CN105884299A - High permeable crystalline type repair material for over-self-healing-scale cracked concrete and preparation method of repair material - Google Patents
High permeable crystalline type repair material for over-self-healing-scale cracked concrete and preparation method of repair material Download PDFInfo
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- CN105884299A CN105884299A CN201610226499.7A CN201610226499A CN105884299A CN 105884299 A CN105884299 A CN 105884299A CN 201610226499 A CN201610226499 A CN 201610226499A CN 105884299 A CN105884299 A CN 105884299A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/72—Repairing or restoring existing buildings or building materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention belongs to the technical field of concrete, and relates to a concrete crack repair material, in particular to a high permeable crystalline type repair material for over-self-healing-scale cracked concrete and a preparation method of the repair material. Raw materials of the repair material comprise solids and water, wherein the solids comprise ordinary Portland cement, quartz sand, flyash, silica fume, aluminate cement, gypsum, sodium hydroxide, water glass, redispersible latex powder, a polycarboxylate superplasticizer, sodium gluconate and polypropylene fibers. The repair material can produce small swelling after water addition and uniform stirring, contact with a concrete matrix can be guaranteed better, and further cracking due to external load can be prevented.
Description
Technical field
The invention belongs to technical field of concrete, relate to a kind of Concrete crack repair material, be specifically related to a kind of super self-healing
Yardstick cracked concrete Thief zone crystallization repair materials and preparation method thereof.
Background technology
Concrete belongs to fragile material, is easier brittle cracking, in it condenses hardening process, will become due to temperature
Changing or the reason such as drying shrinkage produces small crackle, when the later stage comes into operation, the small crackle of part in certain circumstances can
Heal voluntarily, but the lower extension of the effect of major part fine crack environment around becomes bigger crackle, exceedes spontaneous recovery
Closing the yardstick threshold value of probability, this kind of crack is referred to as super self-healing yardstick.The crack of super self-healing yardstick can be to concrete
Overall performance produces and destroys, and ultimately results in concrete works and cannot normally use.This is generally to exist in concrete works
Problem, is also the main cause affecting concrete durability.The deterioration damage that concrete structure crack causes is brought
Economic loss can carry out the description of image with " five times of laws ", i.e. in structured design process, often saves l for reinforcing bar protection beautiful
Unit, that means that: occur adopting remedial measures additional maintenance cost 5 dollars when steel bar corrosion damages;Concrete surface occurs
Adopt remedial measures additional maintenance cost 25 dollars when ftractureing along muscle;Adopt remedial measures during xoncrete structure heavy damage and will chase after
Add maintenance cost 125 dollars.By " five times of laws " it can be seen that cracking concrete is the most early carried out repair process, its maintenance
Expense is the lowest, therefore carries out intervening in time for concrete bracing, retrains its cracking yardstick, it is achieved repair target.
At present, the repair materials for distress in concrete is broadly divided into three kinds, is inorganic repair materials, organic reparation respectively
Material and Organic-inorganic composite repair materials.Inorganic repair materials is primarily referred to as cement based repair materials, and its range of application is the most
Extensively, technology also corresponding comparative maturity, but in application process, adhesive property is bad;Organic repair materials is to have certain
The Organic substance of reparation characteristic, as repairing host, is aided with the organic substances such as toughener, initiator and coupling agent and admixes together,
Making it have the effect repairing distress in concrete, compared with inorganic repair materials, it has a characteristic that adhesion strength is high, but greatly
Partial organic substances belongs to noxious substance, in use should avoid the injury to the person as far as possible;With inorganic material as matrix, auxiliary
With the Organic-inorganic composite repair materials of organic substance composition, the adhesive property of inorganic repair materials can be improved, the most organic
The good flexibility that material is had can give repair materials preferable mobility.
The Concrete crack repair material being had on market mostly completes crack by the hardening of repair materials self
Fill up reparation, it does not carry out the biggest improvement to concrete substrate, therefore, can enter one by admixture in repair materials
Step increases the material of matrix strength, can enter Binder Materials unhydrated in concrete while repair materials hardens
One step excites, and enables original concrete and repair materials preferably to combine together, just seems necessary.
Summary of the invention
It is an object of the invention to provide a kind of super self-healing yardstick cracked concrete Thief zone crystallization repair materials and preparation thereof
Method.
