CN105923261A - Anti-counterfeiting device used for wine bottle - Google Patents
Anti-counterfeiting device used for wine bottle Download PDFInfo
- Publication number
- CN105923261A CN105923261A CN201610493489.XA CN201610493489A CN105923261A CN 105923261 A CN105923261 A CN 105923261A CN 201610493489 A CN201610493489 A CN 201610493489A CN 105923261 A CN105923261 A CN 105923261A
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- CN
- China
- Prior art keywords
- false proof
- bottle
- display screen
- friction generator
- nano friction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D55/00—Accessories for container closures not otherwise provided for
- B65D55/02—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure
- B65D55/028—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure initial opening or unauthorised access being indicated by the presence or absence of an audible or electrical signal
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F3/0291—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
- G09F3/0292—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
- H02N1/00—Electrostatic generators or motors using a solid moving electrostatic charge carrier
- H02N1/04—Friction generators
Abstract
The invention discloses an anti-counterfeiting device used for a wine bottle. The anti-counterfeiting device used for the wine bottle comprises a display screen (1) and a nano friction generator (2) electrically connected with the display screen (1). The display screen (1) is used for displaying an anti-counterfeiting mark; the nano friction generator (2) is used for generating electric energy after deformation occurs and supplying power for the display screen (1); and after the wine bottle is opened, the anti-counterfeiting device is damaged, and the display screen (1) cannot display anti-counterfeiting information again. According to the anti-counterfeiting device used for the wine bottle, the authenticity of a bottle of wine can be verified only by a simple pressing method; the operation is simple and convenient; and the anti-counterfeiting device used for the wine bottle can be flexibly designed in shape, position and the like, and the anti-counterfeiting issue of the wine is effectively solved.
Description
Related application
The application is the filing date Chinese patent application 201310096079.8 of on 03 22nd, 2013
The divisional application of " a kind of false proof device for bottle ".
Technical field
The present invention relates to false proof display field, particularly to a kind of false proof device for bottle.
Background technology
Wine as China entertain guests at a banquet on a kind of culture, become requisite beverage, but, go out at present
Its true and false problem of high-grade wine the most on the market often becomes the one of user and scruples greatly.Therefore, how
The true and false of effective difference wine becomes the problem needing solution badly.
In patent application document disclosed in China 02214915.5, it uses the mode cut off by bottle neck,
User can only be opened once, although this kind of mode can the most effectively prevent bottle
Reuse, but if the wine in bottle still has residue, then wine can not be resealed, thus make
Become the waste of wine.
As can be seen here, in prior art lack one can not either destroy bottle again can flexible design shape
Shape, and realize the false proof device on bottle of false proof purpose.
Summary of the invention
The problem to be solved in the present invention is to provide one can not destroy bottle and Bottle cap structure can be real
The false proof device on bottle of existing false proof purpose.
For solving the problems referred to above, the invention provides a kind of false proof device on bottle, its concrete skill
Art scheme is:
A kind of false proof device for bottle, sends out including display screen and the nano friction electrically connected with display screen
Motor, display screen is used for showing that anti-counterfeiting mark, nano friction generator produce electric energy after deforming upon, for
Display screen is powered, and after bottle is opened, false proof device damages, and display screen cannot show anti-counterfeiting information again.
Relative to existing apparatus, the present invention for the advantage of the false proof device of bottle is:
(1) display screen that the false proof device of the present invention uses is flexible, can be curved as required,
It is shaped to flexible design, can be applicable to the bottle of various profile.And, this false proof device is by aobvious
Display screen display anti-counterfeiting mark, it is possible to intuitive and convenient ground shows false proof result.
(2) false proof device of the present invention uses nano friction generator to power, as long as making in use to receive
Rice friction generator produces deformation and can generate electricity, and does not haves electricity and uses up situation about cannot use, therefore,
The false proof device of the present invention will not be limited by power supply, the most all can use.
(3) use of the nano friction generator in the present invention, inherently can play false proof effect,
If on bottle install false proof device in display screen when nano friction generator deforms upon still
Cannot power, then may determine that the false proof device installed on this bottle is personation, therefore, this wine is also
Imitation.
Accompanying drawing explanation
Fig. 1 be the first embodiment of the false proof device for bottle of the present invention be completed figure；
Fig. 2 be the false proof device for bottle in Fig. 1 disassemble schematic diagram；
Fig. 3 is the assembling figure of the second embodiment of the false proof device for bottle of the present invention；
Fig. 4 be the third embodiment of the false proof device for bottle of the present invention be completed figure；
Fig. 5 is the decomposing schematic representation of the false proof band in Fig. 4 and standing finish；
Fig. 6 be the 4th kind of embodiment of the false proof device for bottle of the present invention be completed figure；
Fig. 7 be the false proof device for bottle in Fig. 6 disassemble schematic diagram；
Fig. 8 be the 5th kind of embodiment of the false proof device for bottle of the present invention be completed figure；
Fig. 9 be the false proof device for bottle in Fig. 8 disassemble schematic diagram；
Figure 10 is being completed of the 6th kind of embodiment of the false proof device for bottle of the present invention
Figure；
Figure 11 is the cut-away view of the false proof device for bottle in Figure 10；
Figure 12 is the decomposing schematic representation of the Anti-theft cap cover in Figure 10；
Figure 13 is the first knot of the nano friction generator in the false proof device for bottle of the present invention
Structure schematic diagram；
Figure 14 is the sectional view of the nano friction generator in Figure 13；
Figure 15 is the second knot of the nano friction generator in the false proof device for bottle of the present invention
Structure schematic diagram；
Figure 16 is the sectional view of the nano friction generator in Figure 15；
Figure 17 is the third knot of the nano friction generator in the false proof device for bottle of the present invention
Structure schematic diagram；
Figure 18 is the sectional view of the nano friction generator in Figure 17.
Detailed description of the invention
In order to be better understood by the purpose of the present invention, structure and function, below in conjunction with the accompanying drawings, to the present invention
A kind of false proof device for bottle do further detailed description.
