CN105946234A - Lace fabric based on 3D printing and preparation method of lace fabric - Google Patents
Lace fabric based on 3D printing and preparation method of lace fabric Download PDFInfo
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- CN105946234A CN105946234A CN201610436262.1A CN201610436262A CN105946234A CN 105946234 A CN105946234 A CN 105946234A CN 201610436262 A CN201610436262 A CN 201610436262A CN 105946234 A CN105946234 A CN 105946234A
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- lace fabric
- printing
- printed based
- printing material
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y80/00—Products made by additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Abstract
The invention provides a preparation method of lace fabric based on 3D printing. The method comprises following steps that firstly, computer aided design is used for designing and modeling patterns of the lace fabric, a built three-dimensional model is scanned layer by layer to obtain data of the lace fabric, and the data of the lace fabric are transmitted into a printing device for standby application; secondly, under the light avoiding environment, a light curing agent is added into a fibroin solution to be sufficiently stirred, photosensitive resin is then added, and after uniform mixing, a three-dimensional printing material is obtained; and thirdly, the three-dimensional printing material serves as a raw material, according to the data of the lace fabric, through printing of a nozzle of the three-dimensional printing machine, light curing and redundant three-dimensional printing material removal, the steps are repeated layer by layer, and the lace fabric based on 3D printing is obtained. The lace fabric prepared through the method is complex in flower type, many layers exist, and the fabric is friendly to skin, flexible and tough.
Description
Technical field
The invention belongs to textile material technical field, be specifically related to a kind of lace fabric printed based on 3D and system thereof
Preparation Method.
Background technology
3D printing technique is the one of rapid shaping technique, 3D printing technique be integrated with computer-aided design,
Layered Manufacturing Technology, mechanical engineering, laser technology, reverse Engineering Technology, material science, Numeric Control Technology, will set
Meter theory is the most directly manufactured into the prototype with certain function.And, 3D printing technique can be by image technology
Fictionalize 3D structure, according to the lamella model data constructed, print at fast forming machine middle group layer, construct
Entity.3D printing technique has been applied in terms of jewelry, footwear, building, Aero-Space and biologic medical,
But the application in textile garment field is the most rare.
A kind of 3D Method of printing based on 3 D weaving disclosed in Chinese patent CN 103353830A, by 3 D weaving
Method combines with 3 D-printing method, and the threedimensional model layering first will processed obtains three-dimensional data information, then
In layer and between adjacent layer, employing 45 ° and 135 ° of two kinds of directions carry out staggered cycles braiding, and recycling can cover
The fiber of adjacent two layers carries out longitudinal knitted.This approach enhance the strength of 3 D-printing product, extend product
Application.A kind of direct printing technique to fabric disclosed in Chinese patent CN 104428126B, by fabric
On the relatively flat pallet being fixed on 3 D-printing system at least partially, according to the pattern designed directly by three-dimensional
Material directly prints, solidified forming, then is removed from 3 D-printing system by article.The method mainly applies to system
Make article of footwear.The footwear assemble method that the disclosed 3D of use of Chinese patent CN 104924611A prints, by footwear
Knitted fabric or fabric in article encode, and by printing server and switch, data are conveyed into three
Dimension print apparatus, the pallet in 3 D-printing device is by textile, natural fabric, synthetic textiles, knitting
Thing, braided material, non-woven materials, net, leather, synthetic leather, polymer, rubber or foam are solid
Fixed, utilize ink, resin, acrylic compounds, polymer, thermoplastic, thermosets or photocuring material
Material directly obtains the bottom of textile upper from printhead prints and ultraviolet light curing effect.
From above-mentioned prior art, it is currently based on the utilization in terms of the textile garment of three-dimensional printing technology the fewest
Seeing, reason is that three-dimensional printing technology is difficult to meet the need such as traditional textile fabric strength, thick and heavy and mass production
Want.Lace fabric is different from traditional interwoven fabric, has characteristic frivolous, penetrating, that decorative pattern is complicated, top grade
Lace fabric complicated process of preparation, applies to three-dimensional printing technology to have in the design and fabrication of high-grade lace fabric
Certain market prospect.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of lace fabric based on 3D printing and preparation method thereof,
Select fibroin, photosensitive resin and light curing agent to prepare 3 D-printing material as raw material, and employing is successively beaten
The method preparation printing, solidify, remove unnecessary material forms lace fabric, and lace fabric flower pattern prepared by the method is multiple
Miscellaneous, level is many, and lace fabric has the skin-friendly of silkworm silk and the pliable and tough of resin and intensity concurrently, has certain clothes
By property, belong to a kind of high-grade lace fabric.
