CN105911657B - A kind of carbon fiber composite cable and preparation method thereof with optical fiber - Google Patents

A kind of carbon fiber composite cable and preparation method thereof with optical fiber Download PDF

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CN105911657B
CN105911657B CN201610375669.8A CN201610375669A CN105911657B CN 105911657 B CN105911657 B CN 105911657B CN 201610375669 A CN201610375669 A CN 201610375669A CN 105911657 B CN105911657 B CN 105911657B
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carbon fiber
optical fiber
fiber
carbon
layer
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CN105911657A (en
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张敏
曹伟伟
乔琨
王永伟
朱波
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Shandong University
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
    • G02B6/4401Optical cables
    • G02B6/4429Means specially adapted for strengthening or protecting the cables
    • G02B6/443Protective covering
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
    • G02B6/4479Manufacturing methods of optical cables

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

The invention discloses a kind of carbon fiber composite cable with optical fiber successively has the antidetonation layer and carbon fiber one-way compound wire layer of optical fiber with metal sleeve, the boundary layer of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon fiber braided sleeving enhancing thermoplasticity thermosetting property compound resin from inside to outside.The invention also discloses the preparation methods of the carbon fiber composite cable with optical fiber.The present invention weaves thermoplasticity boundary layer by carbon fiber and combines with the modification technology on metal sleeve surface, the metal sleeve surface and carbon fibre composite for making optical fiber embedment process form the interface cohesion well infiltrated, reach optical fiber structure by carbon fiber weaving manner to be fixedly secured simultaneously, avoids decentraction problem caused by optical fiber slides in subsequent recombination process;Guarantee whole antidetonation bend resistance characteristic during winding and expansion of composite cable by thermoplastic/thermosetting compound resin antidetonation layer.

Description

A kind of carbon fiber composite cable and preparation method thereof with optical fiber
Technical field
The invention belongs to power transmission and field of power communication, and in particular to a kind of carbon fiber composite cable with optical fiber And preparation method thereof.
Background technique
With the development of modern industry, electric system is higher and higher to communicating requirement, not only needs telephone communication, in addition it is also necessary to The information transmission of the large capacities such as remote control, telemetering, data transmission, the automatic control and tracking of especially many power equipments can be accommodated Detection uses computer, has even more increased significantly the quantity of transmission information.Before many researchers once used communication cable with The compound structure of overhead power cables is to solve the problem of the above demand but since various techniques cross Communication Jamming, the research It stagnates always.
Since optic communication occurs, the new key content that is compound and becoming research of optical cable and power cable.Often at present Aerial cable is steel-cored aluminium strand, and final researcher twists the light with matcoveredn together with aluminum steel into forming whole knot The light composite aerial cable of structure, but the structure is easy to appear light damage caused by laying, stringing and running external force Wound, so this structure brings insecurity factor without large-scale use.With carbon fibre composite conducting wire core material Occur, a large amount of use has been obtained also with the aerial cable that carbon fibre composite enhances.Carbon fibre composite is using height What intensity high modulus carbon fiber and resin matrix were combined has prominent under larger rigidity and alternating hot and cold adverse circumstances stablize The new material power Transmission conducting wire of property.The preparation process of the conducting wire core material of the material is that low temperature glue is passing through with after fiber composite Fast curing-formed, which avoids metallic high temperature melting, therefore realizes the compound of optical fiber and cable core material in this process Compared with metal cable more preferably safety and stability, and flexible fiber and liquid resinous compound it is less prone to machine brought by metal aluminum stranded conductor Tool damage.
The research attached most importance at present with the complex technique of carbon fibre composite cable core material and optical fiber is also more, but That there are still many structural instabilities for the current new structural composite cable: 1. fiber optic materials with carbon fiber composite cable It is also required in recombination process by tension winding, therefore directly using the damage for necessarily bringing fiber optics;2. optical fiber surface is traditional Metal protective sleeve pipe and when carbon fibre composite cable composite molding bring the weakness that interface material mismatches and occurs Problem;3. the specific gravity of optical fiber/metal sleeve composite itself is larger, flexible poor, in composite material cable preparation process Embedment concentric problem be relatively difficult to solve.
