CN105885200A - Mildew-proof anti-corrosion flame-retardant cable material and preparation method thereof - Google Patents
Mildew-proof anti-corrosion flame-retardant cable material and preparation method thereof Download PDFInfo
- Publication number
- CN105885200A CN105885200A CN201610410800.XA CN201610410800A CN105885200A CN 105885200 A CN105885200 A CN 105885200A CN 201610410800 A CN201610410800 A CN 201610410800A CN 105885200 A CN105885200 A CN 105885200A
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- Prior art keywords
- parts
- etfe
- mildew
- magnesium
- silver ion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms containing monomers with other atoms than carbon, hydrogen or oxygen atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Abstract
The invention discloses a mildew-proof anti-corrosion flame-retardant cable material and a preparation method thereof. The cable material is prepared from, by weight, 100-120 parts of ethylene tetrafluoroethylene (ETFE), 15-25 parts of ethylene propylene terpolymer rubber, 15-25 parts of bentonite, 5-10 parts of triguaiacyl phosphite, 3-8 parts of irradiation crosslinking agent, 4-5 parts of nano-magnesium hydroxide, 3-5 parts of nano-silicon dioxide, 6-9 parts of inorganic silver ion-containing silicate, 3-5 parts of wear-resistant powder, 1-3 parts of vinyl-tri(beta-methoxyethoxy)silane, 0.5-5 parts of lubricating agent, 1-3 parts of calcium oxide and 1-3 parts of magnesium oxide. The mildew-proof anti-corrosion flame-retardant cable material is suitable for various complex environments; meanwhile, silver ion-containing silicate is added, a good mildew-proof effect can be achieved, and by means of added aluminum hydroxide and zinc borate, the cable material has a good flame-retardant property.
Description
Technical field
The present invention relates to cable preparation field, particularly belong to the anti-rotten flame retardant type CABLE MATERIALS of a kind of mildew-resistant
And preparation method thereof.
Background technology
In cable for ship production process, cable decay resistance requires the highest, existing many cables
Material employs raw and auxiliary material inferior, although conventional sense qualified, but life-time service will
Copper wire is caused damage.Conventional corrosion-resistant additive easily corrodes copper wire and oxidizing blackening, sternly
The problem that ghost image rings cable performance.And how to suppress the generation of this phenomenon, cable is produced
It is critically important.
Summary of the invention
It is an object of the invention to the anti-rotten flame retardant type CABLE MATERIALS its preparation method of a kind of mildew-resistant, have more
Excellent decay resistance, and copper wire will not be corroded and oxidizing blackening, it is suitable for various complex environments,
With the addition of containing anion silicon hydrochlorate, it is possible to well play pre-mould proof effect simultaneously, add
Aluminium hydroxide, Firebrake ZB make CABLE MATERIALS have a good anti-flammability, formulation cost controls more
Rationally.
Technical scheme is as follows:
The anti-rotten flame retardant type CABLE MATERIALS of a kind of mildew-resistant, each raw material is as follows: ethyl tetra
Ethylene ETFE 100-120 part, ethylene-propylene-diene monomer 15～25 parts, bentonite 15～25 parts,
Triphosphite ester 5～10 parts, cross-linking radiation agent 3～8 parts, nano-sized magnesium hydroxide 4～5 parts,
Nano silicon 3～5 parts, inorganic silver ion silicate 6～9 parts, anti-wear-resisting powder 3～
5 parts；Vinyl three ('beta '-methoxy ethyoxyl) silane 1～3 parts, lubricant 0.5～5
Part, calcium oxide 1～3 parts, magnesium oxide 1～3 parts.
Each raw material is as follows: ETFE ETFE 110 parts, EPDM
Rubber 20 parts, bentonite 20 parts, triphosphite ester 8 parts, cross-linking radiation agent 5 parts, nanometer hydrogen
Magnesium oxide 4.5 parts, nano silicon 4 parts, inorganic silver ion silicate 8 parts, anti-resistance to
Pulverizing agent 4 parts；2 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 4 parts,
Calcium oxide 2 parts, magnesium oxide 2 parts.
