CN105886820A - Porous foamy copper material and production method thereof - Google Patents
Porous foamy copper material and production method thereof Download PDFInfo
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- CN105886820A CN105886820A CN201610295253.5A CN201610295253A CN105886820A CN 105886820 A CN105886820 A CN 105886820A CN 201610295253 A CN201610295253 A CN 201610295253A CN 105886820 A CN105886820 A CN 105886820A
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- porous foam
- foam copper
- copper product
- copper material
- porous
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1121—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers
- B22F3/1125—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers involving a foaming process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention provides a porous foamy copper material and a production method thereof. The porous foamy copper material is prepared from the following components: polyurethane sponges, bronzing powder, sodium dodecylbenzene sulfonate, phosphatidylcholine, methyl 4-hydroxybenzoate, sodium diacetate, polyvinyl alcohol, polyvinyl formal, tristearin, sodium hydroxide, colophony, methyl cellulose, ethyl alcohol, an ammonia solution, and water. The porous foamy copper material is prepared through the following steps of (1) mixing and soaking the polyurethane sponges, the sodium hydroxide and the water; (2) mixing all the remaining components, stirring the mixed components with a stirrer so as to form pulp, and leaving the pulp to stand at room temperature; (3) putting the processed sponges into the pulp for repeated infiltration, and drying the sponges after the infiltration in the air to form a foamy body biscuit; and (4) putting foamy bodies under high vacuum so that copper oxide is decomposed, and performing sintering so as to obtain the porous foamy copper material. The porous foamy copper material disclosed by the invention is high in porosity factor, high in apparent density, and rough in surfaces; besides, the porous foamy copper material disclosed by the invention has a high plateau stress, so that the mechanical property is good.
Description
Technical field
The present invention relates to foamed materials field, be specifically related to a kind of porous foam copper product and preparation method thereof.
Background technology
Along with China's economy and the fast development of science and technology, the development of materials industry also presents the appearance of flourishing growth, wherein, porous metals are a kind of functional structure new engineering material developed rapidly in recent years, have that density is low, impact resistance, thermal conductivity are low, good muffling effect and the high advantage of hardness, are therefore widely used in the industries such as environment protection architecture, space flight and aviation and electrochemistry.The at present research to foam metal is concentrated mainly on the foam metal of low-density high porosity, but the foam metal of high porosity has, and complex process, material selection range be narrow and high in cost of production shortcoming.Therefore, research and develop a kind of porous foam metal with advantages such as porosity are controlled, technique is simple, with low cost to have important practical significance and wide market prospect.
Summary of the invention
Solve the technical problem that:It is an object of the invention to provide a kind of porous foam copper product, porosity is the highest, and apparent density is the biggest, and surface is the most coarse, and the present invention has higher plateau stress simultaneously, and mechanical property is preferable.
Technical scheme:A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 15-20 part, bronze powder 5-10 part, dodecylbenzene sodium sulfonate 0.2-0.4 part, phosphatidylcholine 0.5-1 part, methyl parahydroxybenzoate 0.1-0.2 part, sodium diacetate 0.1-0.3 part, polyvinyl alcohol 0.5-1 part, polyvinyl formal 0.2-0.5 part, glyceryl tristearate 0.1-0.2 part, sodium hydroxide 1-2 part, Colophonium 0.1-0.3 part, methylcellulose 0.2-0.4 part, ethanol 2-4 part, ammonia 0.3-0.8 part, water 40-80 part.
Further preferred, described a kind of porous foam copper product, it is prepared from weight portion by following component: polyurethane sponge 16-19 part, bronze powder 6-9 part, dodecylbenzene sodium sulfonate 0.25-0.35 part, phosphatidylcholine 0.6-0.9 part, methyl parahydroxybenzoate 0.12-0.17 part, sodium diacetate 0.15-0.25 part, polyvinyl alcohol 0.6-0.9 part, polyvinyl formal 0.3-0.4 part, glyceryl tristearate 0.13-0.18 part, sodium hydroxide 1.2-1.8 part, Colophonium 0.15-0.25 part, methylcellulose 0.25-0.35 part, ethanol 2.5-3.5 part, ammonia 0.4-0.7 part, water 50-70 part.
The preparation method of above-mentioned porous foam copper product comprises the following steps:
(1) mixing of polyurethane sponge, sodium hydroxide and 25-40 part water is soaked 1-2 hour；
(2) residue all components is mixed, stir under rotating speed 80-100r/min 3-5 minute with blender and form slurry, at room temperature stand 23-25 hour；
(3) sponge is put in slurry repeatedly infiltrate 3-5 time, be dried in atmosphere and form foams biscuit；
(4) foams make under 850-950 DEG C of fine vacuum copper oxide decompose and be sintered at 900-1000 DEG C and get final product.
