CN105924988A - Wheel-sticking-free emulsified asphalt, preparing method, construction technology and application of wheel-sticking-free emulsified asphalt - Google Patents
Wheel-sticking-free emulsified asphalt, preparing method, construction technology and application of wheel-sticking-free emulsified asphalt Download PDFInfo
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- CN105924988A CN105924988A CN201610318351.6A CN201610318351A CN105924988A CN 105924988 A CN105924988 A CN 105924988A CN 201610318351 A CN201610318351 A CN 201610318351A CN 105924988 A CN105924988 A CN 105924988A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
- C08L95/005—Aqueous compositions, e.g. emulsions
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/22—Binder incorporated in hot state, e.g. heated bitumen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2495/00—Bituminous materials, e.g. asphalt, tar or pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Civil Engineering (AREA)
- Structural Engineering (AREA)
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- Medicinal Chemistry (AREA)
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Abstract
The invention discloses a wheel-sticking-free emulsified asphalt, a preparing method, a construction technology and application of the wheel-sticking-free emulsified asphalt. The wheel-sticking-free emulsified asphalt is prepared from, by mass, 10-50% of matrix asphalt, 10-50% of hard asphalt, 0-5% of a polymer modifier, 0.3-3% of an asphalt emulsifier, 0-1% of a thickening agent and the balance an acid-base regulating agent and water to reach 100%. The preparing method comprises the steps that firstly, the polymer modifier, the asphalt emulsifier and the thickening agent are added into water, the pH value is regulated, and a soap solution is prepared; then, the matrix asphalt is heated to 150 DEG C, the hard asphalt is heated to 160 DEG C, the matrix asphalt and the hard asphalt are stirred evenly in a stirring state, the obtained mixed asphalt and the soap solution are subjected to high-speed shearing with a colloid mill together, and the emulsified asphalt is obtained, wherein the emulsifying process is simple and practical. The emulsified asphalt has the effect of being free of wheel sticking when serving as road tack coat oil, tack coats are prevented from being damaged by construction equipment or transportation vehicles, the construction efficiency is improved, and the effect of preventing environment pollution is also achieved.
Description
Technical field
The present invention relates to pavement material field, be specifically related in newly-built or maintenance road surface between structure sheaf
The not viscous wheel emulsified asphalt of the one of tack coat, preparation method, construction technology and application thereof.
Background technology
In pavement engineering work progress, adjacent structure interlayer generally uses the technique dispensing sticking material, makees
With being to make upper and lower bitumen layer or bitumen layer and structure to be bonded to an entirety completely, promote layer and layer it
Between formed entirety force structure, thus reduce caused by traffic loading interlayer structure dislocation and sidesway, subtract
The generation of few pavement disease, improves pavement durability.
But, in Practical Project is constructed, cause a major reason of interlaminar bonding poor effect to be,
Existing adhesion coating emulsified asphalt is after spread, though breakdown of emulsion film forming completely, the most usually by Construction traffic
Wheel roll after take away, cause the loss of bonding layer material, reduce bond effect, glue the emulsifying walked simultaneously
Surrounding enviroment are also polluted by Colophonium.It addition, the existing adhesion coating emulsified asphalt breakdown of emulsion time is long, dispensing
After, unit in charge of construction would generally wait a few hours, and the vehicle that could allow to pave is marched into the arena and carried out paving of compound,
Efficiency of construction is caused to reduce.
The Chinese patent of Publication No. CN104448848A refer to the preparation of a kind of adhesion coating emulsified asphalt, its
Fast solidifying, the effect of not viscous wheel can also be reached.Colophonium used is matrix pitch, however it is necessary that and adds in Colophonium
Enter Interface enhancer such as polyethylene or polyacrylic polymer, make enhancing modified Colophonium, preparation process need by
Colophonium is heated to 160 DEG C-170 DEG C, then carries out emulsifying and prepares emulsified asphalt.
Summary of the invention
Take turns for easy to stick existing for above-mentioned existing adhesion coating emulsified asphalt, cohesive force insufficient strength, and breakdown of emulsion
The technological deficiencies such as speed is slow and causes efficiency of construction is low are asked, an object of the present invention is to provide one not
The viscous or not wheel emulsified asphalt taking turns, coagulate soon, improve adhesion strength.
