CN105895874A - Method for preparing graphene/tin dioxide quantum dot negative electrode material of lithium ion battery - Google Patents
Method for preparing graphene/tin dioxide quantum dot negative electrode material of lithium ion battery Download PDFInfo
- Publication number
- CN105895874A CN105895874A CN201610260682.9A CN201610260682A CN105895874A CN 105895874 A CN105895874 A CN 105895874A CN 201610260682 A CN201610260682 A CN 201610260682A CN 105895874 A CN105895874 A CN 105895874A
- Authority
- CN
- China
- Prior art keywords
- lithium ion
- ion battery
- tin dioxide
- negative material
- preparing graphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to a method for preparing a graphene/tin dioxide quantum dot negative electrode material of a lithium ion battery. The method comprises the following steps of 1) mixing glucose and stannous chloride, and grinding the glucose and the stannous chloride in an agate mortar; 2) mixing sodium chloride and potassium chloride, and carrying out ball milling by a ball milling machine; 3) uniformly mixing the materials of the step 1) and the step 2), and carrying out pre-heating processing; 4) placing the mixed material after pre-heated in a square ceramic boat, placing the ceramic boat in a tubular furnace, introducing an inertia gas for protection, and carrying out calcination; 5) carrying out heat preservation after calcination; 6) naturally reducing a temperature to a room temperature under the protection of the inertia gas, and taking out a sample; and 7) washing the obtained sample with diluted hydrochloric acid, and obtaining the material by vacuum filtration. With the adoption of one-step synthesis by solid phase reaction, the cheap glucose is taken as a carbon source, and thus, the graphene/tin dioxide quantum dot negative electrode material of the lithium ion battery is synthesized at a large scale and can be widely applied to the existing lithium ion battery.
Description
[technical field]
The present invention relates to the preparation method of a kind of lithium ion battery negative material, be specifically related to one and prepare Graphene/titanium dioxide
The method of stannum quantum dot lithium ion battery negative material, belongs to novel energy resource material technology field.
[background technology]
Lithium ion battery, compared with conventional batteries, has that running voltage is higher, specific energy is higher, more safety and memoryless etc. excellent
Gesture.Since 21 century, environmental pollution is day by day serious, and energy shortage has had become as important the asking of restriction progress of human society development
Topic, this just forces people urgently to develop the life mode of transportation producing more energy-conserving and environment-protective, to reduce the big of the petrochemical industry class energy
Amount uses, and the large-scale use of the most all kinds of electric vehicles is exactly that a kind of important replacement that can reduce environmental pollution is done
Method.In addition, for ensureing good flying power, the overwhelming majority the most of each electric appliances in daily life uses lithium ion
Battery, such as mobile phone, notebook computer, digital camera and videocorder etc..Develop high energy storage density and long circulation life
New type lithium ion battery be a kind of urgent social need, be current social development needs.
The theoretical specific capacity of tin ash is 783mAh/g, and specific capacity is high and cheap, is lithium ion battery negative material
The ideal chose of material.But, tin ash is when Lithium-ion embeding/abjection, it may occur that bigger volumetric expansion/reduce, and causes
Shorter battery life and the drastically decline of capacity.Tin ash is the most generally used to be combined with Graphene, by the bag of Graphene
Cover and can alleviate volumetric expansion problem to a certain extent, significantly improve the electrochemical stability of tin ash negative material.
Graphene is a kind of novel Two-dimensional Carbon nano material, has fabulous conductance property and electrochemical stability, by Graphene bag
Overlay on the surface of tin oxide nano particles, not only increase the electric conductivity of composite, beneficially lithium ion the most embedding
Enter/deviate from, and also improve the cyclical stability of battery, extend the life-span of road battery.
The method preparing Graphene/tin dioxide quantal-point at present is a lot, and many employings first synthesize graphene oxide (GO),
In solution after dioxide composite stannum, carrying out annealing reduction, finally giving redox graphene (RGO)/stannic oxide nanometer
Composite, these method techniques are the most loaded down with trivial details, and productivity is the highest, it is difficult to realize real large-scale application.
Therefore, for solve above-mentioned technical problem, a kind of innovation of necessary offer prepare Graphene/tin ash quantum
The method of some lithium ion battery negative material, to overcome described defect of the prior art.
[summary of the invention]
For solving the problems referred to above, it is an object of the invention to provide a kind of extensive, low cost and prepare Graphene/tin ash amount
The method of son point lithium ion battery negative material.