For achieving the above object, the present invention is by the following technical solutions:
A kind of super self-healing yardstick cracked concrete Thief zone crystallizes repair materials, raw materials used includes solid material and water, solid
Material mass percent consist of: Portland cement 30 ~ 45%, quartz sand 40 ~ 60%, flyash 3 ~ 15%, silicon ash 1 ~ 8%,
Aluminate cement 1 ~ 10%, Gypsum Fibrosum 1 ~ 10%, sodium hydroxide 0.1 ~ 4%, waterglass 0.1 ~ 4%, re-dispersible glue powder 0.1 ~ 2%, poly-carboxylic
Acid based water reducer 0.05 ~ 1.5%, sodium gluconate 0.01 ~ 1% and polypropylene fibre 0.1 ~ 2.5%.
Water is 0.17 ~ 0.2:1 with the mass ratio of solid material.
The mass percent of solid material consists of: Portland cement 30 ~ 45%, quartz sand 40 ~ 60%, flyash 3 ~
10%, silicon ash 2 ~ 6%, aluminate cement 1 ~ 4%, Gypsum Fibrosum 1 ~ 4%, sodium hydroxide 0.5 ~ 2%, waterglass 0.1 ~ 4%, re-dispersible glue powder
0.1 ~ 2%, poly carboxylic acid series water reducer 0.05 ~ 1.5%, sodium gluconate 0.01 ~ 1% and polypropylene fibre 0.1 ~ 2.5%.
Aluminate cement is 0.5 ~ 1.5:1 with the mass ratio of Gypsum Fibrosum;The mass ratio of waterglass and sodium hydroxide is 1.5 ~
2.5:1。
The strength grade of described Portland cement is 42.5 or 52.5, and Blain specific surface is 340 ~ 400m2/Kg;
Quartz sand fineness is 28 ~ 100 mesh;Modulus of water glass is 1.5 ~ 2.5.
Flyash rank is one-level and SiO2Content is not less than 55%;SiO in silicon ash2Content reaches more than 80%.
The water-reducing rate of poly carboxylic acid series water reducer is 30 ~ 40%;A diameter of 25 ~ 35 μm of polypropylene fibre, a length of 2 ~ 4mm.
The preparation method of super self-healing yardstick cracked concrete Thief zone crystallization repair materials, comprises the steps:
(1) each component is weighed in described ratio, standby;
(2) siccative premix: by Portland cement, quartz sand, flyash, silicon ash, aluminate cement, Gypsum Fibrosum and can divide again
Dissipate rubber powder mixing, do time as 8-12min in advance, obtain dry blend A;
(3) sodium hydroxide, waterglass, poly carboxylic acid series water reducer, sodium gluconate and polypropylene fibre are added to the water, stir
Even, obtain fluid mix B;
(4) adding the fluid mix B prepared in dry blend A, stir while adding, mixing time is 5 ~ 10min, stirs evenly
Obtain super self-healing yardstick cracked concrete Thief zone crystallization repair materials.
The using method of super self-healing yardstick cracked concrete Thief zone crystallization repair materials is directly smeared from oozing for using
Repair materials is filled in crack by the mode of formula or employing low pressure pressing-in grouting formula thoroughly.
The repair materials of the present invention is repaired mainly for the crack exceeding autogenous healing conjunction yardstick threshold value, catches this
Critical state carries out upper flow regime repair materials infiltration.On the one hand crack is stoped by repair materials self aquation and high viscosity substance
Continuing cracking, on the other hand in repair materials, activating substance excites cracking position to have lateral reactivity material (unhydrated cement
Grain, mineral admixture etc.) activity, newborn product and fiber reduce fracture scale by modes such as blocking and segmentations so that it is control
System is within self-healing yardstick threshold value so that it is regain self-healing capability.
The method have the advantages that
(1) the anti-folding of repair materials of the present invention, comprcssive strength height, mobile performance is good, and setting time is moderate, the anti-folding of 28d, resistance to compression
Intensity can reach 11.5MPa and 50MPa, initial flow degree and 30min fluidity respectively all can meet strength cement-based grouting material
Technical property requirements, presetting period > 45min, suitably constructs.
(2) osmotic effect is good.Concrete itself belongs to porous material, in the presence of water, and repair materials energy of the present invention
Enough penetrate in small distress in concrete, distress in concrete is repaired.