Summary of the invention
For the above-mentioned prior art, the object of the present invention is to provide a kind of carbon fiber composite cable with optical fiber, this is multiple Close cable be divided into quaternary structure, successively include: from inside to outside with metal sleeve optical fiber, carbon fiber braiding thermoplasticity boundary layer, Carbon fiber weaves thermoplastic/thermosetting compound resin antidetonation layer, carbon fibre composite main body unidirectional ply.Thermoplastic is woven by carbon fiber Property boundary layer combined with the modification technology on metal sleeve surface, keep the metal sleeve surface of optical fiber embedment process and carbon fiber multiple Condensation material forms the interface cohesion well infiltrated, while reaches optical fiber structure by carbon fiber weaving manner and being fixedly secured, keep away Exempt from subsequent recombination process decentraction problem caused by optical fiber sliding;Guaranteed by thermoplastic/thermosetting compound resin antidetonation layer Whole antidetonation bend resistance characteristic during winding and expansion of composite cable;Finally after the above shaping structures, pass through pultrusion Carbon fiber composite structure keeps its stroke composite cable whole.
It is a further object of the present invention to provide the preparation methods of the above-mentioned carbon fiber composite cable with optical fiber.
To achieve the above object, the present invention adopts the following technical solutions:
According to the first aspect of the invention, a kind of carbon fiber composite cable with optical fiber is provided, from inside to outside successively Boundary layer, carbon fiber with optical fiber, carbon fiber braided sleeving enhancing thermoplas tic resin composite with metal sleeve are compiled Knit the antidetonation layer and carbon fiber one-way compound wire layer of casing enhancing thermoplasticity thermosetting property compound resin;
The optical fiber with metal sleeve is made of internal fiber optics and external metal protective sleeve pipe;Wherein institute State optical fiber be selected from single mode optical fiber, multimode fibre and polarization maintaining optical fibre etc. any one;Optical fiber is embedded to quantity can be according to composite cable It is required that any preparation.
The metal protective sleeve pipe of the outer fiber needs to be surface-treated by nitration mixture, and treatment fluid and treatment process are according to gold The adhesive strength for belonging to material and compound interface layer requires to be adjusted flexibly.The diameter of metal protective sleeve pipe is 1-3mm, and length is continuous Length.
In the specific embodiment of the present invention, using the concentrated sulfuric acid/potassium bichromate aqueous solution as mixed acid solution, In 60-65 DEG C of dipping 10-30min, taking-up is rinsed with water, and is dried or is dried at 80 DEG C or less, carries out table to metal protective sleeve pipe Surface treatment.In another embodiment of the invention, using phosphoric acid/chromium oxide/alcohol/formaldehyde mixed liquor, in 15-30 DEG C dipping 10-15min, then washes at 60-80 DEG C, is dry, being surface-treated to metal protective sleeve pipe.
The boundary layer of the described carbon fiber braided sleeving enhancing thermoplas tic resin composite, be formed in it is described through surface at The outside of the metal protective sleeve pipe of reason is formed by the carbon fiber filament of dipping thermoplastic resin in metal sleeve surface weave.
Thermoplastic resin adhesive used is thermoplastic polyurethane, any one in thermoplastic phenolic resin, after impregnation The control of fiber gel content is adjustable between 30-50%.
Available carbon fiber include one of high-strengths carbon fiber such as T300, T700, T800 or it is a variety of mix use, Fibre bundle can be selected that 3K, 6K, 12K etc. be one such or multiple combinations, weave the quantity of tow according to the thickness of metal sleeve Specification is adjusted flexibly.Thermoplas tic resin composite's boundary layer after the braiding of above-mentioned carbon fiber is dried under 70-100 DEG C of environment Dry, heating time is that 3-10min is adjustable.
The antidetonation layer of the carbon fiber braided sleeving enhancing thermoplasticity thermosetting property compound resin, is formed in the carbon fiber Braided sleeving enhances on the boundary layer of thermoplas tic resin composite, and the carbon fiber by dipping thermoplasticity thermosetting property compound resin is long Silk weaves.
The fiber filament of carbon fiber braiding reinforcement used includes in the high-strengths carbon fiber such as T300, T700, T800 It is one or more to mix use;Fibre bundle can be selected that 3K, 6K, 12K etc. be one such or multiple combinations, weave the quantity of tow It is adjusted flexibly according to the thickness specification of the metal sleeve with interfacial TCO layer.
