CN105866876B - A kind of preparation method of polarizing layer, display base plate component, display panel - Google Patents

A kind of preparation method of polarizing layer, display base plate component, display panel Download PDF

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Publication number
CN105866876B
CN105866876B CN201610422764.9A CN201610422764A CN105866876B CN 105866876 B CN105866876 B CN 105866876B CN 201610422764 A CN201610422764 A CN 201610422764A CN 105866876 B CN105866876 B CN 105866876B
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CN
China
Prior art keywords
polarizing layer
base plate
substrate
metal
display base
Prior art date
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Expired - Fee Related
Application number
CN201610422764.9A
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Chinese (zh)
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CN105866876A (en
Inventor
白冰
刘晓锋
孙含嫣
李晓虎
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BOE Technology Group Co Ltd
Beijing BOE Display Technology Co Ltd
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BOE Technology Group Co Ltd
Beijing BOE Display Technology Co Ltd
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Priority to CN201610422764.9A priority Critical patent/CN105866876B/en
Publication of CN105866876A publication Critical patent/CN105866876A/en
Application granted granted Critical
Publication of CN105866876B publication Critical patent/CN105866876B/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3058Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state comprising electrically conductive elements, e.g. wire grids, conductive particles
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • G02F1/133548Wire-grid polarisers

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)

Abstract

The present invention provides a kind of preparation method of polarizing layer, display base plate component, display panel, belongs to display technology field, its can solve existing metal type polarization piece prepare it is difficult, and the problem of display interior can not be accomplished.The present invention using biotechnology prepares metal type polarization layer, using the magnetotactic bacteria adsorbing metal ions on substrate and is allowed to reduction and forms metal simple-substance, metal simple-substance is formed the array of metal lines with polarizing axis, obtain metal type polarization layer.Wherein, not only preparation technology is simple for this method, and cost is low, and unsanctioned light back into backlight source can be changed and put into polarizing layer again after the polarization angle of light and realize blast by its metal type polarization layer for preparing.The display base plate component of the present invention can be formed on built-in polarizing layer as stated above, the display base plate component is applied to various display panels directly using color membrane substrates or array base palte as substrate.

