CN105885199A - Fire-proof composite flame-retardant cable material - Google Patents
Fire-proof composite flame-retardant cable material Download PDFInfo
- Publication number
- CN105885199A CN105885199A CN201610407035.6A CN201610407035A CN105885199A CN 105885199 A CN105885199 A CN 105885199A CN 201610407035 A CN201610407035 A CN 201610407035A CN 105885199 A CN105885199 A CN 105885199A
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- Prior art keywords
- parts
- fire
- fame
- weight
- resistant composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Abstract
The invention discloses a fire-proof composite flame-retardant cable material. The material is prepared from, by weight, 40-50 parts of EVA, 70-90 parts of aluminum hydroxide, 6-8 parts of red phosphorus, 40-50 parts of glass fibers, 40-80 parts of compound ceramic powder, 6-8 parts of a coupling agent and 4-8 parts of cosolvent. The material is quite good in flexibility and elasticity and excellent in moisture resistance and water absorption resistance, a ceramic-state substance obtained after combustion is a hard and uniform cellular shell, a continuous glass ceramic layer film is obtained at the high temperature through the compound ceramic powder, thus an object can have excellent electric insulation performance, thermal insulation performance, fire insulation performance and flame resistance and meanwhile can bear impact and vibration, and water permeation is prevented.
Description
Technical field
The present invention relates to technical field of cable production, particularly belong to a kind of fire-resistant composite fire resistance cable
Material.
Background technology
Existing domestic and international fire-resisting cable mainly has magnesium oxide mineral insulated fireproof cable and mica tape
The fire-resisting cable of wrapped inorganic insulation.Though mineral insulated cable has good fire resistance
Can, but its manufacturing process is complicated, production cost is high, factory length is limited, and cable is non-
Often firmly cannot bend, joint is complicated, and difficulty of construction is the highest, it is difficult to extensively apply.Mica tape around
Although bag fire-resisting cable work technique is simple, factory length is unrestricted, but mica tape is generally deposited
A shortcoming, after high-temp combustion, the mechanical strength of mica tape is greatly lowered, and becomes fragile, and is subject to
After strenuous vibration, easy powder of detached, causes fire-resistant poor effect.And because of easy when mica tape rubs
Dry linting, causes a large amount of dust in wrapped scene to bring threat to the health of operating personnel.Have in recent years
Scientific research personnel's exploratory development ceramic silicon rubber insulating flame-resistant cable, but because of in cable making process
Need to have special mixing, extrude and vulcanizing equipment, complex process, and be difficult at insulating barrier strong
Obtaining balance between degree and fire resistance, ceramic degree is difficult to be tried by the resistance to extreme misery of fire-resisting cable
Test.
Summary of the invention
For the problems referred to above, it is an object of the invention to provide a kind of fire-resistant composite fire resistance cable material
Material, has good flexibility and elasticity, and the moisture resistance of excellence and water absorption resistance, burning
After the material of ceramic-like be hard, uniform cellular housing, utilize composite ceramic
At high temperature, form continuous print glass ceramics tunic, such object have excellent insulating properties,
Thermal insulation, fire insulation fire resistance, can also withstand shocks and shake simultaneously, and prevent oozing of water
Enter.
The technical solution used in the present invention is as follows:
A kind of fire-resistant Composite Fame-retardant Material, described material is by following raw materials by weight portion
Proportioning forms, EVA40-50 part, aluminium hydroxide 70-90 part, red phosphorus 6-8 part, glass fibers
Tie up 40～50 parts, composite ceramic 40～80 parts, coupling agent 6-8 part, cosolvent 4～8
Part.
Described material is made up of following raw materials by weight portion proportioning, EVA50 part, hydroxide
90 parts of aluminum, 8 parts of red phosphorus, glass fibre 50 parts, composite ceramic 80 parts, coupling agent 8
Part, cosolvent 8 parts.
Described material is made up of following raw materials by weight portion proportioning, EVA40 part, hydroxide
70 parts of aluminum, red phosphorus 6-8 part, glass fibre 40 parts, composite ceramic 40 parts, coupling agent
6 parts, cosolvent 4 parts.