Thermoplasticity thermosetting property compound resin glue used is thermoplastic resin (polyethylene, polyurethane, polyamide, polyphenyl One of ether, polysulfones, polyphenylene sulfide, polytetrafluoroethylene (PTFE), polyformaldehyde or polyether-ether-ketone are a variety of) modified epoxy or phenolic aldehyde Resin.
Fiber gel content control after impregnation is adjustable between 30-50%, by the thermoplasticity heat after the braiding of above-mentioned carbon fiber Antidetonation layer precuring under 100-110 DEG C of environment of solidity compound resin, heating time are that 10-30min is adjustable.
It is multiple to be formed in the carbon fiber braided sleeving enhancing thermoplasticity thermosetting property for the carbon fiber one-way compound wire layer On the antidetonation layer of resin, the carbon fibre tow by being impregnated with resin adhesive liquid is coated and is solidified into through pultrusion on the surface of antidetonation layer Type forms.
According to the second aspect of the invention, the preparation method of the above-mentioned carbon fiber composite cable with optical fiber, step are provided It is as follows:
(1) metal protective sleeve pipe is surface-treated using mixed acid solution, light is then embedded in metal protective sleeve pipe It is fine;
(2) outer braid of the metal protective sleeve pipe after surface treated is impregnated with the carbon fiber of thermoplastic resin, leaching Fiber gel content after glue is 30-50%, is dried after the completion of braiding, and carbon fiber braided sleeving enhancing thermoplastic resin is prepared The boundary layer of composite material;
(3) thermoplastic is impregnated in the surface weave of the boundary layer of carbon fiber braided sleeving enhancing thermoplas tic resin composite Property thermosetting property compound resin carbon fiber, the fiber gel content after impregnation is 30-50%, in 100-110 DEG C of ring after the completion of braiding Precuring is handled under border, prepares the antidetonation layer of carbon fiber braided sleeving enhancing thermoplasticity thermosetting property compound resin;
(4) carbon fiber wire for being impregnated with resin adhesive liquid is subjected to pultrusion cladding on the surface of antidetonation layer, then will coated Carbon fibre tow carry out the molding of primary curing and secondary curing, form carbon fiber one-way compound wire layer;
(5) it is quickly cooled down to get the carbon fiber composite cable of optical fiber is had.
The above method, in step (4), curing oven final temperature is 160-180 DEG C, curing time 5-10min.
The above method, in step (4), " resin adhesive liquid " and " carbon fiber wire " does not have special type to limit, for example, " resin adhesive liquid " can be selected from thermosetting resin;" carbon fiber wire " can be in the high-strengths carbon fiber such as T300, T700, T800 One or more mix use.
Beneficial effects of the present invention:
(1) the carbon fiber composite cable with optical fiber of the invention is compiled using metal sleeve process for treating surface and carbon fiber It knits thermoplasticity boundary layer to combine, is effectively formed good infiltration circle of optical fiber surface coat of metal Yu carbon fibre composite layer Face combines.
(2) the carbon fiber composite cable with optical fiber of the invention is using carbon fiber braiding structure outside optical fiber metal sleeve Portion forms stable fibrage positioning, can effectively ensure that optical fiber structure and carbon by the boundary layer that thermoplastic resin is combined The concentric locating of fibrous composite cable core material.
(3) the carbon fiber composite cable with optical fiber of the invention is anti-using carbon fiber braiding thermoplastic/thermosetting compound resin It shakes layer and optical fiber carbon fiber composite cable is effectively improved in subsequent production by the composite construction of compound resin and braided fiber Winding and construction expansion during impact resistance bend characteristic.
(4) the carbon fiber composite cable with optical fiber of the invention cooperates between each layer structure, be one organically It is whole, the overall stability of the carbon fiber composite cable with optical fiber is effectively increased, while multiple protective is played to optical fiber and is made With avoiding the damage in use process to optical fiber.
Detailed description of the invention
Fig. 1: the structural schematic diagram of the carbon fiber composite cable with optical fiber of the invention;
Wherein, 1- optical fiber, 2- metal protective sleeve pipe, 3- boundary layer, 4- antidetonation layer, 5- carbon fiber one-way compound wire layer.
