CN105925099A - Anti-flaming antisepsis leather coating and preparation method thereof - Google Patents
Anti-flaming antisepsis leather coating and preparation method thereof Download PDFInfo
- Publication number
- CN105925099A CN105925099A CN201610317570.2A CN201610317570A CN105925099A CN 105925099 A CN105925099 A CN 105925099A CN 201610317570 A CN201610317570 A CN 201610317570A CN 105925099 A CN105925099 A CN 105925099A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- minute
- stir
- weight
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses an anti-flaming antisepsis leather coating which is composed of, by weight, 2-3 parts of hydrous zinc borate, 1-1.5 parts of linoleic acid calcium soap, 0.1-0.2 part of triterpenoid saponin, 0.7-1 part of calcium naphthenate, 1.7-2 parts of polyvinylpyrrolidone, 0.8-1 part of polyacrylamide, 1.6-2 parts of stannous chloride, 0.1-0.13 part of triethanolamine, 190-200 parts of methyl methacrylate, 3-4 parts of lauryl sodium sulfate, 0.1-0.2 part of urotropine, 0.2-0.3 part of ammonium persulfate, 6-7 parts of a 20%-25% formaldehyde solution, 16-20 parts of zinc acetate, 4-7 parts of silver nitrate, 1-2 part of decabromodiphenyl ether and 0.4-1 part of sodium lauryl sulfate. The anti-flaming antisepsis leather coating has a good antibacterial property and excellent moisture permeability and water resistance. Leather coated with the obtained emulsion is good in antibacterial property and excellent in hygiene property.
Description
Technical field
The present invention relates to leather coating technical field, particularly relate to a kind of flame-proof antibiotic leather coating and preparation method thereof.
Background technology
Leather finishing agent/spinning coating agent is a kind of macromolecule compound being spread evenly across leather/textile surface.It forms one or more layers thin film by adhesive effect at leather/fabric face.Therefore, coating material quality, not only directly affect product appearance, quality, and decide the performance of product to a great extent.The features such as polyacrylate dispersion has the pliable and tough high resilience of film forming, and coating is fast light, ageing-resistant, wet-rub resistance energy is excellent, are the class leather spinning coating materials being widely used at present.But, the existence of some polar groups in conventional polypropylene acid esters emulsion, and product storing, transport, use during affected by environmental condition, often occur going mouldy, the phenomenon such as bacteria breed, raw material is not only wasted time serious, and the important propagating source of disease can be become, endanger human health.Meanwhile, coating material defines one layer of fine and close thin film at leather/fabric face, and the perspiration that Severe blockage human body distributes diffuses to the passage in the external world, causes the sanitation performance of leather goods/textile to suffer extreme influence, and snugness of fit declines.In recent years, along with improving constantly of human living standard, research and development antibiotic property leather/weaving coating material prominent, that sanitation performance is excellent is extremely urgent.
With the raising antibiotic property of polyacrylate coatings, sanitation performance for target exploitation nano-ZnO and the antibiotic property of nanometer ZO/Ag compound particle, prevent coating breed bacteria, go mouldy；Utilize nanometer ZO and specific surface area that nano-ZnO/Ag compound particle is huge, improve the sanitation performance of coating.
It is little that nano material itself has size, surface energy high, is thus susceptible to reunion, bad dispersibility.It addition, in the preparation process of nano composite material, the affinity of the polymeric matrix that nano material and surface can be relatively low is poor, is difficult to compatible when the two is mutually mixed, and space easily occurs in interface, there is phenomenon of phase separation.In order to make nano material be evenly dispersed in polymeric matrix, essential to its modifying surface.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of flame-proof antibiotic leather coating and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of flame-proof antibiotic leather coating, it is made up of the raw material of following weight parts:
Hydration zinc borate 2-3, linoleic acid calcium soap 1-1.5, triterpene saponin 0.1-0.2, calcium naphthenate 0.7-1, polyvinylpyrrolidone 1.7-2, polyacrylamide 0.8-1, stannous chloride 1.6-2, triethanolamine 0.1-0.13, methyl methacrylate 190-200, sodium lauryl sulphate 3-4, hexamethylenamine 0.1-0.2, formalin 6-7 of Ammonium persulfate. 0.2-0.3,20-25%, zinc acetate 16-20, silver nitrate 4-7, decabromodiphenyl oxide 1-2, sodium laurylsulfate 0.4-1.
