CN105884243A - Concrete enhancer and preparation and application method thereof - Google Patents

Concrete enhancer and preparation and application method thereof Download PDF

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Publication number
CN105884243A
CN105884243A CN201410444431.7A CN201410444431A CN105884243A CN 105884243 A CN105884243 A CN 105884243A CN 201410444431 A CN201410444431 A CN 201410444431A CN 105884243 A CN105884243 A CN 105884243A
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CN
China
Prior art keywords
concrete
water
organic polymer
gluconate
acrylic acid
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Pending
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CN201410444431.7A
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Chinese (zh)
Inventor
徐会君
李淳
鲁祥勇
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Anhui Wanke New Technological Development Co Ltd
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Anhui Wanke New Technological Development Co Ltd
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Priority to CN201410444431.7A priority Critical patent/CN105884243A/en
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Pending legal-status Critical Current

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Abstract

The invention provides a concrete enhancer, which comprises an organic polymer I formed by polymerization of acrylic monomers, gluconate II, sulfate III, sulfonated lignin IV and water. An application method of the concrete enhancer comprises the following steps: 1) detecting content (by weight) of a cementing material of concrete; and 2) adding the concrete enhancer which accounts for 0.2-0.8% of weight of the cementing material. By a chemical means, acrylic monomers are polymerized into an organic polymer with a certain molecular weight distribution; the organic polymer is mixed with calcium gluconate, sodium sulfate, calcium lignosulphonate and water; the mixture is stirred at room temperature for a certain period of time so as to obtain enhancer mother liquor with a certain concentration; and the mother liquor is diluted with water according to a certain ratio of the mother liquor to water so as to obtain the concrete enhancer which can be directly used. The concrete enhancer produced by the chemical means is nontoxic, tasteless and non-volatile, and has a wide application prospect.

