CN105924060B - A kind of blast furnace resistance rust anti-corrosion non-shrinkage concrete and preparation method thereof - Google Patents
A kind of blast furnace resistance rust anti-corrosion non-shrinkage concrete and preparation method thereof Download PDFInfo
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- CN105924060B CN105924060B CN201610273650.2A CN201610273650A CN105924060B CN 105924060 B CN105924060 B CN 105924060B CN 201610273650 A CN201610273650 A CN 201610273650A CN 105924060 B CN105924060 B CN 105924060B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/346—Materials exhibiting reduced plastic shrinkage cracking
Abstract
The present invention relates to a kind of blast furnace resistance rust anti-corrosion non-shrinkage concretes and preparation method thereof, belong to building material technical field.A kind of blast furnace of present invention resistance rust anti-corrosion non-shrinkage concrete, is made of the component of following parts by weight:240~290 parts of cement;100~170 parts of hearthstone powder;160~200 parts of water;950~1150 parts of coarse aggregate;700~850 parts of fine aggregate;4~10 parts of corrosion inhibitor;2~7 parts of water-reducing agent;1~5 part of swelling agent.The present invention prepares the concrete for meeting the anti-rotten resistance rust in salt-soda soil and ungauged regions characteristic using specific components and proportioning, and workability is good, intensity is high, and the construction time is convenient for control, concrete construction facility;Formula is simple, has saved great amount of cost, and preparation method is simple and practicable, is not necessarily to mineral admixture, can at home and abroad be applicable.
Description
Technical field
Present invention relates particularly to a kind of blast furnace resistance rust anti-corrosion non-shrinkage concretes and preparation method thereof, belong to construction material
Technical field.
Background technology
For marine structure, sea sand building and varieties in saline-alkali areas building, contain a large amount of chlorine in coastal area or ambient enviroment
Ion and sulfate ion easily generate corrosion effect to reinforcing bar and concrete, reduce concrete basicity, destroy the blunt of rebar surface
Change film, cause steel bar corrosion and expansion, further result in crack and peeling, structure uses function and mechanical property
It can constantly deteriorate.For this purpose, expert proposes that various measures improve the anti-corrosion ability of concrete structure both at home and abroad, wherein in concrete
It is exactly a kind of economical and practical, easy construction effective measures to add corrosion inhibitor.
Concrete foundation is chronically in the environment of this high chloride ion and sulfate ion, can be because Chloride Attack is mixed
Solidifying soil leads to reinforcement corrosion and makes structure that Random early Detection occur, loses the endurance quality of structure, reduce actually making for engineering
With the service life, so must take into consideration the anti-corrosion of concrete structure in terms of mix Design, it has also become in Practical Project
Major issue.
Currently, the thinking of anticorrosive mix Design is " low hydration heat, low internal stress, low early strength ",
Cementitious matter of the low hydration heat cement as mass concrete is used, keeps the early stage internal stress of concrete low, while early stage
Intensity is also very low.And it is more demanding for strength grade and require tighter mass concrete, use existing the construction period
Match ratio be related to technology and be extremely difficult to coastal area high-strength anti-corrosion performance requirement, and the performances such as final concrete strength are not yet
It can meet the requirements.
Non-shrinkage concrete is more in foreign study at present, has been the product of relative maturity, such as American scientist
Lossier is prepared for chemical pre-stressed concrete before and after 1936 using the expansion of entringite, has established important base
Plinth.Then, the U.S. starts to research and develop expansive concrete.1958, American's A. Klein Gordon equations succeeded in developing a kind of aluminium sulfate type
Cement is named K cement, and achieves the patent of expanding cement.The cement started to be used for expansive concrete in 1963, and
Mass production is promoted the use of in various structures.
Between 1965~1972 years, Japan has purchased U.S.'s K-type expanding cement patent, and on this basis, succeeds in developing
Sulphoaluminate expander (Calcium Sulfo-Aluminate, abbreviation CSA).1970, the Japanese fields little Ye company also successfully opened
Lime swelling agent, later stage the 1990s are sent out, the P.K.Mehta in the U.S. etc. is to solve temperature difference of mass concrete crack
Problem, it is proposed that the imagination of 5%MgO, and the magnesia class swelling agent etc. that has thus been born are mixed in cement.Domestic swelling agent
Technology development is later, but makes rapid progress.