Specific embodiment
The present invention is further illustrated in conjunction with the embodiments, it should which explanation, following the description is merely to explain this Invention, is not defined its content.
Embodiment 1:
A kind of carbon fibre composite cable with optical fiber includes four preparation sections from core to most surface: having The surface treatment of the metal sleeve of optical fiber, the boundary layer preparation of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon Prepared by the antidetonation layer that fibrage casing enhances thermoplasticity thermosetting property compound resin and the carbon fiber one-way of outmost surface is compound Conductor layer preparation.
Firstly, being embedded to 2 single mode optical fiber long filaments, metal sleeve surface in the continuous length metal sleeve that diameter is 1mm Using the concentrated sulfuric acid/potassium bichromate aqueous solution after 60-65 DEG C of dipping 10-30min, taking-up is rinsed with water, and is dried or at 80 DEG C It dries below.
12 bursts of T300 high-strength carbon fibers of second, the outer braid 3K of the surface treated metal sleeve with optical fiber Dimension, the carbon fiber impregnate thermoplastic polyurethane before metal sleeve knitting process, and the fiber gel content control after impregnation exists 30%.Carbon fiber braiding after dipping glue is completed to dry under 70 DEG C of environment, heating time 3min.
Third prepares antidetonation layer on the surface with thermoplastic resin boundary layer, in 12 gangs of T700 high of outer braid 3K Strong type carbon fiber, the carbon fiber impregnate PE modified asphalt mixtures modified by epoxy resin before thermoplastic resin interface layer surfaces knitting process Rouge, the fiber gel content after impregnation control between 50%, and antidetonation layer precuring under 110 DEG C of environment outside boundary layer adds The hot time is 30min.
4th, the preparation of outmost surface carbon fiber one-way compound wire layer includes the following steps:
(1) carbon fibre tow impregnating resin glue, the carbon fibre tow speed of service are 900mm/ minutes;
(2) carbon fibre tow for being impregnated with resin adhesive liquid is subjected to pultrusion cladding on the surface of above-mentioned antidetonation layer, then will The carbon fibre tow that has coated carries out the molding of primary curing and secondary curing, and curing oven final temperature is 180 DEG C, and curing time is 10min;
(3) the cable body of rod obtained in step (2) is quickly cooled to 50 DEG C hereinafter, winding collection, that is, be prepared band There is the carbon fibre composite cable of optical fiber.
Embodiment 2:
A kind of carbon fibre composite cable with optical fiber includes four preparation sections from core to most surface: having The list processing of the metal sleeve of optical fiber, the boundary layer preparation of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon fiber Tie up the antidetonation layer preparation of braided sleeving enhancing thermoplasticity thermosetting property compound resin, the carbon fiber one-way compound wire layer of outmost surface Preparation.
Firstly, being embedded to 3 root multimode fiber long filaments, metal sleeve surface in the continuous length metal sleeve that diameter is 3mm It is then lauched at 60-80 DEG C using using phosphoric acid/chromium oxide/alcohol/formaldehyde mixed liquor in 15-30 DEG C of dipping 10-15min It washes, dry.
16 bursts of T700 high-strength carbon fibers of second, the outer braid 6K of the surface treated metal sleeve with optical fiber Dimension, the carbon fiber impregnate thermoplastic phenolic resin glue, the fiber gel content control after impregnation before metal sleeve knitting process System is 40%.Carbon fiber braiding after dipping glue is completed to dry under 100 DEG C of environment, heating time 7min.
Third prepares antidetonation layer on the surface with thermoplastic resin boundary layer, high-strength in external 12 gangs of T700 for compiling 6K Type carbon fiber, the carbon fiber modified epoxy resin of impregnating polyurethane before thermoplastic resin interface layer surfaces knitting process, Fiber gel content after impregnation controls between 40%, antidetonation layer precuring under 110 DEG C of environment outside boundary layer, when heating Between be 20min.
