CN105936690A - Aging resistant polyethylene plastic-wood composite plate for buildings - Google Patents

Aging resistant polyethylene plastic-wood composite plate for buildings Download PDF

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Publication number
CN105936690A
CN105936690A CN201610398306.6A CN201610398306A CN105936690A CN 105936690 A CN105936690 A CN 105936690A CN 201610398306 A CN201610398306 A CN 201610398306A CN 105936690 A CN105936690 A CN 105936690A
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China
Prior art keywords
parts
wood
polyethylene
oleamide
wood composite
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Pending
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CN201610398306.6A
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Chinese (zh)
Inventor
叶伟然
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Huzhou Zhongchen Construction Co Ltd
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Huzhou Zhongchen Construction Co Ltd
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Priority to CN201610398306.6A priority Critical patent/CN105936690A/en
Publication of CN105936690A publication Critical patent/CN105936690A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

The invention discloses an aging resistant polyethylene plastic-wood composite plate for buildings. The composite plate is made of the following components by weight: 80-90 parts of polyethylene, 50-60 parts of Ammopiptanthus mongolicus wood flour, 10-15 parts of butyl etherified resin, 4-8 parts of triallylisocyanurate, 12-18 parts of hydroxypropyl cellulose, 7-15 parts of Pulullan, 18-24 parts of nitrile butadiene rubber, 5-12 parts of tri(nonylphenyl)phosphate, 3-5 parts of oleamide, 2-4 parts of alkyl phenol polyoxyethylene ether, and 2-6 parts of silica. The aging resistant polyethylene plastic-wood composite plate provided by the invention is not easy to crack and fade, has aging resistance, at the same time has improved the impact resistance and tensile strength, is solid and durable, and has long service life. Also, the plate has the advantages of environmental protection and no pollution, strong wood texture, smooth and fine surface, and no granular feel, etc.