See Fig. 1 and Fig. 2, it illustrates the first enforcement of the false proof device for bottle of the present invention
Mode.In the present embodiment, false proof device includes display screen 1 and the nano friction electrically connected with display screen 1
Electromotor 2, wherein, display screen 1 is arranged on the standing finish 8 of circle, and standing finish 8 is fixing to be set
Putting the top at bottle cap 5, nano friction generator 2 is arranged on false proof band 3, it is preferred that anti-
Being provided with accommodating window on pseudo-band 3, it is accommodating that nano friction generator 2 is seated on false proof band 3
In window.False proof band 3 is connected with standing finish 8, and false proof band 3 is fixedly installed on the bottle of bottle
4 and bottle cap 5 on, and nano friction generator 2 is positioned on bottle 4.
Wherein, display screen 1 is flexible display screen, can be current existing LCD screen, Electronic Paper show
Display screen or the display screen etc. of other low-power consumption, display screen 1 can show the anti-counterfeiting mark pre-set
(such as, false proof logo, security code, name of product or product related information etc.)；Nano friction generates electricity
Machine 2 deforms upon and can generate electricity, and for providing electric energy to display screen 1, makes display screen 1 show anti-counterfeiting label
Know.
See Fig. 2, it illustrates the present invention for bottle false proof device disassemble schematic diagram.This enforcement
In example, display screen 1 and nano friction generator 2 are realized by the wire 6 being arranged in false proof band 3
Electrical connection, the false proof band 3 in the present embodiment can be ribbon conventional in existing bottle or silk ribbon etc..
It should be understood of course that display screen 1 and nano friction generator 2 in the present invention may be used without it
His electric connection mode, such as, the false proof band 3 in the present embodiment can be made up of paper material,
Being coated with electrically conductive ink on the false proof band 3 of papery, thus display screen 1 and nano friction generator 2 are just
Electrical connection can be realized by the electrically conductive ink on false proof band 3.
When needs carry out anti-counterfeit recognition to bottle, only the nano friction being positioned on bottle bottle 4 need to be pressed
Electromotor 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then passes through wire
6 are sent to be positioned at the display screen 1 at wine bottle cap 5 top, so that display screen 1 realizes false proof display.
Further, it is the bottle 4 being simultaneously fixedly installed on bottle due to the false proof band 3 in the present embodiment
With on bottle cap 5, therefore when opening wine bottle, need from bottle, first take off false proof band 3, generally use
Mode be to tear or cut off false proof band 3 to shreds, and the wire 6 being now placed on false proof band 3 will break
Open so that the electrical connection of display screen 1 and nano friction generator 2 destroys, thus display screen 1 just cannot
Show anti-counterfeiting information again, reach further false proof function.
See Fig. 3, it illustrates the second embodiment of the false proof device for bottle of the present invention.
In the present embodiment, false proof device includes integrated display screen 1 and nano friction generator 2, preferably
, display screen 1 and nano friction generator 2 be vertically arranged, display screen 1 and nano friction generator
2 realize electrical connection by wire 6.Wherein, display screen 1 is positioned at the top of wine bottle cap 5, and nanometer is rubbed
Wiping electromotor 2 to be positioned on the sidewall of wine bottle cap 5, display screen 1 and nano friction generator 2 are by thoroughly
Bright contraction glued membrane 7 is fixed on wine bottle cap 5.
When needs carry out anti-counterfeit recognition to bottle, only the nanometer being positioned on wine bottle cap 5 sidewall need to be pressed
Friction generator 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then passes through
Wire 6 is sent to be positioned at the display screen 1 at wine bottle cap 5 top, so that display screen 1 realizes false proof
Display.
Further, the glued membrane 7 that shrinks in the present embodiment can be the thermal contraction plastic used on existing wine bottle cap
Material diaphragm seals etc., need when opening wine bottle to remove from the bottle cap of bottle.Therefore, can be by the present embodiment
Connection wire 6 between middle display screen 1 and nano friction generator 2 is extended on contraction glued membrane 7,
It is solidified as a whole with shrinking glued membrane 7, it is preferred that shrink the corresponding position connecting wire 6 on glued membrane 7
Protection adhesive tape 71 can be provided with, connect wire to hide after false proof device is completed, improve safety
Property.Therefore when opening wine bottle, need from the bottle cap 5 of bottle, first take off contraction glued membrane 7, and now position
Will disconnect in the wire 6 shunk on glued membrane 7 so that display screen 1 and the electricity of nano friction generator 2
Continuous damage, thus display screen 1 just cannot show anti-counterfeiting information again, has reached further false proof function.
See Fig. 4 and Fig. 5, it illustrates the third enforcement of the false proof device for bottle of the present invention
Mode.In the present embodiment, false proof device includes display screen 1 and by wire (not shown) and display
The nano friction generator 2 of screen 1 electrical connection, display screen 1 and nano friction generator 2 are co-located on
On circular standing finish 8, standing finish 8 is fixed by snap with false proof band 3 to be connected.This enforcement
In example, standing finish 8 is fixedly installed on the bottle 4 of bottle, namely display screen 1 and nano friction generate electricity
Machine 2 is positioned on the bottle 4 of bottle, and false proof band 3 is then fixedly installed on the bottle cap 5 of bottle.
When needs carry out anti-counterfeit recognition to bottle, only the nano friction being positioned on bottle bottle 4 need to be pressed
Electromotor 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then passes through wire
It is sent to the display screen 1 being similarly positioned on bottle bottle 4, so that display screen 1 realizes false proof display.
Further, the connection wire between display screen 1 and nano friction generator 2 is extended on solid
Determine on the false proof band 3 that accessory 8 is connected, due to band 3 false proof in the present embodiment, standing finish 8 points
It is not positioned on bottle 4 and the bottle cap 5 of bottle, therefore when opening wine bottle, need to be first by false proof band 3 He
Separately, the wire being thus positioned on false proof band 3 will disconnect standing finish 8 so that display screen 1 He
The electrical connection of nano friction generator 2 destroys, thus display screen 1 just cannot show anti-counterfeiting information again, reaches
Arrive further false proof function.