Description

Concrete intensifier and preparation and application thereof
Technical field
The present invention relates to preparation and the use of concrete admixture, refer more particularly to improve concrete strength and be The concrete intensifier of purpose and preparation and application thereof.
Background technology
Concrete is a kind of mostly important and widely used artificial stone material, be widely used in bridge, tunnel, In the civil engineerings such as high ferro, airport and various military affairs, civil buildings, it is the important mark of human civilization progress Will.Concrete mainly by materials such as Binder Materials (such as cement), water, aggregates (stone), makes according to actual With the needs of condition, above-mentioned each material is mixed by suitable " match ratio " and stirred, A kind of continuous, the firm important stone material by hydration reaction, individual component linked together eventually and formed.
The development and production of concrete use the development history that experienced by nearly more than 200 year, and concrete now is got rid of Abandon Site, mainly use concentrated compactness, this be concrete production by extensive production to intensive big life The transformation produced, it achieves the specialization of concrete production, commercialization and socialization, is building dependence technology Progressive change the little mode of production, it is achieved an important reform of building industrialization, thus bring significant society, Economic benefit.
Comprcssive strength and durability are the of paramount importance performance indications of concrete.Production at commerical ready-mixed concrete Cheng Zhong, in order to improve the service behaviour of concrete and improve the intensity of concrete, it is often necessary in concrete Add the various concrete admixtures (such as water reducer, air entraining agent etc.) that proportioning is the least, the addition of these additives Generally the service behaviour of concrete is improved preferably, and the improvement to concrete strength is the most limited, and some Additive is more sensitive, and the adaptability to concrete is not fine, and this also makes these additives specifically should Bigger restriction is received in.
Summary of the invention
Technical problem solved by the invention is to provide the preparation method of a kind of concrete novel additive, it Be mainly characterized by compensate for the deficiency of concrete admixture on existing market, it is the enhancing of a kind of concrete Agent, can save cement, the production cost of reduction concrete, and i.e. it can significantly improve intensity the energy of concrete Optimize the adaptability of other concrete admixture and concrete, improve the durability of concrete simultaneously.
Technical problem solved by the invention realizes by the following technical solutions: a kind of concrete intensifier, Its component includes: organic polymer I that acrylic monomer is polymerized, gluconate II, sulfate III, lignosulfonates IV and water.
Described organic polymer I is formed by acrylic monomer copolymerization, and acrylic monomer includes: acrylic acid, Methacrylic acid, methyl methacrylate.
When synthetic organic polymer I, acrylic acid and methacrylic acid or the consumption weight of methyl methacrylate Amount ratio is 8: 1-3: 1.
When synthetic organic polymer I, the weight of water used by reaction system is two kinds of polymerization total consumptions of monomer 10-12 times.
When synthetic organic polymer I, polymerization reaction time is 4-6 hour, and reaction is adjusted with NaOH after terminating Joint system Ph value is 7-9.
Described gluconate II is calcium gluconate or sodium gluconate, gluconate II and acrylic acid Weight ratio be 0.1-0.5.
Described sulfate III is sodium sulfate or calcium sulfate, and sulfate III with acrylic acid weight ratio is 0.01-0.05。
Described lignosulfonates IV is calcium lignosulfonate or sodium lignin sulfonate, lignosulfonates IV It is 2-0.5 with acrylic acid weight ratio.
The preparation method of a kind of concrete intensifier, comprises the following steps: 1) be dissolved in by acrylic acid by proportioning In water, methacrylic acid is dissolved in the hot water of 60 DEG C, there-necked flask adds water and adds a small amount of drawing Send out agent sodium peroxydisulfate (Na2S4O8), in the case of stirring, in there-necked flask, drip acrylic acid lentamente water-soluble Liquid and metering system aqueous acid, keep at a temperature of 60 DEG C about polyreaction 4-6 hour, reacted Cheng Hou, adding NaOH regulation Ph value in system is about 7-9.
2) by proportioning, calcium gluconate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to fill Divide and dissolve.
3) by proportioning, sodium sulfate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to abundant Dissolve.
4) by proportioning, Fructus Vitis viniferae hydrochlorate calcium is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to Fully dissolve, obtain the mother solution of concrete intensifier.
5) diluting mother solution with a certain amount of water, the finished product concrete that can be used directly of the final present invention of preparing increases Strong agent, the weight of dilution water is 7-10 times of mother solution quality.
The using method of a kind of concrete intensifier, comprises the following steps: 1) detect the Binder Materials of concrete Weight ratio content;