The preparation method of a kind of described flame-proof antibiotic leather coating, comprises the following steps:
(1) by above-mentioned zinc acetate, hexamethylenamine mixing, join in the deionized water of compound weight 60-100 times, stir, for liquid a；
(2) take above-mentioned sodium laurylsulfate, join in the deionized water of its weight 17-20 times, stir, add hydration zinc borate, rise high-temperature and be 60-68 DEG C, insulated and stirred 7-10 minute, obtain fire-retardant dispersion liquid；
(3) above-mentioned polyvinylpyrrolidone is joined in its weight 20-30 times, 70-75% ethanol solution, stir, mix with above-mentioned liquid a, ultrasonic 20-30 minute, being sent in politef reactor, at 160-170 DEG C, microwave hydrothermal 20-30 minute, is cooled to room temperature, filter, obtain precipitation；
(4) above-mentioned precipitation is joined in fire-retardant dispersion liquid, under stirring condition, add above-mentioned calcium naphthenate, stir at 80-90 DEG C and do to water, obtain modified zinc oxide；
(5) by above-mentioned modified zinc oxide, stannous chloride mixing, join in the dehydrated alcohol of compound weight 100-120 times, ultrasonic 3-5 minute, add above-mentioned silver nitrate, triethanolamine, stir, drip the formalin of above-mentioned 20-25%, it is centrifuged off supernatant after dropping, precipitate with deionized water, ethanol are washed 3-4 time successively, be placed in baking oven, it is dried 10-17 minute at 90-100 DEG C, obtains Ag doping modified zinc oxide；
(6) being joined by above-mentioned polyacrylamide in the deionized water of its weight 80-100 times, stir, add acetic acid or ammonia, regulation pH is 6-7, adds above-mentioned Ag doping modified zinc oxide, decabromodiphenyl oxide, ultrasonic 20-30 minute, obtains modified dispersion liquid；
(7) above-mentioned Ammonium persulfate. is joined in the deionized water of its weight 17-20 times, stir；
(8) above-mentioned linoleic acid calcium soap is joined in the dehydrated alcohol of its weight 5-7 times, stir, add triterpene saponin, rise high-temperature and be 50-60 DEG C, insulated and stirred 10-17 minute, add the 20-24% of above-mentioned methyl methacrylate weight, send in the oil bath of 110-120 DEG C, insulated and stirred 6-8 minute, discharging cools down, obtains premix monomer；
(9) remaining methyl methacrylate is mixed with sodium lauryl sulphate, join in above-mentioned modified dispersion liquid, rise high-temperature and be 76-80 DEG C, insulated and stirred 10-14 minute, add above-mentioned premixing monomer, continue insulated and stirred 3-5 minute, drip above-mentioned ammonium persulfate aqueous solution, insulation reaction 120-130 minute after dropping, discharging, adding and remain each raw material, stirring, to room temperature, obtains described coating.
Described a kind of flame-proof antibiotic leather coating, the using method of this coating is: by coating supersound process 20-30 minute of the present invention before using, under the pressure of 0.2MPa, it is sprayed at leather surface with spray gun, normal temperature drying, 76-80 DEG C, press under conditions of 80bar, the most again spray the coating of the present invention, normal temperature drying,.
