CN105924860A - Electricity storage box of small power generation device - Google Patents
Electricity storage box of small power generation device Download PDFInfo
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- CN105924860A CN105924860A CN201610297218.7A CN201610297218A CN105924860A CN 105924860 A CN105924860 A CN 105924860A CN 201610297218 A CN201610297218 A CN 201610297218A CN 105924860 A CN105924860 A CN 105924860A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention relates to an electricity storage box of a small power generation device. The electricity storage box is connected with a power generator of the power generation device and internally provided with a containing cavity, and a storage battery and a power distribution device are installed in the containing cavity; a clamping structure is arranged on the storage battery and comprises a left chuck and a right chuck, a torsional spring is arranged between the left chuck and the right chuck, the left chuck and the right chuck are each provided with a handle and a clamping part, the handles are arranged at the top of the left chuck and the top of the right chuck, and the clamping parts are arranged in the middle of the left chuck and the middle of the right chuck. The clamping structure is made of a composite material prepared from 50-60 parts of polytetrafluoroethylene, 10-30 parts of polyimide, 5-20 parts of polycarbonate, 20-40 parts of coated montmorillonite, 5-15 parts of nano calcium carbide, 3-12 parts of silicon dioxide, 1-5 parts of a silane coupling agent and 3-15 parts of halogen-free flame retardant. The electricity storage box is convenient to assemble and disassemble and suitable for carry and use, the clamping structure is made of the composite material, and therefore the comprehensive performance of the electricity storage box is improved substantially.
Description
Technical field
The present invention relates to a kind of technical field of generators, particularly relate to the storage electricity box of a kind of small-sized electric generating apparatus.
Background technology
Society now, along with people are for demand more and more higher of the energy, the pollution that the energy brings is more and more tighter
Weight, people start to advocate energy-conserving and environment-protective, use green energy resource.Some small-sized electric generating apparatus enter people gradually
Life, such as self generation type wrist-watch, can be along with the swing power generation of arm.Existing one is for bicycle especially
Being the small-sized electric generating apparatus of bicycle, it is electricity that this device is mainly the power-conversion of wheel during bicycle walking
Power, drives the generator rotation of TRT to produce electric power at vehicle wheel rotation specifically.After TRT generating
Will be by the electrical power storage of generation in accumulator, existing accumulator is the most box shaped, it is desirable to have fixed installation position
Install, be not easy to dismount on bicycle, need design one storage electricity box, it is simple to enter at bicycle
The small-sized electric generating apparatus that coordinates of row dismounting uses.
Summary of the invention
The technical problem to be solved in the present invention is: provide the storage electricity box of a kind of small-sized electric generating apparatus, and this storage electricity box is tied
Structure is simple, and easy accessibility is practical.
In order to solve described technical problem, technical scheme: the storage electricity box of a kind of small-sized electric generating apparatus,
Being electrically connected with the electromotor of TRT, inside is provided with receiving chamber, accommodates intracavity and is provided with accumulator and power distribution equipment,
Described storage electricity box is provided with clamp structure, and described clamp structure includes left chuck and right chuck, a described left side
The connection place of chuck and right chuck is provided with torsion spring, left chuck and right chuck and is provided with and breaks hands and clamping part, described
Breaking hands and be arranged on left chuck and the top of right chuck, described clamping part is arranged on left chuck and the middle part of right chuck
Position；Described clamp structure is made up of composite, and described composite includes following constituent
And parts by weight:
Politef: 50-60 part
Polyimides: 10-30 part
Merlon: 5-20 part
Peplos montmorillonite: 20-40 part
Nano silicon carbide calcium: 5-15 part
Silicon dioxide: 3-12 part
Silane coupler: 1-5 part
Halogen-free flame retardants: 3-15 part.