The two of the purpose of the present invention are to provide a kind of preparation method for preparing above-mentioned emulsified asphalt.
The three of the purpose of the present invention are to provide the application technology scheme of a kind of above-mentioned emulsified asphalt.
In order to achieve the above object, the present invention adopts the following technical scheme that:
The not viscous wheel emulsified asphalt of one, the following ingredients including accounting for its gross mass percentage ratio: 10%-50% base
Matter Colophonium, 10%-50% hard grades of bitumen, 0-5% polymer modifiers, 0.3%-3% asphalt emulsifier, 0-1%
Thickening agent, acid-base modifier and water supply 100%.
Further, described matrix pitch uses asphalt, and Asphalt Penetration is
50dmm~100dmm.
Further, described hard grades of bitumen uses asphalt, and Asphalt Penetration is 5dmm~30dmm.
Further, described polymer modifiers is pure-acrylic emulsion, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, polyurethane
Emulsion, silicone acrylic emulsion, polyvinyl acetate emulsion, vinyl acetate-ethylene copolymerization emulsions (EVA emulsion),
Any in polychloroprene latex, or by above-mentioned each emulsion, two or more mixes shape with arbitrary proportion
Become.
Further, described asphalt emulsifier for split soon type asphalt emulsifier, in split type asphalt emulsifier or slow
Split in type asphalt emulsifier any one or more than two kinds be mixed to form with arbitrary proportion.
Further, described asphalt emulsifier is cation asphalt emulgent, nonionic asphalt emulsifier or the moon
In ion asphalt emulsifier any one, or cation asphalt emulgent and other cation asphalt emulgent or non-
Ion asphalt emulsifier is mixed to form with arbitrary proportion, or anionic asphalt emulsion and other anion Colophonium
Emulsifying agent or nonionic asphalt emulsifier are mixed to form with arbitrary proportion.
Further, described thickening agent is methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, gathers
Any one in vinyl alcohol or modified starch.
Further, described acid-base modifier is in hydrochloric acid, phosphoric acid, sulphuric acid, sodium hydroxide or potassium hydroxide
Any one.
The preparation method of a kind of not viscous wheel emulsified asphalt is as follows:
(1) asphalt emulsifier is dissolved in 50 DEG C of-60 DEG C of hot water, then polymer modifiers and thickening agent are added
In water, stir and regulate pH value, being made into soap lye;
(2) then matrix pitch is heated to 150 DEG C, then hard grades of bitumen is heated to 160 DEG C, the two
Stir under stirring, and be maintained at 150 DEG C-160 DEG C;
(3) by mixing Colophonium together with soap lye through colloid mill high speed shear, obtain emulsified asphalt.
A kind of construction technology of described not viscous wheel emulsified asphalt, it is characterised in that its spread temperature arrives in room temperature
Between 80 DEG C, splitting emulsifying agent slowly if used, needing to reach fast emulsion breaking, surface drying, can be at 70-80 DEG C
Insulation spread, can be with breakdown of emulsion, surface drying in general 15 minutes.
Further, general spread quantity, 0.4~0.6Kg/m2, i.e. cannot not can reach viscously wheel, improves adhesion strength
Effect;If strengthening spread quantity to 0.6~1.2Kg/m2, it is also possible to fill up cutting optimal minute crack, prolong
Slow reflection crack produces.
Described emulsified asphalt answering as the tack coat between bituminous paving interlayer or cement pavement repaving asphalt coat
With.
Present invention employs the polymer modifiers of easy film forming, at normal temperatures (< 60 DEG C), can spray
After emulsified asphalt liquid level fast filming, and form network structure, the light composition adsorbing and blocking in Colophonium,
Improve interface and strengthen power, thus reduce the Colophonium adhesion to tire.And at high temperature (> 120 DEG C), bonding
Layer can be softened by hot asphalt mixture, recovers cohesive force.And modifying agent can be added directly in soap lye,
Easy to operate, additionally the adding proportion of modifying agent is the highest.
