CN105924988A - Wheel-sticking-free emulsified asphalt, preparing method, construction technology and application of wheel-sticking-free emulsified asphalt - Google Patents

Wheel-sticking-free emulsified asphalt, preparing method, construction technology and application of wheel-sticking-free emulsified asphalt Download PDF

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Publication number
CN105924988A
CN105924988A CN201610318351.6A CN201610318351A CN105924988A CN 105924988 A CN105924988 A CN 105924988A CN 201610318351 A CN201610318351 A CN 201610318351A CN 105924988 A CN105924988 A CN 105924988A
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asphalt
emulsified asphalt
emulsion
wheel
emulsifier
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CN105924988B (en
Inventor
张云星
许春生
韩开震
吴德龙
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Xiamen Ward highway asphalt Technology Co., Ltd.
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SHANGHAI LONGFU MATERIAL TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C08L95/005Aqueous compositions, e.g. emulsions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/22Binder incorporated in hot state, e.g. heated bitumen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2395/00Bituminous materials, e.g. asphalt, tar or pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2495/00Bituminous materials, e.g. asphalt, tar or pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Dispersion Chemistry (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention discloses a wheel-sticking-free emulsified asphalt, a preparing method, a construction technology and application of the wheel-sticking-free emulsified asphalt. The wheel-sticking-free emulsified asphalt is prepared from, by mass, 10-50% of matrix asphalt, 10-50% of hard asphalt, 0-5% of a polymer modifier, 0.3-3% of an asphalt emulsifier, 0-1% of a thickening agent and the balance an acid-base regulating agent and water to reach 100%. The preparing method comprises the steps that firstly, the polymer modifier, the asphalt emulsifier and the thickening agent are added into water, the pH value is regulated, and a soap solution is prepared; then, the matrix asphalt is heated to 150 DEG C, the hard asphalt is heated to 160 DEG C, the matrix asphalt and the hard asphalt are stirred evenly in a stirring state, the obtained mixed asphalt and the soap solution are subjected to high-speed shearing with a colloid mill together, and the emulsified asphalt is obtained, wherein the emulsifying process is simple and practical. The emulsified asphalt has the effect of being free of wheel sticking when serving as road tack coat oil, tack coats are prevented from being damaged by construction equipment or transportation vehicles, the construction efficiency is improved, and the effect of preventing environment pollution is also achieved.

Description

The not viscous wheel emulsified asphalt of one, preparation method, construction technology and application thereof
Technical field
The present invention relates to pavement material field, be specifically related in newly-built or maintenance road surface between structure sheaf The not viscous wheel emulsified asphalt of the one of tack coat, preparation method, construction technology and application thereof.
Background technology
In pavement engineering work progress, adjacent structure interlayer generally uses the technique dispensing sticking material, makees With being to make upper and lower bitumen layer or bitumen layer and structure to be bonded to an entirety completely, promote layer and layer it Between formed entirety force structure, thus reduce caused by traffic loading interlayer structure dislocation and sidesway, subtract The generation of few pavement disease, improves pavement durability.
But, in Practical Project is constructed, cause a major reason of interlaminar bonding poor effect to be, Existing adhesion coating emulsified asphalt is after spread, though breakdown of emulsion film forming completely, the most usually by Construction traffic Wheel roll after take away, cause the loss of bonding layer material, reduce bond effect, glue the emulsifying walked simultaneously Surrounding enviroment are also polluted by Colophonium.It addition, the existing adhesion coating emulsified asphalt breakdown of emulsion time is long, dispensing After, unit in charge of construction would generally wait a few hours, and the vehicle that could allow to pave is marched into the arena and carried out paving of compound, Efficiency of construction is caused to reduce.
The Chinese patent of Publication No. CN104448848A refer to the preparation of a kind of adhesion coating emulsified asphalt, its Fast solidifying, the effect of not viscous wheel can also be reached.Colophonium used is matrix pitch, however it is necessary that and adds in Colophonium Enter Interface enhancer such as polyethylene or polyacrylic polymer, make enhancing modified Colophonium, preparation process need by Colophonium is heated to 160 DEG C-170 DEG C, then carries out emulsifying and prepares emulsified asphalt.
Summary of the invention
Take turns for easy to stick existing for above-mentioned existing adhesion coating emulsified asphalt, cohesive force insufficient strength, and breakdown of emulsion The technological deficiencies such as speed is slow and causes efficiency of construction is low are asked, an object of the present invention is to provide one not The viscous or not wheel emulsified asphalt taking turns, coagulate soon, improve adhesion strength.
