CN105885656A - Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof - Google Patents

Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof Download PDF

Info

Publication number
CN105885656A
CN105885656A CN201610273403.2A CN201610273403A CN105885656A CN 105885656 A CN105885656 A CN 105885656A CN 201610273403 A CN201610273403 A CN 201610273403A CN 105885656 A CN105885656 A CN 105885656A
Authority
CN
China
Prior art keywords
nano
parts
transparent heat
nanofiber
glass coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610273403.2A
Other languages
Chinese (zh)
Inventor
程言俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Rongcheng Glass Products Co Ltd
Original Assignee
Anhui Rongcheng Glass Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Rongcheng Glass Products Co Ltd filed Critical Anhui Rongcheng Glass Products Co Ltd
Priority to CN201610273403.2A priority Critical patent/CN105885656A/en
Publication of CN105885656A publication Critical patent/CN105885656A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/08—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2231—Oxides; Hydroxides of metals of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an anti-discoloring transparent heat-insulating nano glass coating. The anti-discoloring transparent heat-insulating nano glass coating is prepared from, by weight, 20-21 parts of nano tin and antimony oxide, 0.2-0.3 part of a dispersant SN-5040, 79-81 parts of water-borne polyurethane resin, 30-35 parts of deionized water, 40-50 parts of N,N'-dimethyl formamide, 20-22 parts of 20% sulfuric acid solution, 20-22 parts of perfluoro caprylic acid, 3-4 parts of methyl methacrylate, 0.1-0.2 part of potassium persulfate, 3-3.5 parts of isocyanate, 0.5-0.6 part of BiFeO3 nanofibers, 0.6-0.8 part of titanyl sulfate and 0.3-0.4 part of HfB2. By the adoption of hybrid modification with the BiFeO3 nanofibers, the titanyl sulfate and the HfB2, the BiFeO3 nanofibers and the HfB2 can improve strength and scratch resistance of the coating and can eliminate harmful electromagnetic waves. The titanyl sulfate can prevent the coating from discoloring and prevent attractive appearance and light transmission from being affected.