Each raw material is as follows: ETFE ETFE 100 parts, EPDM
Rubber 15 parts, bentonite 15 parts, triphosphite ester 5 parts, cross-linking radiation agent 3 parts, nanometer hydrogen
Magnesium oxide 4 parts, nano silicon 3 parts, inorganic silver ion silicate 6 parts, anti-wear-resisting
3 parts of powder；1 part of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 0.5 part,
Calcium oxide 1 part, magnesium oxide 1 part.
Each raw material is as follows: ETFE ETFE 120 parts, ethylene-propylene-diene monomer
25 parts, bentonite 25 parts, triphosphite ester 10 parts, cross-linking radiation agent 8 parts, nanometer hydrogen
Magnesium oxide 5 parts, nano silicon 5 parts, inorganic silver ion silicate 9 parts, anti-wear-resisting
5 parts of powder；3 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 5 parts,
Calcium oxide 3 parts, magnesium oxide 3 parts.
A kind of preparation method of environment-friendly light Aviation cable material, (1) ETFE ETFE,
Ethylene-propylene-diene monomer, bentonite, triphosphite ester and nano-sized magnesium hydroxide, nano silicon,
Inorganic silver ion silicate, anti-wear-resisting powder, vinyl three ('beta '-methoxy ethyoxyl)
Silane, lubricant, calcium oxide, magnesium oxide mix according to the above ratio, in high-speed mixer all
Take out after even mixing 12min；
(2) by the raw material of mix homogeneously melt blending in double screw extruder, and extruding pelletization；
Melt extrude temperature at 250 DEG C-280 DEG C；
(3) it is placed again into twin-screw extrusion after being dried by semi-finished product good to melt blending pelletize
Machine, adds a certain proportion of cross-linking agent and carries out blending temperature 250 DEG C-20 DEG C, after extruding pelletization
Drying, sealing is kept in Dark Place.
The present invention has more excellent decay resistance, and will not corrode copper wire and oxidizing blackening,
It is suitable for various complex environments, with the addition of containing anion silicon hydrochlorate, it is possible to well play pre-simultaneously
Mould proof effect, simultaneously in add vinyl three ('beta '-methoxy ethyoxyl) silane, profit
Lubrication prescription, calcium oxide, magnesium oxide improve the compactness of product, get rid of material micropore, improve leaching
Water, resistance to steam performance, meet the requirement of nuclear power Insulation Material combination property.
Detailed description of the invention
The anti-rotten flame retardant type CABLE MATERIALS of 1 one kinds of mildew-resistant of embodiment, each raw material is as follows:
ETFE ETFE 110 parts, ethylene-propylene-diene monomer 20 parts, bentonite 20 parts, Sanya
Phosphate ester 8 parts, cross-linking radiation agent 5 parts, nano-sized magnesium hydroxide 4.5 parts, nano silicon
4 parts, inorganic silver ion silicate 8 parts, anti-4 parts of wear-resisting powder；Vinyl three (β-
Methoxy ethoxy) 2 parts of silane, lubricant 4 parts, calcium oxide 2 parts, magnesium oxide 2 parts.
The anti-rotten flame retardant type CABLE MATERIALS of 2 one kinds of mildew-resistant of embodiment, each raw material is as follows:
Each raw material is as follows: ETFE ETFE 100 parts, ethylene-propylene-diene monomer 15
Part, bentonite 15 parts, triphosphite ester 5 parts, cross-linking radiation agent 3 parts, nanometer hydroxide
4 parts of magnesium, nano silicon 3 parts, inorganic silver ion silicate 6 parts, anti-wear-resisting powder
3 parts；1 part of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 0.5 part, oxygen
Change calcium 1 part, magnesium oxide 1 part.
The anti-rotten flame retardant type CABLE MATERIALS of 3 one kinds of mildew-resistant of embodiment, each raw material is as follows:
Each raw material is as follows: ETFE ETFE 120 parts, ethylene-propylene-diene monomer 25
Part, bentonite 25 parts, triphosphite ester 10 parts, cross-linking radiation agent 8 parts, nanometer hydroxide
5 parts of magnesium, nano silicon 5 parts, inorganic silver ion silicate 9 parts, anti-wear-resisting powder
5 parts；3 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 5 parts, oxidation
Calcium 3 parts, magnesium oxide 3 parts.