For achieving the above object, the technical scheme that the present invention takes is: prepare Graphene/tin dioxide quantal-point lithium ion
The method of cell negative electrode material, it uses one-step synthesis, comprises the technical steps that:
1), glucose and stannous chloride are mixed, grinds in agate mortar；
2), sodium chloride and potassium chloride are mixed, through ball mill ball milling；
3), by step 1) and 2) in the material mixing that obtains uniform, and the pre-heat treatment；
4), the mixing material after the pre-heat treatment is placed in square porcelain boat, porcelain boat is positioned over the centre position of tube furnace, is passed through
Inert gas shielding, calcines under certain heating rate；
5), isothermal holding is carried out after calcining；
6), under inert gas shielding, it is naturally cooling to room temperature, takes out sample；
7), gained sample dilute hydrochloric acid is cleaned, and obtains Graphene/tin dioxide quantal-point lithium-ion electric by vacuum filtration
Pond negative material.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 1), in, the mass ratio of described glucose and stannous chloride is (1-16): 1.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 2), in, the mass ratio of described sodium chloride and potassium chloride is (1-3): 1.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 3), in, the temperature of the pre-heat treatment is 80 DEG C-200 DEG C.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 4), in, heating rate is 5 DEG C-30 DEG C/min；Calcining heat is 950 DEG C-1300 DEG C；Described noble gas is nitrogen.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 5), in, described temperature retention time is 30min-60min.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 6) in, mixture is placed in beaker, adds the dilute hydrochloric acid of 0.5%, excusing from death stirring 30min, uses the filter membrane of 0.5M to carry out very
Empty sucking filtration, adds the dilute hydrochloric acid of 0.5%, repeated washing 3-5 time again；Products therefrom is placed in air dry oven and is dried 24h.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is further: step
Rapid 1) in, needing to add ammonium chloride in the mixture of glucose and stannous chloride, the mass ratio of described glucose and ammonium chloride is 4:
5。
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material of the present invention is also: step 1)
In, glucose 0.1g, stannous chloride 0.1g, grind 50min；Step 2) in, sodium chloride 11.4g and potassium chloride 2.8g, grinds
50min；In step 3), 150 DEG C of the pre-heat treatment 20h；In step 4), being warming up to 1000 DEG C, heating rate is 20 DEG C/min,
Insulation 40min.
Compared with prior art, there is advantages that the present invention uses a single-step solid phase reaction synthetic method,
Use cheap glucose as carbon source, it is achieved that extensive synthesizing graphite alkene/tin dioxide quantal-point lithium ion battery negative
Material, is widely used in current lithium ion battery as negative material.
[accompanying drawing explanation]
Fig. 1 is the X ray diffracting spectrum (XRD) of gained sample of the present invention.
Fig. 2 a and Fig. 2 b is field emission scanning electron microscope (SEM) figure of gained sample of the present invention.
Fig. 3 is transmission electron microscope (TEM) figure of gained sample of the present invention.
[detailed description of the invention]
Embodiment 1:
One, raw material is prefabricated
Weigh 0.8g glucose, 0.05g stannous chloride, after being sufficiently mixed in glove box, be placed in agate mortar grinding
30min, obtains mixture A；Weigh 11.5g sodium chloride and 11.5g potassium chloride, to be placed in grinding in ball grinder after being sufficiently mixed
30min, obtains mixture B；Being mixed by mixture A and B, be placed in square porcelain boat, total mixture amount is less than porcelain boat total amount
2/3rds.
Two, pretreatment
The mixture of gained in step one is placed in vacuum drying oven, at 80 DEG C of heat treatment 10h；
Three, solid state reaction
Gained mixture in step 2 is placed in the middle of tube furnace boiler tube, is passed through nitrogen protection, is warming up to 950 DEG C, heating rate
It is 5 DEG C/min, after reaching target temperature, is incubated 30min, naturally cools to room temperature, take out.
Four, product washing
Porcelain boat product in step 3 is taken out, is placed in 500ml beaker, add the dilute hydrochloric acid of 0.5%, excusing from death stirring 30min, adopt
Carry out vacuum filtration with the filter membrane of 0.5M, again add the dilute hydrochloric acid of 0.5%, repeated washing step, altogether washing 3-5 time.Gained
Product is placed in air dry oven and is dried 24h.