4th, the preparation of outmost surface carbon fiber one-way compound wire layer includes the following steps:
(1) carbon fibre tow impregnating resin glue, the carbon fibre tow speed of service are 600mm/ minutes;
(2) carbon fibre tow for being impregnated with resin adhesive liquid is subjected to pultrusion cladding on the surface of above-mentioned antidetonation layer, then will The carbon fibre tow that has coated carries out the molding of primary curing and secondary curing, and curing oven final temperature is 160 DEG C, and curing time is 5min;
(3) the cable body of rod obtained in step (2) is quickly cooled to 50 DEG C hereinafter, winding is collected.
Embodiment 3:
A kind of carbon fibre composite cable with optical fiber includes four preparation sections from core to most surface: having The list processing of the metal sleeve of optical fiber, the boundary layer preparation of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon fiber Tie up the antidetonation layer preparation of braided sleeving enhancing thermoplasticity thermosetting property compound resin, the carbon fiber one-way compound wire layer of outmost surface Preparation.
Firstly, being embedded to 4 polarization maintaining optical fibre long filaments, metal sleeve surface in the continuous length metal sleeve that diameter is 2mm Using concentrated sulfuric acid 22g/l, in 1-1.5A/dm2Direct current intensity under impregnate 10-15min, then in saturation potassium bichromate solution, 5-20min is impregnated at 95-100 DEG C, is then washed, it is dry.
10 strands of T800 high-strength carbon of second, the outer braid 12K of the surface treated metal sleeve with optical fiber Fiber, the carbon fiber impregnate thermoplastic phenolic resin glue, the fiber gel content after impregnation before metal sleeve knitting process Control is 44%.Carbon fiber braiding after dipping glue is completed to dry under 95 DEG C of environment, heating time 9min.
Third prepares antidetonation layer on the surface with thermoplastic resin boundary layer, in 12 gangs of T800 high of outer braid 3K Strong type carbon fiber, the carbon fiber impregnate polyamide modified asphalt mixtures modified by epoxy resin before thermoplastic resin interface layer surfaces knitting process Rouge, the fiber gel content after impregnation control between 46%, and antidetonation layer precuring under 110 DEG C of environment outside boundary layer adds The hot time is 30min.
4th, the preparation of outmost surface carbon fiber one-way compound wire layer includes the following steps:
(1) carbon fibre tow impregnating resin glue, the carbon fibre tow speed of service are 600mm/ minutes;
(2) carbon fibre tow for being impregnated with resin adhesive liquid is subjected to pultrusion cladding on the surface of above-mentioned antidetonation layer, then will The carbon fibre tow that has coated carries out the molding of primary curing and secondary curing, and curing oven final temperature is 170 DEG C, and curing time is 10min;
(3) the cable body of rod obtained in step (2) is quickly cooled to 50 DEG C hereinafter, winding is collected.
Embodiment 4:
A kind of carbon fibre composite cable with optical fiber includes four preparation sections from core to most surface: having The list processing of the metal sleeve of optical fiber, the boundary layer preparation of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon fiber Tie up the antidetonation layer preparation of braided sleeving enhancing thermoplasticity thermosetting property compound resin, the carbon fiber one-way compound wire layer of outmost surface Preparation.
Firstly, being embedded to 2 root multimode fiber long filaments, metal sleeve surface in the continuous length metal sleeve that diameter is 3mm 10min is impregnated at 70 DEG C using the concentrated sulfuric acid/potassium bichromate aqueous solution, then washes, is dry.
6 bursts of T300 high-strength carbon fibers of second, the outer braid 12K of the surface treated metal sleeve with optical fiber Dimension, the carbon fiber impregnate thermoplastic polyurethane resin glue, the fiber gel content after impregnation before metal sleeve knitting process Control is 39%.Carbon fiber braiding after dipping glue is completed to dry under 100 DEG C of environment, heating time 10min.
Third prepares antidetonation layer on the surface with thermoplastic resin boundary layer, in 12 gangs of T800 high of outer braid 6K Strong type carbon fiber, the carbon fiber impregnate the modified asphalt mixtures modified by epoxy resin of polyphenylene sulfide before thermoplastic resin interface layer surfaces knitting process Rouge, the fiber gel content after impregnation control between 50%, and antidetonation layer precuring under 110 DEG C of environment outside boundary layer adds The hot time is 25min.
