CN105885493A - Anti-microbial stoving varnish cylinder and making method thereof - Google Patents
Anti-microbial stoving varnish cylinder and making method thereof Download PDFInfo
- Publication number
- CN105885493A CN105885493A CN201610368729.3A CN201610368729A CN105885493A CN 105885493 A CN105885493 A CN 105885493A CN 201610368729 A CN201610368729 A CN 201610368729A CN 105885493 A CN105885493 A CN 105885493A
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- Prior art keywords
- bucket
- baking
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- base substrate
- prepared
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a method for making an anti-microbial stoving varnish cylinder. The method comprises the steps of obtaining a green cylinder body M through sheet iron cutting and welding; conducting acid pickling on the green cylinder body M by means of pickling solution, and drying the green cylinder body M for use; mixing and stirring nanometer iron trioxide, styrene, methyl acrylate, ethyl acetate and glycerinum to prepare anti-microbial anti-corrosion paint N, coating the surface of the green cylinder body M with the prepared anti-microbial anti-corrosion paint N evenly, and placing the green cylinder body M into a baking chamber to be baked to obtain the anti-microbial stoving varnish cylinder. The problems of a stoving varnish cylinder made with the traditional process that a stoving varnish surface layer falls off easily, and bacterium breeding occurs easily in the stoving varnish cylinder to affect the quality of materials in the cylinder are solved.
Description
Technical field
The present invention relates to the preparation of pail pack, particularly to a kind of antibacterial baking vanish bucket and preparation method thereof.
Background technology
Baking vanish bucket is a kind of conventional pail pack, and its application is widely.At one layer of baking vanish of metal bucket surface-coated, the most attractive in appearance, moreover it is possible to play good rust-proof effect.But the baking vanish bucket that traditional handicraft prepares, its surface baking vanish layer easily comes off, and the internal easily breed bacteria of baking vanish bucket, influences whether the internal quality containing material simultaneously.
Therefore it provides a kind of baking vanish layer difficult drop-off, and the inside antibacterial baking vanish bucket being difficult to breed bacteria and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
The technical problem to be solved is to provide a kind of antibacterial baking vanish bucket and preparation method thereof, solve the baking vanish bucket that traditional handicraft prepares, its surface baking vanish layer easily comes off, simultaneously the internal easily breed bacteria of baking vanish bucket, the problem influencing whether the internal quality containing material.
For achieving the above object, the present invention provides following technical scheme: the preparation method of a kind of antibacterial baking vanish bucket, and wherein, described preparation method includes:
(1) iron plate cutting, welding are prepared bucket base substrate M；
(2) utilize pickle that bucket base substrate M is carried out pickling, the most standby；
(3) after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, Antimicrobial preservative paint N is prepared, wherein, nanometer iron sesquioxide relative to 100 weight portions, described cinnamic consumption is 30-40 weight portion, the consumption of described acrylic acid methyl ester. is 10-15 weight portion, the consumption of described ethyl acetate is 40-50 weight portion, and the consumption of described glycerol is 1-5 weight portion.
(4) prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M is put into baking in baking box, obtain described antibacterial baking vanish bucket.
Preferably, the raw material of described pickle is made up of hydrochloric acid, nitric acid and water, and the volume ratio of hydrochloric acid, nitric acid and water is 1:1-2:1-2.
Preferably, in described step (2), baking temperature is 40-50 DEG C, and drying time is 5-10min.
Preferably, the particle diameter of described nanometer iron sesquioxide is 20-50nm.
Preferably, the temperature of described baking is 70-80 DEG C, and baking time is 15-20min.
Present invention also offers a kind of antibacterial baking vanish bucket, described antibacterial baking vanish bucket is prepared by above-mentioned preparation method.
Beneficial effect: the invention provides the preparation method of a kind of antibacterial baking vanish bucket, wherein, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M is put into baking in baking box, obtain described antibacterial baking vanish bucket, by the synergism between raw material each in Antimicrobial preservative paint, after the Antimicrobial preservative paint prepared is coated on barrel base substrate, the most easy to crack come off, and make bucket possess excellent bacteriostasis, inside is difficult to breed bacteria, and the method being simultaneously used for preparing this baking vanish bucket is simple.
Detailed description of the invention
The following detailed description of the preferred embodiment of the present invention.
Embodiment 1
The preparation method of a kind of antibacterial baking vanish bucket, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, be dried (baking temperature is 40 DEG C, and drying time is 5min) the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, wherein, nanometer iron sesquioxide 100g, described cinnamic consumption is 30g, the consumption of described acrylic acid methyl ester. is 10g, the consumption of described ethyl acetate is 40g, the consumption of described glycerol is 1g, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M puts into baking in baking box, and (temperature of baking is 70 DEG C, baking time is 15min), obtain described antibacterial baking vanish bucket A1.
Embodiment 2
The preparation method of a kind of antibacterial baking vanish bucket, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, be dried (baking temperature is 50 DEG C, and drying time is 10min) the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, wherein, nanometer iron sesquioxide consumption is 100g, described cinnamic consumption is 40g, the consumption of described acrylic acid methyl ester. is 15g, the consumption of described ethyl acetate is 50g, the consumption of described glycerol is 5g, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M puts into baking in baking box, and (temperature of baking is 80 DEG C, baking time is 20min), obtain described antibacterial baking vanish bucket A2.
Embodiment 3
The preparation method of a kind of antibacterial baking vanish bucket, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, be dried (baking temperature is 45 DEG C, and drying time is 8min) the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, wherein, the consumption of nanometer iron sesquioxide is 100g, described cinnamic consumption is 35g, the consumption of described acrylic acid methyl ester. is 12g, the consumption of described ethyl acetate is 45g, the consumption of described glycerol is 3g, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M puts into baking in baking box, and (temperature of baking is 75 DEG C, baking time is 18min), obtain described antibacterial baking vanish bucket A3.
