949530A
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CN
China
Prior art keywords
parts
glue
rubber
refining
rubber material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610477081.3A
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Chinese (zh)
Inventor
陈金国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HAIXUN INDUSTRY GROUP SHARE Co Ltd
Original Assignee
JIANGSU HAIXUN INDUSTRY GROUP SHARE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by JIANGSU HAIXUN INDUSTRY GROUP SHARE Co Ltd filed Critical JIANGSU HAIXUN INDUSTRY GROUP SHARE Co Ltd
Priority to CN201610477081.3A priority Critical patent/CN105949530A/en
Publication of CN105949530A publication Critical patent/CN105949530A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a composite rubber material for shock absorbers. The composite rubber material comprises the following raw materials in parts by weight: 40-60 parts of modified natural rubber, 20-45 parts of butyl rubber, 30-45 parts of hydrogenated nitrile-butadiene rubber, 5-15 parts of white carbon black, 10-25 parts of aromatic oil, 5-10 parts of sulfur, 10-20 parts of zinc oxide, 15-25 parts of flame retardant, 2-15 parts of anti-aging agent and 5-15 parts of filler. By using the modified natural rubber, butyl rubber and hydrogenated nitrile-butadiene rubber as the base materials, the reinforcing agent, vulcanizing agent, flame retardant and other aids are added to synergetically mill the rubber, so the formula is reasonable, thereby greatly enhancing the shock absorptivity of the composite rubber material. The composite rubber material for shock absorbers has the advantages of simple preparation technique and low cost investment, and the wear resistance and aging resistance of the rubber material are respectively improved.