The famous Crack Control expert Wang Tiemeng professor analysis and summary personal experiences in China and survey data both domestic and external think:
The Causes of Fracture of mechanism object in engineering practice accounts for about 80% caused by belonging to deformation variation (temperature, contraction, differential settlement)
More than;Belong to and accounts for about 20% or so caused by load.Cast-in-place concrete structure is before normal use, i.e., frequent in construction period
Generate crack, at this point, structure usually not yet bears whole load under normal use, this crack mostly because of indirectly-acting such as
Non- load (contraction, temperature etc.) causes, this crack is known as concrete " construction period indirect crack ", and construction period is split indirectly
The main reason for seam occurs is the contraction of concrete, and therefore, it is that solution is this that swelling agent is added in concrete preparation process
Problem best bet.Swelling agent is mainly used in material production, and relatively conventional is cement expansive material and refractory material
Swelling agent.With unshape refractory hardening process, the shrinkage character of Chang Yinwei raw material itself causes to crack concrete.Draw
It is to introduce quantitative volume expansion with swelling agent, the shrinkage value of compensating material itself prevents material from shrinkage cracking, shadow occur
Ring its structure, function and appearance.In recent years, as composite material researches and develops use extensively, intumescent material also obtains industry-by-industry
Pay attention to, is widely used in the manufacturing of material.
Domestic market also lacks multiple functional, and the concrete product of excellent combination property, many key projects must not
It does not spend huge sums and induces one from foreign countries, it is not only expensive, application risk is also added, is researched and developed thus in a kind of blast furnace project, such as stake
The concrete material of the construction demand of the construction parts such as core basis, frame foundation, Equipment Foundations is of great immediate significance.
Invention content
The technical problem to be solved by the present invention is to provide a kind of at low cost, the not only performance with corrosion-prevention rust-resistance, but also with no receipts
The multifunctional concrete of contracting performance.
A kind of blast furnace of present invention resistance rust anti-corrosion non-shrinkage concrete, is made of the component of following parts by weight:
Wherein, the cement is preferably Portland cement, more preferably 42.5R cement.
The coarse aggregate is preferably rubble, more preferably uses grain size for 5~10mm continuous grading microliths, microlith meets state
Mark the regulation to continuous size fraction in GB/T14685-2011.
The fine aggregate is preferably river sand, more preferably uses the river sand of fineness modulus 2.7~2.9, more preferably uses fineness
The river sand of modulus 2.8.
Water-reducing agent commonly used in the art is suitable for the present invention, it is preferred that the water-reducing agent is poly carboxylic acid series water reducer, naphthalene
At least one of based water reducer, ligninsulfonate water-reducing agent, more preferably poly carboxylic acid series water reducer.
A kind of blast furnace described above resistance rust anti-corrosion non-shrinkage concrete, wherein the corrosion inhibitor is nitrite, phosphorus
The compound corrosion inhibitor of hydrochlorate, carbonate, aliphatic ester, MCI, sodium benzoate, sodium chromate, stannous chloride, silicate sodium benzoate,
At least one of calcium formate;Preferably compound corrosion inhibitor, the compound corrosion inhibitor are sodium benzoate+sodium nitrite, Asia
One kind in calcium nitrate+sodium nitrite+calcium formate.
A kind of blast furnace described above resistance rust anti-corrosion non-shrinkage concrete, wherein the swelling agent be calcium sulphoaluminate class,
At least one of calcium sulphoaluminate-calcium oxide, calcium oxide;One kind preferably in calcium sulphoaluminate class.
Further, technical solution more preferably, a kind of blast furnace resistance rust anti-corrosion non-shrinkage concrete described above,
It is preferred that being made of the component of following parts by weight:
It is mixed that second technical problem that the present invention solves is to provide a kind of blast furnace resistance rust anti-corrosion ungauged regions of the present invention
Coagulate the preparation method of soil.
Coarse aggregate, fine aggregate, cement and hearthstone powder, corrosion inhibitor, swelling agent are added in concrete mixer and are stirred successively
It mixes uniformly, while water-reducing agent being added in concrete mixing water and is uniformly mixed, then add water and water-reducing agent mixing liquid
Enter into concrete mixer, after being sufficiently stirred 1~2.5min, take out, a kind of blast furnace resistance rust anti-corrosion ungauged regions are obtained after construction
Concrete.