Comparative example 1
The preparation method of a kind of antibacterial baking vanish bucket, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, be dried (baking temperature is 30 DEG C, and drying time is 2min) the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, wherein, nanometer iron sesquioxide 100g, described cinnamic consumption is 20g, the consumption of described acrylic acid methyl ester. is 5g, the consumption of described ethyl acetate is 30g, the consumption of described glycerol is 0.5g, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M puts into baking in baking box, and (temperature of baking is 60 DEG C, baking time is 10min), obtain described antibacterial baking vanish bucket D1.
Comparative example 2
The preparation method of a kind of antibacterial baking vanish bucket, described preparation method includes: iron plate cutting, welding are prepared bucket base substrate M；Utilize pickle that bucket base substrate M is carried out pickling, be dried (baking temperature is 60 DEG C, and drying time is 15min) the most standby；Antimicrobial preservative paint N is prepared after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, wherein, nanometer iron sesquioxide consumption is 100g, described cinnamic consumption is 50g, the consumption of described acrylic acid methyl ester. is 20g, the consumption of described ethyl acetate is 60g, the consumption of described glycerol is 8g, prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M puts into baking in baking box, and (temperature of baking is 90 DEG C, baking time is 25min), obtain described antibacterial baking vanish bucket D2.
Test case 1
In the environment of prepared antibacterial baking vanish bucket A1-A3, D1 and D2 are placed in 120 DEG C 72 hours, run through the cracking situation that comes off on its surface, and the bacteriostasis rate in staving is detected.
Table 1
Be can be seen that by table 1, the plating baking vanish bucket A1-A3 prepared within the scope of the present invention is after test, and its surface is without cracking and dropping situations, and bacteriostasis rate is high, and there are slight or serious cracking and obscission in its surface of baking vanish bucket D1 and D2 prepared outside the scope of the invention, bacteriostasis rate is low.
Above-described is only the preferred embodiment of the present invention, it is noted that for the person of ordinary skill of the art, without departing from the concept of the premise of the invention, it is also possible to make some deformation and improvement, these broadly fall into protection scope of the present invention.
Claims (6)
1. the preparation method of an antibacterial baking vanish bucket, it is characterised in that described preparation method includes:
(1) iron plate cutting, welding are prepared bucket base substrate M；
(2) utilize pickle that bucket base substrate M is carried out pickling, the most standby；
(3) after the stirring mixing of nanometer iron sesquioxide, styrene, acrylic acid methyl ester., ethyl acetate and glycerol, Antimicrobial preservative paint N is prepared, wherein, nanometer iron sesquioxide relative to 100 weight portions, described cinnamic consumption is 30-40 weight portion, the consumption of described acrylic acid methyl ester. is 10-15 weight portion, the consumption of described ethyl acetate is 40-50 weight portion, and the consumption of described glycerol is 1-5 weight portion；
(4) prepared Antimicrobial preservative paint N is uniformly coated on the surface of described bucket base substrate M, and bucket base substrate M is put into baking in baking box, obtain described antibacterial baking vanish bucket.
Preparation method the most according to claim 1, wherein, the raw material of described pickle is made up of hydrochloric acid, nitric acid and water, and the volume ratio of hydrochloric acid, nitric acid and water is 1:1-2:1-2.
Preparation method the most according to claim 1, wherein, in described step (2), baking temperature is 40-50 DEG C, and drying time is 5-10min.
Preparation method the most according to claim 1, wherein, the particle diameter of described nanometer iron sesquioxide is 20-50nm.
Preparation method the most according to claim 1, wherein, the temperature of described baking is 70-80 DEG C, and baking time is 15-20min.
6. an antibacterial baking vanish bucket, it is characterised in that described antibacterial baking vanish bucket is prepared by the preparation method described in any one in claim 1-5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610368729.3A CN105885493A (en) | 2016-05-30 | 2016-05-30 | Anti-microbial stoving varnish cylinder and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610368729.3A CN105885493A (en) | 2016-05-30 | 2016-05-30 | Anti-microbial stoving varnish cylinder and making method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105885493A true CN105885493A (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610368729.3A Pending CN105885493A (en) | 2016-05-30 | 2016-05-30 | Anti-microbial stoving varnish cylinder and making method thereof |
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|---|---|
| CN (1) | CN105885493A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086548A (en) * | 2015-08-11 | 2015-11-25 | 宿迁市三石包装容器有限公司 | Spray paint special for gasoline drum and manufacture technology thereof |
| CN105462379A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special water-borne rust-associated anti-rust coating having antibacterial and antifungal functions and applied to pump valve |
| CN105600116A (en) * | 2015-10-30 | 2016-05-25 | 苏州凯康化工科技有限公司 | Resin barrel with antibacterial function and anti-oxidation function |
-
2016
- 2016-05-30 CN CN201610368729.3A patent/CN105885493A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086548A (en) * | 2015-08-11 | 2015-11-25 | 宿迁市三石包装容器有限公司 | Spray paint special for gasoline drum and manufacture technology thereof |
| CN105600116A (en) * | 2015-10-30 | 2016-05-25 | 苏州凯康化工科技有限公司 | Resin barrel with antibacterial function and anti-oxidation function |
| CN105462379A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special water-borne rust-associated anti-rust coating having antibacterial and antifungal functions and applied to pump valve |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160824 |
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| RJ01 | Rejection of invention patent application after publication |