Description

A kind of Anti-tarnishing transparent heat-insulated nano-glass coating and preparation method thereof
Technical field
The present invention relates to glass coating technical field, particularly relate to a kind of Anti-tarnishing transparent heat-insulated nano-glass coating and Preparation method.
Background technology
Along with society is to the energy-conservation continuous attention with environmental requirement, can become for people at the heat-protecting glass that different places uses Common requirements, and there is the drawback that performance imperfection, complex process or cost are high in existing heat-protecting glass.Nano oxidized Stannum antimony (ATO) has good visible light permeability and infrared barrier, is a kind of preferably heat-barrier material.By nano tin dioxide Antimony joins to be made the method for transparent heat insulating dope and can effectively solve the heat-insulating problem of glass in coating, compared with similar products, There is the advantage that technique is simple, with low cost, there is high using value and wide market prospect." transparent heat-insulated nanometer The preparation of glass coating and performance study " first a literary composition have studied nano antimony tin oxide dispersive property in water, has investigated pH Value, dispersant and consumption, different dispersion means and the technological parameter impact on the dispersion stabilization of nano antimony tin oxide thereof. Result shows, nano antimony tin oxide isoelectric point, IP in water is at pH=4.27, and during system meta-alkalescence, dispersion stabilization has and significantly carries High.The optimum dispersant of dispersion is a kind of anionic macromolecule dispersing agent, and consumption is about the 2% of ATO particle weight. This article has also investigated the impact on dispersion stabilization of different process for dispersing and process conditions thereof, for single dispersion means, Ball milling dispersion and high speed dispersion effect are better than ultrasonic disperse, are disperseed ATO by secondary ball milling method, can be same in acquisition While secondary ball-milling method same particle sizes, shorten the grinding distribution time.The nano oxygen obtained with above-mentioned optimum formula and dispersing technology Within the particle diameter of change stannum antimony aqueous dispersion is distributed in 100nm.This article also uses the aqueous dispersion of nano antimony tin oxide and aqueous to gather Urethane mixes mutually, adds a certain amount of thickening agent and other auxiliary agent, has prepared transparent heat insulating dope of good performance.By homemade This transparent heat insulating dope is tested by effect of heat insulation test device, and result shows, this coating has good effect of heat insulation. Under the conditions of pigment is 1/5, after system reaches equilibrium temperature, the box chamber air temperature difference of sample and blank glass reaches 6 ° of C, right The discussion of insulating mechanism shows: effect of heat insulation is played a role jointly by absorbing and reflect two parts.This transparent heat insulating dope There is good spectral selection, there is in visible region high permeability and can effectively intercept the heat radiation in infrared light district.Face Base maintains more than 65% than the light transmittance of the coating entirety being 1/5, and near infrared region (900～2500nm), light transmittance drops to again About 40%, coating has obvious spectral selection.By the scanning electron microscope analysis of film is shown, nano antimony tin oxide grain Son major part particle diameter in film smooths less than 100nm, even particle size distribution, film.
But film all has certain water absorption and water penetration, after water suction, easily cause wrinkling coming off, nano indium oxide Stannum is meeting degeneration under the effect of long-term water, affects effect of heat insulation, needs to improve resistance to water.
Additionally glass coating film there is also some problems needs to solve, such as thermostability, wearability, static electricity resistance, toughness, anti- The performances such as bacterium property, resistance to acids and bases, transparency, scratch resistance, environmental-protecting performance, anti-radiation, Anti-tarnishing, anti-flammability, ultra-violet resistance Having different demands under different occasions, current coating still can not meet the needs of all environment, needs further Improve performance, to meet the needs of production.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of transparent heat-insulated nano-glass of Anti-tarnishing is coated with Material and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of Anti-tarnishing transparent heat-insulated nano-glass coating, is prepared by the raw materials in: nano antimony tin oxide 20-21, Dispersant SN-5040 0.2-0.3, waterborne polyurethane resin 79-81, deionized water 30-35, N, N '-dimethyl Methanamide 40- 50,20% sulfuric acid solution 20-22, perfluoro caprylic acid 20-22, methyl methacrylate 3-4, potassium peroxydisulfate 0.1-0.2, Carbimide. Ester 3-3.5, BiFeO3Nanofiber 0.5-0.6, titanyl sulfate 0.6-0.8, HfB2 0.3-0.4。
The preparation method of described Anti-tarnishing transparent heat-insulated nano-glass coating, comprises the following steps:
(1) carrying out being mixed to join N by nano antimony tin oxide and perfluoro caprylic acid, in N '-dimethyl Methanamide, ultrasonic 30-35 divides Clock, drips sulfuric acid solution the most while stirring, is again heated to 80-85 DEG C of stirring reaction 20-30 minute, after terminating reaction, filters, Vacuum drying obtains fluorinated nano tin indium oxide；
(2) dispersant SN-5040, methyl methacrylate being added in deionized water, stir, regulation pH value is 8-9, then Add fluorinated nano tin indium oxide, under 6000-7000 rev/min, carry out magnetic agitation 60-70 minute, be then sonicated 12-13 Minute, add potassium peroxydisulfate, be heated to 63-68 DEG C, continue stirring 20-30 minute, obtain mixed serum；
(3) by BiFeO3Nanofiber, titanyl sulfate, HfB2Mixing, grinds uniformly, obtains modified BiFeO3Nanofiber；
(4) described mixed serum is mixed homogeneously with waterborne polyurethane resin, modified BiFeO3 nanofiber, add other and remain Remaining composition stirs, and to obtain final product.
The invention have the advantage that the present invention uses perfluoro caprylic acid to carry out fluorinated modified to nano antimony tin oxide so that coating Water absorption reduce, prevent nanoparticle from absorbing water degeneration, affect thermal insulation and adhesion strength, simultaneously because fluorinated nano stannum oxide The smooth surface of antimony, Waterproofing/oilproofing, improve the lubricity of film, corrosion resistance and wearability, re-use powder SN-5040, Methyl methacrylate carries out disperseing, graft modification so that nano antimony tin oxide disperses evenly in water, and surface grafting is lived Property group, improves the caking property with resin, thus improves adhesion strength and the wearability of coating；By using BiFeO3Receive Rice fiber, titanyl sulfate, HfB2 carry out mixed and modified, BiFeO3Nanofiber, HfB2Painting film strength and scratch-resistant can be improved Property, and unwanted electromagnetic wave can be eliminated；Titanyl sulfate is prevented from coating color-changing, affects attractive in appearance and light transmission.
Detailed description of the invention
A kind of Anti-tarnishing transparent heat-insulated nano-glass coating, is made up of the raw material of following weight portion (kilogram): nano oxidized Stannum antimony 20, dispersant SN-5040 0.2, waterborne polyurethane resin 79, deionized water 30, N, N '-dimethyl Methanamide 40,20% Sulfuric acid solution 20, perfluoro caprylic acid 20, methyl methacrylate 3, potassium peroxydisulfate 0.1, isocyanates 3, BiFeO3Nanofiber 0.5, titanyl sulfate 0.6, HfB2 0.3。
The preparation method of described Anti-tarnishing transparent heat-insulated nano-glass coating, comprises the following steps:
(1) nano antimony tin oxide and perfluoro caprylic acid are carried out being mixed to join N, in N '-dimethyl Methanamide, ultrasonic 30 minutes, Drip sulfuric acid solution the most while stirring, be again heated to 80 DEG C of stirring reactions 20 minutes, after terminating reaction, filter, vacuum drying Obtain fluorinated nano tin indium oxide；
(2) dispersant SN-5040, methyl methacrylate being added in deionized water, stir, regulation pH value is 8, then adds Enter fluorinated nano tin indium oxide, under 6000 revs/min, carry out magnetic agitation 60 minutes, be then sonicated 12 minutes, added Potassium sulfate, is heated to 63 DEG C, continues stirring 20 minutes, obtains mixed serum；
(3) by BiFeO3Nanofiber, titanyl sulfate, HfB2Mixing, grinds uniformly, obtains modified BiFeO3Nanofiber；
(4) by described mixed serum and waterborne polyurethane resin, modified BiFeO3Nanofiber mix homogeneously, adds other and remains Remaining composition stirs, and to obtain final product.
The coating that this embodiment obtains is coated on glass, is dried 2 hours, by GB/T5739-1996 standard at 70 DEG C Test pencil hardness 2H, is 1 grade according to GB/T1727-92 standard testing adhesive force, according to resistance to by GB/T1786-79 standard testing Mill property, attrition value (10-2G) it is 2.84；The water absorption rate 10.6% of 12 hours films, it is seen that light transmission rate is 76%, sheltering coefficient is 0.75, iodine-tungsten lamp irradiate under this embodiment heat-protecting glass and blank glass between sylphon in Air Temperature Difference reach 8.5 DEG C.