Embodiment 2:
One, raw material is prefabricated
Weigh 0.1g glucose, 0.1g stannous chloride, after being sufficiently mixed in glove box, be placed in agate mortar grinding 50min,
Obtain mixture A；Weigh 11.4g sodium chloride and 2.8g potassium chloride, to be placed in grinding in ball grinder 50min after being sufficiently mixed,
To mixture B；Being mixed by mixture A and B, be placed in square porcelain boat, total mixture amount is less than 2/3rds of porcelain boat total amount.
Two, pretreatment
The mixture of gained in step one is placed in vacuum drying oven, at 150 DEG C of heat treatment 20h；
Three, solid state reaction
Gained mixture in step 2 is placed in the middle of tube furnace boiler tube, is passed through nitrogen protection, is warming up to 1000 DEG C, heating rate
It is 20 DEG C/min, after reaching target temperature, is incubated 40min, naturally cools to room temperature, take out.
Four, product washing
Porcelain boat product in step 3 is taken out, is placed in 500ml beaker, add the dilute hydrochloric acid of 0.5%, excusing from death stirring 30min, adopt
Carry out vacuum filtration with the filter membrane of 0.5M, again add the dilute hydrochloric acid of 0.5%, repeated washing step, altogether washing 3-5 time.Gained
Product is placed in air dry oven and is dried 24h.
Embodiment 3:
One, raw material is prefabricated
Weigh 0.4g glucose, the ammonium chloride of 0.5g, 0.05g stannous chloride, after being sufficiently mixed in glove box, it is placed in Achates and grinds
Alms bowl grinds 60min, obtains mixture A；Weigh 13.5g sodium chloride and 11.5g potassium chloride, to be placed in ball mill after being sufficiently mixed
Middle grinding 60min, obtains mixture B；Being mixed by mixture A and B, be placed in square porcelain boat, total mixture amount is less than porcelain boat
2/3rds of total amount.
Two, pretreatment
The mixture of gained in step one is placed in vacuum drying oven, at 200 DEG C of heat treatment 30h；
Three, solid state reaction
Gained mixture in step 2 is placed in the middle of tube furnace boiler tube, is passed through nitrogen protection, is warming up to 1300 DEG C, heating rate
It is 30 DEG C/min, after reaching target temperature, is incubated 60min, naturally cools to room temperature, take out.
Four, product washing
Porcelain boat product in step 3 is taken out, is placed in 500ml beaker, add the dilute hydrochloric acid of 0.5%, excusing from death stirring 30min, adopt
Carry out vacuum filtration with the filter membrane of 0.5M, again add the dilute hydrochloric acid of 0.5%, repeated washing step, altogether washing 3-5 time.Gained
Product is placed in air dry oven and is dried 24h.
The technique gained sample using the present invention has the feature that
1. as it is shown in figure 1, be X-ray diffraction (XRD) figure of Graphene/tin dioxide quantal-point composite, XRD figure stave
Bright: the main indices of crystallographic plane of complex are basic with the standard X-ray diffraction (pdf document number: 77-0447) of Tetragonal tin ash
Unanimously, such as Tetragonal tin ash (110), (101), (211), (301), (202) face, there is no other impurity peaks or stannum oxide
Peak, illustrates that the sample prepared comprises Tetragonal stannic oxide particle.
2. as in figure 2 it is shown, be the field emission scanning electron microscope figure of Graphene/tin dioxide quantal-point composite.From figure a
Can be seen that and successfully prepared Graphene；The tin dioxide quantal-point of graphene coated, tin ash is can be seen that from figure b
Quantum dot is evenly distributed in graphenic surface.
3. as it is shown on figure 3, be the transmission electron microscope figure of Graphene/tin dioxide quantal-point composite.From figure
It can be seen that tin dioxide quantal-point is evenly distributed in graphenic surface, particle diameter is about 3 nanometers, and tin dioxide quantal-point is brilliant
Change perfection, spacing of lattice about 0.33 nanometer, corresponding (110) crystal face.
Above detailed description of the invention is only the preferred embodiment of this creation, not in order to limit this creation, all in this wound
Any modification, equivalent substitution and improvement etc. done within the spirit made and principle, should be included in this creation protection domain it
In.