The matrix pitch of present invention employing and the emulsified difficulty of hard grades of bitumen mixture generic condition, but will heating
Temperature rises to 150 DEG C-160 DEG C can be with emulsifying.
The present invention use asphalt emulsifier except split soon and in split type asphalt emulsifier, it is also possible to use split slowly
Type asphalt emulsifier, it contains the component of aid dispersion, is more beneficial for the dispersibility of emulsified asphalt and stores steady
Qualitative, if required up fast emulsion breaking, surface drying, can be 70-80 DEG C of insulation spread, general 15 minutes
In can control breakdown of emulsion by temperature with breakdown of emulsion, surface drying, Modulatory character is strong.
Use the present invention can produce following beneficial effect:
1) production technology, the convenient use of construction technology.
2) cannot not there is viscously the characteristic of wheel, it is to avoid the Construction traffic destruction to sticking material, improve bonding
Efficiency and adhesion strength, also improve the durability on road surface.
Accompanying drawing explanation
Fig. 1 is to use after the surface drying to the present invention vehicle to roll test figure.
Fig. 2 is the state diagram after the method for Fig. 1 is tested of the existing adhesion coating emulsified asphalt.
Fig. 3 is the state diagram after the method for Fig. 1 is tested of the not viscous wheel emulsified asphalt of embodiments of the invention 1.
Fig. 4 is the state diagram after the method for Fig. 1 is tested of the not viscous wheel emulsified asphalt of embodiments of the invention 2.
Fig. 5 is that the not viscous wheel emulsified asphalt to the present invention carries out oblique shear Test Drawing.
The product picture of the not viscous wheel emulsified asphalt after the experiment described in Fig. 6 Fig. 5.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment, the present invention is described in detail.
The not viscous wheel emulsified asphalt of the present invention, the following ingredients including accounting for its gross mass percentage ratio:
10%-50% matrix pitch, 10%-50% hard grades of bitumen, 0-5% polymer modifiers, 0.3%-3% Colophonium breast
Agent, 0-1% thickening agent, acid-base modifier and water supply 100%.
It should be noted that the mix asphalt filling hard grades of bitumen formation in matrix pitch needs to meet for soft
Change point and the requirement of needle penetration: softening point is not less than 55 DEG C, needle penetration (25 DEG C, 100g, 5s)≤30dmm.
For above-mentioned embodiment content, if as no specific instructions, the various raw materials of the present invention all can lead to
Cross and be commercially available;Or prepare according to the conventional method of this area.Unless otherwise defined or described herein, herein
Used in the same meaning be familiar with those skilled in the art of all specialties and scientific words.This
The most any method similar or impartial to described content and material all can be applicable in the inventive method
Other aspects of the present invention due to this disclosure, be to those skilled in the art aobvious and
It is clear to.
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are only used for
The bright present invention rather than restriction the scope of the present invention.The experiment side of unreceipted actual conditions in the following example
Method, generally measures according to national standard.If there is no corresponding national standard, then according to general international standard,
Normal condition or carry out according to the condition proposed by manufacturer.Unless otherwise indicated, the most all of part
Number is weight portion, and all of percentage ratio is weight percentage.
One, preparation embodiment
Embodiment 1
Material selection: No. 70 Colophoniumes of middle petrochemical industry are as matrix pitch, and No. 10 asphalt are as hard grades of bitumen;
Select polyacrylate dispersion Acronal A 378 that BASF Aktiengesellschaft produces (solid content 61~63%)
As modifying agent;The cationic that asphalt emulsifier selects Shanghai Longfu Material Technology Co., Ltd. to produce is split slowly
Asphalt emulsifier EM-560;Thickening agent selects the hydroxyethyl cellulose of Shanghai Longfu Material Technology Co., Ltd.