For solving above-mentioned technical problem, the technical scheme is that
A kind of lace fabric printed based on 3D, the described lace fabric printed based on 3D is by 3 D-printing material warp
3 D-printing device is prepared from, and the described lace fabric printed based on 3D uses successively printing, photocuring, goes
Except the method for excess stock is constituted.
Preferred as technique scheme, described 3 D-printing material is liquid, in described 3 D-printing material
Including fibroin, photosensitive resin and light curing agent,
The present invention also provides for the preparation method of a kind of lace fabric printed based on 3D, comprises the following steps:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric；
(2) under light protected environment, by fibroin solutions adds light curing agent, it is sufficiently stirred for, adds photosensitive
Resin, obtains 3 D-printing material after mix homogeneously；
(3) 3 D-printing material step (2) prepared is as raw material, the lace surface obtained according to step (1)
The data of material, through the 3 D-printing material that three-dimensional printer nozzle print, photocuring and removal are unnecessary, successively repeat
Above-mentioned steps, obtains the lace fabric printed based on 3D.
Preferred as technique scheme, in described step (2), the quality of fibroin in fibroin solutions
Mark is 8-10%, and the relative molecular mass of fibroin is 60-110kDa.
Preferred as technique scheme, in described step (2), light curing agent is diaryl group iodized salt or virtue cyclopentadienyl
Iron salt, photosensitive resin is epoxy acrylate or is urethane acrylate.
Preferred as technique scheme, in described step (2), the component in 3 D-printing material, by weight
Part meter, including fibroin 100 parts, light curing agent 8-15 part, photosensitive resin 20-40 part.
Preferred as technique scheme, in described step (3), the viscosity of 3 D-printing material is
6-25mPa s, surface tension is 30-50N/m.
Preferred as technique scheme, in described step (3), the resolution of 3 D-printing machine nozzle is
180dpi, jet orifice diameter is 20 μm.
Preferred as technique scheme, in described step (3), the temperature of photocuring is 60-70 DEG C, and light is solid
The time changed is 30-60s.
Preferred as technique scheme, in described step (3), the method removing unnecessary 3 D-printing material
Processing for hot blast, the temperature of hot blast is 50 DEG C, and wind speed is 0.5-1m/s, processes time 0.5-1s.
Compared with prior art, the method have the advantages that
(1) containing silkworm silk egg in the 3 D-printing material that lace fabric based on 3D printing prepared by the present invention is selected
In vain, light curing agent and photosensitive resin, fibroin has biocompatibility, has the most flexible and can process
Property, under the effect of light curing agent, progressively formed glue again to solid state by liquid, and 3 D-printing material
In possibly together with photosensitive resin, epoxy acrylate that the present invention selects or be urethane acrylate, it solidifies speed
Degree is fast, and solidification effect is good, has certain adhesive property, can be coated on surrounding's formation of fibroin well
Stable curing materials.
(2) lace fabric employing based on 3D printing prepared by the present invention successively prints, solidifies, removes fifth wheel
The method preparation of matter forms lace fabric, and this preparation method is fine, and level is many, can be used in various level complexity flower
The preparation of type, and the solidification effect of level more thin material is the best, more can guarantee that the stability of flower pattern.
(3) the lace fabric flower pattern complexity printed based on 3D prepared by the present invention, level is many, and lace fabric
Have the skin-friendly of silkworm silk and the pliable and tough of resin and intensity concurrently, there is certain taking, belong to a kind of high-grade lace surface
Material.
Detailed description of the invention
The present invention is described in detail, in the illustrative examples of this present invention and say below in conjunction with specific embodiment
Bright being used for explains the present invention, but not as a limitation of the invention.