The two of the purpose of the present invention are to provide a kind of preparation method for preparing above-mentioned emulsified asphalt.
The three of the purpose of the present invention are to provide the application technology scheme of a kind of above-mentioned emulsified asphalt.
In order to achieve the above object, the present invention adopts the following technical scheme that:
The not viscous wheel emulsified asphalt of one, the following ingredients including accounting for its gross mass percentage ratio: 10%-50% base Matter Colophonium, 10%-50% hard grades of bitumen, 0-5% polymer modifiers, 0.3%-3% asphalt emulsifier, 0-1% Thickening agent, acid-base modifier and water supply 100%.
Further, described matrix pitch uses asphalt, and Asphalt Penetration is 50dmm~100dmm.
Further, described hard grades of bitumen uses asphalt, and Asphalt Penetration is 5dmm~30dmm.
Further, described polymer modifiers is pure-acrylic emulsion, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, polyurethane Emulsion, silicone acrylic emulsion, polyvinyl acetate emulsion, vinyl acetate-ethylene copolymerization emulsions (EVA emulsion), Any in polychloroprene latex, or by above-mentioned each emulsion, two or more mixes shape with arbitrary proportion Become.
Further, described asphalt emulsifier for split soon type asphalt emulsifier, in split type asphalt emulsifier or slow Split in type asphalt emulsifier any one or more than two kinds be mixed to form with arbitrary proportion.
Further, described asphalt emulsifier is cation asphalt emulgent, nonionic asphalt emulsifier or the moon In ion asphalt emulsifier any one, or cation asphalt emulgent and other cation asphalt emulgent or non- Ion asphalt emulsifier is mixed to form with arbitrary proportion, or anionic asphalt emulsion and other anion Colophonium Emulsifying agent or nonionic asphalt emulsifier are mixed to form with arbitrary proportion.
Further, described thickening agent is methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, gathers Any one in vinyl alcohol or modified starch.
Further, described acid-base modifier is in hydrochloric acid, phosphoric acid, sulphuric acid, sodium hydroxide or potassium hydroxide Any one.
The preparation method of a kind of not viscous wheel emulsified asphalt is as follows:
(1) asphalt emulsifier is dissolved in 50 DEG C of-60 DEG C of hot water, then polymer modifiers and thickening agent are added In water, stir and regulate pH value, being made into soap lye;
(2) then matrix pitch is heated to 150 DEG C, then hard grades of bitumen is heated to 160 DEG C, the two Stir under stirring, and be maintained at 150 DEG C-160 DEG C;
(3) by mixing Colophonium together with soap lye through colloid mill high speed shear, obtain emulsified asphalt.
A kind of construction technology of described not viscous wheel emulsified asphalt, it is characterised in that its spread temperature arrives in room temperature Between 80 DEG C, splitting emulsifying agent slowly if used, needing to reach fast emulsion breaking, surface drying, can be at 70-80 DEG C Insulation spread, can be with breakdown of emulsion, surface drying in general 15 minutes.
Further, general spread quantity, 0.4~0.6Kg/m2, i.e. cannot not can reach viscously wheel, improves adhesion strength Effect;If strengthening spread quantity to 0.6~1.2Kg/m2, it is also possible to fill up cutting optimal minute crack, prolong Slow reflection crack produces.
Described emulsified asphalt answering as the tack coat between bituminous paving interlayer or cement pavement repaving asphalt coat With.
Present invention employs the polymer modifiers of easy film forming, at normal temperatures (< 60 DEG C), can spray After emulsified asphalt liquid level fast filming, and form network structure, the light composition adsorbing and blocking in Colophonium, Improve interface and strengthen power, thus reduce the Colophonium adhesion to tire.And at high temperature (> 120 DEG C), bonding Layer can be softened by hot asphalt mixture, recovers cohesive force.And modifying agent can be added directly in soap lye, Easy to operate, additionally the adding proportion of modifying agent is the highest.
The matrix pitch of present invention employing and the emulsified difficulty of hard grades of bitumen mixture generic condition, but will heating Temperature rises to 150 DEG C-160 DEG C can be with emulsifying.