CL-12;Acid-base modifier selects concentration to be the concentrated hydrochloric acid of 36%.Above-mentioned each material and water are claimed by following weight
Take:
Soap lye is prepared: EM-560 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to dissolving, then will change
Property agent Acronal A 378 and thickening agent CL-12 is added to the water, and stirs, regulates pH value with concentrated hydrochloric acid
To 2.0-2.5, then adding remaining hot water, supplying overall solution weight is 45kg, is i.e. made into soap lye and protects
Temperature is at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: No. 70 Colophoniumes of middle petrochemical industry are heated to 150 DEG C, then are added by No. 10 asphalt
Heat is to 160 DEG C, and the two stirs under stirring;Mixed Colophonium and above-mentioned 60 DEG C prepared
Soap lye is sufficiently mixed emulsifying in colloid mill, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt that will prepare
It is placed in 80 DEG C of baking oven insulations standby.
Embodiment 2
Material selection: No. 90 Colophoniumes of middle petrochemical industry are as matrix pitch, and No. 10 asphalt are as hard grades of bitumen;
The acrylic acid ester emulsion LFE01 (solid content 50%) selecting Shanghai Saifu Chemical Development Co., Ltd. to produce makees
For modifying agent;Asphalt emulsifier is selected in the cationic that Shanghai Longfu Material Technology Co., Ltd. produces and is split drip
Blue or green emulsifier EM-310 and cationic split asphalt emulsifier EM-560 slowly;Thickening agent selects upper Solenognathus to inspire confidence in
The hydroxyethyl cellulose CL-12 of Materials Technology Ltd.;The dense salt that acid-base modifier selects concentration to be 36%
Acid.Above-mentioned each material and water are weighed by following weight:
Soap lye is prepared: EM-310 and EM-560 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to molten
Solve, then modifer L FE01 and thickening agent CL-12 is added to the water, stir, regulate with concentrated hydrochloric acid
PH value, to 2.0-2.5, then adds remaining hot water, and supplying overall solution weight is 50kg, is i.e. made into soap
Liquid is also incubated at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: No. 90 Colophoniumes of middle petrochemical industry are heated to 150 DEG C, then are added by No. 10 asphalt
Heat is to 160 DEG C, and the two stirs under stirring;Mixed Colophonium and above-mentioned 60 DEG C prepared
Soap lye is sufficiently mixed emulsifying in colloid mill, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt that will prepare
It is placed in 70 DEG C of baking oven insulations standby.
Embodiment 3
Material selection: SK70 Colophonium is as matrix pitch, and No. 20 asphalt are as hard grades of bitumen;Choosing
Styrene-acrylic emulsion Acronal S 400F ap (solid content 57%) conduct produced with BASF Aktiengesellschaft is modified
Agent;The anionic that asphalt emulsifier selects Shanghai Longfu Material Technology Co., Ltd. to produce splits asphalt emulsification slowly
Agent EM-580;Thickening agent selects the hydroxyethyl cellulose CL-12 of Shanghai Longfu Material Technology Co., Ltd.;
Acid-base modifier selects sodium hydroxide.Above-mentioned each material and water are weighed by following weight:
Soap lye is prepared: EM-580 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to dissolving, then will change
Property agent Acronal S 400F ap and thickening agent CL-12 is added to the water, and stirs, adjusts with sodium hydroxide
Joint pH value, to 10.5-11, then adds remaining hot water, and supplying overall solution weight is 60kg, is i.e. made into
Soap lye is also incubated at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: SK70 Colophonium is heated to 150 DEG C, then is heated to by No. 20 asphalt
160 DEG C, the two stirs under stirring;Mixed Colophonium and the above-mentioned 60 DEG C of soap lyes prepared
In colloid mill, it is sufficiently mixed emulsifying, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt prepared is placed in
70 DEG C of baking oven insulations are standby.
Two, Application Example
Embodiment 1
Not viscous for above-mentioned preparation embodiment 1 gained wheel emulsified asphalt is used for the adhesion coating spread of bituminous paving interlayer,
Emulsified asphalt temperature, at 80 DEG C, is 0.6Kg/m according to spread quantity2, spread in bituminous paving, and with
Common emulsified asphalt contrasts.Wherein surface drying experiment is shown in Table 1, is 30 DEG C at temperature, the present embodiment gained
Viscous wheel emulsified asphalt was breakdown of emulsion, surface drying in 15 minutes, and tack-free.And commonly adhesion coating emulsifying drip
Green grass or young crops then needs nearly 40 minutes just surface dryings, and easily touches with one's hand.