Also include following weight parts raw material: anti-termite agent 1-3 part.
Described anti-termite agent, is made up of by weight following component: avilamycin 70-90 part,
Asarinin 5-15 part and Dihydrocapsaicin 5-15 part.
Described coupling agent is made up of the raw material of following parts by weight: vinyltriacetylsilane
1～2 part, butadienyl triethoxysilane 6～8 parts, vinyl silicone oil 0.3～0.4 part,
Diluent 3～5 parts, activating agent 0.05～0.08 part.
Described composite ceramic includes pottery idiosome material and ceramic glaze body material.
Described pottery idiosome material is counted by weight and is included: silica 1 00 part, boron oxide
35 parts, zirconium oxide 25 parts, aluminium oxide 15 parts, strontium oxide 3 parts.
Compared with the prior art, beneficial effects of the present invention is as follows:
The present invention has good flexibility and elasticity, and the moisture resistance of excellence and anti-water suction
Property, the material of the ceramic-like after burning is hard, uniform cellular housing, utilizes multiple
Closing ceramics at high temperature, form continuous print glass ceramics tunic, such object has excellent
Insulating properties, thermal insulation, fire insulation fire resistance, can also withstand shocks and shake simultaneously, and
Prevent the infiltration of water.
Detailed description of the invention
Embodiment 1, a kind of fire-resistant Composite Fame-retardant Material, described material is by as follows
Raw materials by weight portion proportioning forms, and described material is by following raw materials by weight portion proportioning
Composition, EVA50 part, aluminium hydroxide 90 parts, 8 parts of red phosphorus, glass fibre 50 parts, compound
Ceramics 80 parts, coupling agent 8 parts, cosolvent 8 parts, anti-termite agent 3 parts；Described anti-white
Ant agent, is made up of by weight following component: avilamycin 70-90 part, asarinin 5-15
Part and Dihydrocapsaicin 5-15 part；Described coupling agent is by the raw material system of following parts by weight
Become: vinyltriacetylsilane 1～2 parts, butadienyl triethoxysilane 6～8 parts,
Vinyl silicone oil 0.3～0.4 part, diluent 3～5 parts, activating agent 0.05～0.08 part；Institute
The composite ceramic stated includes pottery idiosome material and ceramic glaze body material；Described pottery idiosome material
By weight meter include: silica 1 00 part, boron oxide 35 parts, zirconium oxide 25 parts,
Aluminium oxide 15 parts, strontium oxide 3 parts.
Embodiment 2, a kind of fire-resistant Composite Fame-retardant Material, described material is by as follows
Raw materials by weight portion proportioning forms, and described material is by following raw materials by weight portion proportioning
Composition, described material is made up of following raw materials by weight portion proportioning, and described material is by such as
Lower raw materials by weight portion proportioning forms, EVA40 part, aluminium hydroxide 70 parts, red phosphorus 6-8
Part, glass fibre 40 parts, composite ceramic 40 parts, coupling agent 6 parts, cosolvent 4 parts,
Anti-termite agent 1 part；Described anti-termite agent, is made up of by weight following component: avilamycin
70-90 part, asarinin 5-15 part and Dihydrocapsaicin 5-15 part；Described coupling agent by
The raw material of following parts by weight is made: vinyltriacetylsilane 1～2 parts, butadienyl
Triethoxysilane 6～8 parts, vinyl silicone oil 0.3～0.4 part, diluent 3～5 parts,
Activating agent 0.05～0.08 part；Described composite ceramic includes pottery idiosome material and ceramic glaze
Body material；Described pottery idiosome material is counted by weight and is included: silica 1 00 part, oxygen
Change boron 35 parts, zirconium oxide 25 parts, aluminium oxide 15 parts, strontium oxide 3 parts.
