CN105924022B - A kind of enhancing textile size containing microwax - Google Patents
A kind of enhancing textile size containing microwax Download PDFInfo
- Publication number
- CN105924022B CN105924022B CN201610280447.8A CN201610280447A CN105924022B CN 105924022 B CN105924022 B CN 105924022B CN 201610280447 A CN201610280447 A CN 201610280447A CN 105924022 B CN105924022 B CN 105924022B
- Authority
- CN
- China
- Prior art keywords
- agent
- parts
- microwax
- textile size
- size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of enhancing textile size containing microwax, includes the component of following parts by weight, 0.5~2.5 part of aqueous epoxy resins；2.0~5.0 parts of color fixing agent；1.0~4.0 parts of aqueous unsaturated polyester resin；0.2~0.5 part of coupling agent；1.0~3.0 parts of plasticizer；0.2~0.6 part of microwax；0.2~0.6 part of lubricating oil；0.1~0.3 part of cationic film；0.5~1.0 part of emulsifier；0.5~1 part of assistant for emulsifying agent；0.02-0.06 parts of pH adjusting agent；80~90 parts of deionized water.The size and prior paraffin type size and resin type size ratio this product size wire drawing film strength are high, and yarn matter resilient flexible is good, and processing performance is good without filoplume.Size viscosity is small, and good fluidity is easily recycled, and does not generate greasy filth, recycles size and waste water is Ke Xunhuanliyong, will not cause environmental pollution.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, are infiltrated more particularly, to a kind of enhancing Weave type containing microwax
Agent.
Background technology
In the 1930s, glass fibre takes the lead in being born in the U.S..The fiber glass industry in China is started in 1958, is opened
Begin to produce glass fibre with imitated former Soviet Union crucible method, size mainly uses paraffin wax type.To China's saving of platinum alloy crucible in 1969
Law technology is born, and separate unit crucible is declined to a great extent with platinum amount, and a new road is broken for China's Fiberglass Industry fast development, with
A variety of fiberglass product industrial systems based on the peculiar middle alkali resistance to chemical attack type product in China are formed.China's glass fibers in 2015
3,230,000 tons of yarn total output, 18.5 ten thousand tons of crucible method wire drawing yield are tieed up, though accounting is not high, China's traditional textile deep processing system
Product advantage raw material.Crucible method production Weave type yarn mainly uses paraffin sizing material at present, and paraffin sizing material is mainly with emulsification
Paraffin as protection glass film forming agent, using oil emulsion as lubricant.Compared to resin type size, the advantages of paraffin wax type emulsion
It is to be suitble to textile process, it is at low cost.Disadvantage is mainly that viscosity is big, and the collection of filaments is poor, filoselle is more serious, and a large amount of size flies
Splash also can make silk cylinder tacky on silk cylinder surface, laminated tearing when moving back solution.The size for being splashed to space is hung everywhere, it is difficult to it clears up,
Environment is influenced, discharge waste water influences environmental protection.Environmental Protection in China problem is very prominent at present, has only to resolve size and recycle and ask
Topic, just can ensure that the survival and development of crude wax type crucible manufacturing enterprise.
Invention content
In view of this, the present invention is directed to propose a kind of enhancing textile size containing microwax, the size use
Variety classes aqueous, environmental protective resin substitutes the stickums such as traditional paraffin, vaseline, machine oil, overcomes paraffin size and lacks
It falls into, it can be achieved that enclosed circulation use is without outside waste discharge, while having the characteristics that paraffin and resin infiltration agent, have excellent performance
And environmental protection.
In order to achieve the above objectives, the technical proposal of the invention is realized in this way：
A kind of enhancing textile size containing microwax, includes the component of following parts by weight, aqueous epoxy resins
0.5~2.5 part；Color fixing agent：2.0~5.0 parts；1.0~4.0 parts of aqueous unsaturated polyester resin；0.2~0.5 part of coupling agent；Increase
Mould agent：1.0~3.0 parts；Microwax：0.2~0.6 part；0.2~0.6 part of lubricating oil；0.1~0.3 part of cationic film；Emulsification
0.5~1.0 part of agent；0.5~1 part of assistant for emulsifying agent；0.02-0.06 parts of pH adjusting agent；80~90 parts of deionized water.
Preferably, include the component of following parts by weight, 1~2 part of aqueous epoxy resins；Color fixing agent：3~4.5 parts；It is aqueous
1.5~2.5 parts of unsaturated polyester resin；0.2~0.3 part of coupling agent；Plasticizer：1.0~2.0 parts；Microwax：0.4~0.6
Part；0.4~0.55 part of lubricating oil；0.1~0.3 part of cationic film；0.5~0.8 part of emulsifier；Assistant for emulsifying agent 0.5~0.8
Part；0.02-0.06 parts of pH adjusting agent；85~89 parts of deionized water；The pH value of the size is 6.0-6.5.
Preferably, the color fixing agent is no aldehyde curing agent；Preferably, the no aldehyde curing agent polymerize for polyamines cationoid
Object；Preferably, the lubricating oil is No. 7 or No. 10 machine oil.