It is further preferred that soak time is 1.5 hours in step (1).
It is further preferred that step (2) medium speed 85-95r/min, mixing time is 3.5-4.5 minute, and time of repose is 23.5-24.5 hour.
It is further preferred that infiltration 4 times in step (3).
It is further preferred that decomposition temperature is 900 DEG C in step (4), sintering temperature is 950 DEG C.
Beneficial effect:The porous foam copper product of the present invention has the highest porosity, reaches as high as 89.9%, and apparent density is the biggest, can be to 0.851g/cm3, surface is the most coarse, and the present invention has higher plateau stress simultaneously, reaches as high as 1MPa, and mechanical property is preferable.
Detailed description of the invention
Embodiment 1
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 15 parts, 5 parts of bronze powder, dodecylbenzene sodium sulfonate 0.2 part, phosphatidylcholine 0.5 part, methyl parahydroxybenzoate 0.1 part, sodium diacetate 0.1 part, polyvinyl alcohol 0.5 part, polyvinyl formal 0.2 part, glyceryl tristearate 0.1 part, sodium hydroxide 1 part, Colophonium 0.1 part, methylcellulose 0.2 part, ethanol 2 parts, ammonia 0.3 part, 40 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 25 parts of water mixing are soaked 1 hour by (1)；(2) residue all components is mixed, stir under rotating speed 80r/min 3 minutes with blender and form slurry, at room temperature stand 23 hours；(3) sponge is put in slurry and repeatedly infiltrate 3 times, be dried in atmosphere and form foams biscuit；(4) foams make under 850 DEG C of fine vacuum copper oxide decompose and be sintered at 900 DEG C and get final product.
Embodiment 2
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 17 parts, 8 parts of bronze powder, dodecylbenzene sodium sulfonate 0.3 part, phosphatidylcholine 0.75 part, methyl parahydroxybenzoate 0.15 part, sodium diacetate 0.2 part, polyvinyl alcohol 0.75 part, polyvinyl formal 0.35 part, glyceryl tristearate 0.15 part, sodium hydroxide 1.5 parts, Colophonium 0.2 part, methylcellulose 0.3 part, ethanol 3 parts, ammonia 0.5 part, 60 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 32 parts of water mixing are soaked 1.5 hours by (1)；(2) residue all components is mixed, stir under rotating speed 90r/min 4 minutes with blender and form slurry, at room temperature stand 24 hours；(3) sponge is put in slurry and repeatedly infiltrate 4 times, be dried in atmosphere and form foams biscuit；(4) foams make under 900 DEG C of fine vacuum copper oxide decompose and be sintered at 950 DEG C and get final product.
Embodiment 3
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 20 parts, 10 parts of bronze powder, dodecylbenzene sodium sulfonate 0.4 part, phosphatidylcholine 1 part, methyl parahydroxybenzoate 0.2 part, sodium diacetate 0.3 part, polyvinyl alcohol 1 part, polyvinyl formal 0.5 part, glyceryl tristearate 0.2 part, sodium hydroxide 2 parts, Colophonium 0.3 part, methylcellulose 0.4 part, ethanol 4 parts, ammonia 0.8 part, 80 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 40 parts of water mixing are soaked 2 hours by (1)；(2) residue all components is mixed, stir under rotating speed 100r/min 5 minutes with blender and form slurry, at room temperature stand 25 hours；(3) sponge is put in slurry and repeatedly infiltrate 5 times, be dried in atmosphere and form foams biscuit；(4) foams make under 950 DEG C of fine vacuum copper oxide decompose and be sintered at 1000 DEG C and get final product.
Embodiment 4
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 16 parts, 6 parts of bronze powder, dodecylbenzene sodium sulfonate 0.25 part, phosphatidylcholine 0.6 part, methyl parahydroxybenzoate 0.12 part, sodium diacetate 0.15 part, polyvinyl alcohol 0.6 part, polyvinyl formal 0.3 part, glyceryl tristearate 0.13 part, sodium hydroxide 1.2 parts, Colophonium 0.15 part, methylcellulose 0.25 part, ethanol 2.5 parts, ammonia 0.4 part, 50 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 30 parts of water mixing are soaked 1.5 hours by (1)；(2) residue all components is mixed, stir under rotating speed 85r/min 3.5 minutes with blender and form slurry, at room temperature stand 23.5 hours；(3) sponge is put in slurry and repeatedly infiltrate 4 times, be dried in atmosphere and form foams biscuit；(4) foams make under 900 DEG C of fine vacuum copper oxide decompose and be sintered at 950 DEG C and get final product.