The present invention mainly by choosing the raw material such as concrete cement, sand, stone, additive, carries out concrete mix and sets
Meter adds corrosion inhibitor, hearthstone powder and the swelling agent of certain ingredients in concrete mix, does not add mineral admixture, to
Reduce the heat of hydration of concrete.Tested by mix Design, using specific components and proportioning prepare meet it is saline and alkaline
The concrete of anti-corruption characteristic under ground and coastal area environment.Compared with prior art, the present invention has the advantages that:
1) blast furnace of the present invention is good with anti-rotten resistance rust non-shrinkage concrete workability, intensity is high, and setting time can pass through
The dosage control of water-reducing agent is adjusted, the construction time is convenient for control, concrete construction facility.42.5R cement can be used, what is obtained is mixed
Solidifying soil intensity is high, strength grade C45, is suitable for the tighter anti-rotten resistance rust non-shrinkage concrete of construction period requirement.
2) present invention use certain content cement, sand, stone, water-reducing agent and water, by add special ratios corrosion inhibitor,
Hearthstone powder and swelling agent make the corrosion resistance of its concrete greatly improve, wherein swelling agent and cement, the Shui Shui in concrete
Change reaction to generate the crystallization that volume becomes larger, is expanded so as to cause volume of concrete, generate certain prestressing force, it is mixed to help control
Solidifying soil shrinkage cracking so that concrete has good anti-contracility energy;In addition, because adding corrosion inhibitor so that concrete
Also there is good resistance rust effect, the concrete fully met under domestic and international salt-soda soil environment uses.
3) blast furnace of the present invention is simple with anti-rotten resistance rust non-shrinkage concrete formula, efficiently utilizes Vietnam's locality concrete
Raw material have saved great amount of cost, and preparation method is simple and practicable, are not necessarily to mineral admixture, can be pushed away in Vietnam and domestic salt-soda soil
Wide application.
Specific implementation mode
A kind of blast furnace of present invention resistance rust anti-corrosion non-shrinkage concrete, is made of the component of following parts by weight:
The weight ratio of water used and cement is known as the ratio of mud when mixing concrete, and the ratio of mud influences the rheology of concrete
Compactness after performance, cement mortar coherent structure and its hardening, thus in the case where composition material is given, the ratio of mud is to determine
Determine the major parameter of concrete strength, durability and other a series of physical mechanical properties.To certain cement, just there are one most suitable
Suitable ratio, it is excessive or it is too small all the performances such as intensity can be made to be affected, the ratio of mud is too small to make the heat of hydration larger, and concrete is easy
Cracking, the workability of concrete is poor, is unfavorable for on-site construction operations, the ratio of mud, which crosses conference, reduces the intensity of concrete, thus this hair
The ratio of mud of bright colored concrete of misfiring uses 0.55~0.83, and concrete can not only be made to have good workability, moreover it is possible to
Meet the mechanical property and intensity requirement of concrete.
Wherein, the cement is preferably Portland cement, more preferably 42.5R cement.The cement has intensity
The features such as height, the heat of hydration are big, and frost resistance is good, drying shrinkage is small, and wearability is preferable, carbonization resistance is preferable, can meet special construction place
Requirement to concrete strength.
The coarse aggregate is preferably rubble, more preferably uses grain size for 5~10mm continuous grading microliths, microlith meets state
Mark the regulation to continuous size fraction in GB/T14685-2011.
The fine aggregate is preferably river sand, more preferably uses the river sand of fineness modulus 2.7~2.9, more preferably uses fineness
The river sand of modulus 2.8.River sand be natural stone in its natural state, active force through water collides repeatedly for a long time, rubbing generates,
River sand particle is round and smooth, cleaner, and clay content is few, weak to additive adsorptivity, can give full play to the effect of additive, prepares
Concrete workability out is good, convenient construction, and concrete is not easy to crack because aggregate clay content is high.
Water-reducing agent commonly used in the art is suitable for the present invention, it is preferred that the water-reducing agent is poly carboxylic acid series water reducer, naphthalene
At least one of based water reducer, ligninsulfonate water-reducing agent, more preferably poly carboxylic acid series water reducer.
