CN105879574A - Buffering adjustment device for concentration load of VOCs (Volatile Organic Compounds) - Google Patents

Buffering adjustment device for concentration load of VOCs (Volatile Organic Compounds) Download PDF

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Publication number
CN105879574A
CN105879574A CN201610322291.5A CN201610322291A CN105879574A CN 105879574 A CN105879574 A CN 105879574A CN 201610322291 A CN201610322291 A CN 201610322291A CN 105879574 A CN105879574 A CN 105879574A
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China
Prior art keywords
vocs
tank body
adjusting means
concentration load
vocs concentration
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Application number
CN201610322291.5A
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Chinese (zh)
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CN105879574B (en
Inventor
李大伟
李爱民
龙超
戴建军
周庆
贾李娟
刘笑寒
何宏磊
李浩阳
李志豪
李锦阳
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Jiangsu Guochuang Enviro-Protection Technology Co Ltd
Nanjing University
Nanjing University Yancheng Environmental Protection Technology and Engineering Research Institute
Original Assignee
Jiangsu Guochuang Enviro-Protection Technology Co Ltd
Nanjing University
Nanjing University Yancheng Environmental Protection Technology and Engineering Research Institute
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407Constructional details of adsorbing systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40003Methods relating to valve switching
    • B01D2259/40005Methods relating to valve switching using rotary valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas

Abstract

The invention discloses a buffering adjustment device for the concentration load of VOCs (Volatile Organic Compounds). The buffering adjustment device is arranged at the front of the VOCs purifying treatment equipment, is in a fixed-bed one-way type, a fixed-bed two-way type and a rotary-bed type, and is filled with absorbing materials; and the absorbing material is used for carrying out buffering adjustment of 'peak clipping and valley flattening' on the concentration load of the VOCs under normal temperature and normal pressure. The buffering adjustment device disclosed by the invention has the advantages that the structure is simple, the operation is convenient, the stable operation of the following operation equipment is guaranteed, and the treating efficiency and the operation safety of the treatment process of the VOCs are improved.

Description

A kind of VOCs concentration load buffer adjusting means
Technical field
The present invention relates to organic exhaust gas (VOCs) process field, be specifically related to a kind of VOCs concentration load buffer adjusting means.
Background technology
The fast development of modern industry causes air pollution problems inherent to become increasingly conspicuous, serious harm health and ecological environment.In recent years, China's Fine Chemical quickly grows, and has become pillar industry in some areas, and the pollution problem of consequent volatile organic gas (Volatile Organic Compounds, VOCs) also becomes whole society's focus of attention.
The discharge of fine chemistry industry waste gas is closely related with the ruuning situation of process units, has the features such as complicated component, total release is big, emission equivalent is poor, exhaust gas concentration fluctuation is big.Most VOCs treatment technology all suffers from a difficult point in engineer applied, i.e. due to features such as the fluctuating margin of waste gas intermittent discharge, concentration are big, the scale for the treatment of facility is difficult to Precise spraying, and treatment effeciency is difficult to persistently be ensured, the stability of device is also affected.The fluctuation change of this waste gas concentration of emission proposes challenge to the design of processing equipment: if designing by average emission concentration, then treatment effeciency can be caused to reduce in peak period;If designing by peak concentration, cost can be greatly increased.
As a example by burning method, organic principle is destroyed ratio more thoroughly because of burner hearth high temperature by heat accumulating type oxidation furnace (RTO), and the highest to the selectivity of exhaust gas constituents, has certain advantage in numerous exhaust gas treatment technologies.But RTO system structure is the most fixing, disposal ability has its specific scope of application, when designing incinerator, needs accurate calculation to process air quantity and concentration, obtains optimization process effect.And in actual production, the dynamically change of concentration of emission brings difficulty to safety and the treatment effeciency of exhaust treatment system.If concentration of emission is beyond the load-bearing capacity of RTO, it is not only possible to discharge beyond standards, and can bring and fire potential safety hazard.If concentration of emission is too low, then can increase the consumption of auxiliary fuel, economy is had a greatly reduced quality.
The present invention solves this problem targetedly.
Summary of the invention
The technical problem to be solved is for the problem that in existing industrial waste gas Treatment process, purifier operation stability is poor, potential safety hazard is big, processing cost is high, treatment effeciency is low, it is provided that a kind of VOCs concentration load buffer adjusting means.This device, in industry VOCs master gas, has the advantage that device stability is high, potential safety hazard is little, low cost, treatment effeciency are high.
The technical problem to be solved is achieved by the following technical programs:
A kind of VOCs concentration load buffer adjusting means, the buffer regulating device being filled with adsorbing material is set before being included in VOCs purifying processing device, this buffer regulating device is fixed bed one-way fashion, fixed bed reversible, rotary hearth, wherein adsorbing material has the dynamic adsorption capacity of reversible adsorption desorption is 50-500 mg/g, when VOCs concentration is higher, adsorbing material absorption organic molecule, and when VOCs concentration is relatively low, then it is desorbed in adsorbing material, the organic substance that release is adsorbed, it is achieved VOCs concentration load is carried out the dash adjustment in " peak clipping Pinggu ";Described buffer regulating device runs at normal temperatures and pressures.
Preferably, described adsorbing material includes but not limited to fluoropolymer resin, activated carbon, activated carbon fiber, hydrophobic zeolite molecular sieve, more preferably fluoropolymer resin.
Preferably, the one during described fluoropolymer resin is selected from macroporous resin and hypercrosslinked polymeric resin or mixture.
Preferably, described VOCs purifying processing device is the one in RTO, low-temperature plasma, photooxidation, biological purification plant.More preferably RTO.
Preferably, described fixed bed one-way fashion device includes admission line, tank body, adsorbing material, outlet pipe.
Fixed bed one-way fashion device is in absorption or the detachment status comparison of depending between inlet gas concentration and adsorbance, when the saturated extent of adsorption corresponding to inlet gas concentration in adsorption isotherm is higher than the real-time adsorbance of adsorbing material, then adsorption-buffering device is in adsorbed state, otherwise is then in detachment status.
Preferably, described fixed bed reversible device includes admission line, two-way switching valve door, tank body, adsorbing material, outlet pipe.Preferably, VOCs waste gas is after admission line imports, and through two way valve, first enters tank body from left end (A end), mobile to right-hand member (B end);When being adsorbed onto to a certain degree, switching Steering valve so that organic exhaust gas enters tank body from right-hand member (B end), gas right-hand member (B end) is become clean gas by materials purification after entering, and blow to the left end (A end) adsorbing VOCs, the VOCs desorbing molecules that left end (A end) adsorbs is discharged.Whole process includes the adsorption/desorption process of linkage, can be penetrated by waste gas and control in adsorption tanks, it is to avoid waste gas uncontrolled discharge.
Preferably, the tank body of described fixed bed reversible device can include single tank or double-pot type.
Preferably, rotary hearth device be tank body rotate and valve rotary in one, wherein tank body rotate refer to tank body rotate, be not provided with changeover valve, be connected by sealing ring between tank body with pipeline, sealing ring is with tank body synchronism switching;Valve rotary finger tank body is motionless, utilizes changeover valve to realize the continuous switching of gas.
Preferably, valve is rotary by setting up a changeover valve on tank body sealing ring position, by the synchronism switching of sealing ring Yu changeover valve, it is achieved the change of tank body adsorption/desorption waste gas.The setting of changeover valve refers to the set-up mode of changeover valve in rotary RTO device.
Preferably, tank body is divided into 8-12 fan-shaped block structure and forms the adsorption chamber of respective numbers.
As a example by eight Room rotating vessel adsorbent equipments, absorption tank body is divided into 8 adsorption chambers, wherein has two adsorption chamber Dynamic Closed in rotary course, prevents waste gas from avoiding adjacent two adsorption chambers wind direction contradiction occur in same sector.First gas enter from Room 6,7,8, and through adsorption cleaning, gas enters back into Room 2,3,4 by the closing cavity of the tank body other end and discharges, and now Room the 1st, the 5th seals;After certain time, gas is switched to Room 7,8,1 and enters, and Room 3,4,5 go out, and Room the 2nd, the 6th seals.8 adsorption chambers so circulate work.By being connected with the sealing ring of two adsorption chambers sealing lids between tank body with VOCs exhaust piping.
The invention have the benefit that after have employed technique scheme
The adsorbing material under 1, the present invention uses normal temperature and pressure with higher dynamic adsorption capacity and very fast adsorption/desorption speed is seated in adjusting means, VOCs concentration load is carried out the dash adjustment in " peak clipping Pinggu ", impact to subsequent purification unit when reducing high concentration, and when low concentration, stable air-intake load is provided for subsequent cell, ensure that the stable operation of follow-up operation equipment, it is achieved the continuous operation of clean unit, improve treatment effeciency and processing safety.
2, the VOCs concentration load buffer adjusting means simple in construction that the present invention is arranged, easy to operate.
3, under the design of revolving bed, waste gas is adsorption cleaning in leading portion adsorbent bed, and clean gas carries out desorption release through closing the cavity entrance back segment adsorbent bed VOCs to wherein adsorbing;Revolving bed device can obtain, than fixed bed reversible device, the discharge gas that concentration is more stable.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, the accompanying drawing used required in embodiment or description of the prior art will be briefly described below, apparently, accompanying drawing in describing below is only some embodiments of the present invention, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is assembly of the invention layout drawing.
Fig. 2 is fixed bed one-way fashion buffer regulating device.
Fig. 3 is single tank fixed bed reversible buffer regulating device.
Fig. 4 is 8 sector tank body rotary buffer regulating device schematic diagram.
Fig. 5 is the 8 rotary buffer regulating devices of sector valve.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
Embodiment 1
Process unit used is as shown in Figure 1, wherein buffer regulating device is fixed bed one-way fashion buffer regulating device shown in Fig. 2, purifying processing device is RTO, adsorbing material is activated carbon, the dynamic adsorption capacity of its reversible adsorption desorption is 100mg/g, buffer regulating device runs at normal temperature and pressure, and in VOCs waste gas, VOCs concentration is at 500-10000mg/m3In the range of fluctuate, the concentration after this VOCs waste gas buffered regulation processing means is 3000-7000mg/m3, the stable operation of RTO does not occurs that abnormal conditions, RTO discharge gas all meet environmental requirement for 48 hours.
In addition to casting out buffer regulating device, other operation is identical with aforesaid operations condition, occurs abnormal after RTO runs 10 hours, and RTO discharge gas does not meets environmental requirement.
Embodiment 2
Process unit used is as shown in Figure 1, wherein buffer regulating device is single tank fixed bed reversible buffer regulating device shown in Fig. 3, purifying processing device is RTO, adsorbing material is macroporous resin, the dynamic adsorption capacity of its reversible adsorption desorption is 135mg/g, buffer regulating device runs at normal temperature and pressure, and in VOCs waste gas, VOCs concentration is at 500-10000mg/m3In the range of fluctuate, VOCs waste gas is after admission line imports, and through two way valve, first enters tank body from A end, moves to B end;When being adsorbed onto to a certain degree, switching Steering valve so that organic exhaust gas enters tank body from B end, gas right-hand member B end is adsorbed materials purification after entering and becomes clean gas, and blows to the A end adsorbing VOCs, is discharged by the VOCs desorbing molecules that A end adsorbs.
Concentration after this VOCs waste gas buffered regulation processing means is 4000-6000mg/m3, the stable operation of RTO does not occurs that abnormal conditions, RTO discharge gas all meet environmental requirement for 80 hours.
In addition to casting out buffer regulating device, other operation is identical with aforesaid operations condition, occurs abnormal after RTO runs 10 hours, and RTO discharge gas does not meets environmental requirement.
Embodiment 3
Process unit used is as shown in Figure 1, wherein buffer regulating device is the 8 rotary buffer regulating device of sector valve shown in Fig. 4, purifying processing device is RTO, adsorbing material is hypercrosslinked polymeric resin, the dynamic adsorption capacity of its reversible adsorption desorption is 150mg/g, buffer regulating device runs at normal temperature and pressure, and in VOCs waste gas, VOCs concentration is at 500-10000mg/m3In the range of fluctuate, first VOCs waste gas enter from Room 6,7,8, and through adsorption cleaning, gas enters back into Room 2,3,4 by the closing cavity of the tank body other end and discharges, now the 1st, the 5th Room sealing;After certain time, gas is switched to Room 7,8,1 and enters, and Room 3,4,5 go out, and Room the 2nd, the 6th seals.8 adsorption chambers so circulate work.By being connected with the sealing ring of two adsorption chambers sealing lids between tank body with VOCs exhaust piping.Concentration after this VOCs waste gas buffered regulation processing means is 4500-5500mg/m3, the stable operation of RTO does not occurs that abnormal conditions, RTO discharge gas all meet environmental requirement for 96 hours.
In addition to casting out buffer regulating device, other operation is identical with aforesaid operations condition, occurs abnormal after RTO runs 10 hours, and RTO discharge gas does not meets environmental requirement.
Embodiment described above only have expressed embodiments of the present invention; it describes more concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme using the form of equivalent or equivalent transformation to be obtained, all should fall within the scope and spirit of the invention.

Claims (10)

1. a VOCs concentration load buffer adjusting means, the buffer regulating device being filled with adsorbing material is set before being included in VOCs purifying processing device, described buffer regulating device is fixed bed one-way fashion, fixed bed reversible, rotary hearth, it is 50-500 mg/g that described adsorbing material has the dynamic adsorption capacity of reversible adsorption desorption, when VOCs concentration is higher, adsorbing material absorption organic molecule, and when VOCs concentration is relatively low, then it is desorbed in adsorbing material, the organic substance that release is adsorbed, realize VOCs concentration load is carried out the dash adjustment in " peak clipping Pinggu ";Described buffer regulating device runs at normal temperatures and pressures.
VOCs concentration load buffer adjusting means the most according to claim 1, it is characterised in that one or more in fluoropolymer resin, activated carbon, NACF, hydrophobic zeolite molecular sieve of adsorbing material.
VOCs concentration load buffer adjusting means the most according to claim 2, it is characterised in that adsorbing material bag is a kind of in fluoropolymer resin, preferably macroporous resin and hypercrosslinked polymeric resin or both mixture.
VOCs concentration load buffer adjusting means the most according to claim 1, it is characterised in that fixed bed one-way fashion device includes admission line, tank body, adsorbing material, outlet pipe.
VOCs concentration load buffer adjusting means the most according to claim 1, it is characterised in that fixed bed reversible device includes admission line, two-way switching valve door, tank body, adsorbing material, outlet pipe.
VOCs concentration load buffer adjusting means the most according to claim 5, it is characterised in that VOCs waste gas is after the admission line of fixed bed reversible device imports, through two way valve, first enters tank body from A end, moves to B end;When being adsorbed onto to a certain degree, switching Steering valve so that organic exhaust gas enters tank body from B end, gas adsorbed materials purification after B end enters becomes clean gas, and blows to the A end adsorbing VOCs, is discharged by the VOCs desorbing molecules that A end adsorbs.
VOCs concentration load buffer adjusting means the most according to claim 5, it is characterised in that the tank body of fixed bed reversible device is single tank or double-pot type.
VOCs concentration load buffer adjusting means the most according to claim 1, it is characterized in that rotary hearth device be tank body rotate and valve rotary in one, wherein tank body rotates and refers to that tank body is rotating, it is not provided with changeover valve, being connected by sealing ring between tank body with pipeline, sealing ring is with tank body synchronism switching;Valve rotary finger tank body is motionless, utilizes changeover valve to realize the continuous switching of gas.
VOCs concentration load buffer adjusting means the most according to claim 8, it is characterised in that valve is rotary is by setting up a changeover valve, by the switching of changeover valve between tank body and turnover feed channel, it is achieved the consecutive variations of tank body adsorption/desorption waste gas.
VOCs concentration load buffer adjusting means the most according to claim 8, it is characterised in that described VOCs purifying processing device is the one in RTO, low-temperature plasma, photooxidation, biological purification plant.
CN201610322291.5A 2016-05-16 2016-05-16 A kind of VOCs concentration load buffer regulating device Active CN105879574B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106693642A (en) * 2017-03-09 2017-05-24 上海兰宝环保科技有限公司 Organic waste gas treatment system under working condition of waste gas concentration fluctuation
CN106823776A (en) * 2017-03-03 2017-06-13 北京工业大学 A kind of biological drop of the improvement chemical fibre stench of anti-clogging considers apparatus and method
CN110090528A (en) * 2019-06-04 2019-08-06 江苏大信环境科技有限公司 De- recyclable device is inhaled in rotation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6319484B1 (en) * 1999-12-14 2001-11-20 Engelhard Corporation Compositions for abatement of volatile organic compounds and apparatus and methods using the same
CN101137425A (en) * 2005-01-13 2008-03-05 开利公司 Gas treatment adsorption-oxidation system
JP2010201282A (en) * 2009-02-27 2010-09-16 Nippon Refine Kk Method and apparatus for recovering volatile organic compound
CN102350204A (en) * 2011-10-17 2012-02-15 沈阳环境科学研究院 Modular absorbing and purifying device for volatile organic waste gases
CN204093281U (en) * 2014-06-04 2015-01-14 杭州电子科技大学 A kind of VOCs waste gas treatment device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6319484B1 (en) * 1999-12-14 2001-11-20 Engelhard Corporation Compositions for abatement of volatile organic compounds and apparatus and methods using the same
CN101137425A (en) * 2005-01-13 2008-03-05 开利公司 Gas treatment adsorption-oxidation system
JP2010201282A (en) * 2009-02-27 2010-09-16 Nippon Refine Kk Method and apparatus for recovering volatile organic compound
CN102350204A (en) * 2011-10-17 2012-02-15 沈阳环境科学研究院 Modular absorbing and purifying device for volatile organic waste gases
CN204093281U (en) * 2014-06-04 2015-01-14 杭州电子科技大学 A kind of VOCs waste gas treatment device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106823776A (en) * 2017-03-03 2017-06-13 北京工业大学 A kind of biological drop of the improvement chemical fibre stench of anti-clogging considers apparatus and method
CN106693642A (en) * 2017-03-09 2017-05-24 上海兰宝环保科技有限公司 Organic waste gas treatment system under working condition of waste gas concentration fluctuation
CN106693642B (en) * 2017-03-09 2022-12-06 上海兰宝环保科技有限公司 Organic waste gas treatment system under waste gas concentration fluctuation working condition
CN110090528A (en) * 2019-06-04 2019-08-06 江苏大信环境科技有限公司 De- recyclable device is inhaled in rotation

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