Description

A kind of preparation method of polarizing layer, display base plate component, display panel
Technical field
The invention belongs to display technology field, and in particular to a kind of preparation method of polarizing layer, display base plate component, display Panel.
Background technology
Currently used light polarizing film is generally macromolecule dichroic type, its with macromolecule membrane such as polyvinyl alcohol (PVA, Polyvinyl acetate) it is used as polarization matrix, two colors such as absorption iodine system (Iodine Type) or dyestuff system (Dye Type) Property material, iodide ion or dyestuff spread, penetrated into internal layer PVA, low-grade fever stretching PVA film is formed after alkali process.
Inventor has found that at least there are the following problems in the prior art:Existing light polarizing film is used to have strongly when big visual angle is shown Light leak, it is necessary to arrange in pairs or groups view film to reach high contrast effect;Its weatherability is bad, good mechanical property, needs outer pasting protective film To strengthen mechanical performance;It can only be affixed on outside display use outside.
The research of metal type polarization piece is long-standing, and the degree of polarization of metal type polarization film is about 99%, and penetration is about 44.49% or so, at the same time, the light back into backlight source that metal type polarization piece will can not thrown, change polarization angle Input polaroid realizes blast again afterwards, but prepares difficulty, and can not be accomplished display interior in the prior art.
The content of the invention
The present invention prepared for existing metal type polarization piece it is difficult, and the problem of display interior can not be accomplished, A kind of preparation method of polarizing layer, display base plate component, display panel are provided.
Technical scheme is used by solving present invention problem:
A kind of preparation method of polarizing layer, comprises the following steps:
The substrate being pointed in magnetotactic bacteria solution applies magnetic field, so that magnetotactic bacteria is arranged on substrate;
Metal ion is introduced into the solution, so that magnetotactic bacteria adsorbing metal ions on substrate and by metal ion It is reduced into metal simple-substance;
The part metal simple-substance is removed by photoetching process, so as to form the metallic wire array with polarizing axis on substrate Row.
Preferably, the substrate is made up of polyvinyl alcohol or glass.
Preferably, the substrate is color membrane substrates or array base palte.
Preferably, the concentration of magnetotactic bacteria is 2-6g/L in the solution of the magnetotactic bacteria.
Preferably, it is that the magnetotactic bacteria adds the molten of soluble metallic salt that the magnetotactic bacteria, which introduces metal ion, Liquid, the pH value of the soluble metal solution is 1-5.
Preferably, the soluble metallic salt is golden soluble-salt.
Preferably, the soluble metal metal ion in solution concentration is 20-80mg/L.
The present invention also provides a kind of display base plate component, including display base plate, and shown display base plate is provided with polarizing layer, institute It is the polarizing layer being formed on as stated above using display base plate as substrate to state polarizing layer.
Preferably, it is additionally provided with protective layer on the polarizing layer.
The present invention also provides a kind of display panel, including two the polarizing layer to the display base plate of box and on substrate, Wherein at least one display base plate and polarizing layer thereon are above-mentioned display base plate component.
Preferably, the polarizing layer is formed in display base plate close to the side of another display base plate.
The present invention prepares metal type polarization layer using biotechnology, using the magnetotactic bacteria adsorbing metal ions on substrate simultaneously It is allowed to reduction and forms metal simple-substance, then makes to form the array of metal lines with polarizing axis on substrate, obtain metal type polarization layer. Wherein, not only preparation technology is simple for this method, and cost is low, and its metal type polarization layer prepared can be anti-by unsanctioned light Backlight is emitted back towards, is changed and is put into polarizing layer again after the polarization angle of light and realize blast.The display base plate component of the present invention can Directly using color membrane substrates or array base palte as substrate, to be formed on built-in polarizing layer as stated above, the display base plate Component is applied to various display panels.
Brief description of the drawings
Fig. 1 is the preparation method flow chart of the polarizing layer of embodiments of the invention 1;
Fig. 2-4 is the structural representation of the polarizing layer of embodiments of the invention 2;
Fig. 5 is the structural representation of the display base plate component of embodiments of the invention 3;
Fig. 6-7 is the structural representation of the display panel of embodiments of the invention 4;
Fig. 8-9 be embodiments of the invention 2 polarizing layer in make magnetotactic bacteria wire arrange prepare schematic diagram;
Wherein, reference is:10th, polarizing layer;1st, substrate;2nd, magnetotactic bacteria;21st, photoresist;22nd, mask plate;3rd, it is golden Belong to simple substance;5th, protective layer;6th, display base plate;61st, array base palte;62nd, color membrane substrates.
Embodiment
To make those skilled in the art more fully understand technical scheme, below in conjunction with the accompanying drawings and specific embodiment party Formula is described in further detail to the present invention.
Embodiment 1:
The present embodiment provides a kind of preparation method of polarizing layer, as shown in figure 1, comprising the following steps:
S01, the substrate being pointed in magnetotactic bacteria solution apply magnetic field, so that magnetotactic bacteria is arranged on substrate;
S02, metal ion is introduced into the solution, so that magnetotactic bacteria adsorbing metal ions on substrate and by metal Ion reduction is into metal simple-substance;
S03, by photoetching process remove the part metal simple-substance so that on substrate formed with polarizing axis metal wire Array.
The present embodiment prepares metal type polarization layer using biotechnology, and its preparation technology is simple, and cost is low, prepared by this method Metal type polarization layer unsanctioned light back into backlight source can be put into polarisation again after changing the polarization angle of light Layer realizes blast, strengthens the utilization rate of light energy.
Embodiment 2:
The present embodiment provides a kind of preparation method of polarizing layer, as Figure 1-4, comprises the following steps:
S01, the substrate 1 being pointed in the solution of magnetotactic bacteria 2 apply magnetic field, so that the arrangement of magnetotactic bacteria 2 is formed at substrate 1 On, now entirely it has been covered with magnetotactic bacteria 2 on the surface of substrate 1;Wherein, magnetotactic bacteria 2 (Magnetotactic bacterium) Refer to the bacterium that can make directed movement in the presence of external magnetic field and form nano magnetic particle magnetic corpusculum in vivo.
