CN105884302A - Fast-curing, waterproof and leakage-preventing material capable of being constructed under low temperature condition - Google Patents

Fast-curing, waterproof and leakage-preventing material capable of being constructed under low temperature condition Download PDF

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Publication number
CN105884302A
CN105884302A CN201610231241.6A CN201610231241A CN105884302A CN 105884302 A CN105884302 A CN 105884302A CN 201610231241 A CN201610231241 A CN 201610231241A CN 105884302 A CN105884302 A CN 105884302A
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Prior art keywords
parts
leakage
rapid curing
cryogenic conditions
under cryogenic
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CN201610231241.6A
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Chinese (zh)
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CN105884302B (en
Inventor
邵杰
刘文会
沈恒
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XUZHOU WONIUSHAN NEW WATERPROOF MATERIAL CO Ltd
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XUZHOU WONIUSHAN NEW WATERPROOF MATERIAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Sealing Material Composition (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A fast-curing, waterproof and leakage-preventing material capable of being constructed under the low temperature condition is prepared from raw materials in parts by weight as follows: 45-68 parts of fast-hardening cement, 18-42 parts of aggregate, 0.5-1 part of a dispersing agent, 0.3-1.5 parts of a toughening agent, 0.5-1.2 parts of an adhesion promoter, 2-7 parts of a special additive, 0.5-2.3 parts of a coagulant and 0.6-2.2 parts of a fortifier. The fast-curing, waterproof and leakage-preventing material is cured fast within 10 min at 0 DEG C or below in winter and has functions of resisting cracking as well as high and low temperatures.