The present invention material by reasonable compatibility housing, compounding use politef, polyimides, poly-carbonic acid
Ester is modified, and is also added with peplos montmorillonite, nano silicon carbide calcium, silicon dioxide etc. simultaneously.Wherein Merlon
There is the performance of excellence, the impact resistance of shell, oil resistant, the performance that acidproof and temperature resistant range is wide can be significantly improved,
Polyimides is because containing more rigid radical in strand, and creep resisting ability is strong, has good size steady
Qualitative, and heatproof reaches more than 400 DEG C, resistance to suddenly cold and hot, can life-time service temperature range-200～300 DEG C, profit
With the phenolphthalein type polyimides with special construction, politef is modified, simultaneously the poly-carbonic acid of compounding interpolation
Politef is modified by ester, and with other component synergism, improve politef poor rigidity,
The problems such as easy-cold flow, improve the hot strength of housing, stretch modulus, toughness, resistance to torsion, shock resistance, anti-ageing
Change, low temperature resistant, high temperature resistant, oil resistant, acidproof, corrosion-resistant, fire resistance etc., and then improve combining of storage electricity box
Close performance.
As preferably, the mean diameter of described politef is 20-30 μm, and bulk density is 260-400g/L.
As preferably, described Merlon is prepared ultra high molecular-weight polycarbonate powder weight average by triphosgene and divides
Son amount is 100000-110000.
As preferably, described peplos montmorillonite prepares by the following method: by montmorillonite at 550-580 DEG C
Sinter 6-8 hour, be cooled to room temperature, be subsequently adding and be equivalent to the alkyl polyglucoside of its weight 6-8%, 3-4%
Acrylic acid methyl ester., the deionized water of 3-5%, ultrasonic vibration is after 25-30 minute, then at 70-80 DEG C of water bath with thermostatic control
Middle agitating heating 25-35 minute, obtains modified mixed liquor；Add in modified mixed liquor again and be equivalent to its weight
The concentration of 8-12% is the AlCl3 solution of 30-35%, and being simultaneously introduced proper ammonia regulation pH value is 9-10,
After stirring 20-25min, after standing 3-4 hour, after filtration, washing, dried, at 620-640 DEG C
Sinter 3-5 hour, naturally cool to room temperature and get final product.
As preferably, the particle diameter of described nano silicon carbide calcium is 20-80nm.Further preferably, described nano-sized carbon
Acid calcium is modified nano calcium carbonate, and is modified by the following method: added at a high speed by nano-calcium carbonate powder
In kneader, it is heated to 80-100 DEG C, adds and be equivalent to the titanate coupling agent of powder weight 2-3%, 4-5%
Sodium stearate and the Oleum Cocois of 2-4%, under the rotating speed of 200-300r/min stir 10-15min, then
Dry at 80-90 DEG C, pulverized 100-150 mesh sieve.
As preferably, described silicon dioxide is nanometer silicon dioxide particle I and nanometer silicon dioxide particle II
Mixture, wherein the size of silica dioxide granule I is that 150-250 μm, the size of silica dioxide granule II are
500-600nm.The present invention granulated staged part system by two kinds of sizes, plays good potentiation,
When making stress impact simultaneously, large-size particle can also be collided while mutually colliding between little granule, enter
Row is repeatedly decayed, thus plays good damping of shocks effect, improves shock resistance and the rub resistance of clamp structure
Energy.
Further preferably, in the mixture of silica dioxide granule I and silica dioxide granule II, described titanium dioxide
The content of silicon grain I accounts for the 40-60% of mixture gross mass, and it is total that the content of silica dioxide granule II accounts for mixture
The 40-60% of quality.
As preferably, described halogen-free flame-retardant is the one in ammonium polyphosphate, melamine phosphate, piperazine
Or it is multiple.
The composite of described clamp structure also includes the constituent of some routines, as compatilizer, antioxidant,
Filler etc., all can be selected for the most commercially available.
As preferably, be provided with inclined-plane in the front portion of left chuck and right chuck, inclined-plane by left chuck and right chuck inside
Outward-dipping, inclined-plane is provided with anti-slip tank, inclined plane part constitutes described breaks hands.