(3) adhesion strength is high.Bonding after concrete substrate water is sufficiently humidified so as to, between repair materials and concrete substrate
Intensity can reach more than 3MPa.
(4) effect of prestressed is good.Repair materials of the present invention adds water and can produce small expansion after mixing thoroughly, it is possible to better ensure that
With contacting of concrete substrate, it is possible to prevent to produce further cracking because of external load;Meanwhile, added with appropriate in this product
Polypropylene fibre, it is possible to stop repair materials to crack during harden(ing)by itself.
(5) active ion (SO4 2-、SiO4 4-、AlO3 3-Deng) penetrate into distress in concrete after, it is possible to the Ca in matrix2+
Crystallization generates precipitation, promotes the secondary hydration of unhydrated cement;Meanwhile, activity excitation ion (SO4 2-、OH-Deng) can be to gelling
In material, the activity of fly ash grain excites, and on the one hand promotes the cohesive force of repair materials and matrix, on the other hand also carries
Height self and the intensity of matrix.
(6) this product processes is simple, meets environmental protection simultaneously, and range of application is relatively broad.
Detailed description of the invention
In order to be more fully understood that the present invention, it is further elucidated with present disclosure below in conjunction with embodiment, but present disclosure
It is not limited solely to the following examples.
Embodiment 1
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
The raw material composition of following weight percents: Portland cement 38%, quartz sand 50%, flyash 5%, silicon ash 2.5%, Gypsum Fibrosum
1.5%, aluminate cement 1.5%, re-dispersible glue powder 0.5%, sodium hydroxide 0.2%, waterglass 0.4%, polypropylene fibre 0.1%,
Poly carboxylic acid series water reducer 0.25%, sodium gluconate 0.05%;Water is 0.185 with the mass ratio of solid material.
Requirement to raw material is as follows:
The strength grade of Portland cement is 42.5, and Blain specific surface is 340 ~ 400m2/Kg;Quartz sand fineness is 28 ~
100 mesh;Flyash rank is one-level, SiO2Content is not less than 55%;SiO in silicon ash2Content reaches more than 80%;Modulus of water glass
It is 1.8;The water-reducing rate of poly carboxylic acid series water reducer is 30%;A diameter of 25 μm of polypropylene fibre, a length of 3mm.
Preparation process is as follows:
(1) each component is weighed in described ratio, standby;
(2) siccative premix: by Portland cement, quartz sand, flyash, silicon ash, aluminate cement, Gypsum Fibrosum and can divide again
Dissipate rubber powder mixing, do time as 12min in advance, obtain dry blend A;
(3) sodium hydroxide, waterglass, poly carboxylic acid series water reducer, sodium gluconate and polypropylene fibre are added to the water, stir
Even, obtain fluid mix B;
(4) adding the fluid mix B prepared in dry blend A, stir while adding, mixing time is 10min, stirs evenly i.e.
Self-healing yardstick cracked concrete Thief zone crystallization repair materials must be surpassed.
Embodiment 2
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
Following weight percents raw material composition: Portland cement 40%, quartz sand 45%, flyash 6%, silicon ash 3%, Gypsum Fibrosum 2%,
Aluminate cement 2%, re-dispersible glue powder 0.6%, sodium hydroxide 0.3%, waterglass 0.6%, polypropylene fibre 0.15%, polycarboxylic acids
Based water reducer 0.28%, sodium gluconate 0.07%;Water is 0.18 with the mass ratio of solid material.
Requirement to raw material is as follows:
The strength grade of Portland cement is 42.5, and Blain specific surface is 340 ~ 400m2/Kg;Quartz sand fineness is 28 ~
100 mesh;Flyash rank is one-level, SiO2Content is not less than 55%;SiO in silicon ash2Content reaches more than 80%;Modulus of water glass
It is 2.5;The water-reducing rate of poly carboxylic acid series water reducer is 40%;A diameter of 35 μm of polypropylene fibre, a length of 2mm.
Preparation process is as follows:
(1) each component is weighed in described ratio, standby;
(2) siccative premix: by Portland cement, quartz sand, flyash, silicon ash, aluminate cement, Gypsum Fibrosum and can divide again
Dissipate rubber powder mixing, do time as 8min in advance, obtain dry blend A;
(3) sodium hydroxide, waterglass, poly carboxylic acid series water reducer, sodium gluconate and polypropylene fibre are added to the water, stir
Even, obtain fluid mix B;
(4) adding the fluid mix B prepared in dry blend A, stir while adding, mixing time is 5min, stirs evenly i.e.