Description

A kind of can the rapid curing water-proof plugging material of construction under cryogenic conditions
Technical field
The present invention relates to a kind of inorganic rigid water-proof plugging material, being specifically related to one can low temperature bar The rapid curing water-proof plugging material of construction under part.
Background technology
At present, inorganic leak-stopping material is mainly by quick-hardening cement, aggregate, water reducer, fiber The materials such as element ether, uniform by physical mixed, packed products.Existing product meets GB 23440-2009 inorganic leak-stopping material standard, in the case of standard 20 ± 5 DEG C, initial set Time≤5min, final setting time≤10min.But, when temperature is 0 DEG C in the winter time, final set Time is much larger than 10min, does not has the effect of fast blockage in practice of construction operates.This is Owing to, in the case of 20 ± 5 DEG C, the quick-hardening cement in inorganic leak-stopping material is at coagulant Effect issues raw hydration reaction, and during reaction, quick-hardening cement liberated heat further accelerates instead Should.But in the winter time in the case of 0 DEG C or lower temperature, during reaction, liberated heat is in low temperature Do not have the effect further speeding up reaction.Therefore, in the winter time 0 DEG C time or lower temperature under time, Existing inorganic leak-stopping material cannot realize the effect of fast blockage, generally requires wait several The time of individual hour just can play leak stopping or carry out next process operation.
Such as, prior art CN97111334.3 discloses a kind of waterproof material of high-efficiency multi-function Material;CN201310244735.4 discloses a kind of leakage-blocking water-proof paint;CN97112505.8 Disclosing coating capable of waterproof, seepage control and leakproof, the above-mentioned winter low temperature that all exists is difficult to quick-setting lacking Fall into.
Summary of the invention
The technical problem to be solved be to provide a kind of can construction fast under cryogenic conditions Speed solidification water-proof plugging material, efficiently solves and solves winter low temperature leak stopping length hardening time A difficult problem.
The present invention solves its technical problem and employed technical scheme comprise that, one can be executed under cryogenic conditions The rapid curing loss circulation material of work, is made up of the raw material of following parts by weight, quick-hardening cement 45~ 68 parts, aggregate 18~42 parts, dispersant 0.5~1 part, toughener 0.3~1.5 parts, attached Adhesion promoter 0.5~1.2 parts, special auxiliary agent 2~7 parts, coagulant 0.5~2.3 parts, Reinforcing agent 0.6~2.2 parts.
Further, described quick-hardening cement is sulphate aluminium cement, lumnite cement and high alumina One or more mixture in cement.
Further, described aggregate is silica flour, talcum powder, wollastonite in powder, titanium dioxide, vertical moral One or more mixture in powder, potter's clay, white carbon and calcium carbonate.
Further, described dispersant is calgon.
Further, described toughener is polypropylene fibre or/and lignocellulosic.
Further, described adhesion promoter is re-dispersible glue powder, polyvinyl alcohol, hydroxypropyl One or more mixing in methylcellulose, ethyl cellulose and methylcellulose Thing.
Further, described re-dispersible glue powder be redispersible vinyl acetate/ethylene/copolymer, Vinyl acetate/versatic acid ethylene copolymer or acrylic copolymer.
Further, the one during described special auxiliary agent is calcium oxide, potassium oxide and sodium oxide molybdena or two The mixture planted.
Further, one or both during described coagulant is lithium chloride, lithium carbonate and lithium sulfate Mixture.
Further, described reinforcing agent is calcium chloride.
When mixing with water, exothermic reaction is there is rapidly in the present invention by special auxiliary agent, thus one Aspect is supplied to the reaction heat required for quick-hardening cement hydration reaction, accelerates the anti-of quick-hardening cement Should, it is achieved rapid curing when 0 DEG C or under lower temperature.Such as,
CaO+H2O=Ca (OH)2Release substantial amounts of heat
K2O+H2O=2KOH releases substantial amounts of heat
Na2O+H2O=2NaOH releases substantial amounts of heat
On the other hand the dispersant in formula, coagulant, reinforcing agent and adhesion promoter synergy, Improve low-temperature fast-curing physical property, solve and cement individually adds special auxiliary agent water The Ca (OH) produced when closing reaction2, the change of physical property that causes of KOH or NaOH, such as, The problem of anti-folding and anti-pressing performance degradation.
It is demonstrated experimentally that rigid waterproofing loss circulation material of the present invention is winter 0 DEG C or less than 0 DEG C 10 points Can be with rapid construction within clock, rapid curing is the strongest;There is cracking resistance, high-low temperature resistant simultaneously Function.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is illustrated further.
Embodiment 1
1, raw material composition:
Lumnite cement (sky, Shijiazhuang grand penguin board 52.5 quick-hardening cement) 48
Silica flour (Lingshou County luxuriant mining industry Co., Ltd 200 mesh) 42
Calgon (river, ShenFang,SiChuan city letter phosphorous chemical industry) 0.8
Lignocellulosic (Germany is auspicious steps on Mel ARBOC EL) 1.0
Polyvinyl alcohol (Changchun, Taiwan BP-24) 0.5
Redispersible rubber powder (Germany watt gram 5010N) 0.7
Calcium oxide (upper marine space metallurgy active calcium oxide) 5
Lithium chloride (upper marine lithium group technical grade lithium chloride) 0.6
Calcium chloride (sea, Shandong chemical industry level) 1.4
2, the preparation of rapid curing loss circulation material: by above-mentioned lumnite cement, silica flour, six Sodium metaphosphate, lignocellulosic, polyvinyl alcohol, redispersible rubber powder, calcium oxide, chlorination Lithium, calcium chloride precise, put in agravic mixing kettle successively, mixes 15~20 minutes, Mix, pack discharging.
Embodiment 2
1, raw material composition:
Sulphate aluminium cement (Zibo cloud crane 52.5 quick-hardening cement) 59
Wollastonite in powder (Jiangsu ceramic research 325 mesh) 15
Silica flour (Lingshou County luxuriant mining industry Co., Ltd 200 mesh) 16
Calgon (river, ShenFang,SiChuan city letter phosphorous chemical industry) 0.4
Polypropylene fibre (Shijiazhuang Fen De cellulose Co., Ltd 3mm polypropylene fibre) 1.0
Polyvinyl alcohol (Changchun, Taiwan BP-24) 0.5
Redispersible rubber powder (Germany watt gram 5010N) 0.5
Calcium oxide (upper marine space metallurgy active calcium oxide) 5.5
Lithium sulfate (upper marine lithium group technical grade lithium sulfate) 0.6
Calcium chloride (sea, Shandong chemical industry level) 1.5
2, the preparation of rapid curing loss circulation material: by above-mentioned fast sulphate aluminium cement, wollastonite in powder, Silica flour, calgon, polypropylene fibre, polyvinyl alcohol, redispersible rubber powder, oxygen Change calcium, lithium sulfate, calcium chloride precise, put in agravic mixing kettle successively, mixing 15~20 minutes, mix, pack discharging.
Embodiment 3
1, raw material composition:
Sulphate aluminium cement (Zibo cloud crane 52.5 quick-hardening cement) 68
Silica flour (Lingshou County luxuriant mining industry Co., Ltd 200 mesh) 18
Calgon (river, ShenFang,SiChuan city letter phosphorous chemical industry) 0.6
Lignocellulosic (Germany is auspicious steps on Mel ARBOCEL) 1.0
Polypropylene fibre (Shijiazhuang Fen De cellulose Co., Ltd 3mm polypropylene fibre) 0.2
Polyvinyl alcohol (Changchun, Taiwan BP-24) 0.7
Redispersible rubber powder (Germany watt gram 5010N) 0.5
Calcium oxide (upper marine space metallurgy active calcium oxide) 5
Sodium oxide molybdena 2
Lithium chloride 2.3
Calcium chloride 1.7
2, the preparation of rapid curing loss circulation material: by above-mentioned sulphate aluminium cement, silica flour, six inclined Sodium phosphate, lignocellulosic, polypropylene fibre, polyvinyl alcohol, redispersible rubber powder, oxygen Change calcium, sodium oxide molybdena, lithium chloride, calcium chloride precise, put in agravic mixing kettle successively, Mix 15-20 minute, mix, pack discharging.
Comparative example 4
1, raw material composition:
Sulphate aluminium cement 68
Silica flour 25
Calgon 0.6
Lignocellulosic 1.0
Polypropylene fibre 0.2
Polyvinyl alcohol 0.7
Redispersible rubber powder 0.5
Lithium chloride 2.3
Calcium chloride 1.7
2, the preparation of rapid curing loss circulation material: by above-mentioned sulphate aluminium cement, silica flour, six inclined Sodium phosphate, lignocellulosic, polypropylene fibre, polyvinyl alcohol, redispersible rubber powder, chlorine Change lithium, calcium chloride precise, put in agravic mixing kettle successively, mix 15~20 points Clock, mixes, and packs discharging.
Testing standard and the method for embodiment 1~4 product are inorganic anti-according to GB 23440-2009 Water blocking leakage material standard.
Experimental condition is: temperature 0 DEG C, and relative humidity is (50 ± 5) %;Curing condition is temperature Spending 0 DEG C, relative humidity is more than 90%.
Compression strength and rupture strength are according to GB 23440-2009 inorganic leak-stopping material mark Accurate 6.4 tests.
Test specimen impermeability pressure is according to GB 23440-2009 inorganic leak-stopping material standard 6.5.2 Test.
Adhesive strength is tested according to GB 23440-2009 inorganic leak-stopping material standard 6.6. Heat resistance and Frozen-thawed cycled are respectively according to GB 23440-2009 inorganic leak-stopping material standard 6.7 and 6.8 tests.
The performance test results of embodiment 1~4 product is shown in Table 1.
The performance test results of table 1-embodiment 1~4 product
As shown in Table 1, the quick when product of embodiment 1~3 preparation not only achieves 0 DEG C Solidification, performance indications also meet GB 23440-2009 inorganic leak-stopping material standard simultaneously Requirement;And the product anti-folding and anti-pressing of 1 hour of comparison example 4 preparation, adhesive strength, examination Part impermeability pressure and Frozen-thawed cycled are the most defective.