See Fig. 6 and Fig. 7, it illustrates the 4th kind of enforcement of the false proof device for bottle of the present invention
Mode.In the present embodiment, false proof device includes display screen 1 and by wire (not shown) and display
The nano friction generator 2 of screen 1 electrical connection, display screen 1 and nano friction generator 2 are co-located on
On standing finish 8, the most upper and lower layout.In the present embodiment, standing finish 8 is fixedly installed on bottle
On the sidewall of bottle cap 5, wherein, standing finish 8 is provided with the part of display screen 1 and is fixedly installed on bottle cap
On the body of 5, the part being provided with nano friction generator 2 is fixedly installed on the constraint ring 9 of bottle cap 5.
When needs carry out anti-counterfeit recognition to bottle, only the nano friction being positioned on standing finish 8 need to be pressed
Electromotor 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then passes through wire
It is sent to the display screen 1 being similarly positioned on standing finish 8, so that display screen 1 realizes false proof display.
Further, in the present embodiment constraint ring 9 can be on existing wine bottle cap use connection ring,
Sealing rings etc., need when opening wine bottle to be opened by bottle cap at constraint ring 9.Therefore, can be by this enforcement
In example, connection wire between display screen 1 and nano friction generator 2 is arranged on and is fixed on constraint ring 9
False proof band 3 on.Therefore when opening wine bottle, need first from the bottle cap 5 of bottle, to take off standing finish
8, then at constraint ring 9, bottle cap could be opened, and be now placed in the wire on false proof band 3 just
Can disconnect so that the electrical connection of display screen 1 and nano friction generator 2 destroys, thus display screen 1 is just
Anti-counterfeiting information cannot be shown again, reached further false proof function.
See Fig. 8 and Fig. 9, it illustrates the 5th kind of enforcement of the false proof device for bottle of the present invention
Mode.In the present embodiment, false proof device includes display screen 1 and by wire (not shown) and display
The nano friction generator 2 of screen 1 electrical connection, wherein, display screen 1 is arranged on the standing finish 8 of circle
On, standing finish 8 is fixedly installed on the top of bottle cap 5, and nano friction generator 2 is arranged on false proof bar
On band 3, false proof band 3 is connected with standing finish 8, and one end of false proof band 3 is fixedly installed on bottle cap
On the constraint ring 9 of 5, and nano friction generator 2 is positioned on the sidewall of wine bottle cap 5.
When needs carry out anti-counterfeit recognition to bottle, only the nanometer being positioned on wine bottle cap 5 sidewall need to be pressed
Friction generator 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then passes through
Wire is sent to be positioned at the display screen 1 at wine bottle cap 5 top, so that display screen 1 realizes false proof aobvious
Show.
Further, the constraint ring 9 in the present embodiment being provided with tab 11, tab 11 includes two
The individual bent over arms being oppositely arranged, has certain gap between two bent over arms.False proof bar in the present embodiment
One end with 3 be located on constraint ring 9 by two bent over arms of tab 11, and makes false proof band 3
On nano friction generator 2 be positioned at the top of tab 11, namely nano friction generator 2 is positioned at
Between tab 11 and display screen 1.The most false proof band 3 is positioned at shape in the part below tab 11
Become to have block raised line 31, can prevent false proof band 3 from detaching from the top of tab 11.
Preferably, the false proof band 3 in the present embodiment is positioned at the part above tab 11 by flexibility
Material is made, and is positioned at the part below tab and is made up of hard material.Thus see Fig. 8, work as needs
During opening wine bottle, first false proof band 3 need to be pulled downward on along tab 11, treat that false proof band 3 is soft
Soft part by tab 11 time, by false proof band 3 between two bent over arms of tab 11 between
Extract out at gap, it is achieved the dismounting of the false proof device in the present embodiment.
Additionally, as it is shown in figure 9, be also provided with liquid storing bag on false proof band 3 in the present embodiment
10, liquid storing bag 10 is preferably provided between tab 11 and nano friction generator 2, liquid storing bag 10
In can be equiped with the liquid that can destroy the internal electrification structure of nano friction generator 2, as ink, glue,
Oil or organic solvent etc., after aforesaid liquid enters nano friction generator 2 inside, can make nano friction send out
Motor 2 loses generating capacity.Further, in the present embodiment the liquid storing bag 10 on false proof band 3 with receive
Being provided with fluid passage (not shown) between rice friction generator 2, the liquid in liquid storing bag 10 can lead to
Cross this fluid passage and enter into nano friction generator 2 inside, to damage nano friction generator.
The liquid between liquid storing bag 10 and nano friction generator 2 during original state, in the present embodiment
Being provided with sealing film (not shown) in passage, this sealing film can stop the liquid in liquid storing bag 10
Body enters nano friction generator 2.But when pulling downward on false proof band 3 along tab 11, it is intended to from bottle
During this false proof device of upper dismounting, tab 11 can extrude liquid storing bag 10, makes the liquid in liquid storing bag 10
In a large amount of influent passages, consequent impulsive force can damage the sealing film within fluid passage,
And then it is internal to flow liquid into nano friction generator 2, makes the display screen 1 in false proof device lose energy
Amount source, it is impossible to show anti-counterfeiting information again, reached further false proof function.
See Figure 10 to Figure 12, it illustrates the 6th kind of reality of the false proof device for bottle of the present invention
Execute mode.In the present embodiment, false proof device includes that display screen 1 and the nanometer electrically connected with display screen 1 are rubbed
Wiping electromotor 2, display screen 1 and nano friction generator 2 are co-located on the top of bottle cap 5, preferably
The lower section of display screen 1 it is arranged on for nano friction generator 2.The top being specially bottle cap 5 is provided with recessed
Cell wall 51, forms groove, display screen 1 and nano friction generator 2 between groove walls 51 and bottle cap 5
It is seated in groove.
