CN105908085A - Antibiotic stainless steel - Google Patents

Antibiotic stainless steel Download PDF

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Publication number
CN105908085A
CN105908085A CN201610462806.1A CN201610462806A CN105908085A CN 105908085 A CN105908085 A CN 105908085A CN 201610462806 A CN201610462806 A CN 201610462806A CN 105908085 A CN105908085 A CN 105908085A
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content
copper
chromium
stainless steel
thulium
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CN201610462806.1A
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Chinese (zh)
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竹洪燕
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an antibiotic stainless steel. The antibiotic stainless steel comprises the following chemical components, 0.30-0.50 wt% of nickel, 0.80-1.40 wt% of manganese, 0.20-0.34 wt% of silicon, 0.14-0.18 wt% of carbon, 0.02-0.06 wt% of boron, 0.01-0.02 wt% of phosphorus, 0.015-0.025 wt% of sulfur, 0.08-0.1 wt% of erbium, 0.06-0.2 wt% of vanadium, 0.2-0.3 wt% of thulium, 0.02-0.08 wt% of molybdenum, 0.08-0.1 wt% of titanium, 0.02-0.04 wt% of niobium, 0.06-0.2 wt% of rubidium, 0.08-0.1 wt% of thorium, 0.06-0.08 wt% of chromium and 0.06-0.08 wt% of copper, with the balance being iron, wherein the content of the chromium is five to seven times as much as the content of the copper. The antibiotic stainless steel is excellent in antibiotic property. The antibiotic effect is related to the ratio of the content of the chromium and the content of the copper and the antibiotic effect is best when the content of the chromium is five to seven times as much as the content of the copper.

Description

A kind of anti-bacteria stainless steel
Technical field
The present invention relates to rustless steel, be specifically related to a kind of anti-bacteria stainless steel.
Background technology
Although current stainless steel products has preferable decay resistance and mechanical performance, but does not have preferable sterilization capability.
Will necessarily very be required to compare to environmental health by hospital etc. if able to develop a kind of rustless steel with higher sterilization capability The welcome in high place.
Summary of the invention
It is an object of the invention to provide a kind of anti-bacteria stainless steel.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of anti-bacteria stainless steel, including following chemical composition: 0.30~0.50wt% nickel, 0.80~1.40wt% manganese, 0.20~0.34wt% Silicon, 0.14~0.18wt% carbon, 0.02~0.06wt% boron, 0.01~0.02wt% phosphorus, 0.015~0.025wt% sulfur, 0.08~0.1wt% Erbium, 0.06~0.2wt% vanadium, 0.2~0.3wt% thulium, 0.02~0.08wt% molybdenum, 0.08~0.1wt% titanium, 0.02~0.04wt% niobium, 0.06~0.2wt% rubidium, 0.08~0.1wt% thorium, 0.06~0.08wt% chromium and copper, surplus is ferrum;Wherein, described chromium content is copper 5~7 times of content.
Further, described anti-bacteria stainless steel includes following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum; Wherein, described chromium content is 6 times of copper content.
Further, described anti-bacteria stainless steel includes following chemical composition: 0.30wt% nickel, 0.80wt% manganese, 0.20wt% silicon, 0.14wt% carbon, 0.02wt% boron, 0.01wt% phosphorus, 0.015wt% sulfur, 0.08wt% erbium, 0.06wt% vanadium, 0.2wt% thulium, 0.02wt% molybdenum, 0.08wt% titanium, 0.02wt% niobium, 0.06wt% rubidium, 0.08wt% thorium, 0.06wt% chromium and copper, surplus is ferrum; Wherein, described chromium content is 5 times of copper content.
Further, described anti-bacteria stainless steel includes following chemical composition: 0.50wt% nickel, 1.40wt% manganese, 0.34wt% silicon, 0.18wt% carbon, 0.06wt% boron, 0.02wt% phosphorus, 0.025wt% sulfur, 0.1wt% erbium, 0.2wt% vanadium, 0.3wt% thulium, 0.08wt% Molybdenum, 0.1wt% titanium, 0.04wt% niobium, 0.2wt% rubidium, 0.1wt% thorium, 0.08wt% chromium and copper, surplus is ferrum;Wherein, institute State that chromium content is copper content 7 times.
Advantages of the present invention:
The anti-bacteria stainless steel that the present invention provides has the anti-microbial property of excellence, and this antibacterial effect is relevant with the ratio of chromium and copper content, When chromium content is 5~7 times of copper content, antibacterial effect is best.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.To the greatest extent The present invention is explained in detail by pipe with reference to preferred embodiment, it will be understood by those within the art that, can be to the present invention Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: anti-bacteria stainless steel
Composition: include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% Boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% Titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 6 times.
Embodiment 2: anti-bacteria stainless steel
Composition: include following chemical composition: 0.30wt% nickel, 0.80wt% manganese, 0.20wt% silicon, 0.14wt% carbon, 0.02wt% Boron, 0.01wt% phosphorus, 0.015wt% sulfur, 0.08wt% erbium, 0.06wt% vanadium, 0.2wt% thulium, 0.02wt% molybdenum, 0.08wt% Titanium, 0.02wt% niobium, 0.06wt% rubidium, 0.08wt% thorium, 0.06wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 5 times.
Embodiment 3: anti-bacteria stainless steel
Composition: include following chemical composition: 0.50wt% nickel, 1.40wt% manganese, 0.34wt% silicon, 0.18wt% carbon, 0.06wt% Boron, 0.02wt% phosphorus, 0.025wt% sulfur, 0.1wt% erbium, 0.2wt% vanadium, 0.3wt% thulium, 0.08wt% molybdenum, 0.1wt% titanium, 0.04wt% niobium, 0.2wt% rubidium, 0.1wt% thorium, 0.08wt% chromium and copper, surplus is ferrum;Wherein, described chromium content is that copper contains 7 times of amount.
Embodiment 4: anti-bacteria stainless steel
Composition: include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% Boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% Titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 5 times.
Embodiment 5: anti-bacteria stainless steel
Composition: include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% Boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% Titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 7 times.
Embodiment 6: comparative example, chromium content is 4 times of copper content
Composition: include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% Boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% Titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 4 times.
Embodiment 7: comparative example, chromium content is 8 times of copper content
Composition: include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% Boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% Titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content For copper content 8 times.
Embodiment 8: effect example
Prepare the stainless steel material shown in embodiment 1~7 respectively, the block sample of Φ 20 × 5mm, measure respectively to escherichia coli, The suppression sterilizing rate (%, 30 minutes) of staphylococcus aureus, Candida albicans and clostridium tetani, result see table.
Escherichia coli Staphylococcus aureus Candida albicans Clostridium tetani
Embodiment 1 100 100 100 100
Embodiment 4 98 99 98 97
Embodiment 5 99 98 99 98
Embodiment 6 32 44 38 48
Embodiment 7 31 46 36 45
The fungistatic effect of embodiment 2,3 is basically identical with embodiment 4,5.
The above results shows, the anti-bacteria stainless steel that the present invention provides has the anti-microbial property of excellence, this antibacterial effect and chromium and copper The ratio of content is relevant, and when chromium content is 5~7 times of copper content, antibacterial effect is best.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this. It will be understood by those within the art that, technical scheme can be modified or equivalent, and not take off Essence and protection domain from technical solution of the present invention.

