CN105907211A - Environment-friendly acrylic acid type powder coating - Google Patents

Environment-friendly acrylic acid type powder coating Download PDF

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Publication number
CN105907211A
CN105907211A CN201610492668.1A CN201610492668A CN105907211A CN 105907211 A CN105907211 A CN 105907211A CN 201610492668 A CN201610492668 A CN 201610492668A CN 105907211 A CN105907211 A CN 105907211A
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environment
acrylic acid
acid type
agent
powdery paints
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CN201610492668.1A
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Chinese (zh)
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张莘蔓
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an environment-friendly acrylic acid type powder coating. The environment-friendly acrylic acid type powder coating is prepared from the following raw materials in parts by weight: 85-95 parts of matrix resin, 38-48 parts of pigment filler, 12-16 parts of a curing agent, 4-5 parts of a degassing agent, 1-2 parts of a dispersing agent, 0.4-0.8 part of a hammer tone agent, 0.3-0.6 part of a toughening agent, 0.3-0.5 part of a gloss enhancer, 0.2-0.4 part of a wetting agent, 0.2-0.4 part of a preservative, 0.2-0.3 part of an antioxidant and 0.2-0.3 part of a light stabilizer; the environment-friendly acrylic acid type powder coating is obtained by mixing the raw materials, melting, tabletting, granulating and crushing. The environment-friendly acrylic acid type powder coating has weather fastness, can keep out the direct irradiation of ultraviolet ray for silver powder, has higher corrosion resistance, and is not pulverized and does not turn black after being placed under the sun for a long time, thus being widely applied to surface coating of outdoor metal such as guardrails and door industry.