Claims (2)

1. an Anti-tarnishing transparent heat-insulated nano-glass coating, it is characterised in that: it is prepared by the raw materials in: nano oxygen Change stannum antimony 20-21, dispersant SN-5040 0.2-0.3, waterborne polyurethane resin 79-81, deionized water 30-35, N, N '-diformazan Base Methanamide 40-50, the sulfuric acid solution 20-22 of 20%, perfluoro caprylic acid 20-22, methyl methacrylate 3-4, potassium peroxydisulfate 0.1-0.2, isocyanates 3-3.5, BiFeO3Nanofiber 0.5-0.6, titanyl sulfate 0.6-0.8, HfB2 0.3-0.4。
The preparation method of Anti-tarnishing transparent heat-insulated nano-glass coating the most according to claim 1, it is characterised in that include with Lower step:
(1) carrying out being mixed to join N by nano antimony tin oxide and perfluoro caprylic acid, in N '-dimethyl Methanamide, ultrasonic 30-35 divides Clock, drips sulfuric acid solution the most while stirring, is again heated to 80-85 DEG C of stirring reaction 20-30 minute, after terminating reaction, filters, Vacuum drying obtains fluorinated nano tin indium oxide；
(2) dispersant SN-5040, methyl methacrylate being added in deionized water, stir, regulation pH value is 8-9, then Add fluorinated nano tin indium oxide, under 6000-7000 rev/min, carry out magnetic agitation 60-70 minute, be then sonicated 12-13 Minute, add potassium peroxydisulfate, be heated to 63-68 DEG C, continue stirring 20-30 minute, obtain mixed serum；
(3) by BiFeO3Nanofiber, titanyl sulfate, HfB2Mixing, grinds uniformly, obtains modified BiFeO3Nanofiber；
(4) described mixed serum is mixed homogeneously with waterborne polyurethane resin, modified BiFeO3 nanofiber, add other and remain Remaining composition stirs, and to obtain final product.
CN201610273403.2A 2016-04-27 2016-04-27 Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof Pending CN105885656A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610273403.2A CN105885656A (en) 2016-04-27 2016-04-27 Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610273403.2A CN105885656A (en) 2016-04-27 2016-04-27 Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105885656A true CN105885656A (en) 2016-08-24