Further preferably, described anti-slip tank is made up of epoxy resin composite material, epoxy resin composite material bag
Include following constituent and parts by weight thereof:
Epoxy resin: 80-100 part
The polymer resin of non-epoxy: 40-60 part
Aramid IIII fiber: 5-20 part
Modifying agent: 5-15 part
Firming agent: 2-8 part.
The Material cladding of anti-slip tank of the present invention uses epoxy resin and the polymer resin of non-epoxy, and by adding
Adding reinforcing material aramid IIII fiber, in filament wound composite, fiber subjects Main Load, epoxy resin
With the intrinsic potential that the polymer resin of non-epoxy gives full play to fiber, not only at longitudinal compression, cross directional stretch
Play an important role with under the load effects such as compression, shearing, also dominate other mechanical properties of composite resin,
Such as interlaminar shear strength and modulus, compressive strength and buckling strength etc..The high property that epoxy resin itself has
Can, by the compound action with the polymer resin of non-epoxy, more jointly act on aramid IIII fiber, improve
The combination property of anti-slip tank, the most high temperature resistant, corrosion-resistant, radiation hardness, weatherability, flame resistant, resistance to always
Change and wait the performance relevant with environment.
As preferably, described epoxy resin is bisphenol f type epoxy resin.
As preferably, the polymer resin of described non-epoxy is Noblen and ethylene/octene
The mixture that 3-5:1 in mass ratio mixes.
As preferably, described modifying agent is N, N'-(4,4'-methylenediphenyl) BMI, horse
One or both in maleic anhydride grafted polystyrene.
As preferably, described firming agent is one or both in triethylene tetramine, double focusing cyanamide.
Epoxy resin composite material also includes the constituent of some routines, such as compatilizer, antioxidant, solidification
Accelerator, auxiliary agent, filler etc., all can be selected for the most commercially available.
As preferably, in the middle part of described left chuck and right chuck, it is respectively provided with a camber line groove, in arc groove all
Being furnished with anti-skidding raised line, described camber line groove surrounds one connection holes of formation at left chuck and right chuck when closing.
As preferably, storage electricity box is additionally provided with illuminating lamp and controls the button of luminous lamp switch.
As preferably, described accumulator is arranged in left chuck or right chuck, is arranging the chuck of accumulator
On be additionally provided with LED display lamp and USB interface.
Compared with prior art, present invention have the advantage that
1, the present invention will store up electricity box arrange in clip like, during use, clip is opened, clamps the support of bicycle
Accumulator can be fixed by bar, during dismounting, opens clip, dismounts very convenient, is suitable to carry and makes
With.Storage electricity box is provided with the LED display lamp of illuminating lamp, USB interface and display battery electric quantity, practicality
Good.
2, the clamp structure during the present invention stores up electricity box is made up of the rational composite of compatibility, described composite wood
Material is compounding uses politef, polyimides, Merlon to be modified, be also added with simultaneously peplos montmorillonite,
Nano silicon carbide calcium, silicon dioxide etc., significantly improve the hot strength of clamp structure, stretch modulus, toughness, resistance to
Torsion, shock resistance, aging resistance, low temperature resistant, high temperature resistant, oil resistant, acidproof, corrosion-resistant, fire resistance etc.,
And then improve the combination property of storage electricity box.
3, the anti-slip tank during the present invention stores up electricity box is made up of epoxy resin composite material, and described epoxy resin is multiple
Condensation material compound use epoxy resin and the polymer resin of non-epoxy, and by adding reinforcing material aramid fiber III
Fiber, produces synergism together with other components, improves the combination property of anti-slip tank together, especially improves
High temperature resistant, corrosion-resistant, radiation hardness, weatherability, the flame resistant of anti-slip tank, the property relevant with environment such as ageing-resistant
Can, and then improve the combination property of storage electricity box.
Accompanying drawing explanation
Fig. 1 is present invention installation diagram in small-sized electric generating apparatus；
Fig. 2 is the structural representation of the present invention.
In figure, 3, electromotor；4, connecting tube；5, storage electricity box；6, button；7, LED display lamp；8、
Anti-slip tank；9, left chuck；10, connection holes；11, USB interface；12, right chuck.