Claims (9)
1. the method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material, it is characterised in that: it uses a step
Synthetic method, comprises the technical steps that:
1), glucose and stannous chloride are mixed, grinds in agate mortar；
2), sodium chloride and potassium chloride are mixed, through ball mill ball milling；
3), by step 1) and 2) in the material mixing that obtains uniform, and the pre-heat treatment；
4), the mixing material after the pre-heat treatment is placed in square porcelain boat, porcelain boat is positioned over the centre position of tube furnace, is passed through
Inert gas shielding, calcines under certain heating rate；
5), isothermal holding is carried out after calcining；
6), under inert gas shielding, it is naturally cooling to room temperature, takes out sample；
7), gained sample dilute hydrochloric acid is cleaned, and obtains Graphene/tin dioxide quantal-point lithium-ion electric by vacuum filtration
Pond negative material.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levying and be: in step 1), the mass ratio of described glucose and stannous chloride is (1-16): 1.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levy and be: step 2) in, the mass ratio of described sodium chloride and potassium chloride is (1-3): 1.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levying and be: in step 3), the temperature of the pre-heat treatment is 80 DEG C-200 DEG C.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levying and be: in step 4), heating rate is 5 DEG C-30 DEG C/min；Calcining heat is 950 DEG C-1300 DEG C；Described noble gas is
Nitrogen.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levying and be: in step 5), described temperature retention time is 30min-60min.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levying and be: in step 6), mixture is placed in beaker, adds the dilute hydrochloric acid of 0.5%, excusing from death stirring 30min, uses the filter of 0.5M
Film carries out vacuum filtration, again adds the dilute hydrochloric acid of 0.5%, repeated washing 3-5 time；Products therefrom is placed in air dry oven dry
Dry 24h.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levy and be: in step 1), the mixture of glucose and stannous chloride needs add ammonium chloride, described glucose and the matter of ammonium chloride
Amount ratio is 4:5.
The method preparing Graphene/tin dioxide quantal-point lithium ion battery negative material the most as claimed in claim 1, it is special
Levy and be: in step 1), glucose 0.1g, stannous chloride 0.1g, grind 50min；Step 2) in, sodium chloride 11.4g and chlorination
Potassium 2.8g, grinds 50min；In step 3), 150 DEG C of the pre-heat treatment 20h；In step 4), being warming up to 1000 DEG C, heating rate is
20 DEG C/min, it is incubated 40min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260682.9A CN105895874B (en) | 2016-04-25 | 2016-04-25 | The method for preparing graphene/tin dioxide quantal-point lithium ion battery negative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260682.9A CN105895874B (en) | 2016-04-25 | 2016-04-25 | The method for preparing graphene/tin dioxide quantal-point lithium ion battery negative material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105895874A true CN105895874A (en) | 2016-08-24 |
| CN105895874B CN105895874B (en) | 2018-09-07 |
Family
ID=56704737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610260682.9A Expired - Fee Related CN105895874B (en) | 2016-04-25 | 2016-04-25 | The method for preparing graphene/tin dioxide quantal-point lithium ion battery negative material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105895874B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106803577A (en) * | 2016-12-31 | 2017-06-06 | 浙江工业大学 | A kind of hollow copper quantum dot/mesoporous carbon composite material and its preparation method and application |
| CN108264099A (en) * | 2018-01-03 | 2018-07-10 | 桂林理工大学 | A kind of preparation method of lithium ion battery high-performance two-dimensional sheet nickel oxide negative material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101478043A (en) * | 2009-01-08 | 2009-07-08 | 上海交通大学 | Negative pole material for lithium ionic cell and preparation process thereof |
| US20110033746A1 (en) * | 2009-08-10 | 2011-02-10 | Jun Liu | Self assembled multi-layer nanocomposite of graphene and metal oxide materials |
| CN102208639A (en) * | 2011-05-09 | 2011-10-05 | 北京化工大学 | Graphene/transition metal oxide composite cathode material and preparation method thereof |
| CN103441254A (en) * | 2013-09-03 | 2013-12-11 | 青岛科技大学 | Preparation method of graphene-supported stannic oxide quantum dot negative electrode material for lithium ion battery |
| CN104201357A (en) * | 2014-09-18 | 2014-12-10 | 温州大学 | Graphene quantum dot-graphene composite material as well as preparation method and application thereof |
-
2016
- 2016-04-25 CN CN201610260682.9A patent/CN105895874B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101478043A (en) * | 2009-01-08 | 2009-07-08 | 上海交通大学 | Negative pole material for lithium ionic cell and preparation process thereof |