A kind of blast furnace described above resistance rust anti-corrosion non-shrinkage concrete, wherein the corrosion inhibitor can be selected to sow
Class:Such as compound corrosion inhibitor of nitrite, phosphate, carbonate, aliphatic ester, MCI.Wherein Anodic Type corrosion inhibitor is using most
Extensive material has:Sodium nitrite, calcium nitrite, sodium benzoate, sodium chromate and stannous chloride etc.;Cathode type corrosion inhibitor is using most
Extensive material has (1) surfactant substance:Higher aliphatic acid ammonium salt, phosphate ester etc., cost is higher, and effect is not so good as anode
Type is good, but safety;(2) inorganic salts:Sodium carbonate, dibastic sodium phosphate silicates etc. have certain resistance rust effect, but volume compared with
Greatly;Some substances can improve the resistance of anode and cathode asked, to prevent electrochemical reaction process, prevent steel bar corrosion, because
And the present invention preferentially selects compound corrosion inhibitor, i.e., it is a variety of to hinder being used cooperatively for rust ingredient, due to synergistic effect, resultant effect
It is significantly better than the corrosion inhibitor of one-component.Such as:Sodium benzoate+sodium nitrite;Calcium nitrite+sodium nitrite+calcium formate etc..
Hearthstone powder of the present invention is a kind of blast furnace mountain flour, be steel mill during refining the pig iron, in order to reduce
Production temperature and add lime stone as fluxing agent make iron oxide restore derived from product, cool down, be ground into through water quenching method
Fine-powdered is blast furnace mountain flour, abbreviation hearthstone powder.Its chemical composition is mainly silica, aluminium oxide, calcium oxide and magnesia four
Kind.
Swelling agent, which is mainly used in underground engineering, has the structure position of waterproof requirement, for bridge, the base of jumbo
Seat grouting mud jacking or hydraulic and hydroelectric engineering, nuclear power, petrochemical industry and other hydro-structures etc..The material that volume expansion can be caused is equal
Swelling agent can be processed into.The technological core of swelling agent is exactly to accomplish that the period is controllable, expansion rate is controllable.The intensity of composite material is
From zero to the process having, shrinks and mainly also appear in hardening process early period, give the expansion of certain codomain at this time, you can bring
Advantageous result.And the hardening later stage has been arrived, composite material strength has tended towards stability with structural form, and volume expansion not only can not
Favourable outcome is brought, structure destruction can be caused instead.In conclusion the technological core of expansion agent material does not lie in expansion, and
In when expand, much expansions.Necessarily the period is controllable good swelling agent, expansion rate is controllable.Swelling agent is according to national industry
Standard provides, is divided into three kinds of calcium sulphoaluminate class, calcium sulphoaluminate-calcium oxide and calcium oxide.Calcium sulphoaluminate class swelling agent is mesh
Preceding main product, domestic and international overwhelming majority expansive concrete all use hydrated calcium aluminate sulfate (i.e. entringite) for expansion sources.Separately
Some calcium oxide expansion agents, calcium sulphoaluminate-calcium oxide expansion agents are rarely found in the market.Calcium sulphoaluminate and calcium oxide are swollen
Swollen dose respectively has feature, calcium sulphoaluminate class swelling agent that there is expansion to mitigate, and controllability is good, safe to use, the feature of storage period length,
Thus application is than wide.But the concrete that such swelling agent is prepared is not suitable for the work that long term ambient temperature is 80 DEG C or more
Journey.Calcium oxide expansion agents have expansion energy high, expand the feature that explosive force is strong, early expansion is big, but if calcining control is not
It is good, it is easy to cause late expansion, such swelling agent storage period is short, and control is relatively difficult, is prepared with calcium oxide expansion agents mixed
Solidifying soil is not suitable for seawater or has the engineering of active water.Therefore swelling agent used in the present invention is preferably in calcium sulphoaluminate class
It is a kind of.
Further, technical solution more preferably, a kind of blast furnace resistance rust anti-corrosion non-shrinkage concrete described above,
It is preferred that being made of the component of following parts by weight:
The present invention also provides a kind of blast furnace preparation methods of resistance rust anti-corrosion non-shrinkage concrete.
Coarse aggregate, fine aggregate, cement and hearthstone powder, corrosion inhibitor, swelling agent are specifically added to concrete stirring successively
It is stirred evenly in machine, while water-reducing agent being added in concrete mixing water and is uniformly mixed, then mix water and water-reducing agent
Liquid is added in concrete mixer, after being sufficiently stirred 1~2.5min, is taken out, and a kind of blast furnace resistance rust anti-corrosion is obtained after construction
Non-shrinkage concrete.