Preferably, the plasticizer is one or both of dibutyl ester, dioctyl ester.
Preferably, the emulsifier is one or more of peregal, tween, this Pan.
Preferably, the assistant for emulsifying agent is one or both of stearic acid, oleic acid.
Preferably, the pH adjusting agent is glacial acetic acid.
Preferably, the coupling agent is silane coupling agent；Preferably, the silane coupling agent be KH550, KH560 or
KH570；Preferably, KH550.
Preferably, the cationic film is one or more of fatty acyl amide, quaternary ammonium salt.
The present invention also provides a kind of enhancing textile sizes containing microwax as described above in field of textiles
Application.
Compared with the existing technology, the enhancing textile size of the present invention containing microwax, has the advantage that：
The size combines paraffin sizing material and resin type size advantage, while overcoming two kinds of size disadvantages, with tradition
Paraffin sizing material and resin type size ratio this product size wire drawing film strength are high, and yarn matter resilient flexible is good, processing performance
Well without filoplume.Size viscosity is small, and good fluidity is easily recycled, and does not generate greasy filth, recycles size and waste water is Ke Xunhuanliyong,
It will not cause environmental pollution.
Specific implementation mode
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
Below in conjunction with embodiment, the present invention will be described in detail.
Embodiment one
A kind of enhancing textile size containing microwax, includes the component of following parts by weight, environmentally friendly color fixing agent 4.0
Part；1.5 parts of aqueous epoxy resins；2.0 parts of aqueous unsaturated polyester resin；0.6 part of microcrystalline wax；1.0 parts of dibutyl ester；Peregal
0.5 part；0.5 part of stearic acid；No. 7 0.5 part of machine oil；0.25 part of fatty acid amide cationoid film；0.25% part of KH550；Ice vinegar
0.04 part of acid.The size pH value 6.5.
Using yarn property is such as compared with prior paraffin type size after the size wire drawing spinning of the embodiment of the present invention one
Under：
Produce kind CC9033*1
Produce kind CC1148*1
Note：Fusing refer to certain specific solvent dissolve fiber surface coating, record since enter solvent to coating from
The time to fall off on fiber.Yarn size content and aqueous, refers in particular to the weight percent that yarn includes size and water.More than
The assay method of data using glass fibre examination criteria conventional practices.
The normal production of yarn product is using crucible method wire drawing；About production first C generation of kind CC9033*1, CC
Alkali in table, second C represent continuous fiber, and 90 represent 9 microns of single fiber diameter, and 33 represent the long grammes per square metre common name number of km, most
1 afterwards represents sub-thread.Alkali during similarly first C of CC1148*1CC is represented, second C represent continuous fiber, and 11 represent single fiber
11 microns of diameter, 48 represent the long grammes per square metre of km, are generally called number, last 1 represents sub-thread.These glass fibre standard codes represent
Be Yarn constituent type and model.
The foregoing is merely the preferred embodiments of the invention, are not intended to limit the invention creation, all at this
Within the spirit and principle of innovation and creation, any modification, equivalent replacement, improvement and so on should be included in the invention
Protection domain within.
Claims (12)
1. a kind of enhancing textile size containing microwax, it is characterised in that：Include the component of following parts by weight, it is aqueous
0.5~2.5 part of epoxy resin；Color fixing agent：2.0~5.0 parts；1.0~4.0 parts of aqueous unsaturated polyester resin；Coupling agent 0.2~
0.5 part；Plasticizer：1.0~3.0 parts；Microwax：0.2~0.6 part；0.2~0.6 part of lubricating oil；Cationic film 0.1~0.3
Part；0.5~1.0 part of emulsifier；0.5~1 part of assistant for emulsifying agent；0.02-0.06 parts of pH adjusting agent；80~90 parts of deionized water.
2. the enhancing textile size according to claim 1 containing microwax, it is characterised in that：Including following weight
The component of number, 1~2 part of aqueous epoxy resins；Color fixing agent：3~4.5 parts；1.5~2.5 parts of aqueous unsaturated polyester resin；It is even
Join 0.2~0.3 part of agent；Plasticizer：1.0~2.0 parts；Microwax：0.4~0.6 part；0.4~0.55 part of lubricating oil；Cation is soft
0.1~0.3 part of piece；0.5~0.8 part of emulsifier；0.5~0.8 part of assistant for emulsifying agent；0.02-0.06 parts of pH adjusting agent；Deionized water
85~89 parts；The pH value of the size is 6.0-6.5.
3. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：The fixation
Agent is no aldehyde curing agent；The lubricating oil is No. 7 or No. 10 machine oil.
4. the enhancing textile size according to claim 3 containing microwax, it is characterised in that：The no aldehyde solidification
Agent is polyamines cationoid polymer.
5. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：The plasticising
Agent is one or both of dibutyl ester, dioctyl ester.
6. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：The emulsification
Agent is one or more of peregal, tween, this Pan.
7. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：It is described to help breast
Agent is one or both of stearic acid, oleic acid.
8. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：The pH tune
Section agent is glacial acetic acid.
9. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：The coupling
Agent is silane coupling agent.