2) adding the concrete intensifier of the 0.2%-0.8% of Binder Materials weight, wherein addition is with the material that is gelled The 0.5% of material is optimum, the too little or too much merit that all can not fully demonstrate concrete intensifier of the present invention of addition Effect, if addition is too much, it could even be possible to the decline of concrete strength can be caused.
Compared with disclosed technology, there is advantages below in the present invention: the present invention passes through chemical means, by propylene Acrylic monomer aggregates into the copolymerization organic polymer with certain molecular weight distribution, then by suitable mass ratio, Organic polymer is mixed with calcium gluconate, sodium sulfate, calcium lignosulfonate and water, in room temperature The lower stirring regular hour, just obtain that there is certain density reinforcing agent mother solution, by this mother solution with water with necessarily The proportioning dilution of amount, so that it may the concrete intensifier directly used, the concrete that this invention is produced increases Strong agent is nontoxic, tasteless, non-volatility, is a kind of green chemical industry construction material, along with national energy-saving, consumption reduction Implementing and deeply of industrial policy, the reinforcing agent of the present invention will widely should following concrete is commercially available With.
Detailed description of the invention
In order to make the technological means of the present invention, creation characteristic, workflow, using method reach purpose and merit Effect is easy to understand, and below in conjunction with the embodiment of the present invention, enters the technical scheme in the embodiment of the present invention Row clearly and completely describes, it is clear that described embodiment is only a part of embodiment of the present invention, and It is not all, of embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art are not making The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
Embodiment 1
Take acrylic acid 20.0g to be dissolved in the water of 80ml, take methacrylic acid 5.7g and be dissolved in 100ml temperature and be In the hot water of 60 DEG C, the water adding 100ml in the there-necked flask of 500ml is simultaneously introduced 0.05g persulfuric acid Sodium (Na2S4O8), stir and be warming up to 60 DEG C, then in there-necked flask, being slowly added dropwise acrylic acid solution simultaneously And methacrylic acid solution, insulation reaction 5 hours at 60 DEG C, when system is cooled to room temperature, to system Add NaOH0.5g, make system Ph value regulate to 7.5, in system addition 4.0g calcium gluconate, 0.4g sodium sulfate and 20.0g calcium lignosulfonate, stir 8 minutes to obtain 150.3g concrete intensifier mother solution. Embodiment 2
Take acrylic acid 20.0g to be dissolved in the water of 80ml, take methacrylic acid 5.7g and be dissolved in 100ml temperature and be In the hot water of 60 DEG C, the water adding 100ml in the there-necked flask of 500ml is simultaneously introduced 0.05g persulfuric acid Sodium (Na2S4O8) stir and be warming up to 60 DEG C, then in there-necked flask, it is slowly added dropwise acrylic acid solution simultaneously And methacrylic acid solution, insulation reaction 5 hours at 60 DEG C, when system is cooled to room temperature, to system Add NaOH0.5g, make system Ph value regulate to 7.5, in system addition 4.0g calcium gluconate, 0.4g sodium sulfate and 20.0g calcium lignosulfonate, stir 8 minutes to obtain 150.3g concrete intensifier mother solution, Take mother solution 30g, add the dilution of 240g water, obtain 270g finished product concrete intensifier.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is 1m relative to benchmark sample3Concrete reduces the experiment of 30kg cement, and experimental result illustrates, makes In the case of the finished product reinforcing agent of the present invention, can suitably reduce the cement consumption of concrete and can guarantee that former mixed The design strength of solidifying soil.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is the experiment having added a small amount of concrete intensifier of the present invention relative to benchmark sample, and experimental result illustrates, In the case of the finished product reinforcing agent using the present invention, the intensity of concrete has obtained the most significantly improving.
Taking the finished product concrete intensifier of appropriate embodiment 2, according to the form below concrete proportioning does test block and tests:
The test block experiment concrete of 15 (L) C30 concrete
Comparison specimen is the experiment having added a small amount of concrete intensifier of the present invention relative to benchmark sample, and experimental result is said Bright, in the case of the finished product reinforcing agent using the present invention, the intensity of concrete has obtained the most significantly carrying High.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The industry Skilled person will appreciate that, the present invention is not restricted to the described embodiments, in above-described embodiment and description The principle that the present invention is simply described described, without departing from the spirit and scope of the present invention, the present invention Also having various changes and modifications, these changes and improvements both fall within scope of the claimed invention.This The claimed scope of invention is defined by appending claims and equivalent thereof.