The present invention use asphalt emulsifier except split soon and in split type asphalt emulsifier, it is also possible to use split slowly Type asphalt emulsifier, it contains the component of aid dispersion, is more beneficial for the dispersibility of emulsified asphalt and stores steady Qualitative, if required up fast emulsion breaking, surface drying, can be 70-80 DEG C of insulation spread, general 15 minutes In can control breakdown of emulsion by temperature with breakdown of emulsion, surface drying, Modulatory character is strong.
Use the present invention can produce following beneficial effect:
1) production technology, the convenient use of construction technology.
2) cannot not there is viscously the characteristic of wheel, it is to avoid the Construction traffic destruction to sticking material, improve bonding Efficiency and adhesion strength, also improve the durability on road surface.
Accompanying drawing explanation
Fig. 1 is to use after the surface drying to the present invention vehicle to roll test figure.
Fig. 2 is the state diagram after the method for Fig. 1 is tested of the existing adhesion coating emulsified asphalt.
Fig. 3 is the state diagram after the method for Fig. 1 is tested of the not viscous wheel emulsified asphalt of embodiments of the invention 1.
Fig. 4 is the state diagram after the method for Fig. 1 is tested of the not viscous wheel emulsified asphalt of embodiments of the invention 2.
Fig. 5 is that the not viscous wheel emulsified asphalt to the present invention carries out oblique shear Test Drawing.
The product picture of the not viscous wheel emulsified asphalt after the experiment described in Fig. 6 Fig. 5.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment, the present invention is described in detail.
The not viscous wheel emulsified asphalt of the present invention, the following ingredients including accounting for its gross mass percentage ratio: 10%-50% matrix pitch, 10%-50% hard grades of bitumen, 0-5% polymer modifiers, 0.3%-3% Colophonium breast Agent, 0-1% thickening agent, acid-base modifier and water supply 100%.
It should be noted that the mix asphalt filling hard grades of bitumen formation in matrix pitch needs to meet for soft Change point and the requirement of needle penetration: softening point is not less than 55 DEG C, needle penetration (25 DEG C, 100g, 5s)≤30dmm.
For above-mentioned embodiment content, if as no specific instructions, the various raw materials of the present invention all can lead to Cross and be commercially available;Or prepare according to the conventional method of this area.Unless otherwise defined or described herein, herein Used in the same meaning be familiar with those skilled in the art of all specialties and scientific words.This The most any method similar or impartial to described content and material all can be applicable in the inventive method
Other aspects of the present invention due to this disclosure, be to those skilled in the art aobvious and It is clear to.
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are only used for The bright present invention rather than restriction the scope of the present invention.The experiment side of unreceipted actual conditions in the following example Method, generally measures according to national standard.If there is no corresponding national standard, then according to general international standard, Normal condition or carry out according to the condition proposed by manufacturer.Unless otherwise indicated, the most all of part Number is weight portion, and all of percentage ratio is weight percentage.
One, preparation embodiment
Embodiment 1
Material selection: No. 70 Colophoniumes of middle petrochemical industry are as matrix pitch, and No. 10 asphalt are as hard grades of bitumen; Select polyacrylate dispersion Acronal A 378 that BASF Aktiengesellschaft produces (solid content 61~63%) As modifying agent;The cationic that asphalt emulsifier selects Shanghai Longfu Material Technology Co., Ltd. to produce is split slowly Asphalt emulsifier EM-560;Thickening agent selects the hydroxyethyl cellulose of Shanghai Longfu Material Technology Co., Ltd. CL-12;Acid-base modifier selects concentration to be the concentrated hydrochloric acid of 36%.Above-mentioned each material and water are claimed by following weight Take:
Soap lye is prepared: EM-560 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to dissolving, then will change Property agent Acronal A 378 and thickening agent CL-12 is added to the water, and stirs, regulates pH value with concentrated hydrochloric acid To 2.0-2.5, then adding remaining hot water, supplying overall solution weight is 45kg, is i.e. made into soap lye and protects Temperature is at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: No. 70 Colophoniumes of middle petrochemical industry are heated to 150 DEG C, then are added by No. 10 asphalt Heat is to 160 DEG C, and the two stirs under stirring;Mixed Colophonium and above-mentioned 60 DEG C prepared Soap lye is sufficiently mixed emulsifying in colloid mill, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt that will prepare It is placed in 80 DEG C of baking oven insulations standby.