When needs carry out anti-counterfeit recognition to bottle, only need to press and be positioned at the nano friction at bottle cap 5 top and send out
Motor 2 can realize the generation of electric energy, and the electric current that nano friction generator 2 produces then is passed by wire
Deliver to be positioned at the display screen 1 at wine bottle cap 5 top, so that display screen 1 realizes false proof display.
Further, seeing Figure 11, the sidewall of bottle cap 5 is provided with false proof band 3, sets in false proof band 3
It is equipped with rectification circuit module 12.In the present embodiment, nano friction generator 2 is used for converting mechanical energy into
Electric energy, provides electric energy for display screen 1, and rectification circuit module 12 is then by the first wire 13 and nanometer
The outfan of friction generator 2 is connected, for being converted to by the alternating current that nano friction generator 2 exports
Unidirectional current.Additionally, display screen 1 is then by the outfan phase of the second wire 14 with rectification circuit module 12
Even, in order to the unidirectional current that rectification circuit module 12 exports is supplied to display screen 1, it is achieved false proof display.
Seeing Figure 10 and Figure 12, display screen 1 and nano friction generator 2 in the present embodiment are passed through anti-
Pseudo-lid set 15 is fixed on bottle cap 5, and wherein, Anti-theft cap cover 15 includes the first lid jacket wall 151 and second
Lid jacket wall 152, the first lid jacket wall 151 is provided with multiple pin 153, the second lid jacket wall 152 sets
Having multiple pin hole 154, the first lid jacket wall 151 and the second lid jacket wall 152 are by pin 153 and pin
Hole 154 is fixed together, and forms complete Anti-counterfeit bottle cover 15.
Additionally, the bottom of the first lid jacket wall 151 and the second lid jacket wall 152 can be formed with draw-in groove 155, anti-
Pseudo-band 3 can stretch out at draw-in groove 155, when being intended to opening wine bottle, need to first by Anti-theft cap cover 15 from
Taking off on bottle cap, method can use and pull stretch out at the draw-in groove 155 of Anti-theft cap cover 15 bottom false proof
Band 3, makes the first lid jacket wall 151 and the second lid jacket wall 152 of Anti-theft cap cover 15 separate, Jin Ercong
Anti-theft cap cover 15 is taken off on bottle cap, but connection wire (the first wire 13 He on the most false proof band 3
Second wire 14) will disconnect so that the electrical connection of display screen 1 and nano friction generator 2 destroys,
Thus display screen 1 just cannot show anti-counterfeiting information again, has reached further false proof function.
The false proof device on bottle of the present invention i.e. can verify that wine by simple pressing mode
The true and false, simple to operation, and this device can design shape, position etc. flexibly, effectively solve
The anti-pseudo problem of wine.
The structure shape of the nano friction generator being used in the present invention is described referring to Figure 13 to Figure 18
Formula:
See Figure 13 and Figure 14, it illustrates the first structure of nano friction generator in the present invention.
As shown in figure 14, the nano friction generator 2 in the present embodiment includes: first be cascading
Electrode 21, the first high molecular polymer insulating barrier 22, and the second electrode 23, wherein, the first electrode
21 and second electrode 23 be the voltage and current output electrode of nano friction generator.
Further, the first electrode 21 in the present embodiment is arranged on the first high molecular polymer insulating barrier 22
The first side surface on；Second side surface of the first high molecular polymer insulating barrier 22 and the second electrode 23
Surface contact friction and at the second electrode 23 and the first electrode 21, induce electric charge.Wherein, first
At least one table in two surfaces that high molecular polymer insulating barrier 22 and the second electrode 23 are oppositely arranged
Micro-nano concaveconvex structure 24 it is provided with on face.
Further, the first high molecular polymer insulating barrier 22 in the present embodiment is thin selected from polyimides
Film, aniline-formaldehyde resin thin film, polyformaldehyde thin film, ethyl cellulose film, polyamide film, trimerization
Cyanamide formaldehyde thin film, Polyethylene Glycol succinate thin film, cellulose membrane, cellulose acetate film,
10PE27 thin film, polydiallyl phthalate thin film, fiber (regeneration) sponge are thin
Film, elastic polyurethane body thin film, styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer thin film,
Staple fibre thin film, poly-methyl thin film, methacrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol
Thin film, mylar, polyisobutylene thin film, polyurethane flexible sponge films, poly terephthalic acid second two
Alcohol ester film, polyvinyl butyral film, formaldehyde-phenol thin film, neoprene thin film, butadiene third
Alkene copolymer thin film, natural rubber films, polyacrylonitrile thin film, acrylonitrile vinyl chloride film and polyethylene
One in third diphenol carbonate thin film.
Further, the first electrode 21 material therefor in the present embodiment be indium tin oxide, Graphene,
Nano silver wire film, metal or alloy；Wherein, metal be Au Ag Pt Pd, aluminum, nickel, copper, titanium,
Chromium, selenium, ferrum, manganese, molybdenum, tungsten or vanadium；Alloy be aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy,
Copper alloy, kirsite, manganese alloy, nickel alloy, metal, ashbury metal, cadmium alloy, bismuth alloy, indium
Alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy；Second electrode 23 material therefor
It it is metal or alloy；Wherein, metal be Au Ag Pt Pd, aluminum, nickel, copper, titanium, chromium, selenium,
Ferrum, manganese, molybdenum, tungsten or vanadium；Alloy be aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy, copper alloy,
Kirsite, manganese alloy, nickel alloy, metal, ashbury metal, cadmium alloy, bismuth alloy, indium alloy, gallium
Alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy.