Self-healing yardstick cracked concrete Thief zone crystallization repair materials must be surpassed.
Embodiment 3
Self union concrete foreign aid property penetrant crystalline repair materials, raw materials used includes solid material and water, and solid material is by following heavy
The raw material composition of amount percentage ratio: Portland cement 32%, quartz sand 55%, flyash 4%, silicon ash 3%, Gypsum Fibrosum 1.5%, aluminic acid
Salt cement 2%, re-dispersible glue powder 0.4%, sodium hydroxide 0.5%, waterglass 1.0%, polypropylene fibre 0.2%, polycarboxylic-acid diminishing
Agent 0.3%, sodium gluconate 0.1%;Water is 0.175 with the mass ratio of solid material.
Requirement to raw material is as follows:
The strength grade of Portland cement is 52.5, and Blain specific surface is 340 ~ 400m2/Kg;Quartz sand fineness is 28 ~
100 mesh;Flyash rank is one-level, SiO2Content is not less than 55%;SiO in silicon ash2Content reaches more than 80%;Modulus of water glass
It is 1.5;The water-reducing rate of poly carboxylic acid series water reducer is 35%;A diameter of 30 μm of polypropylene fibre, a length of 4mm.
According to the operation that embodiment 1 is identical during preparation.
Embodiment 4
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
The raw material composition of following weight percents: Portland cement 42%, quartz sand 40%, flyash 8%, silicon ash 3%, Gypsum Fibrosum
2.5%, aluminate cement 2.5%, re-dispersible glue powder 0.8%, sodium hydroxide 0.2%, waterglass 0.5%, polypropylene fibre 0.1%,
Poly carboxylic acid series water reducer 0.3%, sodium gluconate 0.1%;Water is 0.19 with the mass ratio of solid material.
Ingredient requirement is with embodiment 1, according to the operation that embodiment 2 is identical during preparation.
Embodiment 5
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
The raw material composition of following weight percents: Portland cement 35%, quartz sand 50%, flyash 6%, silicon ash 4%, Gypsum Fibrosum
1.5%, aluminate cement 1.5%, re-dispersible glue powder 0.6%, sodium hydroxide 0.25%, waterglass 0.6%, polypropylene fibre 0.2%,
Poly carboxylic acid series water reducer 0.25%, sodium gluconate 0.1%;Water is 0.185 with the mass ratio of solid material.
Ingredient requirement is with embodiment 2, according to the operation that embodiment 1 is identical during preparation.
Embodiment 6
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
Following weight percents raw material composition: Portland cement 34%, quartz sand 50%, flyash 6%, silicon ash 5%, Gypsum Fibrosum 2%,
Aluminate cement 1.5%, re-dispersible glue powder 0.4%, sodium hydroxide 0.25%, waterglass 0.4%, polypropylene fibre 0.1%, poly-carboxylic
Acid based water reducer 0.28%, sodium gluconate 0.07%;Water is 0.18 with the mass ratio of solid material.
Ingredient requirement is with embodiment 3, according to the operation that embodiment 2 is identical during preparation.
Embodiment 7
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
The raw material composition of following weight percents: Portland cement 37.5%, quartz sand 48%, flyash 4.5%, silicon ash 3%, Gypsum Fibrosum
1.8%, aluminate cement 2.5%, re-dispersible glue powder 0.5%, sodium hydroxide 0.5%, waterglass 1.0%, polypropylene fibre 0.25%,
Poly carboxylic acid series water reducer 0.3%, sodium gluconate 0.15%;Water is 0.19 with the mass ratio of solid material.
Ingredient requirement is with embodiment 1, according to the operation that embodiment 1 is identical during preparation.
Embodiment 8
Super self-healing yardstick cracked concrete Thief zone crystallization repair materials, raw materials used includes solid material and water, solid material by
The raw material composition of following weight percents: Portland cement 34.5%, quartz sand 50%, flyash 5.5%, silicon ash 3.5%, stone
Cream 2%, aluminate cement 2.5%, re-dispersible glue powder 0.6%, sodium hydroxide 0.3%, waterglass 0.6%, polypropylene fibre 0.2%,
Poly carboxylic acid series water reducer 0.25%, sodium gluconate 0.05%;Water is 0.185 with the mass ratio of solid material.