Preferably, the concentration of magnetotactic bacteria 2 is 2-6g/L in the solution of the magnetotactic bacteria 2.
That is, when the concentration of magnetotactic bacteria 2 is 2-6g/L, substrate 1 is very fast to the adsorption rate of magnetotactic bacteria 2, inhales Attached rate is higher.
Preferably, the substrate 1 is made up of polyvinyl alcohol or glass.
Preferably, the substrate 1 is color membrane substrates or array base palte.
That is, above-mentioned substrate 1 can be polyvinyl alcohol or glass material, can also be with color membrane substrates or array Substrate forms polarizing layer directly over as substrate 1.
S02, metal ion is introduced into above-mentioned solution, so that magnetotactic bacteria 2 absorbs metal ion and as shown in Figure 3 by gold Belong to ion reduction and form metal simple-substance 3;Wherein, above-mentioned introducing metal ion can add metal salt solution, can also be direct Add metal salt.The present embodiment is illustrated exemplified by adding metal salt solution solution.
Preferably, the introducing metal ion is to add soluble metal solution, the pH of the soluble metal solution It is worth for 1-5.
That is, the speed that the pH value of soluble metal solution absorbs metal ion on magnetotactic bacteria 2 influences to increase, pH It is too big, it is easily caused the precipitation that metal ion forms the hydroxide of metal.
Preferably, the soluble metal solution is the solution of golden (Au).
Wherein, above-mentioned metal ion has very strong compatibility with the nitrogen in the thalline of magnetotactic bacteria 2, sulphur, and the two can occur Redox reaction, generate stable metallic atom.
Preferably, the soluble metal metal ion in solution concentration is 20-80mg/L.
That is, soluble metal metal ion in solution concentration is too low, to be easily caused the uptake of magnetotactic bacteria 2 low.
S03, by photoetching process remove the part metal simple-substance so that on substrate 1 formed with polarizing axis metal Linear array.
Wherein, then the present embodiment removes substrate top as shown in figure 8, first make whole magnetotactic bacteria adsorbing metals again Divide magnetotactic bacteria, arrange remaining magnetotactic bacteria and metal linear.It is understood that can be with as shown in figure 9, first removing Substrate upper part magnetotactic bacteria, make remaining magnetotactic bacteria linear array, then make the magnetotactic bacteria ADSORPTION OF GOLD of the linear alignment again Category forms the array of metal lines with polarizing axis.
Specifically, the part metal simple-substance 3 is removed by photoetching process, as shown in figure 8, first on the surface of metal simple-substance 3 One layer of photoresist 21 is coated, by setting mask plate 22, part photoresist 21 is removed so that the photoresist 21 left is in wire Arrangement, metal simple-substance 3 below is protected equivalent to the photoresist 21 left, and remove the metal simple-substance of the position of photoresist 21 3 are removed magnetotactic bacteria 2 and the metal simple-substance adsorbed with magnetotactic bacteria 23 by way of inactivating magnetotactic bacteria 2 in the lump.
Preferably, the inactivation of magnetotactic bacteria 2 is made to include in the following manner:Heat the solution of the magnetotactic bacteria 2 or to described Any one in strong acid, highly basic, the catabolic enzyme of magnetotactic bacteria 2 is added in the solution of magnetotactic bacteria 2.
That is so that the part magnetotactic bacteria 2 on substrate 1 loses activity, so that the orientated deposition of metal simple-substance 3 The linear alignment is on substrate 1.Wherein so that the mode that magnetotactic bacteria 2 on substrate 1 inactivates has a variety of, makes it by heat inactivation, or Change the acid-base value of solution, or decomposed.
The present embodiment prepares metal type polarization layer using biotechnology, and its preparation technology is simple, and cost is low, prepared by this method Metal type polarization layer unsanctioned light back into backlight source can be put into polarisation again after changing the polarization angle of light Layer realizes blast, strengthens the utilization rate of light energy.
Embodiment 3:
The present embodiment provides a kind of component of display base plate 6, as shown in figure 5, including display base plate 6, on the display base plate 6 The polarizing layer 10 being formed on provided with the method by above-described embodiment with display base plate 6 for substrate.
Preferably, it is additionally provided with protective layer 5 on the polarizing layer 10.
Embodiment 4:
The present embodiment provides a kind of display panel, including two the polarizing layer to the display base plate of box and on substrate, Wherein at least one display base plate and the display base plate that the polarizing layer on substrate is above-described embodiment.
Preferably, the polarizing layer is formed in display base plate close to the side of another display base plate.
Wherein, as shown in Figure 6, Figure 7, display base plate can be color membrane substrates 62 or array base palte 61.That is, directly Polarizing layer 10 is formed on color membrane substrates 62 or array base palte 61.Specifically, by taking array base palte 61 as an example, the one of array base palte 61 Formed with TFT structure on face, because the polarizing layer 10 is relatively thin, polarizing layer 10 can be formed on the another side of array base palte 61, It can also be formed on face of the array base palte 61 formed with TFT structure, i.e., as shown in fig. 7, polarizing layer 10 can be formed at liquid crystal The inside of box, equivalent to built in polarizing layer 10.
It is understood that the polarizing layer 10 but is individually adopted not with array base palte 61 or the common substrate 1 of color membrane substrates 62 With a substrate 1, it is bonded to after being made on array base palte 61 or color membrane substrates 62 and feasible.
Obviously, also many modifications may be made to for the embodiment of the various embodiments described above;Such as:Polarizing layer is formed with being formed TFT sequencing can be according to circumstances adjusted.
Embodiment 5:
A kind of display device is present embodiments provided, it includes any one above-mentioned display panel.The display device can Think:Liquid crystal display panel, Electronic Paper, mobile phone, tablet personal computer, television set, display, notebook computer, DPF, navigation Any product or part with display function such as instrument.
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present and the exemplary implementation that uses Mode, but the invention is not limited in this.For those skilled in the art, the essence of the present invention is not being departed from In the case of refreshing and essence, various changes and modifications can be made therein, and these variations and modifications are also considered as protection scope of the present invention.