When rubbing with high molecular polymer based on metal, metal is more easy to lose electronics, therefore uses in the present invention
Metal electrode and high molecular polymer friction energy are effectively improved energy output.Therefore, above-mentioned nanometer is rubbed
Mainly by metal (the second electrode 23), (the first high molecular polymer insulate with polymer to wipe electromotor
Layer 22) between friction produce the signal of telecommunication, be i.e. the characteristic that make use of metal easily to lose electronics,
Make to be formed between the second electrode 23 and the first high molecular polymer insulating barrier 22 induction field, thus produce
Voltage or electric current.
Introduce the operation principle of nano friction generator in the present embodiment in detail below:
The second electrode when each layer of this nano friction generator is bent downwardly, in nano friction generator
23 produce electrostatic charge, the generation of electrostatic charge with the first high molecular polymer insulating barrier 22 surface phase mutual friction
The electric capacity between the first electrode 21 and the second electrode 23 can be made to change, thus cause the first electrode
21 and second there is electric potential difference between electrode 23.
Due to the existence of electric potential difference between the first electrode 21 and the second electrode 23, free electron will be by outward
Circuit is flowed to, by the side that electromotive force is low, the side that electromotive force is high, thus forms electric current in external circuit.And when being somebody's turn to do
When each layer of nano friction generator returns to original state, at this moment it is formed at the first electrode 21 and second
Built-in potential between electrode 23 disappears, between the most Balanced first electrode 21 and the second electrode 23
To again produce reverse electric potential difference, then free electron forms reverse current by external circuit.From there through
Repeatedly rub and recover, it is possible in external circuit, forming periodic ac signal.
See Figure 15 and Figure 16, it illustrates the second structure of nano friction generator in the present invention.
As shown in figure 16, the nano friction generator 2 in the present embodiment farther includes: be arranged on the second electricity
The second high molecular polymer insulating barrier 25 between pole 23 and the first high molecular polymer insulating barrier 22；
Wherein, the first electrode 21 and voltage and current output electrode that the second electrode 23 is nano friction generator.
Further, the second electrode 23 is arranged on the first side surface of the second high molecular polymer insulating barrier 25
On；Second side surface of the first high molecular polymer insulating barrier 22 and the second high molecular polymer insulating barrier
The second side surface contact of 25 rubs and induces electric charge at the first electrode 21 and the second electrode 23.
Wherein, the first high molecular polymer insulating barrier 22 and the second high molecular polymer insulating barrier 25 are oppositely arranged
Two surfaces at least one surface on be provided with micro-nano concaveconvex structure 24.
Further, the first high molecular polymer insulating barrier 22 and the second high molecular polymerization in the present embodiment
Thing insulating barrier 25 be respectively selected from Kapton, aniline-formaldehyde resin thin film, polyformaldehyde thin film,
Ethyl cellulose film, polyamide film, melamino-formaldehyde thin film, Polyethylene Glycol succinate thin film,
Cellulose membrane, cellulose acetate film, 10PE27 thin film, poly-phthalic acid two
Allyl ester thin film, fiber (regeneration) sponge films, elastic polyurethane body thin film, styrene-acrylonitrile copolymer copolymerization
Thing thin film, styrene-butadiene-copolymer thin film, staple fibre thin film, poly-methyl thin film, metering system
Acid esters thin film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, polyisobutylene thin film, poly-ammonia
Ester flexibility sponge films, pet film, polyvinyl butyral film, formaldehyde
Phenol thin film, neoprene thin film, butadiene-propylene copolymer thin film, natural rubber films, polypropylene
One in nitrile thin film, acrylonitrile vinyl chloride film and polyethylene the third diphenol carbonate thin film.
Further, the first electrode 21 in the present embodiment and the second electrode 23 material therefor are the oxidations of indium stannum
Thing, Graphene, nano silver wire film, metal or alloy；Wherein, metal be Au Ag Pt Pd, aluminum,
Nickel, copper, titanium, chromium, selenium, ferrum, manganese, molybdenum, tungsten or vanadium；Alloy is aluminium alloy, titanium alloy, magnesium conjunction
Gold, beryllium alloy, copper alloy, kirsite, manganese alloy, nickel alloy, metal, ashbury metal, cadmium alloy,
Bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy.
It should be noted that the first high molecular polymer insulating barrier 22 and the second macromolecule in the present embodiment
The material of polymer insulation layer 25 can be identical, it is also possible to different.If but two-layer high molecular polymer
The material of insulating barrier is the most identical, it will the quantity of electric charge causing triboelectrification is the least.It is therefore preferred that this
The first high molecular polymer insulating barrier 22 and material of the second high molecular polymer insulating barrier 25 in embodiment
Matter is different.
Introduce the operation principle of nano friction generator in the present embodiment in detail below:
The first high score when each layer of this nano friction generator is bent downwardly, in nano friction generator
Sub-polymer insulation layer 22 produces electrostatic with the second high molecular polymer insulating barrier 25 surface phase mutual friction
Lotus, the generation of electrostatic charge can make the electric capacity between the first electrode 21 and the second electrode 23 change, from
And cause, between the first electrode 21 and the second electrode 23, electric potential difference occurs.
Due to the existence of electric potential difference between the first electrode 21 and the second electrode 23, free electron will be by outward
Circuit is flowed to, by the side that electromotive force is low, the side that electromotive force is high, thus forms electric current in external circuit.When this is received
When each layer of rice friction generator returns to original state, at this moment it is formed at the first electrode 21 and the second electricity
Built-in potential between pole 23 disappears, will between the most Balanced first electrode 21 and the second electrode 23
Again produce reverse electric potential difference, then free electron forms reverse current by external circuit.From there through instead
Multiple friction and recovery, it is possible in external circuit, form periodic ac signal.
See Figure 17 and Figure 18, it illustrates the third structure of nano friction generator in the present invention.
As shown in figure 18, the nano friction generator of the present embodiment farther includes: be arranged on the first macromolecule
Thin layer 26 between two parties between polymer insulation layer 22 and the second high molecular polymer insulating barrier 25, its
In, the first electrode 21 and the voltage and current output electrode that the second electrode 23 is nano friction generator.