A kind of preparation method of environment-friendly light Aviation cable material, (1) ETFE ETFE,
Ethylene-propylene-diene monomer, bentonite, triphosphite ester and nano-sized magnesium hydroxide, nano silicon,
Inorganic silver ion silicate, anti-wear-resisting powder, vinyl three ('beta '-methoxy ethyoxyl)
Silane, lubricant, calcium oxide, magnesium oxide mix according to the above ratio, in high-speed mixer all
Take out after even mixing 12min；
(2) by the raw material of mix homogeneously melt blending in double screw extruder, and extruding pelletization；
Melt extrude temperature at 250 DEG C-280 DEG C；
(3) it is placed again into twin-screw extrusion after being dried by semi-finished product good to melt blending pelletize
Machine, adds a certain proportion of cross-linking agent and carries out blending temperature 250 DEG C-20 DEG C, after extruding pelletization
Drying, sealing is kept in Dark Place.
The cable performance test of the present invention is as follows:
Impact brittle temperature :-50 DEG C, hot strength, 15.8MPa, elongation at break >=330
%, corrosion resistance: 20 DEG C × 50h of sea water, elongation at break conservation rate 65.0%, tension are strong
Degree conservation rate 82.5%.
The embodiment of the present invention makes the physical property of India-rubber wire
The ultimate principle of the present invention, principal character and the present invention excellent has more than been shown and described
Point.Skilled person will appreciate that of the industry, the present invention is not restricted to the described embodiments, on
State the principle that the present invention is simply described described in embodiment and description, without departing from the present invention
On the premise of spirit and scope, the present invention also has various changes and modifications, and these change and change
Enter to both fall within scope of the claimed invention.Claimed scope is by appended power
Profit claim and equivalent thereof define.
Claims (5)
1. the anti-rotten flame retardant type CABLE MATERIALS of mildew-resistant, it is characterised in that each raw material is with weight portion
Count as follows: ETFE ETFE 100-120 part, ethylene-propylene-diene monomer 15～25 parts, swollen
15～25 parts of profit soil, triphosphite ester 5～10 parts, cross-linking radiation agent 3～8 parts, nanometer
Magnesium hydroxide 4～5 parts, nano silicon 3～5 parts, inorganic silver ion silicate 6～
9 parts, anti-wear-resisting powder 3～5 parts；Vinyl three ('beta '-methoxy ethyoxyl) silane 1～3
Part, lubricant 0.5～5 parts, calcium oxide 1～3 parts, magnesium oxide 1～3 parts.
The anti-rotten flame retardant type CABLE MATERIALS of mildew-resistant the most according to claim 1, it is characterised in that
Each raw material is as follows: ETFE ETFE 110 parts, ethylene-propylene-diene monomer 20
Part, bentonite 20 parts, triphosphite ester 8 parts, cross-linking radiation agent 5 parts, nanometer hydroxide
4.5 parts of magnesium, nano silicon 4 parts, inorganic silver ion silicate 8 parts, anti-abrasion-resistant powder
Agent 4 parts；2 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 4 parts, oxygen
Change calcium 2 parts, magnesium oxide 2 parts.
The anti-rotten flame retardant type CABLE MATERIALS of mildew-resistant the most according to claim 1, it is characterised in that
Each raw material is as follows: ETFE ETFE 100 parts, ethylene-propylene-diene monomer 15
Part, bentonite 15 parts, triphosphite ester 5 parts, cross-linking radiation agent 3 parts, nanometer hydroxide
4 parts of magnesium, nano silicon 3 parts, inorganic silver ion silicate 6 parts, anti-wear-resisting powder
3 parts；1 part of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 0.5 part, oxygen
Change calcium 1 part, magnesium oxide 1 part.
