CN105924031B - A kind of cement additire suitable for municipal works - Google Patents
A kind of cement additire suitable for municipal works Download PDFInfo
- Publication number
- CN105924031B CN105924031B CN201610224268.2A CN201610224268A CN105924031B CN 105924031 B CN105924031 B CN 105924031B CN 201610224268 A CN201610224268 A CN 201610224268A CN 105924031 B CN105924031 B CN 105924031B
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- CN
- China
- Prior art keywords
- parts
- propylben
- methyl hydroxybenzoate
- cement additire
- cement
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of cement additire suitable for municipal works, it is made up of the raw material of following parts by weight：Calcium oxide, 35~45 parts；Calcium acetate, 5~15 parts；IPD, 10~20 parts；Benzyl glycidyl ether, 5~15 parts；Dimethyl silicone polymer, 15~25 parts；Isopropyl palmitate, 5~15 parts；Zinc dialkyl dithiophosphate, 20~30 parts；The mixture of methyl hydroxybenzoate and propylben, 5~7 parts；The weight ratio of the methyl hydroxybenzoate and propylben is 4~6：1.Cement additire provided by the invention can significantly improve the compression strength and rupture strength of cement, improve the smoothness and color of cement products, this may be relevant with the weight ratio of methyl hydroxybenzoate in cement additire and propylben, and the weight ratio of methyl hydroxybenzoate and propylben is 4~6：When between 1, effect is preferable.
Description
Technical field
The present invention relates to municipal works, and in particular to a kind of cement additire suitable for municipal works.
Background technology
With social development, scientific and technological progress, the continuous improvement of mankind's actual life demand, especially in China, due to economy
Flourish, it is necessary to substantial amounts of infrastructure, to meet modernization construction, at present, with road, bridge house and other high
Layer building is on the increase, and increasing cement additire is applied in above-mentioned construction.
Cement additire is a kind of chemical addition agent for improving cement grinding effect and performance, can significantly improve cement grinding mill
Unit-hour output and each age strength of cement.Cement additire can be greatly lowered the Electrostatic Absorption bag ball formed in grinding process and show
As, and the coalescence trend again of the ultra-fine grain formed in grinding process can be reduced, reduced grinding phenomenon.Cement additire
Also cement fluidity can be significantly improved, improves the grinding efficiency of grinding machine and the grinding efficiency of powder concentrator, so as to reduce grinding energy.
As a kind of chemical activator, cement additire can improve concrete scroll and excite the hydration activity of each mixing material, so as to
Improve cement early strength and later strength.
The content of the invention
It is an object of the invention to be to provide a kind of cement additire suitable for municipal works, for improving cement
The combination properties such as intensity, wearability.
The above-mentioned purpose of the present invention is achieved by following technical scheme：
A kind of cement additire for municipal works, it is made up of the raw material of following parts by weight：Calcium oxide, 35~45 parts；
Calcium acetate, 5~15 parts；IPD, 10~20 parts；Benzyl glycidyl ether, 5~15 parts；Dimethyl silicone polymer, 15
~25 parts；Isopropyl palmitate, 5~15 parts；Zinc dialkyl dithiophosphate, 20~30 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 5~7 parts；The weight ratio of the methyl hydroxybenzoate and propylben is 4~6：1.
Further, described cement additire is made up of the raw material of following parts by weight：Calcium oxide, 40 parts；Calcium acetate, 10
Part；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Dimethyl silicone polymer, 20 parts；Isopropyl palmitate, 10
Part；Zinc dialkyl dithiophosphate, 25 parts；The mixture of methyl hydroxybenzoate and propylben, 6 parts；The methyl hydroxybenzoate
Weight ratio with propylben is 5：1.
Further, described cement additire is made up of the raw material of following parts by weight：Calcium oxide, 35 parts；Calcium acetate, 5
Part；IPD, 10 parts；Benzyl glycidyl ether, 5 parts；Dimethyl silicone polymer, 15 parts；Isopropyl palmitate, 5 parts；
Zinc dialkyl dithiophosphate, 20 parts；The mixture of methyl hydroxybenzoate and propylben, 5 parts；The methyl hydroxybenzoate and Buddhist nun
The weight ratio for mooring golden propyl ester is 4：1.
Further, described cement additire is made up of the raw material of following parts by weight：Calcium oxide, 45 parts；Calcium acetate, 15
Part；IPD, 20 parts；Benzyl glycidyl ether, 15 parts；Dimethyl silicone polymer, 25 parts；Isopropyl palmitate, 15
Part；Zinc dialkyl dithiophosphate, 30 parts；The mixture of methyl hydroxybenzoate and propylben, 7 parts；The methyl hydroxybenzoate
Weight ratio with propylben is 6：1.
The preparation method of above-mentioned cement additire is：It is 0.08~0.12mm that calcium oxide and calcium acetate first are ground into granularity
Fine powder, then fine powder is well mixed with surplus stock.
A kind of strong concrete mixture for municipal works, contain above-mentioned cement additire.
Further, the cement additire accounts for the 0.08~0.12% of concrete mix gross weight.