Description

A kind of amortisseur composite rubber material
Technical field
The present invention relates to rubber absorbers technical field, particularly relate to a kind of amortisseur composite rubber material.
Background technology
Along with developing rapidly of modern industry, vibrations and noise have become as the serious problems of every field: it can reduce Performance accuracy, affects product quality;Shorten life of product so that high-precision instrument cisco unity malfunction;Jeopardize safety, make to set Standby or construction early damage;Pollute environment and affect health of human body.Therefore, study and grasp shake control and noise control The key subjects that the industrial development of technology Yi Shi various countries faces.Eliminate the most basic and best method of vibrations and noise be minimizing or Eliminate the vibrations of vibroseis, but the vibrations actually wanting to be completely eliminated vibroseis are impossible, it is therefore necessary to take other The method controlling vibrations.Reality is the most extensive in applying, most efficient method is to use various anti-vibration articles, especially rubber shock-absorbing Goods, rubber absorbers, as the important damper element of a class, have been widely used in all kinds of machineries, automobile, railway locomotive, water Upper means of transport, aircraft and other airborne vehicles, it can be effectively isolated vibrations and excitaton source, it is also possible to relaxes the shake of vibration body Dynamic, therefore it is widely used in dynamic power machine and the auxiliary equipment such as blower fan, water pump of various motor vehicles, aircraft, ships etc. Vibration isolation with instrument.But the damping performance of presently commercially available yielding rubber all cannot meet the need of actual production and life , especially for those for damping performance requires higher equipment or occasion, common composite rubber material is far from This kind of demand can be reached.
Therefore, in order to solve the technical problem of above-mentioned existence, the invention provides a kind of new technology.
Summary of the invention
It is an object of the invention to provide a kind of amortisseur composite rubber material.
The present invention is directed to above-mentioned technological deficiency be the technical scheme is that
A kind of amortisseur composite rubber material, the raw material including following weight portion forms:
Modified natural rubber 40-60 part;
Butyl rubber 20-45 part;
Hydrogenated nitrile-butadiene rubber 30-45 part;
White carbon 5-15 part;
Aromatic naphtha 10-25 part;
Sulfur 5-10 part;
Zinc oxide 10-20 part;
Fire retardant 15-25 part;
Age resistor 2-15 part;
Filler 5-15 part.
Further, during described fire retardant is magnesium hydroxide, antimony oxide, aluminium hydroxide any one or a kind of Above combination.
Further, described age resistor is antioxidant 264.
Further, any one or more than one the combination during described filler is following several material: Pulvis Talci, pottery Soil, calcium carbonate, silicon dioxide.
It is a further object of the present invention to provide the preparation method of a kind of amortisseur composite rubber material, including once refining glue Refining glue with secondary, concrete operation step is as follows:
S1, once refine glue: weigh the modified natural rubber of above weight portion, butyl rubber, hydrogenated nitrile-butadiene rubber, white carbon, virtue Hydrocarbon ils, zinc oxide, fire retardant, age resistor, filler, and be mixed be placed in banbury refining glue, temperature rises to 120-160 DEG C, the refining glue time controls within 10min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, and is cooled to Room temperature and get final product;
S2, secondary refining glue: be again placed in the micelle once refining glue acquisition in banbury and add sulfur carrying out secondary refining glue, refining The glue time controls within 5min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, is cooled to room temperature quiet Set to 0 .5-3d and get final product.
The invention has the beneficial effects as follows: the present invention is using modified natural rubber, butyl rubber and hydrogenated nitrile-butadiene rubber as base Material, is added with reinforcing agent, vulcanizing agent, fire retardant and other auxiliary agents collaborative refining glue, and formula is reasonable, substantially increases compounded rubber The damping performance of material, and preparation technology is simple, and cost puts into low, in anti-wear performance and the ageing-resistant performance of elastomeric material Aspect all makes moderate progress.
Detailed description of the invention
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, this embodiment It is only used for explaining the present invention, is not intended that the restriction to protection scope of the present invention.
A kind of amortisseur composite rubber material, the raw material including following weight portion forms:
Modified natural rubber 40-60 part;
Butyl rubber 20-45 part;
Hydrogenated nitrile-butadiene rubber 30-45 part;
White carbon 5-15 part;
Aromatic naphtha 10-25 part;
Sulfur 5-10 part;
Zinc oxide 10-20 part;
Fire retardant 15-25 part;
Age resistor 2-15 part;
Filler 5-15 part.
Embodiment 1
The preparation method of a kind of amortisseur composite rubber material, including once refining glue and secondary refining glue, concrete operation step is such as Under:
S1, once refine glue: weigh the modified natural rubber 40 parts of above weight portion, butyl rubber 20 parts, hydrogenated nitrile-butadiene rubber 30 Part, white carbon 5 parts, aromatic naphtha 10 parts, zinc oxide 10 parts, 15 parts of magnesium hydroxide, antioxidant 264 2 parts, Pulvis Talci 5 parts, and will Its mixing is placed in banbury refining glue, and temperature rises to 120 DEG C, and the refining glue time is 4min, after refining cementing bundle, by glue temperature drop extremely Less than 100 DEG C carry out plastic emitting, and are cooled to room temperature and get final product;
S2, secondary refining glue: be again placed in the micelle once refining glue acquisition in banbury and add sulfur carrying out secondary refining glue, refining The glue time is 2min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, is cooled to room temperature and stands 1d and get final product.
Embodiment 2
The preparation method of a kind of amortisseur composite rubber material, including once refining glue and secondary refining glue, concrete operation step is such as Under:
S1, once refine glue: weigh the modified natural rubber 50 parts of above weight portion, butyl rubber 35 parts, hydrogenated nitrile-butadiene rubber 40 Part, white carbon 10 parts, aromatic naphtha 20 parts, zinc oxide 15 parts, 20 parts of magnesium hydroxide, antioxidant 264 8 parts, Pulvis Talci 10 parts, and Being mixed and be placed in banbury refining glue, temperature rises to 140 DEG C, and the refining glue time is 6min, after refining cementing bundle, by glue temperature drop Carry out plastic emitting to less than 100 DEG C, and be cooled to room temperature and get final product;
S2, secondary refining glue: be again placed in the micelle once refining glue acquisition in banbury and add sulfur carrying out secondary refining glue, refining The glue time controls within 3min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, is cooled to room temperature quiet Put 2d and get final product.
Embodiment 3
The preparation method of a kind of amortisseur composite rubber material, including once refining glue and secondary refining glue, concrete operation step is such as Under:
S1, once refine glue: weigh the modified natural rubber 60 parts of above weight portion, butyl rubber 45 parts, hydrogenated nitrile-butadiene rubber 45 Part, white carbon 15 parts, aromatic naphtha 25 parts, zinc oxide 20 parts, 25 parts of magnesium hydroxide, antioxidant 264 15 parts, Pulvis Talci 15 parts, and Being mixed and be placed in banbury refining glue, temperature rises to 160 DEG C, and the refining glue time is 8 min, after refining cementing bundle, by glue temperature It is down to less than 100 DEG C and carries out plastic emitting, and be cooled to room temperature and get final product;
S2, secondary refining glue: be again placed in the micelle once refining glue acquisition in banbury and add sulfur carrying out secondary refining glue, refining The glue time is 4min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, is cooled to room temperature and stands 3d and get final product.
The invention has the beneficial effects as follows: the present invention is using modified natural rubber, butyl rubber and hydrogenated nitrile-butadiene rubber as base Material, is added with reinforcing agent, vulcanizing agent, fire retardant and other auxiliary agents collaborative refining glue, and formula is reasonable, substantially increases compounded rubber The damping performance of material, and preparation technology is simple, and cost puts into low, in anti-wear performance and the ageing-resistant performance of elastomeric material Aspect all makes moderate progress.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, that is made any repaiies Change, equivalent, improvement etc., should be included within the scope of the present invention.