Claims (8)

1. a concrete intensifier, it is characterised in that: its component includes: acrylic monomer is polymerized Organic polymer I, gluconate II, sulfate III, lignosulfonates IV and water.
Concrete intensifier the most according to claim 1, it is characterised in that: described organic polymer I Being formed by acrylic monomer copolymerization, acrylic monomer includes: acrylic acid, methacrylic acid, methyl-prop E pioic acid methyl ester.
Concrete intensifier the most according to claim 2, it is characterised in that: at synthetic organic polymer During I, acrylic acid is 8: 1-3: 1 with the consumption weight ratio of methacrylic acid or methyl methacrylate;In synthesis During organic polymer I, the weight of water used by reaction system is 10-12 times of two kinds of polymerization total consumptions of monomer; When synthetic organic polymer I, polymerization reaction time is 4-6 hour, and reaction regulates body with NaOH after terminating It is Ph value for 7-9.
Concrete intensifier the most according to claim 1, it is characterised in that: described gluconate II For calcium gluconate or sodium gluconate, gluconate II and acrylic acid weight ratio are 0.1-0.5.
Concrete intensifier the most according to claim 1, it is characterised in that: described sulfate III is Sodium sulfate or calcium sulfate, sulfate III and acrylic acid weight ratio are 0.01-0.05.
Concrete intensifier the most according to claim 1, it is characterised in that: described lignosulfonates IV is calcium lignosulfonate or sodium lignin sulfonate, and lignosulfonates IV with acrylic acid weight ratio is 2-0.5。
7. a preparation method for concrete intensifier, comprises the following steps: 1) by proportioning, acrylic acid is molten In Xie Yushui, methacrylic acid is dissolved in the hot water of 60 DEG C, there-necked flask adds water and adds a small amount of Initiator sodium peroxydisulfate (Na2S4O8), in the case of stirring, in there-necked flask, drip acrylic acid lentamente Aqueous solution and metering system aqueous acid, keep polyreaction 4-6 hour at a temperature of 60 DEG C, reacted Cheng Hou, adding NaOH regulation Ph value in system is 7-9;
2) by proportioning, calcium gluconate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to fill Divide and dissolve;
3) by proportioning, sodium sulfate is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to abundant Dissolve;
4) by proportioning, Fructus Vitis viniferae hydrochlorate calcium is joined above-mentioned reacted system, stirring at normal temperature several minutes, be allowed to Fully dissolve, obtain the mother solution of concrete intensifier;
5) diluting mother solution with a certain amount of water, the finished product concrete that can be used directly of the final present invention of preparing increases Strong agent, the weight of dilution water is 7-10 times of mother solution quality.
8. a using method for concrete intensifier, comprises the following steps: 1) detection concrete gelling The weight ratio content of material;
2) concrete intensifier of the 0.2%-0.8% of Binder Materials weight is added.
CN201410444431.7A 2014-09-03 2014-09-03 Concrete enhancer and preparation and application method thereof Pending CN105884243A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106396469A (en) * 2016-08-30 2017-02-15 卓达新材料科技集团威海股份有限公司 Delayed coagulating reinforcing agent for three-dimensional printing house slurry
CN111675777A (en) * 2020-07-07 2020-09-18 四川恒泽建材有限公司 Concrete compaction reinforcing agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001342048A (en) * 2000-05-30 2001-12-11 Sumitomo Osaka Cement Co Ltd Coating material for concrete and repairing or protecting method of concrete surface
CN1653031A (en) * 2002-03-13 2005-08-10 格雷斯公司 Beneficiated water reducing compositions
CN1654406A (en) * 2005-01-04 2005-08-17 华南理工大学 Lignins metro shield grouting additive and its preparation method
CN102060463A (en) * 2010-12-03 2011-05-18 山东宏艺科技股份有限公司 Low-cost concrete antifreezing pumping aid and preparation method thereof
CN102731014A (en) * 2012-06-29 2012-10-17 上海市建筑构件制品有限公司 Polycarboxylic acid-lignin composite additive

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001342048A (en) * 2000-05-30 2001-12-11 Sumitomo Osaka Cement Co Ltd Coating material for concrete and repairing or protecting method of concrete surface
CN1653031A (en) * 2002-03-13 2005-08-10 格雷斯公司 Beneficiated water reducing compositions
CN1654406A (en) * 2005-01-04 2005-08-17 华南理工大学 Lignins metro shield grouting additive and its preparation method
CN102060463A (en) * 2010-12-03 2011-05-18 山东宏艺科技股份有限公司 Low-cost concrete antifreezing pumping aid and preparation method thereof
CN102731014A (en) * 2012-06-29 2012-10-17 上海市建筑构件制品有限公司 Polycarboxylic acid-lignin composite additive

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李真 等: "《水溶性聚丙烯酸类高效减水剂的合成及表征》", 《新型建筑材料》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106396469A (en) * 2016-08-30 2017-02-15 卓达新材料科技集团威海股份有限公司 Delayed coagulating reinforcing agent for three-dimensional printing house slurry
CN111675777A (en) * 2020-07-07 2020-09-18 四川恒泽建材有限公司 Concrete compaction reinforcing agent and preparation method thereof

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Application publication date: 20160824