Description

A kind of environment-friendlyacrylic acrylic acid type powdery paints
[technical field]
The invention belongs to coating technology of preparing neck, be specifically related to a kind of environment-friendlyacrylic acrylic acid type powdery paints.
[background technology]
Powdery paints is a kind of to prolong born Novel environment-friendlymaterial material based on petrochemical materials, mainly by low Molecular weight resin, auxiliary agent, filler etc., prepare under certain conditions, spray, toast and formed and have necessarily Outward appearance, gloss, color, and play the film of anticorrosion and decoration function at object surface.Powdery paints is in reality In the application process of border, such as outdoor gate, balcony guardrail etc..Through after a while, film will occur certain journey Degree change, as rust spot, crackle etc. occur in gloss decline, colour-darkening or cool white, coating surface, the most vertical Line silver look powdery paints, owing to its main pigments is aluminium powder, and aluminium is wilfully that one is the most active, and weatherability is poor, Corrosion-prone material, in the sun in general 2-3 month will efflorescence blackening, be therefore only used for indoor.
[summary of the invention]
The present invention provides a kind of environment-friendlyacrylic acrylic acid type powdery paints, weather-proof to solve existing vertical line silver look powdery paints The problem such as property is poor, perishable.The environment-friendlyacrylic acrylic acid type powdery paints of the present invention has weatherability, can block purple The direct projection to silver powder of the outer linear light, has a stronger corrosion resistance, the most in the sun will not efflorescence blackening, extensively General it is applied to the outdoor metal surface applications such as guardrail, Men Ye, aluminium section bar.
For solve above technical problem, the present invention by the following technical solutions:
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 85-95 Part, color stuffing 38-48 part, curing agent 12-16 part, degasser 4-5 part, dispersant 1-2 part, line agent of hanging down 0.4-0.8 part, toughener 0.3-0.6 part, optical brightener 0.3-0.5 part, wetting agent 0.2-0.4 part, preservative 0.2-0.4 Part, antioxidant 0.2-0.3 part, light stabilizer 0.2-0.3 part;Described dispersant is dispersant nc;Described vertical line Agent is the line agent HM-2 that hangs down;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369; Described antioxidant is antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101;Described environmental protection propylene The preparation method of acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 4-6min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains all Even mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 110-114 DEG C by extruder, and leads to Cross compressing tablet crushing mechanism sheet, after cooling, prepare lamellar body;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 150-200 mesh sieve after pulverizing, and prepares environment-friendlyacrylic acrylic acid type powder End coating.
Further, described matrix resin is acrylic resin.
Further, described color stuffing is metallic pigments and extender pigment.
Further, described metallic pigments are silver powder.
Further, described extender pigment is silica flour.
Further, described curing agent is epoxylite.
Further, described degasser is stearic acid.
Further, described toughener is MBS terpolymer.
Further, described optical brightener is optical brightener LD-608.
The method have the advantages that
(1) the environment-friendlyacrylic acrylic acid type powdery paints resistance to impact of the present invention is 82-103kg/cm, and bending resistance is 1.5-1.8mm, adhesive force is 100%, in anti-aging experiment, variable color≤2 grade, loss of gloss≤2 grade, without efflorescence, Bubble, ftracture, the anomaly such as peeling;
(2) the environment-friendlyacrylic acrylic acid type powdery paints of the present invention has weatherability, can block ultraviolet to silver The direct projection of powder, has a stronger corrosion resistance, the most in the sun will not efflorescence blackening, be widely used in protecting The outdoor metal surface applications such as hurdle, Men Ye, aluminium section bar.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to this Bright protection domain, but it is not intended to protection scope of the present invention.
In an embodiment, described environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: Matrix resin 85-95 part, color stuffing 38-48 part, curing agent 12-16 part, degasser 4-5 part, dispersant 1-2 part, vertical line agent 0.4-0.8 part, toughener 0.3-0.6 part, optical brightener 0.3-0.5 part, wetting agent 0.2-0.4 Part, preservative 0.2-0.4 part, antioxidant 0.2-0.3 part, light stabilizer 0.2-0.3 part;Described matrix resin is Acrylic resin;Described color stuffing is metallic pigments and extender pigment;Described metallic pigments are silver powder;Described body Matter pigment is silica flour;Described curing agent is epoxylite;Described degasser is stearic acid;Described dispersant For dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described toughener is methyl methacrylate-fourth two Alkene-styrene copolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant is antioxidant AT-330;Described light is stable Agent is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 4-6min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains all Even mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 110-114 DEG C by extruder, and leads to Cross compressing tablet crushing mechanism sheet, after cooling, prepare lamellar body;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 150-200 mesh sieve after pulverizing, and prepares environment-friendlyacrylic acrylic acid type powder End coating.
Embodiment 1
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 90 Part, color stuffing 42 parts, 15 parts of curing agent, degasser 5 parts, dispersant 1.5 parts, hang down line agent 0.6 part, Toughener 0.5 part, optical brightener 0.4 part, wetting agent 0.3 part, preservative 0.3 part, 0.2 part of antioxidant, light Stabilizer 0.2 part;Described matrix resin is acrylic resin;Described color stuffing is metallic pigments and extender pigment; Described metallic pigments are silver powder;Described extender pigment is silica flour;Described curing agent is epoxylite;Described Degasser is stearic acid;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described increasing Tough dose is MBS terpolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant For antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 4min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains uniformly Mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 110 DEG C by extruder, and passes through Crusher film-making, prepares lamellar body after cooling;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 150 mesh sieve after pulverizing, prepares environment-friendlyacrylic acrylic acid type powder and is coated with Material.