Embodiment 2
Material selection: No. 90 Colophoniumes of middle petrochemical industry are as matrix pitch, and No. 10 asphalt are as hard grades of bitumen; The acrylic acid ester emulsion LFE01 (solid content 50%) selecting Shanghai Saifu Chemical Development Co., Ltd. to produce makees For modifying agent;Asphalt emulsifier is selected in the cationic that Shanghai Longfu Material Technology Co., Ltd. produces and is split drip Blue or green emulsifier EM-310 and cationic split asphalt emulsifier EM-560 slowly;Thickening agent selects upper Solenognathus to inspire confidence in The hydroxyethyl cellulose CL-12 of Materials Technology Ltd.;The dense salt that acid-base modifier selects concentration to be 36% Acid.Above-mentioned each material and water are weighed by following weight:
Soap lye is prepared: EM-310 and EM-560 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to molten Solve, then modifer L FE01 and thickening agent CL-12 is added to the water, stir, regulate with concentrated hydrochloric acid PH value, to 2.0-2.5, then adds remaining hot water, and supplying overall solution weight is 50kg, is i.e. made into soap Liquid is also incubated at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: No. 90 Colophoniumes of middle petrochemical industry are heated to 150 DEG C, then are added by No. 10 asphalt Heat is to 160 DEG C, and the two stirs under stirring;Mixed Colophonium and above-mentioned 60 DEG C prepared Soap lye is sufficiently mixed emulsifying in colloid mill, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt that will prepare It is placed in 70 DEG C of baking oven insulations standby.
Embodiment 3
Material selection: SK70 Colophonium is as matrix pitch, and No. 20 asphalt are as hard grades of bitumen;Choosing Styrene-acrylic emulsion Acronal S 400F ap (solid content 57%) conduct produced with BASF Aktiengesellschaft is modified Agent;The anionic that asphalt emulsifier selects Shanghai Longfu Material Technology Co., Ltd. to produce splits asphalt emulsification slowly Agent EM-580;Thickening agent selects the hydroxyethyl cellulose CL-12 of Shanghai Longfu Material Technology Co., Ltd.; Acid-base modifier selects sodium hydroxide.Above-mentioned each material and water are weighed by following weight:
Soap lye is prepared: EM-580 is dissolved in 50 DEG C of-60 DEG C of hot water of about 30kg, and stirring is to dissolving, then will change Property agent Acronal S 400F ap and thickening agent CL-12 is added to the water, and stirs, adjusts with sodium hydroxide Joint pH value, to 10.5-11, then adds remaining hot water, and supplying overall solution weight is 60kg, is i.e. made into Soap lye is also incubated at 60 DEG C of baking ovens.
Emulsified asphalt is prepared: SK70 Colophonium is heated to 150 DEG C, then is heated to by No. 20 asphalt 160 DEG C, the two stirs under stirring;Mixed Colophonium and the above-mentioned 60 DEG C of soap lyes prepared In colloid mill, it is sufficiently mixed emulsifying, prepares not viscous wheel emulsified asphalt, and the emulsified asphalt prepared is placed in 70 DEG C of baking oven insulations are standby.
Two, Application Example
Embodiment 1
Not viscous for above-mentioned preparation embodiment 1 gained wheel emulsified asphalt is used for the adhesion coating spread of bituminous paving interlayer, Emulsified asphalt temperature, at 80 DEG C, is 0.6Kg/m according to spread quantity2, spread in bituminous paving, and with Common emulsified asphalt contrasts.Wherein surface drying experiment is shown in Table 1, is 30 DEG C at temperature, the present embodiment gained Viscous wheel emulsified asphalt was breakdown of emulsion, surface drying in 15 minutes, and tack-free.And commonly adhesion coating emulsifying drip Green grass or young crops then needs nearly 40 minutes just surface dryings, and easily touches with one's hand.
Use vehicle to roll test after surface drying, make vehicle tyre first pass through tack coat and roll plain paper immediately , thus evaluate the suppression adhesion effect of emulsified asphalt, as seen from Figure 1, common adhesion coating emulsified asphalt is easy Sticking wheel, and Colophonium adhesive tape paper crushes, the not viscous wheel emulsified asphalt of the present embodiment gained is then without sticking Phenomenon.