Embodiment 5
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 19 parts, 9 parts of bronze powder, dodecylbenzene sodium sulfonate 0.35 part, phosphatidylcholine 0.9 part, methyl parahydroxybenzoate 0.17 part, sodium diacetate 0.25 part, polyvinyl alcohol 0.9 part, polyvinyl formal 0.4 part, glyceryl tristearate 0.18 part, sodium hydroxide 1.8 parts, Colophonium 0.25 part, methylcellulose 0.35 part, ethanol 3.5 parts, ammonia 0.7 part, 70 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 35 parts of water mixing are soaked 1.5 hours by (1)；(2) residue all components is mixed, stir under rotating speed 95r/min 4.5 minutes with blender and form slurry, at room temperature stand 24.5 hours；(3) sponge is put in slurry and repeatedly infiltrate 4 times, be dried in atmosphere and form foams biscuit；(4) foams make under 900 DEG C of fine vacuum copper oxide decompose and be sintered at 950 DEG C and get final product.
Comparative example 1
The present embodiment is not contain dodecylbenzene sodium sulfonate and phosphatidylcholine with the difference of embodiment 5.Specifically:
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 19 parts, 9 parts of bronze powder, methyl parahydroxybenzoate 0.17 part, sodium diacetate 0.25 part, polyvinyl alcohol 0.9 part, polyvinyl formal 0.4 part, glyceryl tristearate 0.18 part, sodium hydroxide 1.8 parts, Colophonium 0.25 part, methylcellulose 0.35 part, ethanol 3.5 parts, ammonia 0.7 part, 70 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 35 parts of water mixing are soaked 1.5 hours by (1)；(2) residue all components is mixed, stir under rotating speed 95r/min 4.5 minutes with blender and form slurry, at room temperature stand 24.5 hours；(3) sponge is put in slurry and repeatedly infiltrate 4 times, be dried in atmosphere and form foams biscuit；(4) foams make under 900 DEG C of fine vacuum copper oxide decompose and be sintered at 950 DEG C and get final product.
Comparative example 2
The present embodiment is not contain glyceryl tristearate and Colophonium with the difference of embodiment 5.Specifically:
A kind of porous foam copper product, is prepared from weight portion by following component: polyurethane sponge 19 parts, 9 parts of bronze powder, dodecylbenzene sodium sulfonate 0.35 part, phosphatidylcholine 0.9 part, methyl parahydroxybenzoate 0.17 part, sodium diacetate 0.25 part, polyvinyl alcohol 0.9 part, polyvinyl formal 0.4 part, sodium hydroxide 1.8 parts, methylcellulose 0.35 part, ethanol 3.5 parts, ammonia 0.7 part, 70 parts of water.
The preparation method of above-mentioned porous foam copper product is: polyurethane sponge, sodium hydroxide and 35 parts of water mixing are soaked 1.5 hours by (1)；(2) residue all components is mixed, stir under rotating speed 95r/min 4.5 minutes with blender and form slurry, at room temperature stand 24.5 hours；(3) sponge is put in slurry and repeatedly infiltrate 4 times, be dried in atmosphere and form foams biscuit；(4) foams make under 900 DEG C of fine vacuum copper oxide decompose and be sintered at 950 DEG C and get final product.
The property indices of material of the present invention is as follows, it may be seen that the porosity of the present invention is the highest, reaches as high as 89.9%, and apparent density is the biggest, can be to 0.851g/cm3, surface is the most coarse, and the present invention has higher plateau stress simultaneously, reaches as high as 1MPa, and mechanical property is preferable.
The performance indications of table 1 porous foam copper product
Claims (9)
1. a porous foam copper product, it is characterised in that: it is prepared from weight portion by following component: polyurethane sponge 15-20 part, bronze powder 5-10 part, dodecylbenzene sodium sulfonate 0.2-0.4 part, phosphatidylcholine 0.5-1 part, methyl parahydroxybenzoate 0.1-0.2 part, sodium diacetate 0.1-0.3 part, polyvinyl alcohol 0.5-1 part, polyvinyl formal 0.2-0.5 part, glyceryl tristearate 0.1-0.2 part, sodium hydroxide 1-2 part, Colophonium 0.1-0.3 part, methylcellulose 0.2-0.4 part, ethanol 2-4 part, ammonia 0.3-0.8 part, water 40-80 part.
A kind of porous foam copper product the most according to claim 1, it is characterized in that: be prepared from weight portion by following component: polyurethane sponge 16-19 part, bronze powder 6-9 part, dodecylbenzene sodium sulfonate 0.25-0.35 part, phosphatidylcholine 0.6-0.9 part, methyl parahydroxybenzoate 0.12-0.17 part, sodium diacetate 0.15-0.25 part, polyvinyl alcohol 0.6-0.9 part, polyvinyl formal 0.3-0.4 part, glyceryl tristearate 0.13-0.18 part, sodium hydroxide 1.2-1.8 part, Colophonium 0.15-0.25 part, methylcellulose 0.25-0.35 part, ethanol 2.5-3.5 part, ammonia 0.4-0.7 part, water 50-70 part.