Advantages of the present invention：Cement additire provided by the invention can significantly improve cement compression strength and anti-folding it is strong
Degree, the smoothness and color of cement products are improved, this may be with methyl hydroxybenzoate in cement additire and propylben
Weight ratio is relevant, and the weight ratio of methyl hydroxybenzoate and propylben is 4~6：When between 1, effect is preferable.
Embodiment
The essentiality content of the present invention is further illustrated with reference to embodiment, but present invention protection model is not limited with this
Enclose.Although being explained in detail with reference to preferred embodiment to the present invention, it will be understood by those within the art that, can be right
Technical scheme is modified or equivalent substitution, without departing from the spirit and scope of technical solution of the present invention.
Embodiment 1：The preparation of cement additire
Parts by weight of raw materials ratio：
Calcium oxide, 40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Poly- diformazan
Radical siloxane, 20 parts；Isopropyl palmitate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 6 parts；The weight ratio of methyl hydroxybenzoate and propylben is 5：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 2：The preparation of cement additire
Parts by weight of raw materials ratio：
Calcium oxide, 35 parts；Calcium acetate, 5 parts；IPD, 10 parts；Benzyl glycidyl ether, 5 parts；Poly dimethyl
Siloxanes, 15 parts；Isopropyl palmitate, 5 parts；Zinc dialkyl dithiophosphate, 20 parts；Methyl hydroxybenzoate and propylben
Mixture, 5 parts；The weight ratio of the methyl hydroxybenzoate and propylben is 4：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 3：The preparation of cement additire
Parts by weight of raw materials ratio：
Calcium oxide, 45 parts；Calcium acetate, 15 parts；IPD, 20 parts；Benzyl glycidyl ether, 15 parts；Poly- diformazan
Radical siloxane, 25 parts；Isopropyl palmitate, 15 parts；Zinc dialkyl dithiophosphate, 30 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 7 parts；The weight ratio of methyl hydroxybenzoate and propylben is 6：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 4：The preparation of cement additire
Parts by weight of raw materials ratio：
Calcium oxide, 40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Poly- diformazan
Radical siloxane, 20 parts；Isopropyl palmitate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 6 parts；The weight ratio of methyl hydroxybenzoate and propylben is 4：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 5：The preparation of cement additire
Parts by weight of raw materials ratio：
Calcium oxide, 40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Poly- diformazan
Radical siloxane, 20 parts；Isopropyl palmitate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 6 parts；The weight ratio of methyl hydroxybenzoate and propylben is 6：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 6：The weight ratio of the contrast of embodiment 1, methyl hydroxybenzoate and propylben is 3：1
Parts by weight of raw materials ratio：
Calcium oxide, 40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Poly- diformazan
Radical siloxane, 20 parts；Isopropyl palmitate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 6 parts；The weight ratio of methyl hydroxybenzoate and propylben is 3：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 7：The weight ratio of the contrast of embodiment 1, methyl hydroxybenzoate and propylben is 7：1
Parts by weight of raw materials ratio：
Calcium oxide, 40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Poly- diformazan
Radical siloxane, 20 parts；Isopropyl palmitate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；Methyl hydroxybenzoate and nipalgin third
The mixture of ester, 6 parts；The weight ratio of methyl hydroxybenzoate and propylben is 7：1.
Preparation method：First by calcium oxide and calcium acetate be ground into granularity be 0.08~0.12mm fine powder, then by fine powder with
Surplus stock is well mixed.
Embodiment 8：Effect example, compression strength and rupture strength measure
Cement additire prepared by embodiment 1~7, addition 0.1% are added in the preparation process of cement respectively.So
The 28 days compression strength (MPa) and rupture strength relative value (%) of each cement are determined afterwards.
| Cement additire source | 28 days compression strength (MPa) | 28 days rupture strength relative values (%) |
| Embodiment 1 | 58.9 | 142 |
| Embodiment 4 | 53.4 | 137 |
| Embodiment 5 | 53.2 | 135 |
| Embodiment 6 | 41.4 | 104 |
| Embodiment 7 | 41.6 | 103 |
| Do not add | 40.4 | 100 |
The effect of the effect of embodiment 2 and 3 and embodiment 4 and 5 is basically identical.
The above results show, cement additire provided by the invention can significantly improve cement compression strength and anti-folding it is strong
Degree.
Embodiment 9：Effect example, smoothness and color experiment
Mix the cement additire of the preparation of embodiment 1~7 respectively with the white cement of commercially available 32.5MPa strength grades, it is raw
Production size is 300mm × 300mm × 60mm each 5 pieces of base substrates of smooth concrete plate brick, is stripped after standing 7 days at 20 ± 2 DEG C,
Observe product surface situation.10kg white cements add 0.1kg cement additires.
| Cement additire source | Product surface situation |
| Embodiment 1 | Intact, surface is smooth, glossy |
| Embodiment 4 | Intact, surface is smooth, glossy |
| Embodiment 5 | Intact, surface is smooth, glossy |
| Embodiment 6 | Surface smoothness is poor, matt degree |
| Embodiment 7 | Surface smoothness is poor, matt degree |
| Do not add | Surface smoothness is poor, matt degree |
The effect of the effect of embodiment 2 and 3 and embodiment 4 and 5 is basically identical.
The above results show that cement additire provided by the invention can significantly improve the smoothness and color of cement.
The effect of integrated embodiment 8 and embodiment 9 can be seen that cement additire provided by the invention and can significantly improve
The compression strength and rupture strength of cement, the smoothness and color of cement products are improved, this may be with Buddhist nun in cement additire
It is relevant with the weight ratio of propylben to moor tortoise beetle ester, the weight ratio of methyl hydroxybenzoate and propylben 4~
6：When between 1, effect is preferable.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but the protection of the present invention is not limited with this
Scope.It will be understood by those within the art that technical scheme can be modified or equivalent substitution,
Without departing from the essence and protection domain of technical solution of the present invention.
Claims (7)
1. a kind of cement additire for municipal works, it is characterised in that be made up of the raw material of following parts by weight：Calcium oxide,
35~45 parts；Calcium acetate, 5~15 parts；IPD, 10~20 parts；Benzyl glycidyl ether, 5~15 parts；Poly dimethyl
Siloxanes, 15~25 parts；Isopropyl palmitate, 5~15 parts；Zinc dialkyl dithiophosphate, 20~30 parts；Methyl hydroxybenzoate and
The mixture of propylben, 5~7 parts；The weight ratio of the methyl hydroxybenzoate and propylben is 4~6：1.
2. cement additire according to claim 1, it is characterised in that be made up of the raw material of following parts by weight：Calcium oxide,
40 parts；Calcium acetate, 10 parts；IPD, 15 parts；Benzyl glycidyl ether, 10 parts；Dimethyl silicone polymer, 20 parts；Palm fibre
Palmitic acid isopropyl propionate, 10 parts；Zinc dialkyl dithiophosphate, 25 parts；The mixture of methyl hydroxybenzoate and propylben, 6 parts；Institute
The weight ratio for stating methyl hydroxybenzoate and propylben is 5：1.
3. cement additire according to claim 1, it is characterised in that be made up of the raw material of following parts by weight：Calcium oxide,
35 parts；Calcium acetate, 5 parts；IPD, 10 parts；Benzyl glycidyl ether, 5 parts；Dimethyl silicone polymer, 15 parts；Palm
Isopropyl propionate, 5 parts；Zinc dialkyl dithiophosphate, 20 parts；The mixture of methyl hydroxybenzoate and propylben, 5 parts；It is described
The weight ratio of methyl hydroxybenzoate and propylben is 4：1.
4. cement additire according to claim 1, it is characterised in that be made up of the raw material of following parts by weight：Calcium oxide,
45 parts；Calcium acetate, 15 parts；IPD, 20 parts；Benzyl glycidyl ether, 15 parts；Dimethyl silicone polymer, 25 parts；Palm fibre
Palmitic acid isopropyl propionate, 15 parts；Zinc dialkyl dithiophosphate, 30 parts；The mixture of methyl hydroxybenzoate and propylben, 7 parts；Institute
The weight ratio for stating methyl hydroxybenzoate and propylben is 6：1.
5. the preparation method of any cement additire of Claims 1 to 4, it is characterised in that：First by calcium oxide and calcium acetate
It is ground into granularity and is 0.08~0.12mm fine powder, then fine powder is well mixed with surplus stock.
A kind of 6. strong concrete mixture for municipal works, it is characterised in that：Contain any institute of Claims 1 to 4
The cement additire stated.
7. strong concrete mixture according to claim 6, it is characterised in that：The cement additire accounts for concrete
The 0.08~0.12% of mixture total weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610224268.2A CN105924031B (en) | 2016-04-12 | 2016-04-12 | A kind of cement additire suitable for municipal works |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610224268.2A CN105924031B (en) | 2016-04-12 | 2016-04-12 | A kind of cement additire suitable for municipal works |
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| Publication Number | Publication Date |
|---|---|
| CN105924031A CN105924031A (en) | 2016-09-07 |
| CN105924031B true CN105924031B (en) | 2018-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610224268.2A Expired - Fee Related CN105924031B (en) | 2016-04-12 | 2016-04-12 | A kind of cement additire suitable for municipal works |
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| CN108246250A (en) * | 2016-12-28 | 2018-07-06 | 海门市源美美术图案设计有限公司 | A kind of biology carbon composite and its preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756724A (en) * | 2003-03-05 | 2006-04-05 | 株式会社日本触媒 | Cement admixture, cement composition and method for laying work the same, and method for producing cement hardened product |
| CN104556810A (en) * | 2014-12-24 | 2015-04-29 | 青岛佳尚创意文化有限公司 | Cement grinding additive |
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2016
- 2016-04-12 CN CN201610224268.2A patent/CN105924031B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756724A (en) * | 2003-03-05 | 2006-04-05 | 株式会社日本触媒 | Cement admixture, cement composition and method for laying work the same, and method for producing cement hardened product |
| CN104556810A (en) * | 2014-12-24 | 2015-04-29 | 青岛佳尚创意文化有限公司 | Cement grinding additive |
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