Ingredient requirement is with embodiment 2, according to the operation that embodiment 2 is identical during preparation.
The repairing effect of embodiment 1-8 repair materials is as shown in table 1, by seen from table for two kinds of types of fractures (split the law,
Patterning method) its comprcssive strength recovery rate is different, and the comprcssive strength recovery rate for patterning method crack is higher, substantially 100%
Above, up to 134.6%.And for the comprcssive strength recovery rate in split the law crack substantially more than 85%, up to
95.3%, all disclosure satisfy that application request.
Table 1 each embodiment repairing effect
Note: the intensity (MPa) of 28d concrete test block maintenance 28d;
PW-28d test block splitting does not carries out repairing the intensity (MPa) of direct maintenance 28d after damaging;
PX-28d cleaves maintenance 28d after impaired test block is repaired;
QW-28d test block cutting does not carries out repairing the intensity (MPa) of direct maintenance 28d after damaging;
QX-28d cuts maintenance 28d after impaired test block is repaired.
Claims (8)
1. a super self-healing yardstick cracked concrete Thief zone crystallization repair materials, it is characterised in that raw materials used including consolidates
Body material and water, the mass percent of solid material consists of: Portland cement 30 ~ 45%, quartz sand 40 ~ 60%, flyash 3 ~
15%, silicon ash 1 ~ 8%, aluminate cement 1 ~ 10%, Gypsum Fibrosum 1 ~ 10%, sodium hydroxide 0.1 ~ 4%, waterglass 0.1 ~ 4%, redispersible glue
Powder 0.1 ~ 2%, poly carboxylic acid series water reducer 0.05 ~ 1.5%, sodium gluconate 0.01 ~ 1% and polypropylene fibre 0.1 ~ 2.5%.
2. super self-healing yardstick cracked concrete Thief zone crystallization repair materials as claimed in claim 1, it is characterised in that water
It is 0.17 ~ 0.2:1 with the mass ratio of solid material.
3. super self-healing yardstick cracked concrete Thief zone crystallization repair materials as claimed in claim 1, it is characterised in that Gu
The mass percent of body material consists of: Portland cement 30 ~ 45%, quartz sand 40 ~ 60%, flyash 3 ~ 10%, silicon ash 2 ~
6%, aluminate cement 1 ~ 4%, Gypsum Fibrosum 1 ~ 4%, sodium hydroxide 0.5 ~ 2%, waterglass 0.1 ~ 4%, re-dispersible glue powder 0.1 ~ 2%, poly-
Carboxylic acid water reducing agent 0.05 ~ 1.5%, sodium gluconate 0.01 ~ 1% and polypropylene fibre 0.1 ~ 2.5%.
4. the super self-healing yardstick cracked concrete Thief zone crystallization repair materials as described in any one of claims 1 to 3, it is special
Levying and be, aluminate cement is 0.5 ~ 1.5:1 with the mass ratio of Gypsum Fibrosum;Waterglass is 1.5 ~ 2.5 with the mass ratio of sodium hydroxide:
1。
5. the super self-healing yardstick cracked concrete Thief zone crystallization repair materials as described in any one of claims 1 to 3, it is special
Levying and be, the strength grade of described Portland cement is 42.5 or 52.5, and Blain specific surface is 340 ~ 400m2/Kg;Stone
Sand fineness is 28 ~ 100 mesh;Modulus of water glass is 1.5 ~ 2.5.
6. the super self-healing yardstick cracked concrete Thief zone crystallization repair materials as described in any one of claims 1 to 3, it is special
Levying and be, flyash rank is one-level and SiO2Content is not less than 55%;SiO in silicon ash2Content reaches more than 80%.
7. the super self-healing yardstick cracked concrete Thief zone crystallization repair materials as described in any one of claims 1 to 3, it is special
Levying and be, the water-reducing rate of poly carboxylic acid series water reducer is 30 ~ 40%;A diameter of 25 ~ 35 μm of polypropylene fibre, a length of 2 ~ 4mm.
