CN105924903A - Novel tire sealing composite material containing 601 tackifying resin - Google Patents

Novel tire sealing composite material containing 601 tackifying resin Download PDF

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Publication number
CN105924903A
CN105924903A CN201610456752.8A CN201610456752A CN105924903A CN 105924903 A CN105924903 A CN 105924903A CN 201610456752 A CN201610456752 A CN 201610456752A CN 105924903 A CN105924903 A CN 105924903A
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CN
China
Prior art keywords
composite material
grams
tire
sealing composite
tackifying resin
Prior art date
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Pending
Application number
CN201610456752.8A
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Chinese (zh)
Inventor
冯智勇
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Individual
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Individual
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Priority to CN201610456752.8A priority Critical patent/CN105924903A/en
Publication of CN105924903A publication Critical patent/CN105924903A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • C08L71/03Polyepihalohydrins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a novel tire sealing composite material containing 601 tackifying resin and belongs to the technical field of tires. The formula is characterized by being composed of the 601 tackifying resin, epichlorohydrin rubber, a cross-linking agent BIPB (Bi(butylperoxyisopropyl)benzene), chlorinated polyethylene micro-powder, pine oil, crushed artificial protein fibers, a rubber antioxidant crotonaldehyde, epichlorohydrin rubber particles and epoxy soybean oil. The novel tire sealing composite material is mainly applied to a meridian vacuum tire and is the novel tire sealing composite material which can be used for rapidly self-repairing a notch (with the diameter smaller than or equal to 10mm), is not dried and frozen, is high in reliability and good in stability and is durable; the novel tire sealing composite material can be used in an environment at a temperature ranging from -60 DEG C to 108 DEG C for a long period. The product disclosed by the invention contains a plurality of types of macromolecular polymers; the state of the material in the tire is a sticky state with liquid and solid and can be stably and uniformly stuck on an inner wall of the tire for a long period, so that the dynamic balance of wheels is not influenced and a zero-leakage effect is also realized; compared with the prior art, the novel tire sealing composite material is definitely innovative improvement.

Description

Include the tire seal composite material of 601 tackifying resins
Technical field
The invention belongs to tyre technology, the present invention relates to a kind of self-complementary new material being applied to vacuum tire sealing, specifically relate to And be a kind of tire seal composite material including 601 tackifying resins.
Background technology
One of automobile and the various motor vehicles important symbol becoming modern civilization, during it uses, tire is by road surface Nail or tip and hard object matter puncture and cause disappointing, the phenomenon causing vehicle normally not exercise often occurs.Occur the earliest is automatic Tyre repairing fluid is to start application in U.S. army's wheeled vehicle in twenty or thirty age in last century, is filled with automatically in the tire of military vehicle Tyre repairing fluid, away from the present existing 80-90 history.Its advantage of the automatic mending tyre liquid of prior art is: tire patching need not take off tire, 3 seconds Mend;But, there is also more shortcoming: 1, affect the dynamic balancing of wheel: after employing a tank automatic mending tyre liquid, tire Remain the liquid of 200ml-300ml at inner bottom part, such as same eccentric when this liquid makes wheel operate, both add noise, Reduce again stability, therefore have impact on dynamic balancing when wheel operates and bring traffic safety hidden danger to a certain extent.2 , when tire wound diameter more than 6mm time automatic mending tyre liquid inoperative.3, also there is the automatic mending tyre liquid of some inflation pot types Product, its composition can only make the tire lost heart temporarily inflate and subtract leakage, till treating that nearest overhaul stand exercised by vehicle.4, have Tire repair liquid product can dry up or meet cold snap in tire and freeze, not only loses mending-leakage effect, can damage the interior of tire on the contrary Wall.
The content of invention
It is an object of the invention to: provide one to be applied in vacuum tire, do not affect the dynamic balancing of wheel, energy fast self-compensating breach is (straight Footpath is less than or equal to 10mm), do not dry up, do not freeze, reliability is high, good stability, the most durable tire seal new material.
For achieving the above object, the technical solution adopted in the present invention is to include the tire seal composite material of 601 tackifying resins, The feature of its formula is: by 601 tackifying resins, epichlorohydrin rubber, crosslinking agent B IPB, chlorinated polyethylene micropowder, Oleum Pini, artificial Azelon is broken, crotonic aldehyde, epichlorohydrin rubber granule, epoxy soybean oil form.
The percentage by weight of its component is:
The present invention tire seal composite material containing 601 tackifying resins compared with the existing technology has the following advantages and positive Effect: along with meridian vacuum tire the popularizing in the whole world of advanced technology, now, automatic benefit miscellaneous on market Tire liquid product is because of all reasons, it is difficult to permanently effective use, more cannot be with tire " the most lifelong ".Unlike the prior art: 1, invention applies include 601 tackifying resins and multiple high molecular polymer composition there is the compound new of liquid-solid state characteristic Material tire seal technology, during use, can arrive vehicle repairing factory or tire is taken apart by 4s shop, be uniformly coated with one layer on tire inner wall The product of the present invention, the product of the present invention includes multiple high molecular polymer, its state in tire be liquid-solid and deposit gluing State, energy is steady in a long-term and is uniformly adhered on tire inner wall, thus does not affect the dynamic balancing of wheel, this and prior art Compare the most revolutionary improvement.2, with the epichlorohydrin rubber granule that granularity is 80 mesh-400 mesh, artificial in the middle of the present invention Azelon is broken, filler made by chlorinated polyethylene micropowder, and they are highly dispersed in whole high score with the form of sponge shape network structure In sub-polymeric system, the material of main part of this system is 601 tackifying resins and epichlorohydrin rubber, and the composite material of the present invention can be with Liquid-solid ickiness exists, and is mainly combined and role by the high molecular polymer of multiple difference in functionality.Use After the product of the present invention, when vehicle is exercised, its tire is such as by the iron nail pierce through less than or equal to 10mm bore, before not pulling out iron nail, The new material that seals near iron nail wraps up the nail tip pierced in tire, until being sealed against, afterwards, is pulling out iron nail Moment does not haves gas leakage yet, can play the effect of zero leakage, and this also leads over prior art.3, the formula of the present invention In the middle of be provided with Oleum Pini and rubber antioxygen crotonic aldehyde, its effect is to play to soften and prevent the aging of product of the present invention;It is provided with cross-linking agent The effect of BIPB is: produces chemical bond between the molecule of line style, makes linear molecule be connected with each other, forms network structure, carry The intensity of high polymer and to increase it elastic;It is flexibility agent that the present invention is provided with epoxy soybean oil, makes the product of the present invention not dry up, energy Antirust, there are moist rubber tyre and the effect preventing rubber tyre from chapping.The product of the present invention can be at-60 DEG C~the environment of 108 DEG C Lower life-time service.The present invention includes the tire seal composite material of 601 tackifying resins and is better than prior art, the present invention Product be " can accompany lifelong with tire " innovative product.
Detailed description of the invention
The following examples are to prove the present invention further, the invention is not restricted to this.
Embodiment one
Including the tire seal composite material of 601 tackifying resins, its component and weight proportion are as follows:
The present invention includes the tire seal composite material of 601 tackifying resins, and its method prepared is: by 50 gram of 601 thickening tree Fat, 20 grams of epichlorohydrin rubbers, 3 grams of crosslinking agent B IPB, 4 grams of Oleum Pinis are put in an electrically heated stirred tank, are heated to 158 DEG C and treat Stir 14 minutes after Rong Rong, add 5 grams of epoxy soybean oils, 3 grams of rubber antioxygen crotonic aldehydes continue stirring 11 minutes, so After, add that 7 grams of chlorinated polyethylene micropowders, 4 grams of Azlons be broken, 4 grams of epichlorohydrin rubber granules (80 mesh-400 mesh) are continued Stir 13 minutes, complete after stirring, obtain the finished product that sicker is the present invention of yellowish-brown colour band speckle, by it from stirred tank In pour out, load in jar and complete.
Embodiment two
Including the tire seal composite material of 601 tackifying resins, its component and weight proportion are as follows:
Including the tire seal composite material of 601 tackifying resins, in addition to the weight proportion difference in its component, it is prepared Consistent with described in embodiment one of method.
Embodiment three
Including the tire seal composite material of 601 tackifying resins, its component and weight proportion are as follows:
Including the tire seal composite material of 601 tackifying resins, in addition to the weight proportion difference in its component, it is prepared Consistent with described in embodiment one of method.