Embodiment 1:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 60kDa fibroin by 100 parts of relative molecular masses
Mass fraction be 8% fibroin solutions in add the diaryl group iodized salt light curing agent of 8 parts, be sufficiently stirred for, then add
Enter the epoxy acrylate photosensitive resin of 20 parts, after mix homogeneously, obtain 3 D-printing material.
(3) be 6mPa s by viscosity, surface tension be the 3 D-printing material of 30N/m as raw material, according to flower bud
The data of silk face fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm, at 60 DEG C
Lower photocuring 30s, processes the unnecessary three-dimensional of 0.5s removal through the hot blast that temperature is 50 DEG C and wind speed is 0.5m/s and beats
Printed material material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
Embodiment 2:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 110kDa fibroin by 100 parts of relative molecular masses
The fibroin solutions that mass fraction is 10% in add the iron arene complexes light curing agent of 15 parts, be sufficiently stirred for, then
Add the urethane acrylate photosensitive resin of 40 parts, after mix homogeneously, obtain 3 D-printing material.
(3) being 25mPa s by viscosity, surface tension is that the 3 D-printing material of 50N/m is as raw material, foundation
The data of lace fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm,
Photocuring 60s at 70 DEG C, processes the unnecessary three-dimensional of 1s removal through the hot blast that temperature is 50 DEG C and wind speed is 1m/s and beats
Printed material material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
Embodiment 3:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 80kDa fibroin by 100 parts of relative molecular masses
Mass fraction be 9% fibroin solutions in add the diaryl group iodized salt light curing agent of 12 parts, be sufficiently stirred for, then
Add the urethane acrylate photosensitive resin of 30 parts, after mix homogeneously, obtain 3 D-printing material.
(3) being 15mPa s by viscosity, surface tension is that the 3 D-printing material of 45N/m is as raw material, foundation
The data of lace fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm,
Photocuring 45s at 65 DEG C, processes 0.9s through the hot blast that temperature is 50 DEG C and wind speed is 0.7m/s and removes unnecessary three
Dimension printed material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
Embodiment 4:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 100kDa fibroin by 100 parts of relative molecular masses
The fibroin solutions that mass fraction is 9% in add the iron arene complexes light curing agent of 12 parts, be sufficiently stirred for, then
Add the epoxy acrylate photosensitive resin of 25 parts, after mix homogeneously, obtain 3 D-printing material.
(3) being 20mPa s by viscosity, surface tension is that the 3 D-printing material of 40N/m is as raw material, foundation
The data of lace fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm, 70 DEG C
Lower photocuring 50s, processes 1s through the hot blast that temperature is 50 DEG C and wind speed is 0.5m/s and removes unnecessary 3 D-printing
Material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
Embodiment 5:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 110kDa fibroin by 100 parts of relative molecular masses
The fibroin solutions that mass fraction is 8% in add the iron arene complexes light curing agent of 15 parts, be sufficiently stirred for, then
Add the epoxy acrylate photosensitive resin of 20 parts, after mix homogeneously, obtain 3 D-printing material.
(3) being 20mPa s by viscosity, surface tension is that the 3 D-printing material of 40N/m is as raw material, foundation
The data of lace fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm,
Photocuring 40s at 70 DEG C, processes 0.9s through the hot blast that temperature is 50 DEG C and wind speed is 0.8m/s and removes unnecessary three
Dimension printed material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
Embodiment 6:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, the more three-dimensional mould that will build up
Type successively scans the data obtaining lace fabric, is conveyed in printing device standby by the data of lace fabric.
(2) it is under light protected environment, by weight, 100kDa fibroin by 100 parts of relative molecular masses
The fibroin solutions that mass fraction is 8% in add the diaryl group iodized salt of 12 parts or iron arene complexes photocuring
Agent, is sufficiently stirred for, and adds the epoxy acrylate of 25 parts or for urethane acrylate photosensitive resin, mixed
3 D-printing material is obtained after closing uniformly.
(3) being 18mPa s by viscosity, surface tension is that the 3 D-printing material of 35N/m is as raw material, foundation
The data of lace fabric, are 180dpi through resolution, the three-dimensional printer nozzle print of a diameter of 20 μm,
Photocuring 50s at 70 DEG C, processes 1s through the hot blast that temperature is 50 DEG C and wind speed is 0.6m/s and removes unnecessary three-dimensional
Printed material, successively repeat the above steps, obtain the lace fabric printed based on 3D.
