Concrete intensifier and preparation and application thereof
Technical field
The present invention relates to preparation and the use of concrete admixture, refer more particularly to improve concrete strength and be
The concrete intensifier of purpose and preparation and application thereof.
Background technology
Concrete is a kind of mostly important and widely used artificial stone material, be widely used in bridge, tunnel,
In the civil engineerings such as high ferro, airport and various military affairs, civil buildings, it is the important mark of human civilization progress
Will.Concrete mainly by materials such as Binder Materials (such as cement), water, aggregates (stone), makes according to actual
With the needs of condition, above-mentioned each material is mixed by suitable " match ratio " and stirred,
A kind of continuous, the firm important stone material by hydration reaction, individual component linked together eventually and formed.
The development and production of concrete use the development history that experienced by nearly more than 200 year, and concrete now is got rid of
Abandon Site, mainly use concentrated compactness, this be concrete production by extensive production to intensive big life
The transformation produced, it achieves the specialization of concrete production, commercialization and socialization, is building dependence technology
Progressive change the little mode of production, it is achieved an important reform of building industrialization, thus bring significant society,
Economic benefit.
Comprcssive strength and durability are the of paramount importance performance indications of concrete.Production at commerical ready-mixed concrete
Cheng Zhong, in order to improve the service behaviour of concrete and improve the intensity of concrete, it is often necessary in concrete
Add the various concrete admixtures (such as water reducer, air entraining agent etc.) that proportioning is the least, the addition of these additives
Generally the service behaviour of concrete is improved preferably, and the improvement to concrete strength is the most limited, and some
Additive is more sensitive, and the adaptability to concrete is not fine, and this also makes these additives specifically should
Bigger restriction is received in.
Summary of the invention
Technical problem solved by the invention is to provide the preparation method of a kind of concrete novel additive, it
Be mainly characterized by compensate for the deficiency of concrete admixture on existing market, it is the enhancing of a kind of concrete
Agent, can save cement, the production cost of reduction concrete, and i.e. it can significantly improve intensity the energy of concrete
Optimize the adaptability of other concrete admixture and concrete, improve the durability of concrete simultaneously.
Technical problem solved by the invention realizes by the following technical solutions: a kind of concrete intensifier,
Its component includes: organic polymer I that acrylic monomer is polymerized, gluconate II, sulfate
III, lignosulfonates IV and water.
Described organic polymer I is formed by acrylic monomer copolymerization, and acrylic monomer includes: acrylic acid,
Methacrylic acid, methyl methacrylate.
When synthetic organic polymer I, acrylic acid and methacrylic acid or the consumption weight of methyl methacrylate
Amount ratio is 8: 1-3: 1.
When synthetic organic polymer I, the weight of water used by reaction system is two kinds of polymerization total consumptions of monomer
10-12 times.
When synthetic organic polymer I, polymerization reaction time is 4-6 hour, and reaction is adjusted with NaOH after terminating
Joint system Ph value is 7-9.
Described gluconate II is calcium gluconate or sodium gluconate, gluconate II and acrylic acid
Weight ratio be 0.1-0.5.
Described sulfate III is sodium sulfate or calcium sulfate, and sulfate III with acrylic acid weight ratio is
0.01-0.05。
Described lignosulfonates IV is calcium lignosulfonate or sodium lignin sulfonate, lignosulfonates IV
It is 2-0.5 with acrylic acid weight ratio.
The preparation method of a kind of concrete intensifier, comprises the following steps: 1) be dissolved in by acrylic acid by proportioning
In water, methacrylic acid is dissolved in the hot water of 60 DEG C, there-necked flask adds water and adds a small amount of drawing
Send out agent sodium peroxydisulfate (Na2S4O8), in the case of stirring, in there-necked flask, drip acrylic acid lentamente water-soluble
Liquid and metering system aqueous acid, keep at a temperature of 60 DEG C about polyreaction 4-6 hour, reacted
Cheng Hou, adding NaOH regulation Ph value in system is about 7-9.
2) by proportioning, calcium gluconate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to fill
Divide and dissolve.
3) by proportioning, sodium sulfate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to abundant
Dissolve.
4) by proportioning, Fructus Vitis viniferae hydrochlorate calcium is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to
Fully dissolve, obtain the mother solution of concrete intensifier.
5) diluting mother solution with a certain amount of water, the finished product concrete that can be used directly of the final present invention of preparing increases
Strong agent, the weight of dilution water is 7-10 times of mother solution quality.