Further, the thin layer between two parties 26 in the present embodiment is also high molecular polymer insulating barrier, and institute
State in two faces that thin layer 26 and the first high molecular polymer insulating barrier 22 are oppositely arranged between two parties at least
One face is provided with micro-nano concaveconvex structure 24, and/or described thin layer between two parties 26 and the second high molecular polymerization
At least one face in two faces that thing insulating barrier 25 is oppositely arranged is provided with micro-nano concaveconvex structure 24.Its
In, thin layer 26 is high with the first high molecular polymer insulating barrier 22 second side surface and second respectively between two parties
Second side surface contact of Molecularly Imprinted Polymer insulating barrier 25 rubs and at the first electrode 21 and the second electrode
Electric charge is induced on 23.
Further, first high molecular polymer insulating barrier the 22, second high molecular polymerization in the present embodiment
Thing insulating barrier 25 and between two parties thin layer 26 be respectively selected from Kapton, aniline-formaldehyde resin thin film,
Polyformaldehyde thin film, ethyl cellulose film, polyamide film, melamino-formaldehyde thin film, Polyethylene Glycol
Succinate thin film, cellulose membrane, cellulose acetate film, 10PE27 thin film,
Polydiallyl phthalate thin film, fiber (regeneration) sponge films, elastic polyurethane body thin film,
Styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer thin film, staple fibre thin film, poly-methyl
Thin film, methacrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, poly-different
Butylene thin film, polyurethane flexible sponge films, pet film, polyvinyl alcohol contract
Butyral film, formaldehyde-phenol thin film, neoprene thin film, butadiene-propylene copolymer thin film, natural rubber
In glue thin film, polyacrylonitrile thin film, acrylonitrile vinyl chloride film and polyethylene the third diphenol carbonate thin film
A kind of.
It should be noted that first high molecular polymer insulating barrier the 22, second macromolecule in the present embodiment
The material of polymer insulation layer 25 and thin layer 26 between two parties can be identical, it is also possible to different.If but three
The material of floor height Molecularly Imprinted Polymer insulating barrier is the most identical, then the quantity of electric charge that can cause triboelectrification is the least.Cause
This, it is preferable that the first high molecular polymer insulating barrier 22 in the present embodiment and thin layer 26 between two parties
Material is different, and the second high molecular polymer insulating barrier 25 is different from the material of thin layer 26 between two parties, and the
One high molecular polymer insulating barrier 22 is identical with the material of the second high molecular polymer insulating barrier 25, in order to
Reducing material category, the making making the present invention is convenient.
Further, the first electrode 21 in the present embodiment and the second electrode 23 material therefor are the oxidations of indium stannum
Thing, Graphene, nano silver wire film, metal or alloy；Wherein, metal be Au Ag Pt Pd, aluminum,
Nickel, copper, titanium, chromium, selenium, ferrum, manganese, molybdenum, tungsten or vanadium；Alloy is aluminium alloy, titanium alloy, magnesium conjunction
Gold, beryllium alloy, copper alloy, kirsite, manganese alloy, nickel alloy, metal, ashbury metal, cadmium alloy,
Bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy.
Introduce the operation principle of nano friction generator in the present embodiment in detail below:
The first high score when each layer of this nano friction generator is bent downwardly, in nano friction generator
Sub-polymer insulation layer 22 produces electrostatic charge, the generation meeting of electrostatic charge with thin layer 26 phase mutual friction between two parties
Make the electric capacity between the first electrode 21 and the second electrode 23 change, thus cause the first electrode 21
With second there is electric potential difference between electrode 23.
Due to the existence of electric potential difference between the first electrode 21 and the second electrode 23, free electron will be by outward
Circuit is flowed to, by the side that electromotive force is low, the side that electromotive force is high, thus forms electric current in external circuit.When this is received
When each layer of rice friction generator returns to original state, at this moment it is formed at the first electrode 21 and the second electricity
Built-in potential between pole 23 disappears, will between the most Balanced first electrode 21 and the second electrode 23
Again produce reverse electric potential difference, then free electron forms reverse current by external circuit.From there through instead
Multiple friction and recovery, it is possible in external circuit, form periodic ac signal.
It addition, the micro-nano concaveconvex structure 24 in the nano friction generator of above-mentioned three kinds of structures is the most micro-
Meter level or nano level concaveconvex structure.
Thus, when the nano friction generator of the present invention uses above-mentioned several forms to realize, this bottle
False proof device can realize self-energizing, as long as can be produced electric energy by friction, does not haves battery electricity
The situation that amount exhausts and cannot use, greatly facilitates the use of user.
By specific embodiment the present invention done above further describe it should be understood that, this
In concrete description, should not be construed as the restriction to the spirit and scope of the invention, common in this area
The various amendments that above-described embodiment is made by technical staff after reading this specification, broadly fall into institute of the present invention
The scope of protection.
Claims (24)
1. the false proof device for bottle, it is characterised in that include display screen (1) and with display
The nano friction generator (2) that screen (1) electrically connects, display screen (1) is used for showing anti-counterfeiting mark,
Nano friction generator (2) produces electric energy after deforming upon, and powers for display screen (1), and bottle is opened
After, false proof device damages, and display screen (1) cannot show anti-counterfeiting information again；Display screen (1) is arranged on
On standing finish (8), nano friction generator (2) is arranged on false proof band (3) or standing finish
(8), on, false proof band (3) is connected with standing finish (8).
False proof device for bottle the most according to claim 1, it is characterised in that display screen
(1) being positioned at the top of bottle cap (5), nano friction generator (2) is positioned on bottle (4), passes through
Nano friction generator (2) in pressing bottle (4), can make display screen (1) realize false proof display.
False proof device for bottle the most according to claim 2, it is characterised in that display screen
(1) being arranged on standing finish (8), standing finish (8) is fixedly installed on the top of bottle cap (5),
Nano friction generator (2) is arranged on false proof band (3), false proof band (3) and standing finish
(8) being connected, nano friction generator (2) is positioned on bottle (4), and display screen (1) and nanometer are rubbed
Wipe electromotor (2) and realize electrical connection by the wire (6) being arranged in false proof band (3).