Detailed description of the invention
Below by combining the drawings and specific embodiments, technical scheme is described in further detail.
Seeing in figure, the invention provides the storage electricity box 5 of a kind of small-sized electric generating apparatus, storage electricity box 5 passes through connecting tube
4 and electromotor 3 couple, be covered with electric wire in connecting tube 4, the electric energy that electromotor 3 generating produces is passed by electric wire
The accumulator being passed to store up in electricity box 5 stores.
Storage electricity box 5 is provided with the clamp structure of clip like, and clamp structure includes left chuck 9 and right chuck 12,
The end of left chuck 9 and right chuck 12 is formed with jaws, left chuck 9 and right chuck 12 and can be carried out by clamp mouth part
Break into two with one's hands.It is provided with torsion spring, under naturalness, due to the limit of torsion spring in the connection place of left chuck 9 and right chuck 12
Making, left chuck 9 and right chuck 12 are in closure state, and whole storage electricity box 5 is similar to box-shaped, it is simple to carry.
When to use this TRT to generate electricity, will be able to be stored up by the hands of breaking of left chuck 9 and right chuck 12 front end
Electricity box 5 is opened, left chuck 9 and right chuck 12 front end be provided with an inclined-plane, inclined-plane is by left chuck 9 He
The inner side of right chuck 12 is outward-dipping, is provided with anti-slip tank 8 on inclined-plane, it is simple to opening of storage electricity box 5.?
Respectively offering an arc groove at the medium position of left chuck 9 and right chuck 12, the arc on left chuck 9 is recessed
Arc groove on groove and right chuck 12 is symmetrical arranged, when left chuck 9 and right chuck 12 close, and two arcs
Connected in star surrounds one connection holes 10 of formation, during installation, only need to left chuck 9 and right chuck 12 be broken into two with one's hands, will
The connecting rod of arc groove alignment bicycle, then decontrols left chuck 9 and right chuck 12 so that it is clamp bicycle
Connecting rod.Further, the arc groove of left chuck 9 and right chuck 12 is evenly equipped with anti-skidding raised line,
Anti-skidding raised line can increase the coefficient of friction on connection holes 10 surface and bicycle rod surface, effectively prevents from storing up electricity box
5 slide on connecting rod.
Accumulator may be provided in the left chuck 9 of storage electricity box 5, it is possible to is arranged on the right chuck 12 of storage electricity box 5
In, the chuck at accumulator place it is provided with illuminating lamp and controls the button 6 of illuminating lamp, can be used for illuminating；More
On the chuck at accumulator place, further it is additionally provided with LED display lamp 7 He of display accumulator charge volume
Usb 11 is more convenient for the use of people.
Wherein, described clamp structure is made up of composite, and described composite includes that following composition becomes
Divide and parts by weight:
Politef: 50-60 part
Polyimides: 10-30 part
Merlon: 5-20 part
Peplos montmorillonite: 20-40 part
Nano silicon carbide calcium: 5-15 part
Silicon dioxide: 3-12 part
Silane coupler: 1-5 part
Halogen-free flame retardants: 3-15 part.
As preferably, the mean diameter of described politef is 20-30 μm, and bulk density is 260-400g/L.
As preferably, described Merlon is prepared ultra high molecular-weight polycarbonate powder weight average by triphosgene and divides
Son amount is 100000-110000.
As preferably, described peplos montmorillonite prepares by the following method: by montmorillonite at 550-580 DEG C
Sinter 6-8 hour, be cooled to room temperature, be subsequently adding and be equivalent to the alkyl polyglucoside of its weight 6-8%, 3-4%
Acrylic acid methyl ester., the deionized water of 3-5%, ultrasonic vibration is after 25-30 minute, then at 70-80 DEG C of water bath with thermostatic control
Middle agitating heating 25-35 minute, obtains modified mixed liquor；Add in modified mixed liquor again and be equivalent to its weight
The concentration of 8-12% is the AlCl3 solution of 30-35%, and being simultaneously introduced proper ammonia regulation pH value is 9-10,
After stirring 20-25min, after standing 3-4 hour, after filtration, washing, dried, at 620-640 DEG C
Sinter 3-5 hour, naturally cool to room temperature and get final product.