Embodiment 2
Not viscous for above-mentioned preparation embodiment 2 gained wheel emulsified asphalt is used for the adhesion coating spread of bituminous paving interlayer, Emulsified asphalt temperature, at 70 DEG C, is 0.6Kg/m according to spread quantity2, spread in bituminous paving, and with Common emulsified asphalt contrasts.Wherein surface drying experiment is shown in Table 1, is 30 DEG C at temperature, the present embodiment gained Viscous wheel emulsified asphalt was breakdown of emulsion, surface drying in 15 minutes, and tack-free.And commonly adhesion coating emulsifying drip Green grass or young crops then needs nearly 40 minutes just surface dryings, and easily touches with one's hand.
Use vehicle to roll test (seeing Fig. 1) after surface drying, make vehicle tyre first pass through tack coat and grind immediately Pressure paper blank, thus evaluates the suppression adhesion effect of emulsified asphalt, from Figure 2 it can be seen that common adhesion coating emulsifying Colophonium easily sticks wheel, and Colophonium adhesive tape paper crushes, and the not viscous wheel emulsified asphalt of the present embodiment gained Then without sticking phenomenon (seeing Fig. 3 and Fig. 4).
Table 1 surface drying Experimental Comparison test table
The most respectively the not viscous wheel adhesion coating emulsified asphalt formed in embodiment 1~2 is carried out oblique shear test, Shearing inclination is 45 degree, simulated roadway action of traffic loading lower stress condition, and inspection tack coat is resisted by going The ability of the shear stress that car load level power produces.In view of present invention is generally directed to maintaining process demand, Therefore gradation types selects the easy closely knit Ultra-thin asphalt of ECA-10, conventional modified AC-13 Colophonium coagulation Soil, experimental test picture is as shown in Figure 5 and Figure 6.
For reflecting tack coat practical working situation as far as possible, simulated field work progress, according to " below prefabricated Layer rut plate one brushing tack coat one roll upper strata bituminous concrete one cutting sample " order, rut plate become Cut into the test specimen of 50mmX50mm × 60mm after type with double-side saw, carry out 0 DEG C, 25 DEG C, 50 DEG C three respectively Individual temperature test, oblique scissor test result is as shown in table 2.
Table 2 shearing test result table
From above-mentioned realization and comparing result, the adhesion strength of the not viscous wheel emulsified asphalt of the present invention is better than general Logical emulsified asphalt;And it is little to be characterized in rising high intensity reduction amplitude with temperature, when test temperature is increased to 50 DEG C, Its shear strength in common emulsified asphalt tack coat, has the interlaminar bonding performance of excellence at double, has reached aobvious The technique effect write, effect is also beyond thought.
After the not viscous wheel emulsified asphalt breakdown of emulsion molding of the present invention, intensity is big, temperature influence is little, can spray in a large number Without worrying that bellding disease occurs in overlay;Strengthen fountain height (0.6~1.2Kg/m2Formed on road surface after) Hard coat, emulsion is penetrated into road surface minute crack, dead air space, is delayed crack progressing;It is particularly suited for road There is microcrack (< 2mm) in face, has crack progressing trend, but is not suitable for the disease incidence using milling to process; Thick matter is sprayed and is combined with overlay hot-mixed asphaltic concrete technique, can significantly prolonging service life of pavement.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The industry Skilled person will appreciate that, the present invention is not restricted to the described embodiments, in above-described embodiment and description The principle that the present invention is simply described described, without departing from the spirit and scope of the present invention, the present invention Also having various changes and modifications, these changes and improvements both fall within scope of the claimed invention.This The claimed scope of invention is defined by appending claims and equivalent thereof.

Claims (12)

1. not viscous wheel emulsified asphalt, it is characterised in that described emulsified asphalt includes accounting for its gross mass hundred The following ingredients of proportion by subtraction: 10%-50% matrix pitch, 10%-50% hard grades of bitumen, 0-5% polymer modification Agent, 0.3%-3% asphalt emulsifier, 0-1% thickening agent, acid-base modifier and water supply 100%.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described substrate drip Green grass or young crops uses asphalt, and Asphalt Penetration is 50dmm~100dmm.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described hard drip Green grass or young crops uses asphalt, and Asphalt Penetration is 5dmm~30dmm.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described polymer Modifying agent is pure-acrylic emulsion, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, polyaminoester emulsion, silicone acrylic emulsion, poly-acetic acid second One in alkene emulsion, vinyl acetate-ethylene copolymerization emulsions (EVA emulsion), polychloroprene latex, or by upper State in each emulsion that two or more is mixed to form with arbitrary proportion.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described Colophonium breast Agent for split soon type asphalt emulsifier, in split a kind of in type asphalt emulsifier or slow breaking asphalt emulsifier or two It is mixed to form with arbitrary proportion more than kind.