Description

Wood composite board moulded by a kind of ageing-resistant polyethylene for building
Technical field
The invention belongs to building material technical field, be specifically related to a kind of ageing-resistant poly-second for building Alkene moulds wood composite board.
Background technology
Wood plastic composite is the novel environment friendly building materials the most just occurred, is the most also just Starting.Raw material used by wood-plastic products can use waste or used plastics and discarded timber, agricultural Fructus Citri tangerinae bar etc. Plant fiber makees base material, without any additional harmful components.And recyclable again with, claim Environmental protection truly, energy-conservation, the novel products of resource regeneration must be gone up.
" plastic-wood material ", is also " wood plastic composite ", as the term suggests can be regarded as mainly with Plastics are raw material, are mixed into new wood by adding the useless Plant fiber such as wood powder, rice husk, straw Material, then through the plastic processings such as extruding, mold pressing, injection moulding, the sheet material produced Or section bar.It is mainly used in the industries such as building materials, furniture, logistics packaging.By plastics and wooden powder By a certain percentage through the sheet material of hot extrusion molding after mixing, referred to as extrude wood-plastic composite panel.
The Waterproof corrosion of plastics and two kinds of characteristics of texture of timber are had concurrently so that it becomes owing to moulding wood For a kind of function admirable the most durable outdoor building materials (floor, fence, bench, gardens or Water bank view etc.);Also replace the Wood member that harbour, harbour etc. use, it may also be used for replace Making various packing materials, pallet, warehouse pallet etc. for timber too numerous to enumerate, purposes is extremely wide. Plastic wood sheet, combines Plant fiber and the plurality of advantages of plastics macromolecular material, can replace in a large number For timber, can effectively alleviate the contradiction that China's Forest Resources is poor, wood supply is in short supply, be one Plant the low-carbon (LC) of great development prospect, green, renewable ecological plastic-wood material capable of circulation.
Along with people's raising to environmental resource attention degree, reclaim with waste and old material and resource is combined Close and be utilized as the circular-type economy developmental pattern of core and become the trend of development of world economy.Greatly Power is exploited natural resources recycle utilization, will produce the national economic development and environment sustainable development Profound influence.And utilize waste or used plastics and wood fiber to produce Wood Plastics Composite Product and fit just Answer the good project of this requirement.
Owing to domestic market is still at the initial stage, plastic-wood products market at home does not also have large area Promote.Chinese market is compared with North America market, and the growth of wood plastic composite and manufactured goods also has Sizable space, it is contemplated that domestic Wood plastic composite market yield in recent years will be more than million Ton, the output value is more than 1,000,000,000 yuan, and forms novel wood-plastic composite article system.
Plastic-wood products will become following trend trend place, for consumers, moulds wooden Product belong to energy saving and environment friendly product, not only can well control the discharge of nuisance, additionally it is possible to Accomplish that the waterproof and dampproof of ground waits effect.
Moulding wood composite board is a kind of environment-friendly materials, recyclable reuses, and cheaper starting materials is rich Richness, it has good benefit at minimizing environmental pollution, aspect of promoting economic development, except having Outside the advantages such as modern design, wide ranges and nearly xyloid outward appearance, also has good mechanical performance With features such as excellent decay resistances.But mould wood composite board there is also some shortcomings it Place, such as life-time service, the most outdoor use, is susceptible to catabiosis such as ftractureing, fade, Thus shorten its service life, define its range.
The most how overcoming the deficiencies in the prior art is that current building material technical field needs solution badly Problem certainly.
Summary of the invention
To achieve these goals, the invention provides a kind of ageing-resistant polyethylene for building and mould wood Composite board.
It is an object of the invention to be achieved through the following technical solutions:
Wood composite board moulded by a kind of ageing-resistant polyethylene for building, and it is by following parts by weight Component mix and blend is made: polyethylene 80-90 part, Caulis et Folium Ammopiptanthi Mongolici wood powder 50-60 part, butyl ether Resin 10-15 part, triallyl isocyanate 4-8 part, hydroxypropyl cellulose 12-18 part, Pulullan polysaccharide 7-15 part, nitrile rubber 18-24 part, trisnonylphenyl phosphite 5-12 Part, oleamide 3-5 part, alkylphenol polyoxyethylene 2-4 part, silicon dioxide 2-6 part.
One of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 80 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 50 parts, fourth etherified resin 10 parts, triallyl isocyanate 4 parts, hydroxypropyl Base cellulose 12 parts, pulullan polysaccharide 7 parts, nitrile rubber 18 parts, three nonyl phenyl phosphorous Acid esters 5 parts, oleamide 3 parts, alkylphenol polyoxyethylene 2 parts, silicon dioxide 2 parts.
The two of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 90 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 60 parts, fourth etherified resin 15 parts, triallyl isocyanate 8 parts, hydroxypropyl Base cellulose 18 parts, pulullan polysaccharide 15 parts, nitrile rubber 24 parts, three nonyl phenyl are sub- Phosphate ester 12 parts, oleamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon dioxide 6 parts.
The three of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 82 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 52 parts, fourth etherified resin 12 parts, triallyl isocyanate 5 parts, hydroxypropyl Base cellulose 13 parts, pulullan polysaccharide 8 parts, nitrile rubber 19 parts, three nonyl phenyl phosphorous Acid esters 6 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon dioxide 3 parts.
The four of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 88 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 58 parts, fourth etherified resin 14 parts, triallyl isocyanate 6 parts, hydroxypropyl Base cellulose 16 parts, pulullan polysaccharide 13 parts, nitrile rubber 22 parts, three nonyl phenyl are sub- Phosphate ester 11 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon dioxide 4 parts.
Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, obtains Mixed material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
The method have the advantages that wood moulded by the ageing-resistant polyethylene that the present invention provides compound Sheet material is the most easy to crack, fade, and has ageing-resistant performance, improves the impact resistance of sheet material simultaneously Energy and hot strength, durable, service life is long;And this kind of sheet material is environment friendly and pollution-free, wood Texture is strong, and smooth surface is fine and smooth, without advantages such as granular sensations.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
Wood composite board moulded by a kind of ageing-resistant polyethylene for building, and it is by following parts by weight Component mix and blend is made:
Polyethylene 80 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 50 parts, fourth etherified resin 10 parts, triallyl Isocyanates 4 parts, hydroxypropyl cellulose 12 parts, pulullan polysaccharide 7 parts, nitrile rubber 18 Part, trisnonylphenyl phosphite 5 parts, oleamide 3 parts, alkylphenol polyoxyethylene 2 parts, Silicon dioxide 2 parts.Its preparation method is: carry out batch mixing by weighing above-mentioned each component by proportioning Process, obtain mixed material;Then gained is used extruder by mixed material extrusion molding, I.e. obtain finished product.
Embodiment 2
Wood composite board moulded by a kind of ageing-resistant polyethylene for building, and it is by following parts by weight Component mix and blend is made:
Polyethylene 90 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 60 parts, fourth etherified resin 15 parts, triallyl Isocyanates 8 parts, hydroxypropyl cellulose 18 parts, pulullan polysaccharide 15 parts, nitrile rubber 24 parts, trisnonylphenyl phosphite 12 parts, oleamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon dioxide 6 parts.Its preparation method is: enter weighing above-mentioned each component by proportioning Row mixing treatment, obtains mixed material;Then gained use extruder extruded by mixed material Molding, i.e. obtains finished product.
Embodiment 3
Wood composite board moulded by a kind of ageing-resistant polyethylene for building, and it is by following parts by weight Component mix and blend is made:
Polyethylene 82 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 52 parts, fourth etherified resin 12 parts, triallyl Isocyanates 5 parts, hydroxypropyl cellulose 13 parts, pulullan polysaccharide 8 parts, nitrile rubber 19 Part, trisnonylphenyl phosphite 6 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, Silicon dioxide 3 parts.Its preparation method is: carry out batch mixing by weighing above-mentioned each component by proportioning Process, obtain mixed material;Then gained is used extruder by mixed material extrusion molding, I.e. obtain finished product.
Embodiment 4
Wood composite board moulded by a kind of ageing-resistant polyethylene for building, and it is by following parts by weight Component mix and blend is made:
Polyethylene 88 parts, Caulis et Folium Ammopiptanthi Mongolici wood powder 58 parts, fourth etherified resin 14 parts, triallyl Isocyanates 6 parts, hydroxypropyl cellulose 16 parts, pulullan polysaccharide 13 parts, nitrile rubber 22 parts, trisnonylphenyl phosphite 11 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon dioxide 4 parts.Its preparation method is: enter weighing above-mentioned each component by proportioning Row mixing treatment, obtains mixed material;Then gained use extruder extruded by mixed material Molding, i.e. obtains finished product.