As preferably, the particle diameter of described nano silicon carbide calcium is 20-80nm.Further preferably, described nano-sized carbon
Acid calcium is modified nano calcium carbonate, and is modified by the following method: added at a high speed by nano-calcium carbonate powder
In kneader, it is heated to 80-100 DEG C, adds and be equivalent to the titanate coupling agent of powder weight 2-3%, 4-5%
Sodium stearate and the Oleum Cocois of 2-4%, under the rotating speed of 200-300r/min stir 10-15min, then
Dry at 80-90 DEG C, pulverized 100-150 mesh sieve.
As preferably, described silicon dioxide is nanometer silicon dioxide particle I and nanometer silicon dioxide particle II
Mixture, wherein the size of silica dioxide granule I is that 150-250 μm, the size of silica dioxide granule II are
500-600nm。
Further preferably, in the mixture of silica dioxide granule I and silica dioxide granule II, described titanium dioxide
The content of silicon grain I accounts for the 40-60% of mixture gross mass, and it is total that the content of silica dioxide granule II accounts for mixture
The 40-60% of quality.
As preferably, described halogen-free flame-retardant is the one in ammonium polyphosphate, melamine phosphate, piperazine
Or it is multiple.
The composite of described clamp structure also includes the constituent of some routines, as compatilizer, antioxidant,
Filler etc., all can be selected for the most commercially available.
Described anti-slip tank 8 is made up of epoxy resin composite material, and epoxy resin composite material includes following group
One-tenth composition and parts by weight thereof:
Epoxy resin: 80-100 part
The polymer resin of non-epoxy: 40-60 part
Aramid IIII fiber: 5-20 part
Modifying agent: 5-15 part
Firming agent: 2-8 part.
As preferably, described epoxy resin is bisphenol f type epoxy resin.
As preferably, the polymer resin of described non-epoxy is Noblen and ethylene/octene
The mixture that 3-5:1 in mass ratio mixes.
As preferably, described modifying agent is N, N'-(4,4'-methylenediphenyl) BMI, horse
One or both in maleic anhydride grafted polystyrene.
As preferably, described firming agent is one or both in triethylene tetramine, double focusing cyanamide.
Epoxy resin composite material also includes the constituent of some routines, such as compatilizer, antioxidant, solidification
Accelerator, auxiliary agent, filler etc., all can be selected for the most commercially available.
Below by specific embodiment, the clamp structure in storage electricity box and anti-slip tank 8 are described further.
Embodiment 1
The storage electricity box of a kind of small-sized electric generating apparatus as shown in Figure 1-2, clamp structure is made up of composite, institute
The anti-slip tank 8 stated is made up of epoxy resin composite material.
The composite of described clamp structure includes following constituent and parts by weight thereof: politef:
55 parts, polyimides: 20 parts, Merlon: 15 parts, peplos montmorillonite: 30 parts, nano silicon carbide calcium:
10 parts, silicon dioxide: 8 parts, silane coupler: 3 parts, ammonium polyphosphate: 8 parts.Wherein, described two
Silicon oxide is nanometer silicon dioxide particle I and the mixture of nanometer silicon dioxide particle II, at silica dioxide granule
I and silica dioxide granule II mixture in, the content of described silica dioxide granule I accounts for mixture gross mass
50%, the content of silica dioxide granule II accounts for the 50% of mixture gross mass, and the size of silica dioxide granule I is
150-250 μm, the size of silica dioxide granule II are 500-600nm.The composite of described housing also includes
The constituent of some routines, such as compatilizer, antioxidant, filler etc., all can be selected for the most commercially available.