Claims (2)

1. include the tire seal composite material of 601 tackifying resins, it is characterised in that: the percentage by weight of each component of this formula For: 601 tackifying resin 31%--59%, epichlorohydrin rubber 23%--39%, crosslinking agent B IPB1%--9%, chlorinated polyethylene Micropowder 2%--10%, Oleum Pini 1%--9%, the broken 1%--13% of Azlon, rubber antioxygen crotonic aldehyde 1% --11%, epichlorohydrin rubber granule (80 mesh--400 mesh) 2%--16%, epoxy soybean oil 1%--12%.
The tire seal composite material including 601 tackifying resins the most according to claim 1, is characterized in that: it is prepared Method: 50 gram of 601 tackifying resin, 20 grams of epichlorohydrin rubbers, 3 grams of crosslinking agent B IPB, 4 grams of Oleum Pinis are put into one and electrically heated stirs Mix in still, be heated to 158 DEG C and stir 14 minutes after melted, add 5 grams of epoxy soybean oils, 3 grams of rubber antioxygen Fructus Crotonis Aldehyde continues stirring 11 minutes, then, adds that 7 grams of chlorinated polyethylene micropowders, 4 grams of Azlons be broken, 4 grams of epichlorohydrin rubbers Granule (80 mesh-400 mesh) continues stirring 13 minutes, completes after stirring, and the sicker obtaining yellowish-brown colour band speckle is finished product, It is poured out from stirred tank, loads in jar and complete.
CN201610456752.8A 2016-06-14 2016-06-14 Novel tire sealing composite material containing 601 tackifying resin Pending CN105924903A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610456752.8A CN105924903A (en) 2016-06-14 2016-06-14 Novel tire sealing composite material containing 601 tackifying resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610456752.8A CN105924903A (en) 2016-06-14 2016-06-14 Novel tire sealing composite material containing 601 tackifying resin

Publications (1)

Publication Number Publication Date
CN105924903A true CN105924903A (en) 2016-09-07

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CN201610456752.8A Pending CN105924903A (en) 2016-06-14 2016-06-14 Novel tire sealing composite material containing 601 tackifying resin

Country Status (1)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1774486A (en) * 2003-04-14 2006-05-17 横滨橡胶株式会社 Sealer and method for its application
CN103146173A (en) * 2013-02-28 2013-06-12 谭贤志 Airtight tyre material prepared by blending ecichloro-hydrin rubber with poly vinyl alcohol and preparation method of aright tyre material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1774486A (en) * 2003-04-14 2006-05-17 横滨橡胶株式会社 Sealer and method for its application
CN103146173A (en) * 2013-02-28 2013-06-12 谭贤志 Airtight tyre material prepared by blending ecichloro-hydrin rubber with poly vinyl alcohol and preparation method of aright tyre material

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Application publication date: 20160907

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