The anti-rotten flame retardant type CABLE MATERIALS of mildew-resistant the most according to claim 1, it is characterised in that
Each raw material is as follows: ETFE ETFE 120 parts, ethylene-propylene-diene monomer 25
Part, bentonite 25 parts, triphosphite ester 10 parts, cross-linking radiation agent 8 parts, nanometer hydroxide
5 parts of magnesium, nano silicon 5 parts, inorganic silver ion silicate 9 parts, anti-wear-resisting powder
5 parts；3 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant 5 parts, oxidation
Calcium 3 parts, magnesium oxide 3 parts.
The preparation method of a kind of environment-friendly light Aviation cable material the most according to claim 1,
It is characterized in that, (1) ETFE ETFE, ethylene-propylene-diene monomer, bentonite, three
Phosphite ester and nano-sized magnesium hydroxide, nano silicon, inorganic silver ion silicate, anti-
Wear-resisting powder, vinyl three ('beta '-methoxy ethyoxyl) silane, lubricant, calcium oxide,
Magnesium oxide mixes according to the above ratio, takes out after uniformly mixing 12min in high-speed mixer；
(2) by the raw material of mix homogeneously melt blending in double screw extruder, and extruding pelletization；
Melt extrude temperature at 250 DEG C-280 DEG C；
(3) it is placed again into twin-screw extrusion after being dried by semi-finished product good to melt blending pelletize
Machine, adds a certain proportion of cross-linking agent and carries out blending temperature 250 DEG C-20 DEG C, after extruding pelletization
Drying, sealing is kept in Dark Place.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410800.XA CN105885200A (en) | 2016-06-12 | 2016-06-12 | Mildew-proof anti-corrosion flame-retardant cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410800.XA CN105885200A (en) | 2016-06-12 | 2016-06-12 | Mildew-proof anti-corrosion flame-retardant cable material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN105885200A true CN105885200A (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610410800.XA Pending CN105885200A (en) | 2016-06-12 | 2016-06-12 | Mildew-proof anti-corrosion flame-retardant cable material and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164878A (en) * | 2018-01-05 | 2018-06-15 | 浙江工业大学之江学院 | A kind of anticorrosion antiwear fire-resistant cable material |
| CN110982163A (en) * | 2019-12-12 | 2020-04-10 | 上海矿山电缆制造有限公司 | Wear-resistant cable and preparation method thereof |
| CN115572476A (en) * | 2022-10-10 | 2023-01-06 | 孙明亮 | Antibacterial flame-retardant water-resistant polyurethane elastomer and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104245826A (en) * | 2012-03-26 | 2014-12-24 | 旭硝子株式会社 | Fluorine-containing elastomer composition, method for producing same, molded body, crosslinked product, and covered wire |
| CN104672628A (en) * | 2015-03-12 | 2015-06-03 | 安徽特种电缆集团有限公司 | Radiation-resistant cable insulation material for nuclear power plant |
| CN104829937A (en) * | 2015-04-23 | 2015-08-12 | 苏州圣利线缆有限公司 | Sheath material for aerospace cables and manufacturing method thereof |
-
2016
- 2016-06-12 CN CN201610410800.XA patent/CN105885200A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104245826A (en) * | 2012-03-26 | 2014-12-24 | 旭硝子株式会社 | Fluorine-containing elastomer composition, method for producing same, molded body, crosslinked product, and covered wire |
| CN104672628A (en) * | 2015-03-12 | 2015-06-03 | 安徽特种电缆集团有限公司 | Radiation-resistant cable insulation material for nuclear power plant |
| CN104829937A (en) * | 2015-04-23 | 2015-08-12 | 苏州圣利线缆有限公司 | Sheath material for aerospace cables and manufacturing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164878A (en) * | 2018-01-05 | 2018-06-15 | 浙江工业大学之江学院 | A kind of anticorrosion antiwear fire-resistant cable material |
| CN110982163A (en) * | 2019-12-12 | 2020-04-10 | 上海矿山电缆制造有限公司 | Wear-resistant cable and preparation method thereof |
| CN115572476A (en) * | 2022-10-10 | 2023-01-06 | 孙明亮 | Antibacterial flame-retardant water-resistant polyurethane elastomer and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20160824 |