The invention have the advantage that first zinc oxide particles is evenly dispersed in the ethanol solution of stannous chloride by the present invention, Sn2+ will promptly be adsorbed onto zinc oxide surface；Then, adding the ethanol solution of Ag (TEA) 2+ in above-mentioned reactant liquor, Sn2+ can occur ion-exchange reactions with Ag (TEA) 2+ added so that Ag+ absorption forms silver kind at zinc oxide surface；In the reaction later stage, in solution, gradually drip formalin continuously stirred, make Ag be reduced into Ag granule；
The resistance to water of ZnO/Ag compound particle of the present invention own is preferable, is introduced in polyacrylate and can effectively prevent hydrone from penetrating in thin film, and then reduces the water absorption rate of laminated film, improves its resistance to water；
ZnO/Ag compound particle of the present invention has good anti-microbial property, and under illumination condition, ZnO surface produces substantial amounts of electronics and hole, the electronics that nanometer Ag capture generates, and obtains Ag-, and then, the oxygen molecule of Ag-with ZnO surface adsorption reacts, and generates superoxide ion;Superoxide ion reacts further with water, generates perhydroxyl radical and hydrogen peroxide;Hole and H2O or the HO-ionic reaction of ZnO surface adsorption, form the activity hydroxy with strong oxidizing property, and activity hydroxy mutually merges generation hydrogen peroxide.The oxidability of activity hydroxy is the strongest in water body oxidant, it is possible to the many Organic substances of degraded；Additionally, oxidant superoxide ion, hydrogen peroxide, perhydroxyl radical etc. all can be destroyed biological cell structure by biomacromolecule effects such as oxidation reaction and protein, enzyme, lipid and nucleic acid, thus killed antibacterial.In course of reaction, silver ion plays the effect of catalytic active center, and itself does not consume.Nanometer Ag is owing to granularity is minimum, specific surface area big, and surface can be higher, is easily adsorbed by various antibacterials, the most just constrains the activity of antibacterial, makes the living environment disorder of antibacterial lack of proper care, suppresses it to breathe, and ultimately results in antibacterial and " contact death " occurs.
The coating of the present invention has good antibiotic property, excellent water vapor permeability and resistance to water, and the leather antibacterial after the covering with paint of gained emulsion is good, sanitation performance is excellent.Present invention adds hydration zinc borate, decabromodiphenyl oxide etc., effectively raise the fire resistance of finished product coating.
Detailed description of the invention
A kind of flame-proof antibiotic leather coating, it is made up of the raw material of following weight parts:
Hydration zinc borate 2, linoleic acid calcium soap 1, triterpene saponin 0.1, calcium naphthenate 0.7, polyvinylpyrrolidone 1.7, polyacrylamide 0.8, stannous chloride 1.6, triethanolamine 0.1, methyl methacrylate 190, sodium lauryl sulphate 3, hexamethylenamine 0.1, the formalin 6 of Ammonium persulfate. 0.2,20%, zinc acetate 16, silver nitrate 4, decabromodiphenyl oxide 1, sodium laurylsulfate 0.4.
