CN105903266A - Nano composite filter material capable of removing heavy metals in water and sterilizing water - Google Patents

Nano composite filter material capable of removing heavy metals in water and sterilizing water Download PDF

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Publication number
CN105903266A
CN105903266A CN201610342630.6A CN201610342630A CN105903266A CN 105903266 A CN105903266 A CN 105903266A CN 201610342630 A CN201610342630 A CN 201610342630A CN 105903266 A CN105903266 A CN 105903266A
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water
nano
activated carbon
filter material
parts
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CN201610342630.6A
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CN105903266B (en
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不公告发明人
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Shuifa Environmental Technology Co.,Ltd.
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Cai Liufeng
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • B01D39/06Inorganic material, e.g. asbestos fibres, glass beads or fibres
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/165Natural alumino-silicates, e.g. zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1208Porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4812Sorbents characterised by the starting material used for their preparation the starting material being of organic character
    • B01J2220/4843Algae, aquatic plants or sea vegetals, e.g. seeweeds, eelgrass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4881Residues from shells, e.g. eggshells, mollusk shells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agronomy & Crop Science (AREA)
  • Analytical Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Geology (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a nano composite filter material capable of removing heavy metals in water and sterilizing water. According to the adopted technical scheme, the nano composite filter material capable of removing heavy metals in water and sterilizing water is prepared according to the following steps: A, algae clay, E33 and zeolite powder are mixed and ground; B, the mixture obtained from step A is mixed evenly with activated carbon, and then water is added; C, firing is carried out at a high temperature; and D, the product obtained in step C is mixed with nano titanium dioxide to obtain a nano composite filter material. The nano composite filter material provided by the invention has an extremely strong adsorption capability, is capable of removing heavy metals in water with good sterilization property, and is safe and non-toxic without secondary pollution, and thus applicable to purifying drinking water or sewage.