Claims (9)

1. one kind can the rapid curing water-proof plugging material of construction under cryogenic conditions, it is characterised in that It is made up of the raw material of following parts by weight, quick-hardening cement 45~68 parts, aggregate 18~42 parts, Dispersant 0.5~1 part, toughener 0.3~1.5 parts, adhesion promoter 0.5~1.2 parts, Special auxiliary agent 2~7 parts, coagulant 0.5~2.3 parts, reinforcing agent 0.6~2.2 parts, wherein, Described special auxiliary agent is one or both the mixture in calcium oxide, potassium oxide and sodium oxide molybdena.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described quick-hardening cement be sulphate aluminium cement, lumnite cement and One or more mixture in alumina cement.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described aggregate be silica flour, talcum powder, wollastonite in powder, titanium dioxide, One or more mixture in lithopone, potter's clay, white carbon and calcium carbonate.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described dispersant is calgon.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described toughener is polypropylene fibre or/and lignocellulosic.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described adhesion promoter is re-dispersible glue powder, polyvinyl alcohol, hydroxyl One or more mixed in propyl methocel, ethyl cellulose and methylcellulose Compound.
The most according to claim 6 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described re-dispersible glue powder is that redispersible vinyl acetate/ethylene/is total to Polymers, vinyl acetate/versatic acid ethylene copolymer or acrylic copolymer.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described coagulant be the one in lithium chloride, lithium carbonate and lithium sulfate or The mixture of two kinds.
The most according to claim 1 can the rapid curing waterproofing and leakage-stopping material of construction under cryogenic conditions Material, it is characterised in that described reinforcing agent is calcium chloride.
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517969A (en) * 2016-11-14 2017-03-22 吴佳鹏 Rapid solidifying type water leakage plugging material and preparation method thereof
CN107188472A (en) * 2017-06-28 2017-09-22 李福发 A kind of novel permeation crystallization sealing agent and construction method
CN107216061A (en) * 2017-06-08 2017-09-29 徐州卧牛山新型防水材料有限公司 Reinforcement cracking resistance liquid that a kind of material for quickly stopping leakage is used and preparation method thereof
CN107352925A (en) * 2017-06-30 2017-11-17 苏州吉云新材料技术有限公司 A kind of high performance spherical silicon powder material for repairing
CN107663065A (en) * 2017-10-26 2018-02-06 北京中建瑞特防水建材有限公司 A kind of high-strength impervious mending-leakage material and preparation method thereof
CN108689661A (en) * 2018-06-20 2018-10-23 河南阳光防水科技有限公司 The special sealing agent of subway tunnel
CN108840623A (en) * 2018-06-20 2018-11-20 河南阳光防水科技有限公司 Nano-silicon instant leakage-blocking agent
CN109180085A (en) * 2018-10-26 2019-01-11 王志文 A kind of water-proofing powder
CN111560989A (en) * 2020-06-04 2020-08-21 深圳市维特耐新材料有限公司 Polypropylene non-woven water plugging bag with hydrophilicity and water permeability and water plugging method
CN111635202A (en) * 2020-06-19 2020-09-08 深圳市卓宝科技股份有限公司 Fast-hardening inorganic waterproof plugging material
CN112159174A (en) * 2020-09-27 2021-01-01 彭圳凡 Low-temperature fast-curing concrete and preparation method thereof
CN112174618A (en) * 2020-10-20 2021-01-05 陕西煤业化工技术研究院有限责任公司 Mining high-strength anti-shrinkage water plugging material and preparation method thereof
CN115557764A (en) * 2022-02-15 2023-01-03 上海牛元工贸有限公司 Waterproof enhanced inorganic plugging material and preparation method thereof