10. the enhancing textile size according to claim 9 containing microwax, it is characterised in that：The silane is even
It is KH550, KH560 or KH570 to join agent.
11. the enhancing textile size according to claim 1 or 2 containing microwax, it is characterised in that：It is described sun from
Sub- film is one or more of fatty acyl amide, quaternary ammonium salt.
12. containing the enhancing textile size of microwax in field of textiles according to claim 1~11 any one of them
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610280447.8A CN105924022B (en) | 2016-04-28 | 2016-04-28 | A kind of enhancing textile size containing microwax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610280447.8A CN105924022B (en) | 2016-04-28 | 2016-04-28 | A kind of enhancing textile size containing microwax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105924022A CN105924022A (en) | 2016-09-07 |
| CN105924022B true CN105924022B (en) | 2018-10-30 |
Family
ID=56837875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610280447.8A Expired - Fee Related CN105924022B (en) | 2016-04-28 | 2016-04-28 | A kind of enhancing textile size containing microwax |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105924022B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107382097A (en) * | 2017-06-08 | 2017-11-24 | 南通哥班玻璃纤维制品有限公司 | A kind of super large emery wheel reinforcing glass fiber mat roving sizing agent |
| CN107216051A (en) * | 2017-06-14 | 2017-09-29 | 安徽丹凤电子材料股份有限公司 | A kind of new size and preparation method thereof |
| CN107686251A (en) * | 2017-08-25 | 2018-02-13 | 淄博丑牛特种纤维科技有限公司 | A kind of novel electron cloth paraffin sizing material and preparation method thereof |
| CN109279789A (en) * | 2018-10-18 | 2019-01-29 | 山东兴国大成特种纤维科技有限公司 | A kind of electronics cloth warp thread sizing agent special and its preparation process |
| CN114605091B (en) * | 2022-04-27 | 2024-04-19 | 单县大道玻纤有限公司 | Glass fiber impregnating compound |
| CN115477481A (en) * | 2022-09-14 | 2022-12-16 | 重庆海科保温材料有限公司 | Mineral oil for glass wool products and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101306921B (en) * | 2008-06-30 | 2011-02-16 | 淄博新力玻璃纤维有限公司 | Paraffin sizing material for electronic cloth of low solid content |
| CN101638298B (en) * | 2009-08-18 | 2011-06-01 | 淄博新力特种纤维科技有限公司 | Wetting agent used for pretreated enhancement type filter cloth |
-
2016
- 2016-04-28 CN CN201610280447.8A patent/CN105924022B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105924022A (en) | 2016-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105924022B (en) | A kind of enhancing textile size containing microwax | |
| CN107189354A (en) | A kind of graphene nanometer sheet strengthens the preparation method of carbon fibre composite | |
| CN103951830B (en) | A kind of preparation method of hyper-branched polyester graft modification sisal cellulose crystallite | |
| CN103787592A (en) | Direct twistless rough yarn impregnating compound for reinforcing epoxy resin | |
| CN1968907A (en) | Epoxy sizing composition for filament winding | |
| CN104527177B (en) | A kind of recyclable prepreg, cured sheets, copper-clad plate and its preparation for printed circuit board (PCB), recovery method | |
| CN108249784A (en) | A kind of glass fibre continuous strand felt size | |
| CN105419012A (en) | Preparation method for straw-based crystalline cellulose nanocrystals and rubber composite material of straw-based crystalline cellulose nanocrystals | |
| ATE457374T1 (en) | METHOD FOR PRODUCING NANOFIBERS | |
| CN106277847A (en) | A kind of glass fiber infiltration agent | |
| Hari Sankar et al. | The effect of fiber length on tensile properties of polyester resin composites reinforced by the fibers of Sansevieria trifasciata | |
| CN105038194A (en) | Polyurethane acrylate composite material for artificial marble and preparation method thereof | |
| CN104975527A (en) | Method for manufacturing oil-gas-exploration special fiber rope | |
| Ali et al. | Mechanical and physical characteristics of hybrid particles/fibers-polymer composites: A review | |
| CN105155267B (en) | A kind of mineral fibres softening agent | |
| CN104275883A (en) | Nanofiber reinforced polylactic acid/polycaprolactone composite material and preparation method thereof | |
| CN101723603A (en) | Special sizing agent for chopped strands for strengthening phenolic resin | |
| CN104861857A (en) | Method for preparing environment-friendly synthetic paper ink-jet printing coating | |
| CN105367801A (en) | Nanometer / micron particle prepared from UV cured organosilicon, and preparation method and application thereof | |
| Arun et al. | Time dependent behaviour of amino silane-treated aramid fibre and waste latex rubber powder toughened epoxy composite | |
| CN104448711A (en) | Epoxy resin/carbon fiber/halloysite nanotube composite material and preparation method thereof | |
| CN105176070A (en) | Modified 3D printing material and preparation method thereof | |
| CN107141782A (en) | High glaze fiberglass reinforced modification of nylon | |
| CN106626535B (en) | Mono- polymer composites of a kind of high microsteping volume content PHBV and preparation method thereof | |
| CN109250926A (en) | A kind of double walled tank e-glass fiber infiltrant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20181030 Termination date: 20190428 |