CN105860917A - Novel hot-melt adhesive and preparation method thereof - Google Patents
Novel hot-melt adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN105860917A CN105860917A CN201610273342.XA CN201610273342A CN105860917A CN 105860917 A CN105860917 A CN 105860917A CN 201610273342 A CN201610273342 A CN 201610273342A CN 105860917 A CN105860917 A CN 105860917A
- Authority
- CN
- China
- Prior art keywords
- melt adhesive
- epoxy
- new type
- type hot
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a novel hot-melt adhesive and a preparation method thereof, particularly a novel hot-melt adhesive suitable for bonding and compounding metals and ABS (acrylonitrile-butadiene-styrene) plastics and a preparation method thereof. The invention is mainly characterized in that the novel hot-melt adhesive comprises the following raw materials in percentage by mass: 45-50% of nylon type copolyamide, 34-37% of thermoplastic polyurethane, 0.3-1% of epoxy compatilizer, 10-15% of tackifier, 1-5% of filler and 0.1-0.3% of antioxidant. The preparation method comprises the following steps: selecting raw materials according to specific percents, carrying out polymerization reaction to form the nylon type copolyamide with favorable bonding properties for metals, and proportionally carrying out blend melting and extrusion on the nylon type copolyamide, thermoplastic polyurethane and the other auxiliary materials under the synergistic action of the specific compatilizer, thereby obtaining the novel hot-melt adhesive with favorable bonding properties for metals and ABS plastics. The product disclosed by the invention satisfies the demands, is simple in technique, and is convenient for industrial production and application.
Description
Technical field
The present invention relates to a kind of new type hot-melt adhesive and preparation method thereof, particularly one is suitable to the metal material such as aluminum, rustless steel
Expect compound new type hot-melt adhesive bonding with ABS plastic and preparation method thereof.
Background technology
ABS resin is one of five big synthetic resin, its impact resistance, thermostability, lower temperature resistance, chemical proofing and electricity
Gas function admirable, also has the features such as easily processing, product size is stable, lustrous surface property is good, easy application, coloring, it is also possible to
Carry out surface metallization, electroplate, weld, hot pressing and the secondary operations such as bonding, be widely used in machinery, automobile, electronic apparatus,
Instrument and meter, weave and the industrial circle such as building, be the thermoplastic engineering plastic that a kind of purposes is the widest.The bonding of ABS plastic is asked
Topic is a very important problem, and the glue that market is sold has following several: G-977 is based on polyvinyl
One-component solvent-based adhesive, high-low temperature resistant, different viscosities adhering speed solidifies complete to several h in several seconds；KD-833 ternary second
Third adhesive tape instant drying adhesive water, can several seconds or several tens of seconds quick-binding, but glue-line is the most crisp, is weak to more than 60 degree hot-water soaks；
QN-505 bi-component glue, glue-line is soft, but resistance to elevated temperatures is poor；The single-component room temperature vulcanized glue of G-988, is elastomer after solidification
Having outstanding waterproof, shockproof binding agent, high-low temperature resistant, if 1-2mm thickness, about 10 minutes the most solid, and 5-6h is the most solid
Change, have certain intensity, if being fully cured, need at least 24h.
But seldom have and study its cementation with metal, preferably process for material and actual application, sometimes need
Plastics and metal material combined, also the adhesion of bi-material to be had higher requirement simultaneously.Yet with
Metal and the difference of frosting, it is insecure that the adhesive of use one-component bonds, and adhesion strength is the highest, it is easy to relatively
Pullled out under little external force.In order to improve the adhesion strength of metal and ABS plastic, in the urgent need to a kind of novel plastics-gold
Belong to binding agent.
Summary of the invention
It is an object of the invention to solve above-mentioned technical problem, it is provided that a kind of new type hot-melt adhesive and preparation method thereof so that
The new type hot-melt adhesive drawn is prepared, it is possible to meet the compound sticking requirement of metal and ABS plastic by the present invention.
The technical solution adopted in the present invention is: a kind of new type hot-melt adhesive, and its raw material is constituted, by mass percentage and, bag
Include: nylon type copolyamide 45% ~ 50%, thermoplastic polyurethane 34% ~ 37%, compatilizer 0.3% ~ 1%, viscosifier 10% ~ 15%, filler
1% ~ 5%, and antioxidant 0.1%-0.3%.
Above-mentioned nylon type copolyamide by caprolactam, nylon salt and three kinds of primary raw materials of NYLON610 salt appropriate
It is polymerized under water and end-capping reagent stearic acid effect, and the molar percentage of described three kinds of primary raw materials is respectively 28% ~ 32%,
23% ~ 28% and 42% ~ 48%；Described stearic acid and the mol ratio 1 ~ 1.2:100 of described three kinds of primary raw material sums.
The fusing point of above-mentioned thermoplastic polyurethane is 80 DEG C ~ 100 DEG C, and melt index is 40 ~ 45g/10min/2.16kg/190
℃；
Above-mentioned compatilizer is polyethylene terminal epoxy wax or epoxy-functional polyolefins elastomer, and the ring of polyethylene terminal epoxy wax
Oxygen degree of functionality is 0.75 ~ 1, and the epoxy functionalities of epoxy-functional polyolefins elastomer is 1 ~ 1.5.
Above-mentioned viscosifier one in rosin resin, terpene resin, phenolic resin or hydrogenated petroleum resin；
Above-mentioned filler is selected from as the one in Pulvis Talci, White Carbon black, kaolin powder；
Above-mentioned antioxidant selected from antioxidant 1010 (four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester) or
One in antioxidant BHT (2,6-di-tert-butyl methyl phenol).
When preparing this new type hot-melt adhesive, specifically comprise the following steps that
(1) first, prepare nylon type copolyamide, with reference to the proportioning raw materials of above-mentioned nylon type copolyamide, weigh 28% ~ 32%
Three kinds of primary raw materials of the NYLON610 salt of caprolactam, the nylon salt of 23% ~ 28% and 42% ~ 48%, and appropriate stearic acid and
Water, is put in reactor, first leads to the air that nitrogen evacuation eliminates in reactor, is re-filled with high pure nitrogen unlatching and stirs
Mix, be to slowly warm up to 250 DEG C, insulation reaction 2h under 1.8MPa pressure, the most slowly it is decompressed to normal pressure, and continues to be decompressed to
0.05MPa is dehydrated 1h, then blowing and get final product；
(2) secondly, by mass percentage, weigh above-mentioned nylon type copolyamide 45% ~ 50%, thermoplastic polyurethane 34% ~ 37%,
Compatilizer 0.3% ~ 1%, viscosifier 10% ~ 15%, filler 1% ~ 5%, and antioxidant 0.1% ~ 0.3%, put into mixed at high speed
Mix homogeneously in machine；
(3) by the material after above-mentioned mix homogeneously, put in screw extruder, blended melted after extrude, obtain Novel hot
Melten gel.
The visual demand of this new type hot-melt adhesive makes powdery, granular, strip, glued membrane shape or retinitis etc., for convenience of metal with
The bonding composite industrial of ABS plastic is applied, and this new type hot-melt adhesive is preferably made glued membrane shape or retinitis.
When needing to make glued membrane shape, with this new type hot-melt adhesive above-mentioned as raw material, by casting machine or hot melt after being melted
Coating apparatus is coated can be prepared by；The preferred 0.1mm of thickness of this new-type heat-melting glued membrane.
When needing to make retinitis, with this new type hot-melt adhesive above-mentioned as raw material, directly by melt-out spinning web-forming equipment i.e.
Can prepare.
Beneficial effects of the present invention, first passes through design specified raw material and proportioning, and polymerization forms nylon type copolyamide, then
By its with thermoplastic polyurethane under the synergism of specific compatilizer, extrude, i.e. after other adjuvants blended melting in proportion
Metal and ABS plastic all must there be is the new type hot-melt adhesive of good bonding performance.Meanwhile, also one layer can be made in conjunction with actual demand
Can the hot melt adhesive film of direct combination metal and ABS plastic or hot-melt adhesive film, be suitable to commercial production and application；Further, by mistake
Metal, at 100 DEG C, is combined by hot pressing with ABS plastic under the conditions of 30s, can obtain by the new type hot-melt adhesive prepared by the present invention
Obtaining preferable bond effect, adhesion strength is big, and bond effect is lasting, and hot pressing temperature is relatively low, and the time is short, is not result in ABS plastic
Deformation.
Detailed description of the invention
Below by embodiment, the present invention is addressed further under, but is not limited thereto.