The preparation method of a kind of described flame-proof antibiotic leather coating, comprises the following steps:
(1) by above-mentioned zinc acetate, hexamethylenamine mixing, join in the deionized water of compound weight 60 times, stir, for liquid a；
(2) taking above-mentioned sodium laurylsulfate, join in the deionized water of its weight 17 times, stir, add hydration zinc borate, rising high-temperature is 60 DEG C, and insulated and stirred 7 minutes obtains fire-retardant dispersion liquid；
(3) above-mentioned polyvinylpyrrolidone is joined in its weight 20 times, the ethanol solution of 70%, stir, mix with above-mentioned liquid a, ultrasonic 20 minutes, it is sent in politef reactor, microwave hydrothermal 20 minutes at 160 DEG C, it is cooled to room temperature, filters, obtain precipitation；
(4) above-mentioned precipitation is joined in fire-retardant dispersion liquid, under stirring condition, add above-mentioned calcium naphthenate, stir at 80 DEG C and do to water, obtain modified zinc oxide；
(5) by above-mentioned modified zinc oxide, stannous chloride mixing, join in the dehydrated alcohol of compound weight 100 times, ultrasonic 3 minutes, add above-mentioned silver nitrate, triethanolamine, stir, drip the formalin of above-mentioned 20%, it is centrifuged off supernatant after dropping, precipitate with deionized water, ethanol is washed successively 3 times, be placed in baking oven, it is dried 10 minutes at 90 DEG C, obtains Ag doping modified zinc oxide；
(6) being joined by above-mentioned polyacrylamide in the deionized water of its weight 80 times, stir, add acetic acid or ammonia, regulation pH is 6, adds above-mentioned Ag doping modified zinc oxide, decabromodiphenyl oxide, ultrasonic 20 minutes, obtains modified dispersion liquid；
(7) above-mentioned Ammonium persulfate. is joined in the deionized water of its weight 17 times, stir；
(8) above-mentioned linoleic acid calcium soap is joined in the dehydrated alcohol of its weight 5 times, stir, add triterpene saponin, rising high-temperature is 50 DEG C, and insulated and stirred 10 minutes adds the 20% of above-mentioned methyl methacrylate weight, send in the oil bath of 110 DEG C, insulated and stirred 6 minutes, discharging cools down, obtains premix monomer；
(9) remaining methyl methacrylate is mixed with sodium lauryl sulphate, joining in above-mentioned modified dispersion liquid, rising high-temperature is 76 DEG C, insulated and stirred 10 minutes, add above-mentioned premixing monomer, continue insulated and stirred 3 minutes, drip above-mentioned ammonium persulfate aqueous solution, insulation reaction 120 minutes after dropping, discharging, adding and remain each raw material, stirring, to room temperature, obtains described coating.
Described a kind of flame-proof antibiotic leather coating, the using method of this coating is: by the coating supersound process 20 minutes of the present invention before using, under the pressure of 0.2MPa, it is sprayed at leather surface with spray gun, normal temperature drying, 76 DEG C, press under conditions of 80bar, the most again spray the coating of the present invention, normal temperature drying,.
Performance test:
Leather after liquid is covered with paint, lacquer, colour wash, etc. is 96.33% to the bacteriostasis rate of Candida albicans, and the bacteriostasis rate to mycete is 80.0%.
Claims (3)
1. a flame-proof antibiotic leather coating, it is characterized in that, it is made up of the raw material of following weight parts: hydration zinc borate 2-3, linoleic acid calcium soap 1-1.5, triterpene saponin 0.1-0.2, calcium naphthenate 0.7-1, polyvinylpyrrolidone 1.7-2, polyacrylamide 0.8-1, stannous chloride 1.6-2, triethanolamine 0.1-0.13, methyl methacrylate 190-200, sodium lauryl sulphate 3-4, hexamethylenamine 0.1-0.2, Ammonium persulfate. 0.2-0.3, formalin 6-7 of 20-25%, zinc acetate 16-20, silver nitrate 4-7, decabromodiphenyl oxide 1-2, sodium laurylsulfate 0.4-1.