Claims (11)

1. a kind of preparation method of polarizing layer, it is characterised in that comprise the following steps:
The substrate being pointed in magnetotactic bacteria solution applies magnetic field, so that magnetotactic bacteria is arranged on substrate;
Metal ion is introduced into the solution, so as to the magnetotactic bacteria adsorbing metal ions on substrate and reduce metal ion Into metal simple-substance;
The part metal simple-substance is removed by photoetching process, so as to form the array of metal lines with polarizing axis on substrate.
2. the preparation method of polarizing layer according to claim 1, it is characterised in that the substrate is by polyvinyl alcohol or glass Form.
3. the preparation method of polarizing layer according to claim 1, it is characterised in that the substrate is color membrane substrates or array Substrate.
4. the preparation method of polarizing layer according to claim 1, it is characterised in that magnetotactic in the solution of the magnetotactic bacteria The concentration of bacterium is 2-6g/L.
5. the preparation method of polarizing layer according to claim 1, it is characterised in that described to introduce gold to the magnetotactic bacteria Category ion is the solution that soluble metallic salt is added to the magnetotactic bacteria, and the pH value of the solution of the soluble metallic salt is 1- 5。
6. the preparation method of polarizing layer according to claim 5, it is characterised in that the soluble metallic salt can for gold Soluble.
7. the preparation method of polarizing layer according to claim 6, it is characterised in that the soluble metal GOLD FROM PLATING SOLUTION category Ion concentration is 20-80mg/L.
8. a kind of display base plate component, including display base plate, the display base plate is provided with polarizing layer, it is characterised in that described Polarizing layer is the polarizing layer being formed on by any one of claim 1-7 methods described using display base plate as substrate.
9. display base plate component according to claim 8, it is characterised in that be additionally provided with protective layer on the polarizing layer.
10. a kind of display panel, including two the polarizing layer to the display base plate of box and on substrate, it is characterised in that its In at least one display base plate and polarizing layer thereon be the display base plate component described in claim 8.
11. display panel according to claim 10, it is characterised in that the polarizing layer is formed in display base plate close to another The side of one display base plate.
CN201610422764.9A 2016-06-14 2016-06-14 A kind of preparation method of polarizing layer, display base plate component, display panel Expired - Fee Related CN105866876B (en)

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CN110415610A (en) * 2019-07-22 2019-11-05 安徽华米信息科技有限公司 Display panel and its manufacturing method, display device

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1825146A (en) * 2005-02-21 2006-08-30 精工爱普生株式会社 Method for manufacturing optical element
CN1979231A (en) * 2005-11-30 2007-06-13 达信科技股份有限公司 Method for making polarizing lens

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI509279B (en) * 2012-03-28 2015-11-21 Sony Corp An optical element and a method for manufacturing the same, an optical system, an image pickup device, an optical device, and a master disk

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1825146A (en) * 2005-02-21 2006-08-30 精工爱普生株式会社 Method for manufacturing optical element
CN1979231A (en) * 2005-11-30 2007-06-13 达信科技股份有限公司 Method for making polarizing lens

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Granted publication date: 20180316