The epoxy resin composite material of described anti-slip tank includes following constituent and parts by weight thereof: Bisphenol F
Type epoxy resin: 90 parts, the polymer resin of non-epoxy: 50 parts, aramid IIII fiber: 10 parts, modification
Agent: 10 parts, firming agent: 5 parts.The polymer resin of described non-epoxy be Noblen with ethylene/
The mixture that octene copolymer 4:1 in mass ratio mixes；Described modifying agent is N, N'-(4,4'-methylene
Diphenyl) BMI；Described firming agent is triethylene tetramine.Epoxy resin composite material also includes
The constituent of some routines, such as compatilizer, antioxidant, curing accelerator, auxiliary agent, filler etc., all
Can be selected for the most commercially available.
Embodiment 2
Difference with embodiment 1 is: the composite of described clamp structure include following constituent and
Parts by weight: politef: 52 parts, polyimides: 25 parts, Merlon: 10 parts, peplos cover de-
Soil: 35 parts, nano silicon carbide calcium: 8 parts, silicon dioxide: 5 parts, silane coupler: 4 parts, phosphoric acid trimerization
Cyanamide: 12 parts.Wherein, described silicon dioxide is nanometer silicon dioxide particle I and nano silicon
The mixture of grain II, in the mixture of silica dioxide granule I and silica dioxide granule II, described silicon dioxide
The content of granule I accounts for the 45% of mixture gross mass, and the content of silica dioxide granule II accounts for mixture gross mass
55%, the size of silica dioxide granule I is that 150-250 μm, the size of silica dioxide granule II are
500-600nm。
The epoxy resin composite material of described anti-slip tank includes following constituent and parts by weight thereof: Bisphenol F
Type epoxy resin: 85 parts, the polymer resin of non-epoxy: 55 parts, aramid IIII fiber: 15 parts, modification
Agent: 8 parts, firming agent: 6 parts.The polymer resin of described non-epoxy be Noblen with ethylene/
The mixture that octene copolymer 4:1 in mass ratio mixes；Described modifying agent is N, N'-(4,4'-methylene
Diphenyl) BMI and maleic anhydride grafted polystyrene arbitrarily than mixture；Described solidification
Agent be triethylene tetramine with double focusing cyanamide arbitrarily than mixture.
Embodiment 3
Difference with embodiment 1 is: the composite of described clamp structure include following constituent and
Parts by weight: politef: 50 parts, polyimides: 30 parts, Merlon: 5 parts, peplos cover de-
Soil: 40 parts, nano silicon carbide calcium: 5 parts, silicon dioxide: 12 parts, silane coupler: 1 part, phosphoric acid trimerization
Cyanamide: 15 parts.Wherein, described silicon dioxide is nanometer silicon dioxide particle I and nano silicon
The mixture of grain II, in the mixture of silica dioxide granule I and silica dioxide granule II, described silicon dioxide
The content of granule I accounts for the 60% of mixture gross mass, and the content of silica dioxide granule II accounts for mixture gross mass
40%, the size of silica dioxide granule I is that 150-250 μm, the size of silica dioxide granule II are
500-600nm。
The epoxy resin composite material of described anti-slip tank includes following constituent and parts by weight thereof: Bisphenol F
Type epoxy resin: 80 parts, the polymer resin of non-epoxy: 60 parts, aramid IIII fiber: 5 parts, modification
Agent: 15 parts, firming agent: 2 parts.The polymer resin of described non-epoxy be Noblen with ethylene/
The mixture that octene copolymer 3:1 in mass ratio mixes；Described modifying agent is that maleic anhydride grafting is poly-
Styrene；Described firming agent is triethylene tetramine.
Embodiment 4
Difference with embodiment 1 is: the composite of described clamp structure include following constituent and
Parts by weight: politef: 60 parts, polyimides: 10 parts, Merlon: 20 parts, peplos cover de-
Soil: 20 parts, nano silicon carbide calcium: 5 parts, silicon dioxide: 12 parts, silane coupler: 1 part, piperazine: 15
Part.Wherein, described silicon dioxide is nanometer silicon dioxide particle I and the mixing of nanometer silicon dioxide particle II
Thing, in the mixture of silica dioxide granule I and silica dioxide granule II, containing of described silica dioxide granule I
Amount accounts for the 40% of mixture gross mass, and the content of silica dioxide granule II accounts for the 60% of mixture gross mass, and two
The size of silicon oxide particle I be 150-250 μm, the size of silica dioxide granule II be 500-600nm.