| US20110033746A1 (en) * | 2009-08-10 | 2011-02-10 | Jun Liu | Self assembled multi-layer nanocomposite of graphene and metal oxide materials |
| CN102208639A (en) * | 2011-05-09 | 2011-10-05 | 北京化工大学 | Graphene/transition metal oxide composite cathode material and preparation method thereof |
| CN103441254A (en) * | 2013-09-03 | 2013-12-11 | 青岛科技大学 | Preparation method of graphene-supported stannic oxide quantum dot negative electrode material for lithium ion battery |
| CN104201357A (en) * | 2014-09-18 | 2014-12-10 | 温州大学 | Graphene quantum dot-graphene composite material as well as preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| JIAN LIN，ET AL.: "Graphene Nanoribbon and Nanostructured SnO2 Composite Anodes for Lithium Ion Batteries", 《ACS NANO》 * |
| XUYANG WANG，ET AL.: "A SnO2/graphene composite as a high stability electrode for lithium ion batteries", 《CARBON》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106803577A (en) * | 2016-12-31 | 2017-06-06 | 浙江工业大学 | A kind of hollow copper quantum dot/mesoporous carbon composite material and its preparation method and application |
| CN106803577B (en) * | 2016-12-31 | 2019-06-14 | 浙江工业大学 | A kind of hollow copper quantum dot/mesoporous carbon composite material and its preparation method and application |
| CN108264099A (en) * | 2018-01-03 | 2018-07-10 | 桂林理工大学 | A kind of preparation method of lithium ion battery high-performance two-dimensional sheet nickel oxide negative material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105895874B (en) | 2018-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Huang et al. | Hierarchical red phosphorus incorporated TiO2 hollow sphere heterojunctions toward superior photocatalytic hydrogen production | |
| Gong et al. | The synthesis of graphene-TiO 2/gC 3 N 4 super-thin heterojunctions with enhanced visible-light photocatalytic activities | |
| Li et al. | Synthesis of TiO 2@ ZnIn 2 S 4 hollow nanospheres with enhanced photocatalytic hydrogen evolution | |
| Liu et al. | The synergic effects of Na and K co-doping on the crystal structure and electrochemical properties of Li4Ti5O12 as anode material for lithium ion battery | |
| Zhang et al. | Preparation and properties of mixed metal oxides based layered double hydroxide as anode materials for dye-sensitized solar cell | |
| Zahedifar et al. | Synthesis of LaVO4: Dy3+ luminescent nanostructure and optimization of its performance as down-converter in dye-sensitized solar cells | |
| CN105870447B (en) | Sodium-ion battery N doping rutile TiO2The preparation method of/C negative materials | |
| CN102376937A (en) | Nanometer lithium titanate/graphene composite negative electrode material and preparation process thereof | |
| CN105789595A (en) | Preparation method of graphene/molybdenum disulfide composite material | |
| McNulty et al. | The effect of particle size, morphology and C-rates on 3D structured Co3O4 inverse opal conversion mode anode materials | |
| CN106602047A (en) | Preparation method for carbon and lithium titanate compound material | |
| Wang et al. | A facile route for PbO@ C nanocomposites: An electrode candidate for lead-acid batteries with enhanced capacitance | |
| CN109742353A (en) | A kind of SnSe quantum dot/r-GO compound and its preparation method and application | |
| Mao et al. | Ionic liquid-assisted hydrothermal synthesis of square BiOBr nanoplates with highly efficient photocatalytic activity | |
| CN106450219A (en) | Multi-dimensional assembled three-dimensional vanadium trioxide/carbon composite nano material as well as preparation method and application thereof | |
| CN106410199A (en) | Preparation method of graphene/ferro-tin alloy composite anode material for lithium ion battery | |
| Liu et al. | Ultrafast one-step synthesis of N and Ti 3+ codoped TiO 2 nanosheets via energetic material deflagration | |
| CN108408773A (en) | A kind of preparation method and applications of BiOCl materials | |
| CN111370755A (en) | Anion-doped ion conductor material and preparation method and application thereof | |
| Feng et al. | CeO2 composite metal organic framework is used to construct high-performance lithium-sulfur batteries | |
| Gao et al. | Enhanced visible-light-driven photocatalytic H2-production activity of CdS-loaded TiO2 microspheres with exposed (001) facets | |
| CN105826547A (en) | Method for preparing graphene-doped/carbon-clad lithium titanate composite negative electrode material through three-step method | |
| CN105895874A (en) | Method for preparing graphene/tin dioxide quantum dot negative electrode material of lithium ion battery | |
| Dong et al. | Rational design of hollow Ti2Nb10O29 nanospheres towards High-Performance pseudocapacitive Lithium-Ion storage | |
| Cao et al. | Special sea urchin-like CdS/g-C3N4 photocatalyst with high specific surface area and efficient charge separation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180907 Termination date: 20200425 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |