CN105884068A - Electroplating solution purifying system - Google Patents

Electroplating solution purifying system Download PDF

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Publication number
CN105884068A
CN105884068A CN201610377411.1A CN201610377411A CN105884068A CN 105884068 A CN105884068 A CN 105884068A CN 201610377411 A CN201610377411 A CN 201610377411A CN 105884068 A CN105884068 A CN 105884068A
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CN
China
Prior art keywords
purifying
electroplating solution
activated carbon
nonactive
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610377411.1A
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Chinese (zh)
Inventor
赵海涛
赵德甫
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Shenzhen Qianhai Guangda New Material Co Ltd
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Shenzhen Qianhai Guangda New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Shenzhen Qianhai Guangda New Material Co Ltd filed Critical Shenzhen Qianhai Guangda New Material Co Ltd
Priority to CN201610377411.1A priority Critical patent/CN105884068A/en
Publication of CN105884068A publication Critical patent/CN105884068A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/06Filtering particles other than ions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention provides an electroplating solution purifying system. An electroplating solution to be treated in a solution groove is pumped by a circulation pump into a water guide pipe of a purifying device, large metal blocks to enter the water guide pipe are filtered away through a filter film or a filter cloth at the lower end of the water guide pipe at first, purifying filler in the water guide pipe makes sufficient contact with the electroplating solution and adsorbs hazardous substance and metal ions in the electroplating solution, online treatment of the electroplating solution is achieved, no additional carbon treating groove or standing groove is needed, occupied area is reduced, treating time is short, the electroplating solution can be thoroughly purified, and cleanliness and environmental pollution are achieved.

Description

Purifying electroplating solution system
Technical field
The invention belongs to electroplating technology field, particularly relate to a kind of purifying electroplating solution system.
Background technology
At present, existing purifying electroplating solution system uses following steps: first the electroplating solution purified will be needed to be pumped into carbon treatment trough by circulating pump, adds hydrogen peroxide, hydrogen peroxide is warming up to 60 DEG C and processes a period of time in carbon treatment trough;It is subsequently added into active carbon powder, stir process certain time, then after standing a period of time;Finally the solution on carbon treatment trough upper strata is pumped into additionally mounted standing groove, in standing groove, uses PP filter element filtering, fully remove the carbon dust of residual in solution;By above operation, the longest, purify the most up to standard.
Summary of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, it is provided that a kind of clarification time is short and the purifying electroplating solution system of good purification.
The present invention is realized in, a kind of purifying electroplating solution system, the solution tank of electroplating solution, a circulating pump and a purifier is filled including one, the water inlet of described circulating pump and water inlet pipe connection, the outlet of described circulating pump and outlet pipe connection, the described water inlet pipe other end is located at the bottom of described solution tank, the water inlet of described water inlet pipe is provided with a drainage screen, described outlet pipe connects with described purifier, the outlet of described purifier and drain pipe connection, the other end of described drain pipe is located in described solution tank;
Described purifier includes a support and some intervals and vertically-mounted aqueduct on the bracket, the lower end of each described aqueduct connects with described outlet pipe respectively, the upper end of each described aqueduct connects with drain pipe respectively, the water inlet of described aqueduct and outlet are separately installed with a filter membrane or filter cloth, purification filler it is filled with in described aqueduct, described purification filler includes ceramic packing, molecular sieve, activated carbon powder, nonactive powdered carbon, activated carbon granule, charcoal non activated granule, any one or two or more combination in quartz sand and adsorbent resin;
When purifying filler and being ceramic packing, the parameter of ceramic packing is: specific surface area: 1-2000m2/ g, voidage: 1-90%, bulk density: 1-2000KG/m, ceramic packing be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being molecular sieve, the parameter of molecular sieve is: mesh number: 1-1000, bulk density: 1-2000KG/m, specific surface area: 1-2000 m2/ g, pore volume: 0.1-10 cm3/ g, molecular sieve be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being activated carbon powder, the parameter of activated carbon powder is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2/ g, PH:3-12, activated carbon powder is medium, wooden or coconut husk matter;
When purifying filler and being nonactive powdered carbon, the parameter of nonactive powdered carbon is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2The nonactive powdered carbon of/g, PH:3-12 is medium, wooden or coconut husk matter;
When purifying filler and being activated carbon grain, the parameter of activated carbon grain is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, activated carbon grain is medium, wooden or coconut husk matter, activated carbon grain be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying the nonactive carbon granule of filler, the parameter of nonactive carbon granule is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, nonactive carbon granule be activated carbon grain be medium, wooden or coconut husk matter, nonactive carbon granule be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying filler and being quartz sand, the parameter of quartz sand is: bulk density is 0.5-5 ton/cubic meter, fusing point less than 2500 DEG C, and magnitude range is: 0.1-50mm;
When purifying filler and being adsorbent resin, the parameter of adsorbent resin is: aperture: 1-1000nm, specific surface area: 1-2000m2/ g, granularity 1-800 mesh, being shaped as of adsorbent resin is spherical.
Further, described water inlet pipe, described outlet pipe and described drain pipe are mounted on a control valve.
Specifically, as when being shaped as cylindric of activated carbon grain, a diameter of 0.1-100mm of activated carbon grain, axial length is 1-100mm.
Specifically, as when being shaped as cylindric of nonactive carbon granule, a diameter of 0.1-100mm of nonactive carbon granule, axial length is 1-100mm.
Preferably, described filter membrane is polypropylene thermal spray fiber membrane, polypropylene superfine fiber film or nylon politef microporous filter membrane.
Preferably, described filter cloth is non-woven fabrics or the weaving cloth by the braiding of textile fabric yarn.
Preferably, the material of described circulating pump, described water inlet pipe, described outlet pipe, described drain pipe, described support, described aqueduct and described control valve is PP.
The purifying electroplating solution system that the present invention provides, by circulating pump, electroplating solution pending in solution tank is pumped in the aqueduct of purifier, first filter membrane or filter cloth by aqueduct lower end filters the bigger metal agglomerates being prepared to enter in aqueduct, then the harmful substance being fully contacted by the purification filler in aqueduct and electroplating solution and adsorb in electroplating solution and metal ion, achieve the online treatment of electroplating solution, need not extra carbon treatment trough and stand groove, decrease floor space, the process time is short, electroplating solution can be made thoroughly to purify, clean environment firendly.
Accompanying drawing explanation
In order to be illustrated more clearly that technical scheme, the accompanying drawing used required in embodiment will be briefly described below, apparently, accompanying drawing in describing below is only some embodiments of the present invention, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is the schematic diagram of the purifying electroplating solution system that the present invention provides.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
As shown in Figure 1, a kind of purifying electroplating solution system that the embodiment of the present invention provides, including solution tank 1, circulating pump 2 filling electroplating solution and a purifier 3, water inlet and a water inlet pipe 4 of circulating pump 2 connect, outlet and an outlet pipe 5 of circulating pump 2 connect, water inlet pipe 4 other end is located at the bottom of solution tank 1, the water inlet of water inlet pipe 4 is provided with a drainage screen 41, outlet pipe 5 connects with purifier 3, outlet and a drain pipe 6 of purifier 3 connect, and the other end of drain pipe 6 is located in solution tank 1;
Purifier 3 includes a support 31 and some intervals and the aqueduct 32 being vertically installed on support 31, the lower end of each aqueduct 32 connects with outlet pipe 5 respectively, the upper end of each aqueduct 32 connects with drain pipe 6 respectively, the water inlet of aqueduct 32 and outlet are separately installed with filter membrane 33 or a filter cloth, it is filled with purification filler in aqueduct 32, purifies filler and include the combination of any one or more in ceramic packing, molecular sieve, activated carbon powder, nonactive powdered carbon, activated carbon grain, nonactive carbon granule, quartz sand or adsorbent resin;
When purifying filler and being ceramic packing, the parameter of ceramic packing is: specific surface area: 1-2000m2/ g, voidage: 1-90%, bulk density: 1-2000KG/m, ceramic packing be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being molecular sieve, the parameter of molecular sieve is: mesh number: 1-1000, bulk density: 1-2000KG/m, specific surface area: 1-2000 m2/ g, pore volume: 0.1-10 cm3/ g, molecular sieve be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being activated carbon powder, the parameter of activated carbon powder is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2/ g, PH:3-12, activated carbon powder is medium, wooden or coconut husk matter;
When purifying filler and being nonactive powdered carbon, the parameter of nonactive powdered carbon is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2The nonactive powdered carbon of/g, PH:3-12 is medium, wooden or coconut husk matter;
When purifying filler and being activated carbon grain, the parameter of activated carbon grain is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, activated carbon grain is medium, wooden or coconut husk matter, activated carbon grain be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying the nonactive carbon granule of filler, the parameter of nonactive carbon granule is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, nonactive carbon granule be activated carbon grain be medium, wooden or coconut husk matter, nonactive carbon granule be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying filler and being quartz sand, the parameter of quartz sand is: bulk density is 0.5-5 ton/cubic meter, fusing point less than 2500 DEG C, and magnitude range is: 0.1-50mm;
When purifying filler and being adsorbent resin, the parameter of adsorbent resin is: aperture: 1-1000nm, specific surface area: 1-2000m2/ g, granularity 1-800 mesh, being shaped as of adsorbent resin is spherical.
Wherein, when purifying filler and being two or more combinations, in composition included by above-mentioned purification filler, the percentage by weight of ceramic packing can be 0 ~ 50%, the percentage by weight of molecular sieve can be 0 ~ 50%, the percentage by weight of activated carbon powder can be 0 ~ 50%, the percentage by weight of nonactive powdered carbon can be 0 ~ 50%, the percentage by weight of activated carbon grain can be 0 ~ 100%, the percentage by weight of nonactive carbon granule can be 0 ~ 100%, the percentage by weight of quartz sand can be 0 ~ 50%, and the percentage by weight of adsorbent resin can be 0 ~ 60%.
Further, described water inlet pipe 4, outlet pipe 5 and drain pipe 6 are mounted on a control valve 7, the size of current in water inlet pipe 4, outlet pipe 5 and drain pipe 6 can be controlled respectively by control valve 7, it is simple to purify the electroplating solution in aqueduct 32.
Specifically, as when being shaped as cylindric of activated carbon grain, a diameter of 0.1-100mm of activated carbon grain, axial length is 1-100mm.
Specifically, as when being shaped as cylindric of nonactive carbon granule, a diameter of 0.1-100mm of nonactive carbon granule, axial length is 1-100mm.
Preferably, described filter membrane is polypropylene thermal spray fiber membrane, polypropylene superfine fiber film or nylon politef microporous filter membrane.
Preferably, described filter cloth is non-woven fabrics or the weaving cloth by the braiding of textile fabric yarn.
Preferably, the material of described circulating pump 2, water inlet pipe 4, outlet pipe 5, drain pipe 6, support 31, aqueduct 32 and control valve 7 is PP(polypropylene), select PP material, the acidic materials corrosion in resistance to electroplating solution.
The purifying electroplating solution system that the present invention provides, by circulating pump 2, pending electroplating solution in solution tank 1 is pumped in the aqueduct 32 of purifier 3, first filter membrane 33 or filter cloth by aqueduct 32 lower end filters the bigger metal agglomerates being prepared to enter in aqueduct 32, then the harmful substance being fully contacted by the purification filler in aqueduct 32 and electroplating solution and adsorb in electroplating solution and metal ion, achieve the online treatment of electroplating solution, need not extra carbon treatment trough and stand groove, decrease floor space, the process time is short, electroplating solution can be made thoroughly to purify, clean environment firendly.
The above is the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (7)

1. a purifying electroplating solution system, it is characterized in that, the solution tank of electroplating solution, a circulating pump and a purifier is filled including one, the water inlet of described circulating pump and water inlet pipe connection, the outlet of described circulating pump and outlet pipe connection, the described water inlet pipe other end is located at the bottom of described solution tank, the water inlet of described water inlet pipe is provided with a drainage screen, described outlet pipe connects with described purifier, the outlet of described purifier and drain pipe connection, the other end of described drain pipe is located in described solution tank;
Described purifier includes a support and some intervals and vertically-mounted aqueduct on the bracket, the lower end of each described aqueduct connects with described outlet pipe respectively, the upper end of each described aqueduct connects with drain pipe respectively, the water inlet of described aqueduct and outlet are separately installed with a filter membrane or filter cloth, being filled with purification filler in described aqueduct, described purification filler includes the combination of any one or more in ceramic packing, molecular sieve, activated carbon powder, nonactive powdered carbon, activated carbon granule, charcoal non activated granule, quartz sand and adsorbent resin;
When purifying filler and being ceramic packing, the parameter of ceramic packing is: specific surface area: 1-2000m2/ g, voidage: 1-90%, bulk density: 1-2000KG/m, ceramic packing be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being molecular sieve, the parameter of molecular sieve is: mesh number: 1-1000, bulk density: 1-2000KG/m, specific surface area: 1-2000 m2/ g, pore volume: 0.1-10 cm3/ g, molecular sieve be shaped as ball, elliptical shape ball, corrugated, lamellar, cellular or cylindric;
When purifying filler and being activated carbon powder, the parameter of activated carbon powder is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2/ g, PH:3-12, activated carbon powder is medium, wooden or coconut husk matter;
When purifying filler and being nonactive powdered carbon, the parameter of nonactive powdered carbon is: granularity: 10-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=30 ml/g, ash≤15%, specific surface area: 1-3000m2The nonactive powdered carbon of/g, PH:3-12 is medium, wooden or coconut husk matter;
When purifying filler and being activated carbon grain, the parameter of activated carbon grain is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, activated carbon grain is medium, wooden or coconut husk matter, activated carbon grain be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying the nonactive carbon granule of filler, the parameter of nonactive carbon granule is: granularity: 80-800 mesh, iodine sorption value >=40 mg/g, methylene blue number >=20 ml/g, loading density 20-1000 g/l, PH:3-12, specific surface area 1-2000m2/ g, nonactive carbon granule be activated carbon grain be medium, wooden or coconut husk matter, nonactive carbon granule be shaped as ball, elliptical shape ball, corrugated, lamellar, cylindric or cellular;
When purifying filler and being quartz sand, the parameter of quartz sand is: bulk density is 0.5-5 ton/cubic meter, fusing point less than 2500 DEG C, and magnitude range is: 0.1-50mm;
When purifying filler and being adsorbent resin, the parameter of adsorbent resin is: aperture: 1-1000nm, specific surface area: 1-2000m2/ g, granularity 1-800 mesh, being shaped as of adsorbent resin is spherical.
Purifying electroplating solution system the most according to claim 1, it is characterised in that be mounted on a control valve on described water inlet pipe, described outlet pipe and described drain pipe.
Purifying electroplating solution system the most according to claim 1, it is characterised in that as when being shaped as cylindric of activated carbon grain, a diameter of 0.1-100mm of activated carbon grain, axial length is 1-100mm.
Purifying electroplating solution system the most according to claim 1, it is characterised in that as when being shaped as cylindric of nonactive carbon granule, a diameter of 0.1-100mm of nonactive carbon granule, axial length is 1-100mm.
Purifying electroplating solution system the most according to claim 1, it is characterised in that described filter membrane is polypropylene thermal spray fiber membrane, polypropylene superfine fiber film or nylon politef microporous filter membrane.
Purifying electroplating solution system the most according to claim 1, it is characterised in that described filter cloth is non-woven fabrics or the weaving cloth by the braiding of textile fabric yarn.
Purifying electroplating solution system the most according to claim 2, it is characterised in that the material of described circulating pump, described water inlet pipe, described outlet pipe, described drain pipe, described support, described aqueduct and described control valve is PP.
CN201610377411.1A 2016-06-01 2016-06-01 Electroplating solution purifying system Pending CN105884068A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106865644A (en) * 2017-03-08 2017-06-20 王慈 A kind of environment-protection electroplating filter
CN113274805A (en) * 2020-02-20 2021-08-20 林士隆 Filter module and etching solution regeneration method
CN113846371A (en) * 2021-10-28 2021-12-28 株洲岱勒新材料有限责任公司 Plating solution purification method for electroplated diamond wire saw

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205222853U (en) * 2015-12-16 2016-05-11 吴海潮 Nickel rinsing purifying water process device
CN105601000A (en) * 2015-11-18 2016-05-25 苏浩强 Acidic electroplating waste liquid purifying system
EP3165269A1 (en) * 2015-11-06 2017-05-10 Ruscho-Schotenröhr GmbH Water filter designed in the form of an outlet mouthpiece

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3165269A1 (en) * 2015-11-06 2017-05-10 Ruscho-Schotenröhr GmbH Water filter designed in the form of an outlet mouthpiece
CN105601000A (en) * 2015-11-18 2016-05-25 苏浩强 Acidic electroplating waste liquid purifying system
CN205222853U (en) * 2015-12-16 2016-05-11 吴海潮 Nickel rinsing purifying water process device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106865644A (en) * 2017-03-08 2017-06-20 王慈 A kind of environment-protection electroplating filter
CN113274805A (en) * 2020-02-20 2021-08-20 林士隆 Filter module and etching solution regeneration method
CN113846371A (en) * 2021-10-28 2021-12-28 株洲岱勒新材料有限责任公司 Plating solution purification method for electroplated diamond wire saw

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Application publication date: 20160824