False proof device for bottle the most according to claim 3, it is characterised in that false proof bar
Band (3) is fixedly installed on bottle (4) and the bottle cap (5) of bottle, need to pull down anti-during opening wine bottle
Pseudo-band (3), the electrical connection of display screen (1) and nano friction generator (2) will disconnect, aobvious
Display screen (1) cannot show anti-counterfeiting information again.
False proof device for bottle the most according to claim 1, it is characterised in that display screen
(1) it is positioned on bottle (4) with nano friction generator (2), by receiving in pressing bottle (4)
Rice friction generator (2), can make display screen (1) realize false proof display.
False proof device for bottle the most according to claim 5, it is characterised in that display screen
(1) being arranged on standing finish (8) with nano friction generator (2), standing finish (8) is with anti-
Pseudo-band (3) is connected, and standing finish (8) is fixedly installed on bottle (4), false proof band (3)
It is fixedly installed on bottle cap (5).
False proof device for bottle the most according to claim 6, it is characterised in that display screen
(1) the connection wire and between nano friction generator (2) is extended on and standing finish (8)
On the false proof band (3) being connected, need to be by false proof band (3) and standing finish (8) during opening wine bottle
Separately, the connection wire between display screen (1) and nano friction generator (2) will disconnect, display
Screen (1) cannot show anti-counterfeiting information again.
False proof device for bottle the most according to claim 1, it is characterised in that display screen
(1) it is fixedly installed on the sidewall of bottle cap (5) with nano friction generator (2), passes through pressing bottle
Nano friction generator (2) on lid (5) sidewall, can make display screen (1) realize false proof display.
False proof device for bottle the most according to claim 8, it is characterised in that display screen
(1) being arranged on standing finish (8) with nano friction generator (2), standing finish sets on (8)
The part having display screen (1) is fixedly installed on the body of bottle cap (5), is provided with nano friction generator
(2) part is fixedly installed on the constraint ring (9) of bottle cap (5).
False proof device for bottle the most according to claim 9, it is characterised in that display screen
(1) the connection wire and between nano friction generator (2) is arranged on and is fixed in constraint ring (9)
False proof band (3) on, standing finish (8) need to be taken off from bottle cap (5) during opening wine bottle, aobvious
Connection wire between display screen (1) and nano friction generator (2) will disconnect, display screen (1)
Anti-counterfeiting information cannot be shown again.
11. false proof devices for bottle according to claim 1, it is characterised in that display screen
(1) being arranged on standing finish (8), standing finish (8) is fixedly installed on the top of bottle cap (5),
Nano friction generator (2) is arranged on false proof band (3), false proof band (3) and standing finish
(8) being connected, nano friction generator (2) is positioned on the sidewall of bottle cap (5), by pressing bottle cap
(5) nano friction generator on sidewall (2), can make display screen (1) realize false proof display.
12. false proof devices for bottle according to claim 11, it is characterised in that false proof
One end of band (3) be located in the bundle of bottle cap (5) by the tab (11) in constraint ring (9)
Tiing up on ring (9), the nano friction generator (2) on false proof band (3) is positioned at tab (11)
Top, false proof band (3) be positioned at tab (11) lower section part on be formed with block raised line (31).
13. false proof devices for bottle according to claim 12, it is characterised in that locking
Button (11) includes two bent over arms being oppositely arranged, and has certain gap between two bent over arms, false proof
One end of band (3) be located in constraint ring (9) by two bent over arms of tab (11), false proof
The part being positioned at tab (11) top on band (3) is fabricated from a flexible material, and is positioned under tab
The part of side is made up of hard material, and the part soft when false proof band (3) passes through tab (11)
Time, the false proof band (3) gap location between two bent over arms of tab (11) can be extracted out.
14. false proof devices for bottle according to claim 13, it is characterised in that false proof
The liquid storing bag being positioned between tab (11) and nano friction generator (2) it is provided with on band (3)
(10), liquid storing bag (10) is equiped with can destroy nano friction generator (2) internal generating knot
The liquid of structure, has between liquid storing bag (10) and the nano friction generator (2) on false proof band (3)
Set the fluid passage of sealing film in having, along tab (11) pull downward on false proof band (3) time,
Damage sealing film in liquid influent passage in liquid storing bag (10), and then it is flowed into nano friction
Electromotor (2) is internal, makes display screen (1) lose energy source, it is impossible to show anti-counterfeiting information again.
15. false proof devices for bottle according to claim 1, it is characterised in that display screen
(1) and nano friction generator (2) is co-located on the top of bottle cap (5), nano friction generates electricity
Machine (2) is positioned at the lower section of display screen (1), is generated electricity by the nano friction at pressing bottle cap (5) top
Machine (2), can make display screen (1) realize false proof display.
16. false proof devices for bottle according to claim 15, it is characterised in that bottle cap
(5) top is provided with groove walls (51), forms groove between groove walls (51) and bottle cap (5),
Display screen (1) and nano friction generator (2) are seated in groove.
17. false proof devices for bottle according to claim 15, it is characterised in that bottle cap
(5) sidewall is provided with false proof band (3), and false proof band is provided with rectification circuit module in (3)
(12), rectification circuit module (12) is by the first wire (13) and nano friction generator (2)
Outfan be connected, for the alternating current that nano friction generator (2) exports is converted to unidirectional current,
Display screen (1) is connected with the outfan of rectification circuit module (12) by the second wire (14), with
Just the unidirectional current that rectification circuit module (12) exports is supplied to display screen (1), it is achieved false proof display.