Use vehicle to roll test after surface drying, make vehicle tyre first pass through tack coat and roll plain paper immediately
, thus evaluate the suppression adhesion effect of emulsified asphalt, as seen from Figure 1, common adhesion coating emulsified asphalt is easy
Sticking wheel, and Colophonium adhesive tape paper crushes, the not viscous wheel emulsified asphalt of the present embodiment gained is then without sticking
Phenomenon.
Embodiment 2
Not viscous for above-mentioned preparation embodiment 2 gained wheel emulsified asphalt is used for the adhesion coating spread of bituminous paving interlayer,
Emulsified asphalt temperature, at 70 DEG C, is 0.6Kg/m according to spread quantity2, spread in bituminous paving, and with
Common emulsified asphalt contrasts.Wherein surface drying experiment is shown in Table 1, is 30 DEG C at temperature, the present embodiment gained
Viscous wheel emulsified asphalt was breakdown of emulsion, surface drying in 15 minutes, and tack-free.And commonly adhesion coating emulsifying drip
Green grass or young crops then needs nearly 40 minutes just surface dryings, and easily touches with one's hand.
Use vehicle to roll test (seeing Fig. 1) after surface drying, make vehicle tyre first pass through tack coat and grind immediately
Pressure paper blank, thus evaluates the suppression adhesion effect of emulsified asphalt, from Figure 2 it can be seen that common adhesion coating emulsifying
Colophonium easily sticks wheel, and Colophonium adhesive tape paper crushes, and the not viscous wheel emulsified asphalt of the present embodiment gained
Then without sticking phenomenon (seeing Fig. 3 and Fig. 4).
Table 1 surface drying Experimental Comparison test table
The most respectively the not viscous wheel adhesion coating emulsified asphalt formed in embodiment 1~2 is carried out oblique shear test,
Shearing inclination is 45 degree, simulated roadway action of traffic loading lower stress condition, and inspection tack coat is resisted by going
The ability of the shear stress that car load level power produces.In view of present invention is generally directed to maintaining process demand,
Therefore gradation types selects the easy closely knit Ultra-thin asphalt of ECA-10, conventional modified AC-13 Colophonium coagulation
Soil, experimental test picture is as shown in Figure 5 and Figure 6.
For reflecting tack coat practical working situation as far as possible, simulated field work progress, according to " below prefabricated
Layer rut plate one brushing tack coat one roll upper strata bituminous concrete one cutting sample " order, rut plate become
Cut into the test specimen of 50mmX50mm × 60mm after type with double-side saw, carry out 0 DEG C, 25 DEG C, 50 DEG C three respectively
Individual temperature test, oblique scissor test result is as shown in table 2.
Table 2 shearing test result table
From above-mentioned realization and comparing result, the adhesion strength of the not viscous wheel emulsified asphalt of the present invention is better than general
Logical emulsified asphalt;And it is little to be characterized in rising high intensity reduction amplitude with temperature, when test temperature is increased to 50 DEG C,
Its shear strength in common emulsified asphalt tack coat, has the interlaminar bonding performance of excellence at double, has reached aobvious
The technique effect write, effect is also beyond thought.
After the not viscous wheel emulsified asphalt breakdown of emulsion molding of the present invention, intensity is big, temperature influence is little, can spray in a large number
Without worrying that bellding disease occurs in overlay;Strengthen fountain height (0.6~1.2Kg/m2Formed on road surface after)
Hard coat, emulsion is penetrated into road surface minute crack, dead air space, is delayed crack progressing;It is particularly suited for road
There is microcrack (< 2mm) in face, has crack progressing trend, but is not suitable for the disease incidence using milling to process;
Thick matter is sprayed and is combined with overlay hot-mixed asphaltic concrete technique, can significantly prolonging service life of pavement.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The industry
Skilled person will appreciate that, the present invention is not restricted to the described embodiments, in above-described embodiment and description
The principle that the present invention is simply described described, without departing from the spirit and scope of the present invention, the present invention
Also having various changes and modifications, these changes and improvements both fall within scope of the claimed invention.This
The claimed scope of invention is defined by appending claims and equivalent thereof.