Description

Heavy metal in water the nano combined filtrate that can sterilize can be removed
Technical field
The present invention relates to a kind of nano combined filtrate preparation method, belong to water treatment agent field.
Background technology
Water purification agent can improve water quality, brings the biggest benefit to the life of people, health, but water purification agent to be also equipped with Good water purification filtrate, the absorbability power of filtrate is directly connected to the effect filtered.
Water purification filtrate, including: fibrous nodules, shell filtrate, selected ANTHRACITE FILTER MEDIA, purity quartzite filtrate, magnetic iron ore are filtered Material, manganese sand filtering material, limestone filtrate, ceramic grain filter, cobble, zeolite, garnet, Maifanitum, corundum, rare earth porcelain grit, activity Aluminium oxide, cocoanut active charcoal, active fruit shell carbon, wood powder shaped activated carbon, ature of coal column-shaped active carbon, ature of coal granule charcoal, KDF, E33 Deng.Filtrate the most on the market is mostly activated carbon or KDF or E33 filtrate, and the absorbability of these single filtrates can not Deal with the most serious water pollution to process.
Chinese patent 201310111109.8 discloses a kind of fibre filtering material, is the fiber made of compound Nano carbon fiber Filter material, is made up of fibre bundle and core, and fibre bundle is fixedly arranged at the center of core, and core both sides fibre bundle length is equal or not Deng, compound Nano carbon fiber tow is to have the nano level micropowder of honeycomb microporous structure to become with having honeycomb microporous structure Gesture polyester modification section melt spinning and make.Possess outside the feature that filtering accuracy is high, filtering velocity is high, pollutant holding capability is big, also have Standby oil removing, deodorization, removing heavy metals ion, decolour, the several functions such as sterilization, backwash effect more preferably, its life-span longer, can be extensively It is applied to industrial oily waste water, municipal wastewater, food processing wastewater, aquiculture recycled water, dyeing waste water, landscape water etc., respectively Plant performance indications advantages.
Chinese patent CN201310295572 discloses a kind of Nano-metal compound filter material, wherein contains KDF component, KDF Filter material electrochemical reaction causes heavy metal pollution, and after i.e. zinc ion exceeds standard and lost efficacy, copper ion etc. exceed standard, and there is heavy metal poisoning Potential danger, a lot of countries forbid KDF use in family water purifier, and the most Japanese, European etc., KDF is currently mainly For industry controlling the water circulation.
Summary of the invention
Goal of the invention: the defect existed for prior art, the present invention provides a kind of safety and environmental protection, high adsorption capacity, mistake Filter the preparation method of effective nano combined filtrate.
For achieving the above object, the present invention is by the following technical solutions:
A kind of preparation method of nano combined filtrate, by the following technical solutions: A, by algae clay, conch meal, E33 and zeolite powder Mixing, mills;B, by step A gained mixture and activated carbon stirring and evenly mixing, add water;C, high-temperature firing;D, step C is made Product mixes with nano titanium oxide, obtains a kind of nano combined filtrate.
High-temperature firing in described step C is to carry out under 1000-1500 degree Celsius.
The parts by weight of algae clay, E33, zeolite powder, activated carbon and nano titanium oxide are: algae clay 20~60, shell Powder 15-30, E33 are 10~50, zeolite powder 5~20, activated carbon 20~60 and nano titanium oxide 5~20.
The parts by weight of algae clay, E33, zeolite powder, activated carbon and nano titanium oxide are: algae clay 20~40, shell Powder 20-30, E33 are 15-35, zeolite powder 10-15, activated carbon 30-50 and nano titanium oxide 8-16.
The percentage by weight of algae clay, conch meal, E33, zeolite powder, activated carbon and nano titanium oxide is: algae clay 35%, E33 are 20%, zeolite powder 10%, activated carbon 30% and nano titanium oxide 5%.
According to above-mentioned technical scheme, it is known that the nano combined filtrate of one that the present invention provides, compared to existing technology, have Following beneficial effect:
1, the nano combined filtrate of the present invention has extremely strong absorbability, can remove the heavy metal in water, has the sterilization of excellence Performance;Safety non-toxic, non-secondary pollution, can be used for drinking water or dirty water purification.
2, product composite filtering material of the present invention has very abundant pore structure, and during drainage, the contact area with water is big, can Little drawback is amassed with water engaging surface when overcoming KDF filtrate to be used alone.
Specific embodiment
By the following examples the present invention is further explained:
Embodiment 1
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 20 parts, conch meal 15 parts, E33 are 10 parts, zeolite powder 5 parts, activated carbon 20 parts and nanometer titanium dioxide Titanium 5 parts;Then, algae clay, conch meal, E33 and zeolite powder are mixed, after milling, by mixed with activated carbon stirring for gained mixture After even, add water and be modulated;Finally under 1000 degrees Celsius, carry out high-temperature firing, be cooled to after coming out of the stove under room temperature and nanometer two Titanium oxide mixes, and i.e. can get a kind of nano combined filtrate.
Embodiment 2
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 50 parts, conch meal 30 parts, E33 are 25 parts, zeolite powder 5 parts, activated carbon 35 parts and nanometer titanium dioxide Titanium 15 parts;Then, algae clay, conch meal, E33 and zeolite powder are mixed, after milling, by mixed with activated carbon stirring for gained mixture After even, add water and be modulated;Finally carry out high-temperature firing at 1100 degrees celsius, be cooled to after coming out of the stove under room temperature and nanometer two Titanium oxide mixes, and i.e. can get a kind of nano combined filtrate
Embodiment 3
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 60 parts, conch meal 25 parts, E33 are 50 parts, zeolite powder 15 parts, activated carbon 40 parts and nano-silica Change titanium 20 parts;Then, algae clay, conch meal, E33 and zeolite powder are mixed, after milling, gained mixture is stirred with activated carbon After mixing, add water and be modulated;Finally under 1300 degrees Celsius, carry out high-temperature firing, be cooled to after coming out of the stove under room temperature and nanometer Titanium dioxide mixes, and i.e. can get a kind of nano combined filtrate.
Embodiment 4
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 60 parts, conch meal 15 parts, E33 are 50 parts, zeolite powder 20 parts, activated carbon 60 parts and nano-silica Change titanium 20 parts;Then, algae clay, conch meal, E33 and zeolite powder are mixed, after milling, gained mixture is stirred with activated carbon After mixing, add water and be modulated;Finally under 1500 degrees Celsius, carry out high-temperature firing, be cooled to after coming out of the stove under room temperature and nanometer Titanium dioxide mixes, and i.e. can get a kind of nano combined filtrate.
Comparative example 1
This comparative example 1 is the comparative example of embodiment 3, specifically:
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 60 parts, E33 are 50 parts, zeolite powder 15 parts, activated carbon 40 parts and nano titanium oxide 20 parts;Connect , algae clay, E33 and zeolite powder are mixed, after milling, after gained mixture and activated carbon stirring and evenly mixing, add water and carry out Modulation;Finally under 1300 degrees Celsius, carry out high-temperature firing, be cooled to after coming out of the stove mix with nano titanium oxide under room temperature, Obtain a kind of nano combined filtrate.
Comparative example 2
This comparative example is the comparative example of embodiment 4, specifically:
Nano composite material of the present invention includes algae clay, E33, zeolite powder, activated carbon and nano titanium oxide;First, Weigh according to formula: algae clay 60 parts, E33 are 50 parts, zeolite powder 20 parts, activated carbon 60 parts and nano titanium oxide 20 parts;Connect , algae clay, E33 and zeolite powder are mixed, after milling, after gained mixture and activated carbon stirring and evenly mixing, add water and carry out Modulation;Finally under 1500 degrees Celsius, carry out high-temperature firing, be cooled to after coming out of the stove mix with nano titanium oxide under room temperature, Obtain a kind of nano combined filtrate.
The present invention is as follows with the contrast of the using effect of traditional filter material in terms of tap water purifying:
Each embodiment of the present invention is as follows in the effect that tap water carries out 15 minutes purified treatment:
The above is only the preferred embodiment of the present invention, it should be pointed out that: those skilled in the art are come Saying, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should be regarded as Protection scope of the present invention.