3. a kind of porous foam copper product as claimed in claim 1, it is characterised in that: the PPI(of described polyurethane sponge spongioplasm per square inch) it is 9-10.
4. a kind of porous foam copper product as claimed in claim 1, it is characterised in that: described ancient copper powder size is 5-30 μm.
5. the preparation method of a kind of porous foam copper product described in any one of claim 1 to 2, it is characterised in that: comprise the following steps:
(1) mixing of polyurethane sponge, sodium hydroxide and 25-40 part water is soaked 1-2 hour；
(2) residue all components is mixed, stir under rotating speed 80-100r/min 3-5 minute with blender and form slurry, at room temperature stand 23-25 hour；
(3) sponge is put in slurry repeatedly infiltrate 3-5 time, be dried in atmosphere and form foams biscuit；
(4) foams make under 850-950 DEG C of fine vacuum copper oxide decompose and be sintered at 900-1000 DEG C and get final product.
The preparation method of a kind of porous foam copper product the most according to claim 5, it is characterised in that: in described step (1), soak time is 1.5 hours.
The preparation method of a kind of porous foam copper product the most according to claim 5, it is characterised in that: described step (2) medium speed 85-95r/min, mixing time is 3.5-4.5 minute, and time of repose is 23.5-24.5 hour.
The preparation method of a kind of porous foam copper product the most according to claim 5, it is characterised in that: infiltration 4 times in described step (3).
The preparation method of a kind of porous foam copper product the most according to claim 5, it is characterised in that: in described step (4), decomposition temperature is 900 DEG C, and sintering temperature is 950 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610295253.5A CN105886820A (en) | 2016-05-06 | 2016-05-06 | Porous foamy copper material and production method thereof |
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| CN201610295253.5A CN105886820A (en) | 2016-05-06 | 2016-05-06 | Porous foamy copper material and production method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641729A (en) * | 2017-09-29 | 2018-01-30 | 成都新柯力化工科技有限公司 | A kind of method that liquid polymer auxiliary foaming prepares foam metal material |
| CN111235422A (en) * | 2020-02-27 | 2020-06-05 | 山东大学 | Preparation method and application of porous platinum |
| CN111378998A (en) * | 2020-04-09 | 2020-07-07 | 烟台东方新程科技有限公司 | Foam metal processing technology |
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| CN101608271A (en) * | 2009-07-20 | 2009-12-23 | 河北工业大学 | A kind of preparation method of through-hole foam copper |
| CN103215470A (en) * | 2013-05-03 | 2013-07-24 | 中南大学 | Preparation method of open-pore copper foam with controllable pore structure parameter |
| CN103526064A (en) * | 2013-10-11 | 2014-01-22 | 昆明理工大学 | Preparation method for foamy copper |
| CN104451234A (en) * | 2014-12-14 | 2015-03-25 | 辛长礼 | Preparation method of ventilating metal |
| CN105525123A (en) * | 2015-11-11 | 2016-04-27 | 陕西盛迈石油有限公司 | Preparation method for high-porosity foamy copper |
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2016
- 2016-05-06 CN CN201610295253.5A patent/CN105886820A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608271A (en) * | 2009-07-20 | 2009-12-23 | 河北工业大学 | A kind of preparation method of through-hole foam copper |
| CN103215470A (en) * | 2013-05-03 | 2013-07-24 | 中南大学 | Preparation method of open-pore copper foam with controllable pore structure parameter |
| CN103526064A (en) * | 2013-10-11 | 2014-01-22 | 昆明理工大学 | Preparation method for foamy copper |
| CN104451234A (en) * | 2014-12-14 | 2015-03-25 | 辛长礼 | Preparation method of ventilating metal |
| CN105525123A (en) * | 2015-11-11 | 2016-04-27 | 陕西盛迈石油有限公司 | Preparation method for high-porosity foamy copper |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641729A (en) * | 2017-09-29 | 2018-01-30 | 成都新柯力化工科技有限公司 | A kind of method that liquid polymer auxiliary foaming prepares foam metal material |
| CN107641729B (en) * | 2017-09-29 | 2019-12-10 | 泰州亿丰达电器有限公司 | method for preparing foam metal material by liquid polymer auxiliary foaming |
| CN111235422A (en) * | 2020-02-27 | 2020-06-05 | 山东大学 | Preparation method and application of porous platinum |
| CN111378998A (en) * | 2020-04-09 | 2020-07-07 | 烟台东方新程科技有限公司 | Foam metal processing technology |
| CN111378998B (en) * | 2020-04-09 | 2022-03-01 | 烟台东方新程科技有限公司 | Foam metal processing technology |
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