Claims (12)
1. not viscous wheel emulsified asphalt, it is characterised in that described emulsified asphalt includes accounting for its gross mass hundred
The following ingredients of proportion by subtraction: 10%-50% matrix pitch, 10%-50% hard grades of bitumen, 0-5% polymer modification
Agent, 0.3%-3% asphalt emulsifier, 0-1% thickening agent, acid-base modifier and water supply 100%.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described substrate drip
Green grass or young crops uses asphalt, and Asphalt Penetration is 50dmm~100dmm.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described hard drip
Green grass or young crops uses asphalt, and Asphalt Penetration is 5dmm~30dmm.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described polymer
Modifying agent is pure-acrylic emulsion, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, polyaminoester emulsion, silicone acrylic emulsion, poly-acetic acid second
One in alkene emulsion, vinyl acetate-ethylene copolymerization emulsions (EVA emulsion), polychloroprene latex, or by upper
State in each emulsion that two or more is mixed to form with arbitrary proportion.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described Colophonium breast
Agent for split soon type asphalt emulsifier, in split a kind of in type asphalt emulsifier or slow breaking asphalt emulsifier or two
It is mixed to form with arbitrary proportion more than kind.
Not viscous wheel emulsified asphalt the most according to claim 5, it is characterised in that described Colophonium breast
Agent is a kind of in cation asphalt emulgent, nonionic asphalt emulsifier or anionic asphalt emulsion, or
Cation asphalt emulgent and other cation asphalt emulgent or nonionic asphalt emulsifier are with arbitrary proportion
It is mixed to form, or anionic asphalt emulsion and other anionic asphalt emulsion or nonionic asphalt emulsifier
It is mixed to form with arbitrary proportion.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described thickening agent
For the one in methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol or modified starch.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described soda acid is adjusted
Joint agent is the one in hydrochloric acid, phosphoric acid, sulphuric acid, sodium hydroxide or potassium hydroxide.
The preparation method of not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that institute
State preparation method as follows:
(1) asphalt emulsifier is dissolved in 50 DEG C of-60 DEG C of hot water, then polymer modifiers and thickening agent are added
In water, stir and regulate pH value, being made into soap lye;
(2) then matrix pitch is heated to 150 DEG C, then hard grades of bitumen is heated to 160 DEG C, the two
Stir under stirring, and be maintained at 150 DEG C-160 DEG C;
(3) by mixing Colophonium together with soap lye through colloid mill high speed shear, obtain emulsified asphalt.
The construction technology of not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that its
Spread temperature is between room temperature to 80 DEG C;If using and splitting emulsifying agent slowly, need to reach fast emulsion breaking, surface drying,
Spread can be incubated at 70-80 DEG C.
The construction technology of 11. not viscous wheel emulsified asphalts according to claim 10, it is characterised in that
Further, general spread quantity, 0.4~0.6Kg/m2, i.e. cannot not can reach viscously wheel, improves adhesion strength
Effect;If strengthening spread quantity to 0.6~1.2Kg/m2, it is also possible to fill up cutting optimal minute crack, prolong
Slow reflection crack produces.
The application of 12. not viscous wheel emulsified asphalts according to claim 1, it is characterised in that described breast
Change the Colophonium application as the tack coat between bituminous paving interlayer or cement pavement repaving asphalt coat.
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Publication number | Priority date | Publication date | Assignee | Title |
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CN106928732A (en) * | 2017-04-20 | 2017-07-07 | 北京市政路桥建材集团有限公司 | Normal temperature fast emulsion breaking, easily prepared anti-stick emulsified asphalt and preparation method thereof |
CN106996904A (en) * | 2017-04-20 | 2017-08-01 | 北京市政路桥建材集团有限公司 | A kind of viscous wheel effect evaluation method of emulsified asphalt |
CN107083232A (en) * | 2017-05-26 | 2017-08-22 | 山西省交通科学研究院 | A kind of bio-based does not glue wheel sticking layer oil and preparation method thereof |
CN107099040A (en) * | 2017-04-20 | 2017-08-29 | 北京市政路桥建材集团有限公司 | The anti-of normal temperature fast emulsion breaking curing molding sticks emulsified asphalt and preparation method thereof |
CN107189757A (en) * | 2017-07-21 | 2017-09-22 | 张娟 | A kind of preparation method of constructional engineering adhesive |
CN108892961A (en) * | 2018-07-26 | 2018-11-27 | 江苏增光复合材料科技有限公司 | A kind of high viscosity modified emulsifying asphalt and preparation method thereof |
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CN109054409A (en) * | 2018-06-25 | 2018-12-21 | 重庆交通大学 | A kind of viscous micro- cover construction method of formula special asphalt of interlayer height |
CN109135668A (en) * | 2018-08-10 | 2019-01-04 | 陈娟 | Glutinous not viscous wheel sticking layer oil of height and preparation method thereof |
CN109370513A (en) * | 2018-09-29 | 2019-02-22 | 南京兴佑交通科技有限公司 | A kind of adhesion coating emulsified asphalt and preparation method thereof |
CN110878174A (en) * | 2018-09-06 | 2020-03-13 | 中国石油化工股份有限公司 | Emulsified asphalt for non-stick wheel and preparation method thereof |
CN111235998A (en) * | 2020-01-16 | 2020-06-05 | 西安博望新材料科技有限公司 | Low-noise embedded fiber wearing layer and construction method thereof |
CN111471128A (en) * | 2020-06-04 | 2020-07-31 | 甘肃省公路交通建设集团有限公司酒泉路衍产业开发分公司 | Water-based acrylic elastic emulsion, preparation method thereof and application thereof in asphalt pavement |
CN111621035A (en) * | 2020-04-14 | 2020-09-04 | 南通通沙沥青科技有限公司 | Emulsified asphalt and preparation method thereof |
CN112280319A (en) * | 2020-10-14 | 2021-01-29 | 河北伦特化工集团有限公司 | Preparation method and application of non-sticky wheel modified emulsified asphalt |
CN113105748A (en) * | 2021-05-30 | 2021-07-13 | 南方高科工程技术有限公司 | Super-viscous self-healing non-emulsified oil for sticking layer |
CN115449231A (en) * | 2022-09-30 | 2022-12-09 | 中路交科科技股份有限公司 | High-toughness wheel-sticking-free emulsified asphalt and preparation method thereof |
US11708508B2 (en) * | 2019-03-15 | 2023-07-25 | Russell Standard Corp. | High performance tack coat |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5114483A (en) * | 1986-10-31 | 1992-05-19 | Chevron Research And Technology Company | Open-graded asphalt |
CN101397201A (en) * | 2008-08-22 | 2009-04-01 | 厦门华特集团有限公司 | Modified emulsified bitumen for tie coat |
CN102558885A (en) * | 2011-12-30 | 2012-07-11 | 上海龙孚材料技术有限公司 | Emulsified asphalt used for high-speed railway, mortar containing emulsified asphalt and preparation method of mortar |
CN104403335A (en) * | 2014-11-21 | 2015-03-11 | 江苏省交通科学研究院股份有限公司 | Adhesive layer emulsified asphalt and preparation method thereof |
CN104448848A (en) * | 2014-11-21 | 2015-03-25 | 江苏省交通科学研究院股份有限公司 | Quick-set wheel-adhesion-free sticky layer emulsified asphalt and preparation method thereof |
-
2016
- 2016-05-13 CN CN201610318351.6A patent/CN105924988B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5114483A (en) * | 1986-10-31 | 1992-05-19 | Chevron Research And Technology Company | Open-graded asphalt |
CN101397201A (en) * | 2008-08-22 | 2009-04-01 | 厦门华特集团有限公司 | Modified emulsified bitumen for tie coat |
CN102558885A (en) * | 2011-12-30 | 2012-07-11 | 上海龙孚材料技术有限公司 | Emulsified asphalt used for high-speed railway, mortar containing emulsified asphalt and preparation method of mortar |
CN104403335A (en) * | 2014-11-21 | 2015-03-11 | 江苏省交通科学研究院股份有限公司 | Adhesive layer emulsified asphalt and preparation method thereof |
CN104448848A (en) * | 2014-11-21 | 2015-03-25 | 江苏省交通科学研究院股份有限公司 | Quick-set wheel-adhesion-free sticky layer emulsified asphalt and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
徐峰等: "《涂膜防水材料与应用》", 31 January 2007, 化学工业出版社 * |
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CN106928732A (en) * | 2017-04-20 | 2017-07-07 | 北京市政路桥建材集团有限公司 | Normal temperature fast emulsion breaking, easily prepared anti-stick emulsified asphalt and preparation method thereof |
CN106996904A (en) * | 2017-04-20 | 2017-08-01 | 北京市政路桥建材集团有限公司 | A kind of viscous wheel effect evaluation method of emulsified asphalt |
CN107099040A (en) * | 2017-04-20 | 2017-08-29 | 北京市政路桥建材集团有限公司 | The anti-of normal temperature fast emulsion breaking curing molding sticks emulsified asphalt and preparation method thereof |
CN107083232A (en) * | 2017-05-26 | 2017-08-22 | 山西省交通科学研究院 | A kind of bio-based does not glue wheel sticking layer oil and preparation method thereof |
CN107189757A (en) * | 2017-07-21 | 2017-09-22 | 张娟 | A kind of preparation method of constructional engineering adhesive |
CN109054409A (en) * | 2018-06-25 | 2018-12-21 | 重庆交通大学 | A kind of viscous micro- cover construction method of formula special asphalt of interlayer height |
CN108892961A (en) * | 2018-07-26 | 2018-11-27 | 江苏增光复合材料科技有限公司 | A kind of high viscosity modified emulsifying asphalt and preparation method thereof |
CN109135668A (en) * | 2018-08-10 | 2019-01-04 | 陈娟 | Glutinous not viscous wheel sticking layer oil of height and preparation method thereof |
CN108997766A (en) * | 2018-09-03 | 2018-12-14 | 江苏中路工程技术研究院有限公司 | A kind of hgh-performance emulsified pitch and preparation method thereof |
CN110878174A (en) * | 2018-09-06 | 2020-03-13 | 中国石油化工股份有限公司 | Emulsified asphalt for non-stick wheel and preparation method thereof |
CN109370513A (en) * | 2018-09-29 | 2019-02-22 | 南京兴佑交通科技有限公司 | A kind of adhesion coating emulsified asphalt and preparation method thereof |
US11708508B2 (en) * | 2019-03-15 | 2023-07-25 | Russell Standard Corp. | High performance tack coat |
CN111235998A (en) * | 2020-01-16 | 2020-06-05 | 西安博望新材料科技有限公司 | Low-noise embedded fiber wearing layer and construction method thereof |
CN111621035A (en) * | 2020-04-14 | 2020-09-04 | 南通通沙沥青科技有限公司 | Emulsified asphalt and preparation method thereof |
CN111471128A (en) * | 2020-06-04 | 2020-07-31 | 甘肃省公路交通建设集团有限公司酒泉路衍产业开发分公司 | Water-based acrylic elastic emulsion, preparation method thereof and application thereof in asphalt pavement |
CN112280319A (en) * | 2020-10-14 | 2021-01-29 | 河北伦特化工集团有限公司 | Preparation method and application of non-sticky wheel modified emulsified asphalt |
CN113105748A (en) * | 2021-05-30 | 2021-07-13 | 南方高科工程技术有限公司 | Super-viscous self-healing non-emulsified oil for sticking layer |
CN113105748B (en) * | 2021-05-30 | 2022-10-18 | 南方高科工程技术有限公司 | Super-viscous self-healing non-emulsified oil for sticking layer |
CN115449231A (en) * | 2022-09-30 | 2022-12-09 | 中路交科科技股份有限公司 | High-toughness wheel-sticking-free emulsified asphalt and preparation method thereof |
CN115449231B (en) * | 2022-09-30 | 2023-09-12 | 中路交科科技股份有限公司 | High-toughness non-stick emulsified asphalt and preparation method thereof |
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