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CN1163919A (en) * 1997-02-04 1997-11-05 北京市海淀区东海防腐防水技术开发工程公司 Single component inorganic water-proofing agent
CN104291740A (en) * 2013-07-20 2015-01-21 吕孟龙 Waterproof alkali activated inorganic polymer coating
CN104944870A (en) * 2015-05-25 2015-09-30 孙庆军 Self-flowing based waterproof coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1163919A (en) * 1997-02-04 1997-11-05 北京市海淀区东海防腐防水技术开发工程公司 Single component inorganic water-proofing agent
CN104291740A (en) * 2013-07-20 2015-01-21 吕孟龙 Waterproof alkali activated inorganic polymer coating
CN104944870A (en) * 2015-05-25 2015-09-30 孙庆军 Self-flowing based waterproof coating

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517969B (en) * 2016-11-14 2019-05-28 吴佳鹏 Rapid-hardening water does not leak and preparation method thereof
CN106517969A (en) * 2016-11-14 2017-03-22 吴佳鹏 Rapid solidifying type water leakage plugging material and preparation method thereof
CN107216061A (en) * 2017-06-08 2017-09-29 徐州卧牛山新型防水材料有限公司 Reinforcement cracking resistance liquid that a kind of material for quickly stopping leakage is used and preparation method thereof
CN107188472A (en) * 2017-06-28 2017-09-22 李福发 A kind of novel permeation crystallization sealing agent and construction method
CN107352925A (en) * 2017-06-30 2017-11-17 苏州吉云新材料技术有限公司 A kind of high performance spherical silicon powder material for repairing
CN107663065A (en) * 2017-10-26 2018-02-06 北京中建瑞特防水建材有限公司 A kind of high-strength impervious mending-leakage material and preparation method thereof
CN108840623A (en) * 2018-06-20 2018-11-20 河南阳光防水科技有限公司 Nano-silicon instant leakage-blocking agent
CN108689661A (en) * 2018-06-20 2018-10-23 河南阳光防水科技有限公司 The special sealing agent of subway tunnel
CN109180085A (en) * 2018-10-26 2019-01-11 王志文 A kind of water-proofing powder
CN111560989A (en) * 2020-06-04 2020-08-21 深圳市维特耐新材料有限公司 Polypropylene non-woven water plugging bag with hydrophilicity and water permeability and water plugging method
CN111635202A (en) * 2020-06-19 2020-09-08 深圳市卓宝科技股份有限公司 Fast-hardening inorganic waterproof plugging material
CN112159174A (en) * 2020-09-27 2021-01-01 彭圳凡 Low-temperature fast-curing concrete and preparation method thereof
CN112174618A (en) * 2020-10-20 2021-01-05 陕西煤业化工技术研究院有限责任公司 Mining high-strength anti-shrinkage water plugging material and preparation method thereof
CN112174618B (en) * 2020-10-20 2022-05-31 陕西煤业化工技术研究院有限责任公司 Mining high-strength anti-shrinkage water plugging material and preparation method thereof
CN115557764A (en) * 2022-02-15 2023-01-03 上海牛元工贸有限公司 Waterproof enhanced inorganic plugging material and preparation method thereof
CN115557764B (en) * 2022-02-15 2023-09-22 上海牛元工贸有限公司 Waterproof enhanced inorganic plugging material and preparation method thereof

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