The using method of a kind of concrete intensifier, comprises the following steps: 1) detect the Binder Materials of concrete
Weight ratio content;
2) adding the concrete intensifier of the 0.2%-0.8% of Binder Materials weight, wherein addition is with the material that is gelled
The 0.5% of material is optimum, the too little or too much merit that all can not fully demonstrate concrete intensifier of the present invention of addition
Effect, if addition is too much, it could even be possible to the decline of concrete strength can be caused.
Compared with disclosed technology, there is advantages below in the present invention: the present invention passes through chemical means, by propylene
Acrylic monomer aggregates into the copolymerization organic polymer with certain molecular weight distribution, then by suitable mass ratio,
Organic polymer is mixed with calcium gluconate, sodium sulfate, calcium lignosulfonate and water, in room temperature
The lower stirring regular hour, just obtain that there is certain density reinforcing agent mother solution, by this mother solution with water with necessarily
The proportioning dilution of amount, so that it may the concrete intensifier directly used, the concrete that this invention is produced increases
Strong agent is nontoxic, tasteless, non-volatility, is a kind of green chemical industry construction material, along with national energy-saving, consumption reduction
Implementing and deeply of industrial policy, the reinforcing agent of the present invention will widely should following concrete is commercially available
With.
Detailed description of the invention
In order to make the technological means of the present invention, creation characteristic, workflow, using method reach purpose and merit
Effect is easy to understand, and below in conjunction with the embodiment of the present invention, enters the technical scheme in the embodiment of the present invention
Row clearly and completely describes, it is clear that described embodiment is only a part of embodiment of the present invention, and
It is not all, of embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
Embodiment 1
Take acrylic acid 20.0g to be dissolved in the water of 80ml, take methacrylic acid 5.7g and be dissolved in 100ml temperature and be
In the hot water of 60 DEG C, the water adding 100ml in the there-necked flask of 500ml is simultaneously introduced 0.05g persulfuric acid
Sodium (Na2S4O8), stir and be warming up to 60 DEG C, then in there-necked flask, being slowly added dropwise acrylic acid solution simultaneously
And methacrylic acid solution, insulation reaction 5 hours at 60 DEG C, when system is cooled to room temperature, to system
Add NaOH0.5g, make system Ph value regulate to 7.5, in system addition 4.0g calcium gluconate,
0.4g sodium sulfate and 20.0g calcium lignosulfonate, stir 8 minutes to obtain 150.3g concrete intensifier mother solution.
Embodiment 2
Take acrylic acid 20.0g to be dissolved in the water of 80ml, take methacrylic acid 5.7g and be dissolved in 100ml temperature and be
In the hot water of 60 DEG C, the water adding 100ml in the there-necked flask of 500ml is simultaneously introduced 0.05g persulfuric acid
Sodium (Na2S4O8) stir and be warming up to 60 DEG C, then in there-necked flask, it is slowly added dropwise acrylic acid solution simultaneously
And methacrylic acid solution, insulation reaction 5 hours at 60 DEG C, when system is cooled to room temperature, to system
Add NaOH0.5g, make system Ph value regulate to 7.5, in system addition 4.0g calcium gluconate,
0.4g sodium sulfate and 20.0g calcium lignosulfonate, stir 8 minutes to obtain 150.3g concrete intensifier mother solution,
Take mother solution 30g, add the dilution of 240g water, obtain 270g finished product concrete intensifier.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is 1m relative to benchmark sample3Concrete reduces the experiment of 30kg cement, and experimental result illustrates, makes
In the case of the finished product reinforcing agent of the present invention, can suitably reduce the cement consumption of concrete and can guarantee that former mixed
The design strength of solidifying soil.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is the experiment having added a small amount of concrete intensifier of the present invention relative to benchmark sample, and experimental result illustrates,
In the case of the finished product reinforcing agent using the present invention, the intensity of concrete has obtained the most significantly improving.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is the experiment having added a small amount of concrete intensifier of the present invention relative to benchmark sample, and experimental result is said
Bright, in the case of the finished product reinforcing agent using the present invention, the intensity of concrete has obtained the most significantly carrying
High.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The industry
Skilled person will appreciate that, the present invention is not restricted to the described embodiments, in above-described embodiment and description
The principle that the present invention is simply described described, without departing from the spirit and scope of the present invention, the present invention
Also having various changes and modifications, these changes and improvements both fall within scope of the claimed invention.This
The claimed scope of invention is defined by appending claims and equivalent thereof.