Not viscous wheel emulsified asphalt the most according to claim 5, it is characterised in that described Colophonium breast Agent is a kind of in cation asphalt emulgent, nonionic asphalt emulsifier or anionic asphalt emulsion, or Cation asphalt emulgent and other cation asphalt emulgent or nonionic asphalt emulsifier are with arbitrary proportion It is mixed to form, or anionic asphalt emulsion and other anionic asphalt emulsion or nonionic asphalt emulsifier It is mixed to form with arbitrary proportion.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described thickening agent For the one in methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol or modified starch.
Not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that described soda acid is adjusted Joint agent is the one in hydrochloric acid, phosphoric acid, sulphuric acid, sodium hydroxide or potassium hydroxide.
The preparation method of not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that institute State preparation method as follows:
(1) asphalt emulsifier is dissolved in 50 DEG C of-60 DEG C of hot water, then polymer modifiers and thickening agent are added In water, stir and regulate pH value, being made into soap lye;
(2) then matrix pitch is heated to 150 DEG C, then hard grades of bitumen is heated to 160 DEG C, the two Stir under stirring, and be maintained at 150 DEG C-160 DEG C;
(3) by mixing Colophonium together with soap lye through colloid mill high speed shear, obtain emulsified asphalt.
The construction technology of not viscous wheel emulsified asphalt the most according to claim 1, it is characterised in that its Spread temperature is between room temperature to 80 DEG C;If using and splitting emulsifying agent slowly, need to reach fast emulsion breaking, surface drying, Spread can be incubated at 70-80 DEG C.
The construction technology of 11. not viscous wheel emulsified asphalts according to claim 10, it is characterised in that Further, general spread quantity, 0.4~0.6Kg/m2, i.e. cannot not can reach viscously wheel, improves adhesion strength Effect;If strengthening spread quantity to 0.6~1.2Kg/m2, it is also possible to fill up cutting optimal minute crack, prolong Slow reflection crack produces.
The application of 12. not viscous wheel emulsified asphalts according to claim 1, it is characterised in that described breast Change the Colophonium application as the tack coat between bituminous paving interlayer or cement pavement repaving asphalt coat.
CN201610318351.6A 2016-05-13 2016-05-13 Wheel-sticking-free emulsified asphalt, preparation method, construction process and application thereof Active CN105924988B (en)

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CN106928732A (en) * 2017-04-20 2017-07-07 北京市政路桥建材集团有限公司 Normal temperature fast emulsion breaking, easily prepared anti-stick emulsified asphalt and preparation method thereof
CN106996904A (en) * 2017-04-20 2017-08-01 北京市政路桥建材集团有限公司 A kind of viscous wheel effect evaluation method of emulsified asphalt
CN107083232A (en) * 2017-05-26 2017-08-22 山西省交通科学研究院 A kind of bio-based does not glue wheel sticking layer oil and preparation method thereof
CN107099040A (en) * 2017-04-20 2017-08-29 北京市政路桥建材集团有限公司 The anti-of normal temperature fast emulsion breaking curing molding sticks emulsified asphalt and preparation method thereof
CN107189757A (en) * 2017-07-21 2017-09-22 张娟 A kind of preparation method of constructional engineering adhesive
CN108892961A (en) * 2018-07-26 2018-11-27 江苏增光复合材料科技有限公司 A kind of high viscosity modified emulsifying asphalt and preparation method thereof
CN108997766A (en) * 2018-09-03 2018-12-14 江苏中路工程技术研究院有限公司 A kind of hgh-performance emulsified pitch and preparation method thereof
CN109054409A (en) * 2018-06-25 2018-12-21 重庆交通大学 A kind of viscous micro- cover construction method of formula special asphalt of interlayer height
CN109135668A (en) * 2018-08-10 2019-01-04 陈娟 Glutinous not viscous wheel sticking layer oil of height and preparation method thereof