The epoxy resin composite material of described anti-slip tank includes following constituent and parts by weight thereof: Bisphenol F
Type epoxy resin: 100 parts, the polymer resin of non-epoxy: 40 parts, aramid IIII fiber: 20 parts, change
Property agent: 5 parts, firming agent: 8 parts.The polymer resin of described non-epoxy be Noblen with ethylene/
The mixture that octene copolymer 5:1 in mass ratio mixes；Described modifying agent is N, N'-(4,4'-methylene
Diphenyl) BMI；Described firming agent is double focusing cyanamide.
The mean diameter of the politef described in above-described embodiment 1-4 clamp structure composite is
20-30 μm, bulk density is 260-400g/L.Described Merlon is prepared supra polymer by triphosgene
Amount polycarbonate powder weight average molecular weight is 100000-110000.Described peplos montmorillonite is all by such as lower section
Method prepares: montmorillonite is sintered 6-8 hour at 550-580 DEG C, is cooled to room temperature, is subsequently adding and is equivalent to
The alkyl polyglucoside of its weight 6-8%, the acrylic acid methyl ester. of 3-4%, the deionized water of 3-5%, ultrasonic vibration 25-30
After minute, agitating heating 25-35 minute in 70-80 DEG C of water bath with thermostatic control, obtain modified mixed liquor；Changing again
Property mixed liquor in add and be equivalent to the AlCl that concentration is 30-35% of its weight 8-12%3Solution, is simultaneously introduced
Proper ammonia regulation pH value is 9-10, after stirring 20-25min, after standing 3-4 hour, through filtering, washing
Wash, after dried, sinter 3-5 hour at 620-640 DEG C, naturally cool to room temperature and get final product.Described nanometer
Acetylenogen. is the modified nano calcium carbonate of particle diameter 20-80nm, and this modified nano calcium carbonate is all by such as lower section
Method is modified: is added in high-speed kneading machine by nano-calcium carbonate powder, is heated to 80-100 DEG C, adds quite
In the titanate coupling agent of powder weight 2-3%, the sodium stearate of 4-5% and the Oleum Cocois of 2-4%,
Stir 10-15min under the rotating speed of 200-300r/min, then dry at 80-90 DEG C, pulverized 100-150 mesh
Sieve.
The present invention will store up electricity box and arrange in clip like, be opened by clip during use, clamp the steady arm of bicycle i.e.
Accumulator can be fixed, during dismounting, open clip, dismount very convenient, be suitable to carry use.
Being provided with the LED display lamp of illuminating lamp, USB interface and display battery electric quantity on storage electricity box, practicality is good；
And use the rational composite of compatibility to make clamp structure and anti-slip tank, significantly improve the comprehensive of storage electricity box
Energy.
Specific embodiment described herein is only to present invention spirit explanation for example.Skill belonging to the present invention
Described specific embodiment can be made various amendment or supplements or use by the technical staff in art field
Similar mode substitutes, but without departing from the spirit of the present invention or surmount defined in appended claims
Scope.
Claims (10)
1. a storage electricity box for small-sized electric generating apparatus, is electrically connected with the electromotor of TRT, and inside is provided with receiving
Chamber, accommodates intracavity and is provided with accumulator and power distribution equipment, it is characterised in that described storage electricity box is provided with clamping
Structure, described clamp structure includes that left chuck and right chuck, described left chuck and the connection place of right chuck set
Having torsion spring, left chuck and right chuck to be provided with and break hands and clamping part, described hands of breaking is arranged on left chuck and right folder
The top of head, described clamping part is arranged at the medium position of left chuck and right chuck；Described clamp structure
Being made up of composite, described composite includes following constituent and parts by weight thereof:
Politef: 50-60 part
Polyimides: 10-30 part
Merlon: 5-20 part
Peplos montmorillonite: 20-40 part
Nano silicon carbide calcium: 5-15 part
Silicon dioxide: 3-12 part
Silane coupler: 1-5 part
Halogen-free flame retardants: 3-15 part.