Claims (5)

1. an amortisseur composite rubber material, it is characterised in that: include that the raw material of following weight portion forms:
Modified natural rubber 40-60 part;
Butyl rubber 20-45 part;
Hydrogenated nitrile-butadiene rubber 30-45 part;
White carbon 5-15 part;
Aromatic naphtha 10-25 part;
Sulfur 5-10 part;
Zinc oxide 10-20 part;
Fire retardant 15-25 part;
Age resistor 2-15 part;
Filler 5-15 part.
A kind of amortisseur composite rubber material the most according to claim 1, it is characterised in that: described fire retardant is hydrogen-oxygen Change any one or more than one the combination in magnesium, antimony oxide, aluminium hydroxide.
A kind of amortisseur composite rubber material the most according to claim 1, it is characterised in that: described age resistor is for anti-old Agent 264.
A kind of amortisseur composite rubber material the most according to claim 1, it is characterised in that: described filler is following several Any one or more than one combination in kind material: Pulvis Talci, potter's clay, calcium carbonate, silicon dioxide.
The preparation method of a kind of amortisseur composite rubber material the most according to claim 1, it is characterised in that: include one Secondary refining glue and secondary refining glue, concrete operation step is as follows:
S1, once refine glue: weigh the modified natural rubber of above weight portion, butyl rubber, hydrogenated nitrile-butadiene rubber, white carbon, virtue Hydrocarbon ils, zinc oxide, fire retardant, age resistor, filler, and be mixed be placed in banbury refining glue, temperature rises to 120-160 DEG C, the refining glue time controls within 10min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, and is cooled to Room temperature and get final product;
S2, secondary refining glue: be again placed in the micelle once refining glue acquisition in banbury and add sulfur carrying out secondary refining glue, refining The glue time controls within 5min, after refining cementing bundle, carries out plastic emitting by below glue temperature drop to 100 DEG C, is cooled to room temperature quiet Set to 0 .5-3d and get final product.
CN201610477081.3A 2016-06-27 2016-06-27 Composite rubber material for shock absorbers Pending CN105949530A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610477081.3A CN105949530A (en) 2016-06-27 2016-06-27 Composite rubber material for shock absorbers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610477081.3A CN105949530A (en) 2016-06-27 2016-06-27 Composite rubber material for shock absorbers

Publications (1)

Publication Number Publication Date
CN105949530A true CN105949530A (en) 2016-09-21

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163313A (en) * 2017-07-03 2017-09-15 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation technology
CN107189247A (en) * 2017-06-27 2017-09-22 苏州菱慧电子科技有限公司 A kind of electronic product damping elastomeric material
CN108219214A (en) * 2017-12-19 2018-06-29 常州思宇环保材料科技有限公司 A kind of abrasive rubber lining material
CN109181040A (en) * 2018-09-20 2019-01-11 王景硕 A kind of preparation method of Rubber shock-absorbing pad
CN110204797A (en) * 2019-05-07 2019-09-06 南漳富元鼎航空器材配件有限公司 A kind of rubber spring sizing material and preparation method thereof that high temperature resistant is ageing-resistant
CN117511006A (en) * 2023-07-31 2024-02-06 云南国为机械科技有限公司 Rubber shock pad and preparation process thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189247A (en) * 2017-06-27 2017-09-22 苏州菱慧电子科技有限公司 A kind of electronic product damping elastomeric material
CN107163313A (en) * 2017-07-03 2017-09-15 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation technology
CN107163313B (en) * 2017-07-03 2019-02-22 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation process
CN108219214A (en) * 2017-12-19 2018-06-29 常州思宇环保材料科技有限公司 A kind of abrasive rubber lining material
CN109181040A (en) * 2018-09-20 2019-01-11 王景硕 A kind of preparation method of Rubber shock-absorbing pad
CN110204797A (en) * 2019-05-07 2019-09-06 南漳富元鼎航空器材配件有限公司 A kind of rubber spring sizing material and preparation method thereof that high temperature resistant is ageing-resistant
CN117511006A (en) * 2023-07-31 2024-02-06 云南国为机械科技有限公司 Rubber shock pad and preparation process thereof
CN117511006B (en) * 2023-07-31 2024-08-23 云南国为机械科技有限公司 Rubber shock pad and preparation process thereof

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Application publication date: 20160921

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