2. the preparation method of a flame-proof antibiotic leather coating as claimed in claim 1, it is characterised in that comprise the following steps:
(1) by above-mentioned zinc acetate, hexamethylenamine mixing, join in the deionized water of compound weight 60-100 times, stir, for liquid a；
(2) take above-mentioned sodium laurylsulfate, join in the deionized water of its weight 17-20 times, stir, add hydration zinc borate, rise high-temperature and be 60-68 DEG C, insulated and stirred 7-10 minute, obtain fire-retardant dispersion liquid；
(3) above-mentioned polyvinylpyrrolidone is joined in its weight 20-30 times, 70-75% ethanol solution, stir, mix with above-mentioned liquid a, ultrasonic 20-30 minute, being sent in politef reactor, at 160-170 DEG C, microwave hydrothermal 20-30 minute, is cooled to room temperature, filter, obtain precipitation；
(4) above-mentioned precipitation is joined in fire-retardant dispersion liquid, under stirring condition, add above-mentioned calcium naphthenate, stir at 80-90 DEG C and do to water, obtain modified zinc oxide；
(5) by above-mentioned modified zinc oxide, stannous chloride mixing, join in the dehydrated alcohol of compound weight 100-120 times, ultrasonic 3-5 minute, add above-mentioned silver nitrate, triethanolamine, stir, drip the formalin of above-mentioned 20-25%, it is centrifuged off supernatant after dropping, precipitate with deionized water, ethanol are washed 3-4 time successively, be placed in baking oven, it is dried 10-17 minute at 90-100 DEG C, obtains Ag doping modified zinc oxide；
(6) being joined by above-mentioned polyacrylamide in the deionized water of its weight 80-100 times, stir, add acetic acid or ammonia, regulation pH is 6-7, adds above-mentioned Ag doping modified zinc oxide, decabromodiphenyl oxide, ultrasonic 20-30 minute, obtains modified dispersion liquid；
(7) above-mentioned Ammonium persulfate. is joined in the deionized water of its weight 17-20 times, stir；
(8) above-mentioned linoleic acid calcium soap is joined in the dehydrated alcohol of its weight 5-7 times, stir, add triterpene saponin, rise high-temperature and be 50-60 DEG C, insulated and stirred 10-17 minute, add the 20-24% of above-mentioned methyl methacrylate weight, send in the oil bath of 110-120 DEG C, insulated and stirred 6-8 minute, discharging cools down, obtains premix monomer；
(9) remaining methyl methacrylate is mixed with sodium lauryl sulphate, join in above-mentioned modified dispersion liquid, rise high-temperature and be 76-80 DEG C, insulated and stirred 10-14 minute, add above-mentioned premixing monomer, continue insulated and stirred 3-5 minute, drip above-mentioned ammonium persulfate aqueous solution, insulation reaction 120-130 minute after dropping, discharging, adding and remain each raw material, stirring, to room temperature, obtains described coating.
3. according to a kind of flame-proof antibiotic leather coating described in claim 1,2, it is characterized in that, the using method of this coating is: by coating supersound process 20-30 minute of the present invention before using, under the pressure of 0.2MPa, it is sprayed at leather surface with spray gun, normal temperature drying, 76-80 DEG C, press under conditions of 80bar, the most again spray the coating of the present invention, normal temperature drying,.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610317570.2A CN105925099A (en) | 2016-05-11 | 2016-05-11 | Anti-flaming antisepsis leather coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610317570.2A CN105925099A (en) | 2016-05-11 | 2016-05-11 | Anti-flaming antisepsis leather coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105925099A true CN105925099A (en) | 2016-09-07 |
Family
ID=56834729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610317570.2A Pending CN105925099A (en) | 2016-05-11 | 2016-05-11 | Anti-flaming antisepsis leather coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105925099A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106380986A (en) * | 2016-11-07 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Whisker-type antibacterial leather paint and preparation method thereof |
| CN106380987A (en) * | 2016-11-08 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Oxidation-resistant antibacterial leather paint and preparation method thereof |
| CN106380984A (en) * | 2016-09-30 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Decorative antibacterial leather coating and preparation method thereof |
| CN106497290A (en) * | 2016-09-30 | 2017-03-15 | 芜湖市鸿坤汽车零部件有限公司 | A kind of Ag doping modification antibacterial leather coating and preparation method thereof |