The storage electricity box of small-sized electric generating apparatus the most according to claim 1, it is characterised in that described poly-four
The mean diameter of fluorothene is 20-30 μm, and bulk density is 260-400g/L.
The storage electricity box of small-sized electric generating apparatus the most according to claim 1, it is characterised in that described is poly-
It is 100000-110000 that carbonic ester is prepared ultra high molecular-weight polycarbonate powder weight average molecular weight by triphosgene.
The storage electricity box of small-sized electric generating apparatus the most according to claim 1, it is characterised in that described two
Silicon oxide is nanometer silicon dioxide particle I and the mixture of nanometer silicon dioxide particle II, wherein silicon dioxide
The size of grain I be 150-250 μm, the size of silica dioxide granule II be 500-600nm.
The storage electricity box of small-sized electric generating apparatus the most according to claim 4, it is characterised in that in titanium dioxide
In the mixture of silicon grain I and silica dioxide granule II, it is total that the content of described silica dioxide granule I accounts for mixture
The 40-60% of quality, the content of silica dioxide granule II accounts for the 40-60% of mixture gross mass.
The storage electricity box of small-sized electric generating apparatus the most according to claim 1, it is characterised in that at left chuck
Being provided with inclined-plane with the front portion of right chuck, inclined-plane, by outward-dipping inside left chuck and right chuck, is provided with on inclined-plane
Anti-slip tank, inclined plane part constitutes described breaks hands.
The storage electricity box of small-sized electric generating apparatus the most according to claim 6, it is characterised in that described is anti-
Chute is made up of epoxy resin composite material, and epoxy resin composite material includes following constituent and weight thereof
Number:
Epoxy resin: 80-100 part
The polymer resin of non-epoxy: 40-60 part
Aramid IIII fiber: 5-20 part
Modifying agent: 5-15 part
Firming agent: 2-8 part.
The storage electricity box of small-sized electric generating apparatus the most according to claim 7, it is characterised in that described ring
Epoxy resins is bisphenol f type epoxy resin, and the polymer resin of described non-epoxy is Noblen and ethylene
The mixture that/octene copolymer 3-5:1 in mass ratio mixes.
The storage electricity box of small-sized electric generating apparatus the most according to claim 7, it is characterised in that described changes
Property agent is N, in N'-(4,4'-methylenediphenyl) BMI, maleic anhydride grafted polystyrene
One or both.
The storage electricity box of small-sized electric generating apparatus the most according to claim 6, it is characterised in that a described left side
It is respectively provided with a camber line groove in the middle part of chuck and right chuck, in arc groove, is evenly equipped with anti-skidding raised line, described arc
Line groove surrounds one connection holes of formation at left chuck and right chuck when closing；Storage electricity box is additionally provided with illuminating lamp
And control the button of luminous lamp switch；Described accumulator is arranged in left chuck or right chuck, is arranging
LED display lamp and USB interface it is additionally provided with on the chuck of accumulator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610297218.7A CN105924860A (en) | 2016-05-06 | 2016-05-06 | Electricity storage box of small power generation device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610297218.7A CN105924860A (en) | 2016-05-06 | 2016-05-06 | Electricity storage box of small power generation device |
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Family
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| CN201610297218.7A Pending CN105924860A (en) | 2016-05-06 | 2016-05-06 | Electricity storage box of small power generation device |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101189293A (en) * | 2005-09-28 | 2008-05-28 | 通用电气公司 | Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
| CN205131471U (en) * | 2015-11-17 | 2016-04-06 | 长安大学 | A wind power generation portable power source equipment for on bicycle |
-
2016
- 2016-05-06 CN CN201610297218.7A patent/CN105924860A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101189293A (en) * | 2005-09-28 | 2008-05-28 | 通用电气公司 | Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
| CN205131471U (en) * | 2015-11-17 | 2016-04-06 | 长安大学 | A wind power generation portable power source equipment for on bicycle |
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