Embodiment 3, a kind of fire-resistant Composite Fame-retardant Material, described material is by following raw material
Proportioning composition by weight, described material is made up of following raw materials by weight portion proportioning,
EVA45 part, aluminium hydroxide 80 parts, 7 parts of red phosphorus, glass fibre 45 parts, composite ceramic
60 parts, coupling agent 7 parts, cosolvent 6 parts, anti-termite agent 2 parts；Described anti-termite agent,
Be made up of by weight following component: avilamycin 70-90 part, asarinin 5-15 part and
Dihydrocapsaicin 5-15 part；Described coupling agent is made up of the raw material of following parts by weight: second
Thiazolinyl triacetyl silane 1～2 parts, butadienyl triethoxysilane 6～8 parts, vinyl
Silicone oil 0.3～0.4 part, diluent 3～5 parts, activating agent 0.05～0.08 part；Described answers
Close ceramics and include pottery idiosome material and ceramic glaze body material；Described pottery idiosome material is by weight
Number meter includes: silica 1 00 part, boron oxide 35 parts, zirconium oxide 25 parts, aluminium oxide
15 parts, strontium oxide 3 parts.
The physical property of embodiment of the present invention 1.5mm2 India-rubber wire
The present invention has good flexibility and elasticity, and the moisture resistance of excellence and anti-water suction
Property, the material of the ceramic-like after burning is hard, uniform cellular housing, utilizes multiple
Closing ceramics at high temperature, form continuous print glass ceramics tunic, such object has excellent
Insulating properties, thermal insulation, fire insulation fire resistance, can also withstand shocks and shake simultaneously, and
Prevent the infiltration of water.
The ultimate principle of the present invention, principal character and the present invention excellent has more than been shown and described
Point.Skilled person will appreciate that of the industry, the present invention is not restricted to the described embodiments, on
State the principle that the present invention is simply described described in embodiment and description, without departing from the present invention
On the premise of spirit and scope, the present invention also has various changes and modifications, and these change and change
Enter to both fall within scope of the claimed invention.Claimed scope is by appended power
Profit claim and equivalent thereof define.
Claims (8)
1. a fire-resistant Composite Fame-retardant Material, it is characterised in that: described material is by such as
Lower raw materials by weight portion proportioning forms, EVA40-50 part, aluminium hydroxide 70-90 part, red
Phosphorus 6-8 part, glass fibre 40～50 parts, composite ceramic 40～80 parts, coupling agent 6-8
Part, cosolvent 4～8 parts.
Fire-resistant Composite Fame-retardant Material the most according to claim 1, it is characterised in that:
Described material is made up of following raw materials by weight portion proportioning, EVA50 part, aluminium hydroxide 90
Part, 8 parts of red phosphorus, glass fibre 50 parts, composite ceramic 80 parts, coupling agent 8 parts, help
Solvent 8 parts.
Fire-resistant Composite Fame-retardant Material the most according to claim 1, it is characterised in that:
Described material is made up of following raw materials by weight portion proportioning, EVA40 part, aluminium hydroxide 70
Part, red phosphorus 6-8 part, glass fibre 40 parts, composite ceramic 40 parts, coupling agent 6 parts,
Cosolvent 4 parts.
Fire-resistant Composite Fame-retardant Material the most according to claim 1, it is characterised in that:
Also include following weight parts raw material: anti-termite agent 1-3 part.
Fire-resistant Composite Fame-retardant Material the most according to claim 4, it is characterised in that:
Described anti-termite agent, is made up of by weight following component: avilamycin 70-90 part, Herba Asari
Fat element 5-15 part and Dihydrocapsaicin 5-15 part.
Fire-resistant Composite Fame-retardant Material the most according to claim 1, it is characterised in that:
Described coupling agent is made up of the raw material of following parts by weight: vinyltriacetylsilane 1～
2 parts, butadienyl triethoxysilane 6～8 parts, vinyl silicone oil 0.3～0.4 part, dilute
Release agent 3～5 parts, activating agent 0.05～0.08 part.
Fire-resistant Composite Fame-retardant Material the most according to claim 1, it is characterised in that:
Described composite ceramic includes pottery idiosome material and ceramic glaze body material.