Claims (4)

1. an anti-bacteria stainless steel, it is characterised in that include following chemical composition: 0.30~0.50wt% nickel, 0.80~1.40wt% Manganese, 0.20~0.34wt% silicon, 0.14~0.18wt% carbon, 0.02~0.06wt% boron, 0.01~0.02wt% phosphorus, 0.015~0.025wt% Sulfur, 0.08~0.1wt% erbium, 0.06~0.2wt% vanadium, 0.2~0.3wt% thulium, 0.02~0.08wt% molybdenum, 0.08~0.1wt% titanium, 0.02~0.04wt% niobium, 0.06~0.2wt% rubidium, 0.08~0.1wt% thorium, 0.06~0.08wt% chromium and copper, surplus is ferrum;Wherein, Described chromium content is 5~7 times of copper content.
Anti-bacteria stainless steel the most according to claim 1, it is characterised in that include following chemical composition: 0.40wt% nickel, 1.10wt% manganese, 0.27wt% silicon, 0.16wt% carbon, 0.04wt% boron, 0.015wt% phosphorus, 0.020wt% sulfur, 0.09wt% erbium, 0.13wt% vanadium, 0.25wt% thulium, 0.05wt% molybdenum, 0.09wt% titanium, 0.03wt% niobium, 0.13wt% rubidium, 0.09wt% thorium, 0.07wt% chromium and copper, surplus is ferrum;Wherein, described chromium content is 6 times of copper content.
Anti-bacteria stainless steel the most according to claim 1, it is characterised in that include following chemical composition: 0.30wt% nickel, 0.80wt% manganese, 0.20wt% silicon, 0.14wt% carbon, 0.02wt% boron, 0.01wt% phosphorus, 0.015wt% sulfur, 0.08wt% erbium, 0.06wt% vanadium, 0.2wt% thulium, 0.02wt% molybdenum, 0.08wt% titanium, 0.02wt% niobium, 0.06wt% rubidium, 0.08wt% thorium, 0.06wt% chromium and copper, surplus is ferrum;Wherein, described chromium content is 5 times of copper content.
Anti-bacteria stainless steel the most according to claim 1, it is characterised in that include following chemical composition: 0.50wt% nickel, 1.40wt% manganese, 0.34wt% silicon, 0.18wt% carbon, 0.06wt% boron, 0.02wt% phosphorus, 0.025wt% sulfur, 0.1wt% erbium, 0.2wt% vanadium, 0.3wt% thulium, 0.08wt% molybdenum, 0.1wt% titanium, 0.04wt% niobium, 0.2wt% rubidium, 0.1wt% thorium, 0.08wt% Chromium and copper, surplus is ferrum;Wherein, described chromium content is 7 times of copper content.
CN201610462806.1A 2016-06-22 2016-06-22 Antibiotic stainless steel Pending CN105908085A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107761008A (en) * 2017-10-09 2018-03-06 上海前引科技有限公司 A kind of antibacterial and mouldproof anion stainless steel and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102168226A (en) * 2011-04-02 2011-08-31 裘德鑫 Martensite antibacterial stainless steel and manufacturing method thereof
CN103276300A (en) * 2013-04-29 2013-09-04 宁波市博祥新材料科技有限公司 Copper-containing antibacterial stainless steel and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102168226A (en) * 2011-04-02 2011-08-31 裘德鑫 Martensite antibacterial stainless steel and manufacturing method thereof
CN103276300A (en) * 2013-04-29 2013-09-04 宁波市博祥新材料科技有限公司 Copper-containing antibacterial stainless steel and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107761008A (en) * 2017-10-09 2018-03-06 上海前引科技有限公司 A kind of antibacterial and mouldproof anion stainless steel and preparation method thereof

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