The specific implementation mode of the present invention is further described with reference to embodiment, is not therefore limited the present invention
System is among the embodiment described range.
Embodiment 1
One, the preparation of concrete
It is to rely on to get over South Platform modeling industrial No. 1, No. 2 blast furnace engineering EPC Projects of responsibility Co., Ltd of the quiet steel in river.It is logical
Cross the raw material such as selection Vietnam locality concrete cement, sand, stone, additive, carry out mix Design, mainly by
Corrosion inhibitor, hearthstone powder and the swelling agent that certain ingredients are added in concrete mix, because project is located in the more counties Nanhe River Jing Sheng Qi Ying
Coastal area, geological mapping report, which is shown, contains a large amount of chlorion and sulfate ion in blast furnace local ground watering, by adding
Add corrosion inhibitor to reach the requirement of coast area improved corrosion performance, design strength class requirement is C45.
1 each component ingredient of table and its weight proportion
Raw material cement in embodiment is using PCB40 cement (being equivalent to domestic common 42.5R cement);Coarse aggregate uses grain
Diameter is 5~10mm continuous grading microliths;Fine aggregate use fineness modulus for 2.8 river sand;Water-reducing agent uses BMQ-06 board diminishings
Agent;Swelling agent selects a kind of local BMQ-KANA6 models swelling agent;Admixture chooses Taiwan curing cement limited liability company of system
The hearthstone powder of production;Corrosion inhibitor uses the CABR-MS605 corrosion inhibitors of Beijing CABR Kunlun Technology Co., Ltd.'s production;Water meets
Concrete mixing water standard.According to technical solution, after mixtures optimal design, according to K1~K5 each group distribution ratios in table 1, use tricks
Amount claims to weigh cement respectively, 5~20mm continuous grading rubbles, river sand, mixing water, western card water-reducing agent, and corrosion inhibitor successively will
The raw material such as rubble, river sand, cement, hearthstone powder, corrosion inhibitor, swelling agent, which are added in concrete mixer, to stir evenly, and pays attention to
Water-reducing agent must be added in concrete mixing water first simultaneously goes to mix, and is then added to water and additive mixing liquid mixed
In solidifying soil blender, after being sufficiently stirred 1min~2.5min, concrete mix is drawn off from blender, is transported by concrete tank
It is defeated to arrive construction site, carry out subsequent construction.
There is no particular/special requirement in work progress, after mainly having poured concrete, second plastering is carried out with spatula, reinforces supporting
Shield, avoids concrete surface from cracking.
Two, testing concrete performance
According to《Standard for quality control of concrete》GB/50164-2011,《Normal concrete long-term behaviour and endurance quality examination
Test method standard》GB/T50082-2009,《Building structure inspection technical standard》GB/T50344-2004,《Reinforcement in concrete
Detection technique regulation》JGJ/T52-2008 (uses the long-term behaviour of concrete, sulphate-corrosion resistance energy, chloride-penetration resistance
Chloride ion transport coefficient-RCM methods), concrete shrinkage amount, the performances such as Corroded Reinforced Concrete probability are detected.
2 each test group concrete performance of table compares
From Table 2, it can be seen that number is K2, K3, K4, K5, D1, D2, D3 due to various originals inside concrete mix
It is not the dosage optimized between material, the concrete comprehensive performance configured is not good enough.It is appropriate due to being added in concrete
Corrosion inhibitor, make concrete that there is certain resistance rust anti-corrosion function;Again due to adding suitable swelling agent in concrete, this is swollen
The swollen dose of self-constriction that concrete is effectively compensated in the hydration process of concrete so that inside concrete contraction crack is reduced,
The resistance to corrosion for also improving concrete simultaneously is arranged under being matched using specified weight of the present invention with number K1
To blast furnace resistance rust anti-corrosion non-shrinkage concrete due to adding the additives such as corrosion inhibitor, swelling agent, by concrete match ratio
Than Optimal Experimental, its match ratio is optimal, and it is 5% to survey its concrete corrosion probability through overtesting, Anti-Chloride Ion Penetration etc.