CN109370513A (en) * 2018-09-29 2019-02-22 南京兴佑交通科技有限公司 A kind of adhesion coating emulsified asphalt and preparation method thereof
CN110878174A (en) * 2018-09-06 2020-03-13 中国石油化工股份有限公司 Emulsified asphalt for non-stick wheel and preparation method thereof
CN111235998A (en) * 2020-01-16 2020-06-05 西安博望新材料科技有限公司 Low-noise embedded fiber wearing layer and construction method thereof
CN111471128A (en) * 2020-06-04 2020-07-31 甘肃省公路交通建设集团有限公司酒泉路衍产业开发分公司 Water-based acrylic elastic emulsion, preparation method thereof and application thereof in asphalt pavement
CN111621035A (en) * 2020-04-14 2020-09-04 南通通沙沥青科技有限公司 Emulsified asphalt and preparation method thereof
CN112280319A (en) * 2020-10-14 2021-01-29 河北伦特化工集团有限公司 Preparation method and application of non-sticky wheel modified emulsified asphalt
CN113105748A (en) * 2021-05-30 2021-07-13 南方高科工程技术有限公司 Super-viscous self-healing non-emulsified oil for sticking layer
CN115449231A (en) * 2022-09-30 2022-12-09 中路交科科技股份有限公司 High-toughness wheel-sticking-free emulsified asphalt and preparation method thereof
US11708508B2 (en) * 2019-03-15 2023-07-25 Russell Standard Corp. High performance tack coat

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106928732A (en) * 2017-04-20 2017-07-07 北京市政路桥建材集团有限公司 Normal temperature fast emulsion breaking, easily prepared anti-stick emulsified asphalt and preparation method thereof
CN106996904A (en) * 2017-04-20 2017-08-01 北京市政路桥建材集团有限公司 A kind of viscous wheel effect evaluation method of emulsified asphalt
CN107099040A (en) * 2017-04-20 2017-08-29 北京市政路桥建材集团有限公司 The anti-of normal temperature fast emulsion breaking curing molding sticks emulsified asphalt and preparation method thereof
CN107083232A (en) * 2017-05-26 2017-08-22 山西省交通科学研究院 A kind of bio-based does not glue wheel sticking layer oil and preparation method thereof
CN107189757A (en) * 2017-07-21 2017-09-22 张娟 A kind of preparation method of constructional engineering adhesive
CN109054409A (en) * 2018-06-25 2018-12-21 重庆交通大学 A kind of viscous micro- cover construction method of formula special asphalt of interlayer height
CN108892961A (en) * 2018-07-26 2018-11-27 江苏增光复合材料科技有限公司 A kind of high viscosity modified emulsifying asphalt and preparation method thereof
CN109135668A (en) * 2018-08-10 2019-01-04 陈娟 Glutinous not viscous wheel sticking layer oil of height and preparation method thereof
CN108997766A (en) * 2018-09-03 2018-12-14 江苏中路工程技术研究院有限公司 A kind of hgh-performance emulsified pitch and preparation method thereof
CN110878174A (en) * 2018-09-06 2020-03-13 中国石油化工股份有限公司 Emulsified asphalt for non-stick wheel and preparation method thereof
CN109370513A (en) * 2018-09-29 2019-02-22 南京兴佑交通科技有限公司 A kind of adhesion coating emulsified asphalt and preparation method thereof
US11708508B2 (en) * 2019-03-15 2023-07-25 Russell Standard Corp. High performance tack coat
CN111235998A (en) * 2020-01-16 2020-06-05 西安博望新材料科技有限公司 Low-noise embedded fiber wearing layer and construction method thereof
CN111621035A (en) * 2020-04-14 2020-09-04 南通通沙沥青科技有限公司 Emulsified asphalt and preparation method thereof
CN111471128A (en) * 2020-06-04 2020-07-31 甘肃省公路交通建设集团有限公司酒泉路衍产业开发分公司 Water-based acrylic elastic emulsion, preparation method thereof and application thereof in asphalt pavement
CN112280319A (en) * 2020-10-14 2021-01-29 河北伦特化工集团有限公司 Preparation method and application of non-sticky wheel modified emulsified asphalt
CN113105748A (en) * 2021-05-30 2021-07-13 南方高科工程技术有限公司 Super-viscous self-healing non-emulsified oil for sticking layer
CN113105748B (en) * 2021-05-30 2022-10-18 南方高科工程技术有限公司 Super-viscous self-healing non-emulsified oil for sticking layer
CN115449231A (en) * 2022-09-30 2022-12-09 中路交科科技股份有限公司 High-toughness wheel-sticking-free emulsified asphalt and preparation method thereof
CN115449231B (en) * 2022-09-30 2023-09-12 中路交科科技股份有限公司 High-toughness non-stick emulsified asphalt and preparation method thereof

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