Family

ID=56701793

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610273403.2A Pending CN105885656A (en) 2016-04-27 2016-04-27 Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105885656A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110054983A (en) * 2019-05-09 2019-07-26 山东光韵智能科技有限公司 One kind hating oily self-cleaning dust-proof coatings and its manufacturing method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301290A (en) * 1997-11-12 2001-06-27 昭和电工株式会社 Water-repellent coating material and article with water-repellent surface
CN101885943A (en) * 2010-07-23 2010-11-17 富思特制漆（北京）有限公司 Nano-glass heat insulation paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301290A (en) * 1997-11-12 2001-06-27 昭和电工株式会社 Water-repellent coating material and article with water-repellent surface
CN101885943A (en) * 2010-07-23 2010-11-17 富思特制漆（北京）有限公司 Nano-glass heat insulation paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
唐富龙: "透明隔热纳米玻璃涂料的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110054983A (en) * 2019-05-09 2019-07-26 山东光韵智能科技有限公司 One kind hating oily self-cleaning dust-proof coatings and its manufacturing method

Similar Documents

Publication Publication Date Title
US20210189143A1 (en) Coated pigment
CN108059917A (en) A kind of nano modification polysilazane anti-static material and preparation method thereof
CN106366892B (en) A kind of resistance to scratch-type open air powdery paints
CN105802471A (en) Scratch-resisting transparent heat-insulation nano glass coating and preparation method of scratch-resisting transparent heat-insulation nano glass coating
CN105802469A (en) Environmentally friendly anti-fog transparent thermal insulation nano glass coating and preparation method thereof
CN106010177A (en) Wear-resistant transparent heat-insulation nano glass coating and preparation method thereof
CN111748270B (en) Coating for projection screen and preparation method thereof
CN105819678A (en) Modified high-length/diameter ratio wollastonite fiber and preparation method thereof
CN105838218A (en) Antibacterial transparent heat-insulation nanometer glass paint and preparing method thereof
CN105885656A (en) Anti-discoloring transparent heat-insulating nano glass coating and preparation method thereof
CN108388040B (en) Resin optical filter and preparation method thereof
JP2007169378A (en) Metallic coating composition and method for producing the same
CN105838219A (en) High-toughness transparent thermal insulation nano glass coating and preparation method thereof
CN105860804A (en) Transparent scratch-resistant heat-insulation nano glass paint and preparation method thereof
CN105860805A (en) Anti-static transparent heat-insulating nano glass paint and preparation method thereof
CN105838215A (en) Heat-resisting, transparent and heat-insulating nanometer glass paint and preparation method thereof
CN105838213A (en) Flame retardant, transparent and heat insulating nano glass coating and preparation method thereof
CN105885654A (en) Nano-indium modified transparent heat-insulating nano glass coating and preparation method thereof
CN105802470A (en) Anti-ultraviolet, water-resistant and transparent insulation nano glass coating and preparation method thereof
CN103642379B (en) A kind of PU light reality look finish paint of high paint film clarity and hardness and preparation method thereof
CN105885655A (en) Radiation-resistant transparent heat-insulating nanometer glass coating and preparation method thereof
CN105820734A (en) Environment-friendly transparent heat insulation nano glass coating and preparation method thereof
CN105838217A (en) Aging-resistant, transparent and heat-insulating nanometer glass paint and preparation method thereof
CN105838216A (en) Heat-resisting, dense, transparent and heat-insulating nanometer glass paint and preparation method thereof
CN104788997B (en) Modified oxide, powdery paints and its preparation method and application

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160824

RJ01 Rejection of invention patent application after publication