Grade is V grades (fine), and 28 days shrinkages of concrete are 0.05mm, and concrete initial slump is big, and the workability of concrete is preferable, and guarantor is collapsed
Work well, through when slump-loss it is minimum, be conducive to long-distance transportation and the summer high temperature construction of concrete, while its early stage
7 days intensity and 28 days assessment intensities have larger promotion, and resultant effect is fairly obvious, strong after the completion of concrete construction
Degree meets the requirements, and concrete corrosion resistant is functional.
The present invention is prepared to be prepared a kind of resistance of blast furnace and becomes rusty anti-corrosion ungauged regions pea gravel concreten, and workability is good, intensity
It meets the requirements, concrete construction facility, because adding good hearthstone powder, corrosion inhibitor and swelling agent, concrete in the concrete
Resistance rust anti-corrosion, shrinkage-void can be improved, meet the technology requirement of blast furnace project under the saline and alkaline geological environment of Vietnam.The skill
For art achievement in Successful utilization to more South Platform modeling 1, No. 2 20,000 multi-party concrete of blast furnace project, application effect is good;This skill
Art efficiently utilizes Vietnam's locality concrete raw material, has saved great amount of cost, and preparation method is simple and practicable, can be in Vietnam
And wide popularization and application under domestic saline and alkaline geological environment.
Claims (11)
1. a kind of blast furnace resistance rust anti-corrosion non-shrinkage concrete, which is characterized in that be made of the component of following parts by weight:
254 parts of cement;
140 parts of hearthstone powder;
174 parts of water;
1007 parts of coarse aggregate;
760 parts of fine aggregate;
6 parts of corrosion inhibitor;
3.15 parts of water-reducing agent;
3.4 parts of swelling agent;
The coarse aggregate uses grain size for 5~10mm continuous grading microliths, and the fine aggregate is using fineness modulus 2.7~2.9
River sand.
2. a kind of blast furnace according to claim 1 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The cement is
Portland cement.
3. a kind of blast furnace according to claim 2 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The cement is
42.5R cement.
4. a kind of blast furnace according to claim 1 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The fine aggregate
Using the river sand of fineness modulus 2.8.
5. a kind of blast furnace according to claim 1 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The water-reducing agent
For at least one of poly carboxylic acid series water reducer, naphthalene water reducer, ligninsulfonate water-reducing agent.
6. a kind of blast furnace according to claim 5 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The water-reducing agent
For poly carboxylic acid series water reducer.
7. a kind of blast furnace according to claim 1 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The corrosion inhibitor
For nitrite, phosphate, carbonate, aliphatic ester, the compound corrosion inhibitors of MCI, sodium benzoate, sodium chromate, stannous chloride, first
At least one of sour calcium.
8. a kind of blast furnace according to claim 7 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The corrosion inhibitor
For compound corrosion inhibitor, the compound corrosion inhibitor is in sodium benzoate+sodium nitrite, calcium nitrite+sodium nitrite+calcium formate
One kind.
9. a kind of blast furnace according to claim 1 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The swelling agent
For at least one of calcium sulphoaluminate class, calcium sulphoaluminate-calcium oxide, calcium oxide.
10. a kind of blast furnace according to claim 9 resistance rust anti-corrosion non-shrinkage concrete, it is characterised in that:The expansion
Agent is one kind in calcium sulphoaluminate class.
11. a kind of blast furnace of claim 1~10 any one of them preparation method of resistance rust anti-corrosion non-shrinkage concrete, special
Sign is:Coarse aggregate, fine aggregate, cement and hearthstone powder, corrosion inhibitor, swelling agent are added in concrete mixer and are stirred successively
Uniformly, while water-reducing agent being added in concrete mixing water and is uniformly mixed, then water and water-reducing agent mixing liquid are added
It into concrete mixer, after being sufficiently stirred 1~2.5min, takes out, it is mixed with resistance rust anti-corrosion ungauged regions that a kind of blast furnace is obtained after construction
Solidifying soil.
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CN109776014B (en) * | 2019-02-18 | 2022-03-18 | 绵阳市安州区荣盛建材有限公司 | Double-component rust inhibitor for alkali-free accelerator and preparation and use methods thereof |
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TWI454439B (en) * | 2012-02-15 | 2014-10-01 | Non - shrinkable cement additive and non - shrink cement and its application | |
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