| CN106497291A (en) * | 2016-09-30 | 2017-03-15 | 芜湖市鸿坤汽车零部件有限公司 | A kind of long-acting stable antibacterial leather coating and preparation method thereof |
| CN106566353A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Aluminum sol modified antibacterial leather coating and preparation method thereof |
| CN106566357A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Antibacterial leather coating and preparation method thereof |
| CN106566351A (en) * | 2016-11-07 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Anti-static anti-microbial leather coating and preparation method thereof |
| CN106566356A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市长江起重设备制造有限公司 | High polymer antibacterial leather coating and preparation method thereof |
| CN106566364A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Flexible antimicrobial leather coating and preparation method thereof |
| CN106566352A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市长江起重设备制造有限公司 | Composite fiber-modifying anti-microbial leather coating and preparation method thereof |
| CN106590295A (en) * | 2016-11-07 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Silane modified antibacterial leather coating and preparation method thereof |
| CN106590296A (en) * | 2016-11-08 | 2017-04-26 | 芜湖市长江起重设备制造有限公司 | Anticorrosive and anti-bacterial leather coating and preparation method thereof |
| CN106590297A (en) * | 2016-11-08 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Hydrophobic antibacterial leather coating and preparation method thereof |
| CN106634366A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Smooth antibacterial leather coating and preparation method thereof |
| CN106634369A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Hard antibacterial leather coating and preparation method thereof |
| CN106634367A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Saponified antibacterial leather coating and preparation method thereof |
| CN106634368A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Titanium sol antibacterial leather coating and preparation method thereof |
| CN110195131A (en) * | 2019-06-19 | 2019-09-03 | 南宝树脂（佛山）有限公司 | A kind of aqueous leather environmental protection treatment agent |
| CN114606065A (en) * | 2022-03-25 | 2022-06-10 | 杭州临港化纤有限公司 | Nozzle cleaning agent and preparation method and cleaning process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898921A (en) * | 2012-10-25 | 2013-01-30 | 陕西科技大学 | Preparation method of antibacterial leather coating material |
| CN103170331A (en) * | 2013-03-04 | 2013-06-26 | 中国科学院合肥物质科学研究院 | Preparation method of micrometer/nanometer zinc oxide efficient loaded silver nanometer particle |
-
2016
- 2016-05-11 CN CN201610317570.2A patent/CN105925099A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898921A (en) * | 2012-10-25 | 2013-01-30 | 陕西科技大学 | Preparation method of antibacterial leather coating material |
| CN103170331A (en) * | 2013-03-04 | 2013-06-26 | 中国科学院合肥物质科学研究院 | Preparation method of micrometer/nanometer zinc oxide efficient loaded silver nanometer particle |
Non-Patent Citations (1)
| Title |
|---|
| 杨学稳等: "《化学建材》", 31 August 2006, 重庆大学出版社 * |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634368A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Titanium sol antibacterial leather coating and preparation method thereof |
| CN106380984A (en) * | 2016-09-30 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Decorative antibacterial leather coating and preparation method thereof |
| CN106497290A (en) * | 2016-09-30 | 2017-03-15 | 芜湖市鸿坤汽车零部件有限公司 | A kind of Ag doping modification antibacterial leather coating and preparation method thereof |
| CN106497291A (en) * | 2016-09-30 | 2017-03-15 | 芜湖市鸿坤汽车零部件有限公司 | A kind of long-acting stable antibacterial leather coating and preparation method thereof |
| CN106634367A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Saponified antibacterial leather coating and preparation method thereof |
| CN106634369A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Hard antibacterial leather coating and preparation method thereof |
| CN106634366A (en) * | 2016-09-30 | 2017-05-10 | 芜湖市鸿坤汽车零部件有限公司 | Smooth antibacterial leather coating and preparation method thereof |
| CN106590295A (en) * | 2016-11-07 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Silane modified antibacterial leather coating and preparation method thereof |
| CN106380986A (en) * | 2016-11-07 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Whisker-type antibacterial leather paint and preparation method thereof |