Claims (5)

1. wood composite board moulded by an ageing-resistant polyethylene for building, it is characterised in that it be by The component of following parts by weight prepares: polyethylene 80-90 part, Caulis et Folium Ammopiptanthi Mongolici wood powder 50-60 part, Fourth etherified resin 10-15 part, triallyl isocyanate 4-8 part, hydroxypropyl cellulose 12-18 Part, pulullan polysaccharide 7-15 part, nitrile rubber 18-24 part, trisnonylphenyl phosphite 5-12 part, oleamide 3-5 part, alkylphenol polyoxyethylene 2-4 part, silicon dioxide 2-6 Part.
Wood composite board moulded by one the most according to claim 1 ageing-resistant polyethylene for building Material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 80 parts, sand Ilicis Purpureae wood powder 50 parts, fourth etherified resin 10 parts, triallyl isocyanate 4 parts, hydroxypropyl Cellulose 12 parts, pulullan polysaccharide 7 parts, nitrile rubber 18 parts, three nonyl phenylphosphonous acid Ester 5 parts, oleamide 3 parts, alkylphenol polyoxyethylene 2 parts, silicon dioxide 2 parts.
Wood composite board moulded by one the most according to claim 1 ageing-resistant polyethylene for building Material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 90 parts, sand Ilicis Purpureae wood powder 60 parts, fourth etherified resin 15 parts, triallyl isocyanate 8 parts, hydroxypropyl Cellulose 18 parts, pulullan polysaccharide 15 parts, nitrile rubber 24 parts, three nonyl phenyl phosphorous Acid esters 12 parts, oleamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon dioxide 6 parts.
Wood composite board moulded by one the most according to claim 1 ageing-resistant polyethylene for building Material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 82 parts, sand Ilicis Purpureae wood powder 52 parts, fourth etherified resin 12 parts, triallyl isocyanate 5 parts, hydroxypropyl Cellulose 13 parts, pulullan polysaccharide 8 parts, nitrile rubber 19 parts, three nonyl phenylphosphonous acid Ester 6 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon dioxide 3 parts.
Wood composite board moulded by one the most according to claim 1 ageing-resistant polyethylene for building Material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 88 parts, sand Ilicis Purpureae wood powder 58 parts, fourth etherified resin 14 parts, triallyl isocyanate 6 parts, hydroxypropyl Cellulose 16 parts, pulullan polysaccharide 13 parts, nitrile rubber 22 parts, three nonyl phenyl phosphorous Acid esters 11 parts, oleamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon dioxide 4 parts.
CN201610398306.6A 2016-06-06 2016-06-06 Aging resistant polyethylene plastic-wood composite plate for buildings Pending CN105936690A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107936599A (en) * 2017-10-20 2018-04-20 贵州中亚高科涂料有限公司 A kind of production method of Ecology floor tile

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977446A (en) * 2012-11-29 2013-03-20 熊雪平 Flame-retardant wood-plastic composite material and preparation method thereof
CN103073906A (en) * 2013-02-05 2013-05-01 山西峰岩新型建材股份有限公司 Polyethylene wood plastic and preparation method thereof
CN104861249A (en) * 2014-12-22 2015-08-26 王玉燕 Polyethylene wholly plastic wood-imitating material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977446A (en) * 2012-11-29 2013-03-20 熊雪平 Flame-retardant wood-plastic composite material and preparation method thereof
CN103073906A (en) * 2013-02-05 2013-05-01 山西峰岩新型建材股份有限公司 Polyethylene wood plastic and preparation method thereof
CN104861249A (en) * 2014-12-22 2015-08-26 王玉燕 Polyethylene wholly plastic wood-imitating material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107936599A (en) * 2017-10-20 2018-04-20 贵州中亚高科涂料有限公司 A kind of production method of Ecology floor tile

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Application publication date: 20160914