Embodiment 2
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 85 Part, color stuffing 38 parts, 12 parts of curing agent, degasser 4 parts, dispersant 1 part, line agent 0.4 part of hanging down, increasing Tough dose 0.3 part, optical brightener 0.3 part, wetting agent 0.2 part, preservative 0.2 part, 0.2 part of antioxidant, light steady Determine agent 0.2 part;Described matrix resin is acrylic resin;Described color stuffing is metallic pigments and extender pigment; Described metallic pigments are silver powder;Described extender pigment is silica flour;Described curing agent is epoxylite;Described Degasser is stearic acid;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described increasing Tough dose is MBS terpolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant For antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 6min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains uniformly Mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 114 DEG C by extruder, and passes through Crusher film-making, prepares lamellar body after cooling;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 200 mesh sieve after pulverizing, prepares environment-friendlyacrylic acrylic acid type powder and is coated with Material.
Embodiment 3
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 95 Part, color stuffing 48 parts, 16 parts of curing agent, degasser 5 parts, dispersant 2 parts, line agent-0.8 part of hanging down, increasing Tough dose 0.6 part, optical brightener 0.5 part, wetting agent 0.4 part, preservative 0.4 part, 0.3 part of antioxidant, light steady Determine agent 0.3 part;Described matrix resin is acrylic resin;Described color stuffing is metallic pigments and extender pigment; Described metallic pigments are silver powder;Described extender pigment is silica flour;Described curing agent is epoxylite;Described Degasser is stearic acid;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described increasing Tough dose is MBS terpolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant For antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 5min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains uniformly Mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 112 DEG C by extruder, and passes through Crusher film-making, prepares lamellar body after cooling;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 180 mesh sieve after pulverizing, prepares environment-friendlyacrylic acrylic acid type powder and is coated with Material.
Embodiment 4
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 90 Part, color stuffing 40 parts, 14 parts of curing agent, degasser 4 parts, dispersant 1 part, line agent 0.5 part of hanging down, increasing Tough dose 0.3 part, optical brightener 0.3 part, wetting agent 0.2 part, preservative 0.2 part, 0.2 part of antioxidant, light steady Determine agent 0.2 part;Described matrix resin is acrylic resin;Described color stuffing is metallic pigments and extender pigment; Described metallic pigments are silver powder;Described extender pigment is silica flour;Described curing agent is epoxylite;Described Degasser is stearic acid;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described increasing Tough dose is MBS terpolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant For antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 4min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains uniformly Mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 110 DEG C by extruder, and passes through Crusher film-making, prepares lamellar body after cooling;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 200 mesh sieve after pulverizing, prepares environment-friendlyacrylic acrylic acid type powder and is coated with Material.
Embodiment 5
A kind of environment-friendlyacrylic acrylic acid type powdery paints, in units of weight, including following raw material: matrix resin 92 Part, color stuffing 45 parts, 16 parts of curing agent, degasser 5 parts, dispersant 2 parts, line agent 0.7 part of hanging down, increasing Tough dose 0.5 part, optical brightener 0.4 part, wetting agent 0.4 part, preservative 0.4 part, 0.3 part of antioxidant, light steady Determine agent 0.3 part;Described matrix resin is acrylic resin;Described color stuffing is metallic pigments and extender pigment; Described metallic pigments are silver powder;Described extender pigment is silica flour;Described curing agent is epoxylite;Described Degasser is stearic acid;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described increasing Tough dose is MBS terpolymer;Described optical brightener is optical brightener LD-608;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant For antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101.
The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: by matrix resin, color stuffing, curing agent, degasser, dispersant, hang down line agent, toughener, increasing Compounding jar premixing 5min put into by photo etching, wetting agent, preservative, antioxidant, light stabilizer, obtains uniformly Mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 114 DEG C by extruder, and passes through Crusher film-making, prepares lamellar body after cooling;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 160 mesh sieve after pulverizing, prepares environment-friendlyacrylic acrylic acid type powder and is coated with Material.
The performance indications of the environment-friendlyacrylic acrylic acid type powdery paints that detection embodiment 1-5 prepares, use following experiment.
The environment-friendlyacrylic acrylic acid type flush coater used for powder coating preparing embodiment 1-5 sprays to the Ma Kou of 0.2mm On the cold rolling iron plate of iron plate and 0.5mm, baking-curing obtains the uniform coating of 50-70 μm, then to this Film carries out following performance detection, and concrete test result and index are as shown in the table.
As seen from the above table: the environment-friendlyacrylic acrylic acid type powdery paints resistance to impact of the present invention is 82-103kg/cm, anti- Bendability is 1.5-1.8mm, and adhesive force is 100%, in anti-aging experiment, and variable color≤2 grade, loss of gloss≤2 grade, Without efflorescence, bubble, ftracture, the anomaly such as peeling, the environment-friendlyacrylic acrylic acid type powdery paints of the present invention is described Can be excellent.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, for skill belonging to the present invention For the those of ordinary skill in art field, without departing from the inventive concept of the premise, it is also possible to make some letters Single deduction or replace, all should be considered as belonging to the patent protection model that the present invention is determined by the claims submitted to Enclose.