| CN106566351A (en) * | 2016-11-07 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Anti-static anti-microbial leather coating and preparation method thereof |
| CN106566353A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Aluminum sol modified antibacterial leather coating and preparation method thereof |
| CN106566352A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市长江起重设备制造有限公司 | Composite fiber-modifying anti-microbial leather coating and preparation method thereof |
| CN106590296A (en) * | 2016-11-08 | 2017-04-26 | 芜湖市长江起重设备制造有限公司 | Anticorrosive and anti-bacterial leather coating and preparation method thereof |
| CN106590297A (en) * | 2016-11-08 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Hydrophobic antibacterial leather coating and preparation method thereof |
| CN106566364A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Flexible antimicrobial leather coating and preparation method thereof |
| CN106566356A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市长江起重设备制造有限公司 | High polymer antibacterial leather coating and preparation method thereof |
| CN106566357A (en) * | 2016-11-08 | 2017-04-19 | 芜湖市鸿坤汽车零部件有限公司 | Antibacterial leather coating and preparation method thereof |
| CN106380987A (en) * | 2016-11-08 | 2017-02-08 | 芜湖市鸿坤汽车零部件有限公司 | Oxidation-resistant antibacterial leather paint and preparation method thereof |
| CN110195131A (en) * | 2019-06-19 | 2019-09-03 | 南宝树脂（佛山）有限公司 | A kind of aqueous leather environmental protection treatment agent |
| CN114606065A (en) * | 2022-03-25 | 2022-06-10 | 杭州临港化纤有限公司 | Nozzle cleaning agent and preparation method and cleaning process thereof |
| CN114606065B (en) * | 2022-03-25 | 2023-09-05 | 杭州临港化纤有限公司 | Nozzle cleaning agent and preparation method and cleaning process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105925099A (en) | Anti-flaming antisepsis leather coating and preparation method thereof | |
| CN105936788A (en) | Self-cleaning antibiosis leather coating and preparation method thereof | |
| CN103614719B (en) | A kind of preparation method of anti-bacteria stainless steel | |
| CN106380987A (en) | Oxidation-resistant antibacterial leather paint and preparation method thereof | |
| CN105176216A (en) | Diatom ooze coating and preparation method thereof | |
| CN106106522A (en) | A kind of nano zine oxide carries silver chitosan compound anti-bacteria agent and preparation method thereof | |
| WO2020177485A1 (en) | Nano silver particle/cellulosic fiber composite material and preparation method | |
| CN108126231A (en) | A kind of preparation method of the antibacterial hospital gauze of high intensity | |
| CN105177995A (en) | Preparation method for anti-bacteria pure cotton fabric | |
| CN110051837A (en) | A kind of CuO/ZnO/Au nanoparticle and its preparation method and application | |
| CN108818795A (en) | A method of heat treatment improves bamboo cane fungus-resistant with chemical treatment | |
| CN106497291A (en) | A kind of long-acting stable antibacterial leather coating and preparation method thereof | |
| CN106634368A (en) | Titanium sol antibacterial leather coating and preparation method thereof | |
| Zhang et al. | A controllable, universal, and natural supramolecular assembly coating strategy for multifunctionality textiles of antibacterial properties, UV resistance, antioxidant, and secondary reactivity | |
| CN106590295A (en) | Silane modified antibacterial leather coating and preparation method thereof | |
| WO2017092232A1 (en) | Method for preparing high-silver-content zirconium phosphate powder | |
| CN106566352A (en) | Composite fiber-modifying anti-microbial leather coating and preparation method thereof | |
| CN106566353A (en) | Aluminum sol modified antibacterial leather coating and preparation method thereof | |
| CN106566356A (en) | High polymer antibacterial leather coating and preparation method thereof | |
| CN101798749A (en) | Antibiotic finishing process on conductive fabric by adopting sol-gel method | |
| CN106566351A (en) | Anti-static anti-microbial leather coating and preparation method thereof | |
| CN106380984A (en) | Decorative antibacterial leather coating and preparation method thereof | |
| CN106380986A (en) | Whisker-type antibacterial leather paint and preparation method thereof | |
| CN106566357A (en) | Antibacterial leather coating and preparation method thereof | |
| CN106566364A (en) | Flexible antimicrobial leather coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160907 |
|
| RJ01 | Rejection of invention patent application after publication |