Claims (1)

1. a nano combined filtrate, it is characterised in that use following preparation method prepare: A, by algae clay, conch meal, E33 and zeolite powder mixing, mill;B, by step A gained mixture and activated carbon stirring and evenly mixing, add water;C, high-temperature firing;D、 Made for step C product is mixed with nano titanium oxide, obtains a kind of nano combined filtrate;
High-temperature firing in described step C is to carry out under 1000-1500 degree Celsius;
The parts by weight of algae clay, E33, zeolite powder, activated carbon and nano titanium oxide are: algae clay 20~40, conch meal 20- 30, E33 is 15-35, zeolite powder 10-15, activated carbon 30-50 and nano titanium oxide 8-16.
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CN201610342630.6A Active CN105903266B (en) 2014-11-14 2014-11-14 Heavy metal in water and the nano combined filtrate that can be sterilized can be removed
CN201610342633.XA Expired - Fee Related CN105903267B (en) 2014-11-14 2014-11-14 A kind of nano combined filtrate for removing heavy metal in water
CN201610342634.4A Active CN105903268B (en) 2014-11-14 2014-11-14 The preparation method of the nano combined filtrate of heavy metal in water can be removed
CN201610342628.9A Pending CN105923687A (en) 2014-11-14 2014-11-14 Nano-composite filter material capable of removing heavy metal out of water
CN201610342627.4A Active CN106390592B (en) 2014-11-14 2014-11-14 It can sterilize, remove the nano combined filtrate of heavy metal in water
CN201610342635.9A Active CN105903269B (en) 2014-11-14 2014-11-14 The preparation method of heavy metal in water and the nano combined filtrate that can be sterilized can be removed
CN201610342626.XA Expired - Fee Related CN105797482B (en) 2014-11-14 2014-11-14 A kind of nano combined filtrate sterilized, remove heavy metal in water
CN201410644645.9A Active CN104474781B (en) 2014-11-14 2014-11-14 A kind of preparation method of nano combined filtrate

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CN201610342634.4A Active CN105903268B (en) 2014-11-14 2014-11-14 The preparation method of the nano combined filtrate of heavy metal in water can be removed
CN201610342628.9A Pending CN105923687A (en) 2014-11-14 2014-11-14 Nano-composite filter material capable of removing heavy metal out of water
CN201610342627.4A Active CN106390592B (en) 2014-11-14 2014-11-14 It can sterilize, remove the nano combined filtrate of heavy metal in water
CN201610342635.9A Active CN105903269B (en) 2014-11-14 2014-11-14 The preparation method of heavy metal in water and the nano combined filtrate that can be sterilized can be removed
CN201610342626.XA Expired - Fee Related CN105797482B (en) 2014-11-14 2014-11-14 A kind of nano combined filtrate sterilized, remove heavy metal in water
CN201410644645.9A Active CN104474781B (en) 2014-11-14 2014-11-14 A kind of preparation method of nano combined filtrate

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CN104826389A (en) * 2015-04-21 2015-08-12 安徽凤凰滤清器股份有限公司 Adsorbing and filtering agent special for high-strength dirt catcher and making method of adsorption filtering agent
CN105293667A (en) * 2015-10-23 2016-02-03 苏州书瑞环保科技有限公司 Environment-friendly water treatment agent for removing chromium ions and preparation method thereof
CN105561912B (en) * 2015-12-16 2018-04-17 浙江省海洋水产研究所 A kind of method of modified oyster shell whiting processing effluent containing heavy metal ions
CN105478072B (en) * 2015-12-16 2017-12-01 浙江省海洋水产研究所 A kind of preparation method of modified oyster shell whiting
CN105964052A (en) * 2016-06-24 2016-09-28 马鞍山市顺达环保设备有限公司 Filtering material used for mine dust collector and preparation method of filtering material
CN106186361A (en) * 2016-08-24 2016-12-07 安徽正田能源科技有限公司 A kind of silicon chip processing waste water is with natural purification filtrate
CN107262068A (en) * 2017-08-11 2017-10-20 中山市华帝环境科技有限公司 It is a kind of to be loaded with granular activated carbon of titanium dioxide and preparation method thereof
US11713255B2 (en) 2017-11-02 2023-08-01 Aqua Chira International Incorporated Water filter cartridge
US11053137B1 (en) 2017-11-02 2021-07-06 Aqua Clara International Incorporated Water filter cartridge

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