After testing, embodiment 1-6 prepare based on 3D print the elasticity of lace fabric, mechanical strength result such as
Shown in lower:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Elongation at break (%) | 7.6 | 5.4 | 6.2 | 6.4 | 7.0 | 6.9 |
| Fracture strength (cN) | 36.4 | 39.5 | 37.2 | 37.3 | 38.4 | 36.9 |
As seen from the above table, lace fabric based on 3D printing prepared by the present invention has certain elasticity and strength,
There is certain wearability.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for limiting the present invention.Any
Those skilled in the art all can under the spirit and the scope of the present invention, above-described embodiment is modified or
Change.Therefore, such as art has usually intellectual without departing from disclosed spirit with
All equivalences completed under technological thought are modified or change, and must be contained by the claim of the present invention.
Claims (10)
1. the lace fabric printed based on 3D, it is characterized in that: the described lace fabric printed based on 3D is prepared from through 3 D-printing device by 3 D-printing material, the described lace fabric printed based on 3D uses successively printing, photocuring, the method for removal excess stock to constitute.
A kind of lace fabric printed based on 3D the most according to claim 1, it is characterised in that: described 3 D-printing material is liquid, and described 3 D-printing material includes fibroin, photosensitive resin and light curing agent.
3. the preparation method of the lace fabric printed based on 3D, it is characterised in that comprise the following steps:
(1) utilize computer-aided design that the decorative pattern of lace fabric is designed modeling, then the threedimensional model built up successively is scanned the data obtaining lace fabric, the data of lace fabric are conveyed in printing device standby；
(2) under light protected environment, by fibroin solutions adds light curing agent, it is sufficiently stirred for, adds photosensitive resin, after mix homogeneously, obtain 3 D-printing material；
(3) 3 D-printing material step (2) prepared is as raw material, data according to the lace fabric that step (1) obtains, through the 3 D-printing material that three-dimensional printer nozzle print, photocuring and removal are unnecessary, successively repeat the above steps, obtains the lace fabric printed based on 3D.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterized in that: in described step (2), in fibroin solutions, the mass fraction of fibroin is 8-10%, and the relative molecular mass of fibroin is 60-110kDa.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterized in that: in described step (2), light curing agent is diaryl group iodized salt or iron arene complexes, and photosensitive resin is epoxy acrylate or is urethane acrylate.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterised in that: in described step (2), the component in 3 D-printing material, by weight, including fibroin 100 parts, light curing agent 8-15 part, photosensitive resin 20-40 part.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterised in that: in described step (3), the viscosity of 3 D-printing material is 6-25mPa s, and surface tension is 30-50N/m.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterised in that: in described step (3), the resolution of 3 D-printing machine nozzle is 180dpi, and jet orifice diameter is 20 μm.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterised in that: in described step (3), the temperature of photocuring is 60-70 DEG C, and the time of photocuring is 30-60s.
The preparation method of a kind of lace fabric printed based on 3D the most according to claim 3, it is characterized in that: in described step (3), the method removing unnecessary 3 D-printing material is that hot blast processes, and the temperature of hot blast is 50 DEG C, wind speed is 0.5-1m/s, processes time 0.5-1s.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610436262.1A CN105946234A (en) | 2016-06-16 | 2016-06-16 | Lace fabric based on 3D printing and preparation method of lace fabric |
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| CN201610436262.1A CN105946234A (en) | 2016-06-16 | 2016-06-16 | Lace fabric based on 3D printing and preparation method of lace fabric |
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Cited By (3)
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| CN111516259A (en) * | 2020-05-29 | 2020-08-11 | 西安工程大学 | 3D printing method of rhombic flower type fabric |
| CN111745952A (en) * | 2020-07-06 | 2020-10-09 | 福建华峰运动用品科技有限公司 | Waterborne polyurethane primer, 3D (three-dimensional) pattern fabric using primer and manufacturing method of fabric |
| CN111873413A (en) * | 2020-07-07 | 2020-11-03 | 浙江迅实科技有限公司 | Manufacturing process of 3D fabric |
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