18. false proof devices for bottle according to claim 17, it is characterised in that display
Screen (1) and nano friction generator (2) are fixed on bottle cap (5) by Anti-theft cap cover (15),
Anti-theft cap cover (15) includes the first lid jacket wall (151) and the second lid jacket wall (152), the first lid jacket wall
(151) it is provided with at least one pin (153) on, the second lid jacket wall (152) is provided with at least
One pin hole (154), the first lid jacket wall (151) and the second lid jacket wall (152) pass through pin (153)
It is fixed together with pin hole (154), forms complete Anti-theft cap cover (15).
19. false proof devices for bottle according to claim 18, it is characterised in that first
The bottom of lid jacket wall (151) and the second lid jacket wall (152) is formed with draw-in groove (155), false proof band
(3) can stretch out from draw-in groove (155), need to pull during opening wine bottle from Anti-theft cap cover (15) bottom
The false proof band (3) that draw-in groove (155) place stretches out, makes the first lid jacket wall (151) of Anti-theft cap cover (15)
With the second lid jacket wall (152) separately, the first wire (13) and second being positioned on false proof band (3)
Wire (14) will disconnect so that display screen (1) cannot show anti-counterfeiting information again.
20. false proof devices for bottle according to claim 1, it is characterised in that nanometer is rubbed
Wipe electromotor (2) to include:
First high molecular polymer insulating barrier (22)；
First electrode (21), is arranged on the first side surface of the first high molecular polymer insulating barrier (22)
On；
Second electrode (23), the surface of the second electrode (23) and the first high molecular polymer insulating barrier (22)
Second side surface contact；
Two surfaces that first high molecular polymer insulating barrier (22) and the second electrode (23) are oppositely arranged
In at least one surface on be provided with micro-nano concaveconvex structure (24)；
First electrode (21) and the voltage and current output that the second electrode (23) is nano friction generator
Electrode.
21. false proof devices for bottle according to claim 20, it is characterised in that nanometer
Friction generator (2) farther includes:
Second be arranged between the second electrode (23) and the first high molecular polymer insulating barrier (22) is high
Molecularly Imprinted Polymer insulating barrier (25)；
Second electrode (23) is arranged on the first side surface of the second high molecular polymer insulating barrier (25),
Second side surface of the first high molecular polymer insulating barrier (22) and the second high molecular polymer insulating barrier
(25) the second side surface contact；
First high molecular polymer insulating barrier (22) is relative with the second high molecular polymer insulating barrier (25)
It is provided with micro-nano concaveconvex structure (24) at least one surface in two surfaces arranged；
First electrode (21) and the voltage and current output that the second electrode (23) is nano friction generator
Electrode.
22. false proof devices for bottle according to claim 21, it is characterised in that first
High molecular polymer insulating barrier (22) is different from the material of the second high molecular polymer insulating barrier (25).
23. false proof devices for bottle according to claim 21, it is characterised in that nanometer
Friction generator (2) farther includes:
It is arranged on the first high molecular polymer insulating barrier (22) and the second high molecular polymer insulating barrier (25)
Between thin layer between two parties (26), thin layer (26) is high molecular polymer insulating barrier between two parties, and occupy
Between in two faces being oppositely arranged of thin layer (26) and the first high molecular polymer insulating barrier (22) extremely
A few face is provided with micro-nano concaveconvex structure (24), and/or thin layer (26) and the second high score between two parties
At least one face in two faces that sub-polymer insulation layer (25) is oppositely arranged is provided with the concavo-convex knot of micro-nano
Structure (24)；
Between two parties thin layer (26) respectively with the first high molecular polymer insulating barrier (22) second side surface and
Second side surface contact of the second high molecular polymer insulating barrier (25) rubs and in the first electrode (21)
Electric charge is induced with on the second electrode (23)；
First electrode (21) and the voltage and current output that the second electrode (23) is nano friction generator
Electrode.
24. false proof devices for bottle according to claim 23, it is characterised in that first
High molecular polymer insulating barrier (22) is different from the material of thin layer between two parties (26), the first polyphosphazene polymer
Compound insulating barrier (22) is identical with the material of the second high molecular polymer insulating barrier (25).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610493489.XA CN105923261B (en) | 2013-03-22 | 2013-03-22 | A kind of false proof device for bottle |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310096079.8A CN104058168B (en) | 2013-03-22 | 2013-03-22 | Anti-counterfeiting device for wine bottle |
| CN201610493489.XA CN105923261B (en) | 2013-03-22 | 2013-03-22 | A kind of false proof device for bottle |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310096079.8A Division CN104058168B (en) | 2013-03-22 | 2013-03-22 | Anti-counterfeiting device for wine bottle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105923261A true CN105923261A (en) | 2016-09-07 |
| CN105923261B CN105923261B (en) | 2018-06-22 |
Family
ID=51546158
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310096079.8A Active CN104058168B (en) | 2013-03-22 | 2013-03-22 | Anti-counterfeiting device for wine bottle |
| CN201610493489.XA Active CN105923261B (en) | 2013-03-22 | 2013-03-22 | A kind of false proof device for bottle |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310096079.8A Active CN104058168B (en) | 2013-03-22 | 2013-03-22 | Anti-counterfeiting device for wine bottle |
Country Status (2)
| Country | Link |
|---|---|
| CN (2) | CN104058168B (en) |
| WO (1) | WO2014146466A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2566958A (en) * | 2017-09-28 | 2019-04-03 | Saralon Gmbh | Anti-counterfeiting system |
| CN110675743A (en) * | 2019-10-16 | 2020-01-10 | 济南嘉源电子有限公司 | Power supply separation type anti-counterfeiting display screen |
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| CN203186788U (en) * | 2013-03-22 | 2013-09-11 | 纳米新能源（唐山）有限责任公司 | Anti-fake device for wine bottle |
| CN203186786U (en) * | 2013-03-22 | 2013-09-11 | 纳米新能源（唐山）有限责任公司 | Anti-fake device for wine bottle |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104058168A (en) | 2014-09-24 |
| CN104058168B (en) | 2017-04-12 |
| CN105923261B (en) | 2018-06-22 |
| WO2014146466A1 (en) | 2014-09-25 |
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