Fire-resistant Composite Fame-retardant Material the most according to claim 7, it is characterised in that:
Described pottery idiosome material is counted by weight and is included: silica 1 00 part, boron oxide 35
Part, zirconium oxide 25 parts, aluminium oxide 15 parts, strontium oxide 3 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610407035.6A CN105885199A (en) | 2016-06-12 | 2016-06-12 | Fire-proof composite flame-retardant cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610407035.6A CN105885199A (en) | 2016-06-12 | 2016-06-12 | Fire-proof composite flame-retardant cable material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105885199A true CN105885199A (en) | 2016-08-24 |
Family
ID=56729985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610407035.6A Pending CN105885199A (en) | 2016-06-12 | 2016-06-12 | Fire-proof composite flame-retardant cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105885199A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108417309A (en) * | 2018-05-04 | 2018-08-17 | 上海汉欣电线电缆有限公司 | Ceramic fire resistant band and preparation method thereof |
| CN109535606A (en) * | 2018-12-05 | 2019-03-29 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-retardant plastic-steel wallboard and preparation method thereof |
| CN109553886A (en) * | 2018-11-29 | 2019-04-02 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC foamed wallboard and preparation method thereof |
| CN109553887A (en) * | 2018-11-29 | 2019-04-02 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC floor and preparation method thereof |
| CN109575474A (en) * | 2018-11-29 | 2019-04-05 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC Plastic steel tile and preparation method thereof |
| CN111849057A (en) * | 2020-06-30 | 2020-10-30 | 浙江太湖远大新材料股份有限公司 | B1-grade low-smoke halogen-free insulating material and preparation method thereof |
| CN114171247A (en) * | 2021-12-09 | 2022-03-11 | 安庆横电电缆有限公司 | Ceramic polyolefin insulation high-flame-retardant fireproof cable and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101404189A (en) * | 2008-11-25 | 2009-04-08 | 南京工业大学 | Fast ceramic flame-resistant cable and its production method |
| CN104341676A (en) * | 2014-11-03 | 2015-02-11 | 安徽天元电缆有限公司 | Novel low-smoke zero halogen flame-retardant cable material |
| CN105367965A (en) * | 2015-11-30 | 2016-03-02 | 中广核三角洲（苏州）高聚物有限公司 | Halogen-free flame-retardant ceramic polyolefin cable material for fire-resisting cables and preparation method for halogen-free flame-retardant ceramic polyolefin cable material |
-
2016
- 2016-06-12 CN CN201610407035.6A patent/CN105885199A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101404189A (en) * | 2008-11-25 | 2009-04-08 | 南京工业大学 | Fast ceramic flame-resistant cable and its production method |
| CN104341676A (en) * | 2014-11-03 | 2015-02-11 | 安徽天元电缆有限公司 | Novel low-smoke zero halogen flame-retardant cable material |
| CN105367965A (en) * | 2015-11-30 | 2016-03-02 | 中广核三角洲（苏州）高聚物有限公司 | Halogen-free flame-retardant ceramic polyolefin cable material for fire-resisting cables and preparation method for halogen-free flame-retardant ceramic polyolefin cable material |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108417309A (en) * | 2018-05-04 | 2018-08-17 | 上海汉欣电线电缆有限公司 | Ceramic fire resistant band and preparation method thereof |
| CN109553886A (en) * | 2018-11-29 | 2019-04-02 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC foamed wallboard and preparation method thereof |
| CN109553887A (en) * | 2018-11-29 | 2019-04-02 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC floor and preparation method thereof |
| CN109575474A (en) * | 2018-11-29 | 2019-04-05 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-proof PVC Plastic steel tile and preparation method thereof |
| CN109535606A (en) * | 2018-12-05 | 2019-03-29 | 广讯检测（广东）有限公司 | A kind of imitative glaze flame-retardant plastic-steel wallboard and preparation method thereof |
| CN111849057A (en) * | 2020-06-30 | 2020-10-30 | 浙江太湖远大新材料股份有限公司 | B1-grade low-smoke halogen-free insulating material and preparation method thereof |
| CN114171247A (en) * | 2021-12-09 | 2022-03-11 | 安庆横电电缆有限公司 | Ceramic polyolefin insulation high-flame-retardant fireproof cable and preparation process thereof |
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| PB01 | Publication | ||
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Application publication date: 20160824 |