4th, the preparation of outmost surface carbon fiber one-way compound wire layer includes the following steps:
(1) carbon fibre tow impregnating resin glue, the carbon fibre tow speed of service are 500mm/ minutes;
(2) carbon fibre tow for being impregnated with resin adhesive liquid is subjected to pultrusion cladding on the surface of above-mentioned antidetonation layer, then will The carbon fibre tow that has coated carries out the molding of primary curing and secondary curing, and curing oven final temperature is 175 DEG C, and curing time is 10min;
(3) the cable body of rod obtained in step (2) is quickly cooled to 50 DEG C hereinafter, winding is collected.

Claims (8)

1. a kind of carbon fiber composite cable with optical fiber, which is characterized in that it is from inside to outside successively are as follows: with metal sleeve Optical fiber, the boundary layer of carbon fiber braided sleeving enhancing thermoplas tic resin composite, carbon fiber braided sleeving enhancing thermoplasticity heat The antidetonation layer and carbon fiber one-way compound wire layer of solidity compound resin;The optical fiber with metal sleeve, by internal light Fiber and the external metal protective sleeve pipe through nitration mixture surface treatment form;The boundary layer, be formed in it is described through surface at The outside of the metal protective sleeve pipe of reason is formed by the carbon fiber filament of dipping thermoplastic resin in metal sleeve surface weave;Institute The antidetonation layer stated, is formed on the boundary layer, is woven by the carbon fiber filament of dipping thermoplasticity thermosetting property compound resin; The carbon fiber one-way compound wire layer, is formed on the antidetonation layer, and the carbon fibre tow by being impregnated with resin adhesive liquid exists The surface of antidetonation layer is formed through pultrusion cladding and curing molding;
The optical fiber is selected from any one of single mode optical fiber, multimode fibre and polarization maintaining optical fibre;
The carbon fiber composite cable with optical fiber is prepared by the following method:
(1) metal protective sleeve pipe is surface-treated using mixed acid solution, optical fiber is then embedded in metal protective sleeve pipe;
(2) outer braid of the metal protective sleeve pipe after surface treated is impregnated with the carbon fiber of thermoplastic resin, after impregnation Fiber gel content be 30-50%, braiding after the completion of dry, boundary layer is prepared;
(3) carbon fiber of thermoplasticity thermosetting property compound resin is impregnated in the surface weave of boundary layer, the fiber after impregnation contains glue Amount is 30-50%, and precuring is handled under 100-110 DEG C of environment after the completion of braiding, and antidetonation layer is prepared;
(4) carbon fiber wire for being impregnated with resin adhesive liquid is subjected to pultrusion cladding, the carbon that then will have been coated on the surface of antidetonation layer Fibre bundle carries out the molding of primary curing and secondary curing, forms carbon fiber one-way compound wire layer;
(5) it is quickly cooled down to get the carbon fiber composite cable of optical fiber is had.
2. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that the metal protective sleeve pipe Diameter is 1-3mm, and length is continuous length.
3. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that form heat used in boundary layer Plastic resin is thermoplastic polyurethane, any one in thermoplastic phenolic resin, and the fiber gel content after impregnation is 30- 50%.
4. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that form carbon used in boundary layer Fiber is selected from one of T300, T700 or T800 high-strength carbon fiber or a variety of;Fibre bundle in 3K, 6K or 12K one Kind is a variety of.
5. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that form carbon used in antidetonation layer Fiber is selected from one of T300, T700 or T800 high-strength carbon fiber or a variety of;Fibre bundle in 3K, 6K or 12K one Kind is a variety of.
6. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that form heat used in antidetonation layer Plasticity thermosetting property compound resin glue is thermoplastic resin modified epoxy resin or phenolic resin.
7. having the carbon fiber composite cable of optical fiber as claimed in claim 6, which is characterized in that the thermoplastic resin is selected from One of polyethylene, polyurethane, polyamide, polyphenylene oxide, polysulfones, polyphenylene sulfide, polytetrafluoroethylene (PTFE), polyformaldehyde or polyether-ether-ketone Or it is a variety of.
8. having the carbon fiber composite cable of optical fiber as described in claim 1, which is characterized in that in step (4), solidification is final Temperature is 160-180 DEG C, curing time 5-10min.
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CN105003209A (en) * 2015-07-21 2015-10-28 山东大学 Sucker rod with composite spiral abrasion-resistant layer, manufacturing device and manufacturing method
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