Claims (9)

1. an environment-friendlyacrylic acrylic acid type powdery paints, it is characterized in that, in units of weight, including following raw material: matrix resin 85-95 part, color stuffing 38-48 part, curing agent 12-16 part, degasser 4-5 part, dispersant 1-2 part, hang down line agent 0.4-0.8 part, toughener 0.3-0.6 part, optical brightener 0.3-0.5 part, wetting agent 0.2-0.4 part, preservative 0.2-0.4 part, antioxidant 0.2-0.3 part, light stabilizer 0.2-0.3 part;Described dispersant is dispersant nc;Described vertical line agent is the line agent HM-2 that hangs down;Described wetting agent is wetting agent CF-10;Described preservative is Liquid BPF-369;Described antioxidant is antioxidant AT-330;Described light stabilizer is light stabilizer HS-3101;The preparation method of described environment-friendlyacrylic acrylic acid type powdery paints, comprises the following steps:
S1: matrix resin, color stuffing, curing agent, degasser, dispersant, line agent of hanging down, toughener, optical brightener, wetting agent, preservative, antioxidant, light stabilizer are put into compounding jar premixing 4-6min, obtains a homogeneous mixture;
S2: homogeneous mixture step S1 prepared is melt extruded at 110-114 DEG C by extruder, and by crusher film-making, after cooling, prepare lamellar body;
S3: lamellar body step S2 prepared uses cutting knife to shear, and prepares pelletizing;
S4: pelletizing step S3 prepared crosses 150-200 mesh sieve after pulverizing, and prepares environment-friendlyacrylic acrylic acid type powdery paints.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described matrix resin is acrylic resin.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described color stuffing is metallic pigments and extender pigment.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 3, it is characterised in that described metallic pigments are silver powder.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 3, it is characterised in that described extender pigment is silica flour.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described curing agent is epoxylite.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described degasser is stearic acid.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described toughener is MBS terpolymer.
Environment-friendlyacrylic acrylic acid type powdery paints the most according to claim 1, it is characterised in that described optical brightener is optical brightener LD-608.
CN201610492668.1A 2016-06-25 2016-06-25 Environment-friendly acrylic acid type powder coating Pending CN105907211A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147321A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of environment-friendly novel emulsion paint
CN106147330A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of environment friendly emulsion paint
CN106147320A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of novel environment friendly emulsion paint
CN106147331A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of high-performance emulsion paint
CN106221332A (en) * 2016-09-13 2016-12-14 广西南宁智翠科技咨询有限公司 A kind of environment-friendly and high-performance emulsion paint
CN112011244A (en) * 2020-09-02 2020-12-01 合肥工业大学 Continuous production method of GMA acrylic resin powder coating

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773123A (en) * 2014-01-15 2014-05-07 芜湖市宝艺游乐科技设备有限公司 Sand-textured metallic heat-dissipating coating material
CN104559569A (en) * 2014-12-31 2015-04-29 天津盛达粉末涂料有限公司 Powder coating capable of being recoated

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773123A (en) * 2014-01-15 2014-05-07 芜湖市宝艺游乐科技设备有限公司 Sand-textured metallic heat-dissipating coating material
CN104559569A (en) * 2014-12-31 2015-04-29 天津盛达粉末涂料有限公司 Powder coating capable of being recoated

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147321A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of environment-friendly novel emulsion paint
CN106147330A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of environment friendly emulsion paint
CN106147320A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of novel environment friendly emulsion paint
CN106147331A (en) * 2016-09-13 2016-11-23 广西南宁智翠科技咨询有限公司 A kind of high-performance emulsion paint
CN106221332A (en) * 2016-09-13 2016-12-14 广西南宁智翠科技咨询有限公司 A kind of environment-friendly and high-performance emulsion paint
CN112011244A (en) * 2020-09-02 2020-12-01 合肥工业大学 Continuous production method of GMA acrylic resin powder coating

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Application publication date: 20160831