8. the preparation method of super self-healing yardstick cracked concrete Thief zone crystallization repair materials, its feature described in claim 1
It is: comprise the steps:
(1) each component is weighed in described ratio, standby;
(2) siccative premix: by Portland cement, quartz sand, flyash, silicon ash, aluminate cement, Gypsum Fibrosum and can divide again
Dissipate rubber powder mixing, obtain dry blend A;
(3) sodium hydroxide, waterglass, poly carboxylic acid series water reducer, sodium gluconate and polypropylene fibre are added to the water, stir
Even, obtain fluid mix B;
(4) in dry blend A, add the fluid mix B prepared, stir evenly and i.e. obtain super self-healing yardstick cracked concrete height and ooze
Thoroughly crystallize repair materials.
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CN107686302A (en) * | 2017-08-23 | 2018-02-13 | 浙江裕洋隧道管片制造有限公司 | A kind of cementitious capillary waterproofing material |
CN108265997A (en) * | 2018-02-06 | 2018-07-10 | 黄淮学院 | A kind of crystal structure self-healing grouting method |
CN108298936A (en) * | 2018-03-30 | 2018-07-20 | 常州达奥新材料科技有限公司 | A kind of preparation method of self-healing cement-based material |
CN109336525A (en) * | 2018-09-26 | 2019-02-15 | 冯丽霞 | A kind of Bridge Crack repair materials and preparation method thereof with selfreparing effect |
US20190112231A1 (en) * | 2017-10-18 | 2019-04-18 | Evan Daniel Vokes | Composition and method for making self adhering concrete and synthetic sedimentary rock from cementitious materials |
PL423560A1 (en) * | 2017-11-23 | 2019-06-03 | Walbet A D K Walkowiak Spolka Jawna | Integrated concrete self-repair activating agent and the concrete mix with the integrated activating agent and its application |
CN111848062A (en) * | 2020-07-01 | 2020-10-30 | 苏州市兴邦化学建材有限公司 | Permeable crystallization type quick-setting grouting material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100230689B1 (en) * | 1997-08-14 | 1999-12-01 | 노영민 | The manufacturing method of the cement based crack-repalring material for concrete slab and flooring mortar |
CN101891432A (en) * | 2010-07-14 | 2010-11-24 | 江苏博特新材料有限公司 | Permeable crystalline waterproof coating |
CN102173708A (en) * | 2011-02-10 | 2011-09-07 | 乌鲁木齐市建筑建材科学研究院有限责任公司 | Aggregate-free cement-based grouting material |
CN101531497B (en) * | 2009-04-13 | 2011-12-14 | 天津城市建设学院 | Crack-resistant waterproof cement-based permeable composite repairing material and method for preparing same |
CN103992079A (en) * | 2014-05-30 | 2014-08-20 | 中铁十八局集团第四工程有限公司 | Repair material for cracks of concrete products as well as preparation method and construction method thereof |
-
2016
- 2016-04-13 CN CN201610226499.7A patent/CN105884299A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100230689B1 (en) * | 1997-08-14 | 1999-12-01 | 노영민 | The manufacturing method of the cement based crack-repalring material for concrete slab and flooring mortar |
CN101531497B (en) * | 2009-04-13 | 2011-12-14 | 天津城市建设学院 | Crack-resistant waterproof cement-based permeable composite repairing material and method for preparing same |
CN101891432A (en) * | 2010-07-14 | 2010-11-24 | 江苏博特新材料有限公司 | Permeable crystalline waterproof coating |
CN102173708A (en) * | 2011-02-10 | 2011-09-07 | 乌鲁木齐市建筑建材科学研究院有限责任公司 | Aggregate-free cement-based grouting material |
CN103992079A (en) * | 2014-05-30 | 2014-08-20 | 中铁十八局集团第四工程有限公司 | Repair material for cracks of concrete products as well as preparation method and construction method thereof |
Non-Patent Citations (1)
Title |
---|
李要增等: "《可分散胶粉对水泥基修补砂浆的改性研究》", 《混凝土》 * |
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US20190112231A1 (en) * | 2017-10-18 | 2019-04-18 | Evan Daniel Vokes | Composition and method for making self adhering concrete and synthetic sedimentary rock from cementitious materials |
PL423560A1 (en) * | 2017-11-23 | 2019-06-03 | Walbet A D K Walkowiak Spolka Jawna | Integrated concrete self-repair activating agent and the concrete mix with the integrated activating agent and its application |
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