Embodiment 1
Prepare nylon type copolyamide: by 113.16g caprolactam (1mol), 224.87g nylon salt (0.857mol),
545.14g NYLON610 salt (1.714mol), 10.16g stearic acid (0.0357mol) and 100g deionized water, join a band
Have in agitator, thermometer and manometric 2L autoclave；After having fed intake, with nitrogen displacement evacuation, eliminate anti-
Answer the air in still；Being then charged with the high pure nitrogen of 0.2MPa, heating is slowly ramped to 250 DEG C, under the pressure of 1.8MPa, protects
Temperature reaction 2h, is slowly decompressed to normal pressure, and after continuing to be decompressed to 0.05MPa dehydration 1h；Then blowing i.e. obtains nylon type copolymerization acyl
Amine (PA-1).
Preparation NEW TYPE OF COMPOSITE PUR, by 450g nylon type copolyamide (PA-1), 350g thermoplastic polyurethane, (fusing point is
100 DEG C, melt index is 40g/10min/2.16kg/190 DEG C), 3g polyethylene terminal epoxy wax (epoxy functionalities is 0.75),
150g Colophonium, 45g Pulvis Talci, 2g antioxidant 1010 puts into mix homogeneously in high-speed mixer；Mixed material is put into double
In screw extruder, extrude after melting, obtain this new type hot-melt adhesive.
This new type hot-melt adhesive sample is labeled as A1.
Embodiment 2
Prepare nylon type copolyamide: by 121.24g caprolactam (1.071mol), 262.35g nylon salt (1mol), 477g
NYLON610 salt (1.5mol), 10.16g stearic acid (0.0357mol) and 100g deionized water, join one with agitator,
In thermometer and manometric 2L autoclave；After having fed intake, with nitrogen displacement evacuation, eliminate the sky in reactor
Gas；Being then charged with the high pure nitrogen of 0.2MPa, heating is slowly ramped to 250 DEG C, under the pressure of 1.8MPa, and insulation reaction 2h,
Slowly it is decompressed to normal pressure, and after continuing to be decompressed to 0.05MPa dehydration 1h；Blowing pelletizing obtains granular nylon type copolyamide
(PA-2)。
Prepare new type hot-melt adhesive: (fusing point is 80 DEG C, molten by 480g dimer acid type copolyamide, 370g thermoplastic polyurethane
Melt index and be 45g/10min/2.16kg/190 DEG C), 7g polyethylene terminal epoxy wax (epoxy functionalities is 1), 132g terpenes tree
Fat, 10g Kaolin, 1g antioxidant BHT, put into high-speed mixer mix homogeneously；The material mixed is put into the double spiral shell of TE35
In bar extruder, extrude after blended melting, obtain this new type hot-melt adhesive.
This new type hot-melt adhesive sample is labeled as A2.
Embodiment 3
Prepare nylon type copolyamide: by 117.2g caprolactam (1.036mol), 215.5g nylon salt (0.821mol),
545.14g NYLON610 salt (1.714mol), 11.18g stearic acid (0.0393mol) and 100g deionized water, join a band
Have in agitator, thermometer and manometric 2L autoclave；After having fed intake, with nitrogen displacement evacuation, eliminate anti-
Answer the air in still；Being then charged with the high pure nitrogen of 0.2MPa, heating is slowly ramped to 250 DEG C, under the pressure of 1.8MPa, protects
Temperature reaction 2h, is slowly decompressed to normal pressure, and after continuing to be decompressed to 0.05MPa dehydration 1h；Blowing pelletizing obtains granular nylon type
Copolyamide (PA-3).
Prepare new type hot-melt adhesive: (fusing point is 88 DEG C, molten by 500g dimer acid type copolyamide, 340g thermoplastic polyurethane
Melt index and be 42g/10min/2.16kg/190 DEG C), 9g epoxy-functional polyolefins elastomer (epoxy functionalities is 1), 98g phenolic aldehyde
Resin, 50g Pulvis Talci, 3g antioxidant 1010, put into high-speed mixer mix homogeneously；Then the material mixed is put into
In TE35 double screw extruder, extrude after blended melting, obtain this new type hot-melt adhesive.
This new type hot-melt adhesive sample is labeled as A3.
Embodiment 4
Prepare nylon type copolyamide: by 129.33g caprolactam (1.143mol), 224.87g nylon salt (0.857mol),
499.71g NYLON610 salt (1.571mol), 12.19g stearic acid (0.0429mol) and 100g deionized water, join a band
Have in agitator, thermometer and manometric 2L autoclave；After having fed intake, with nitrogen displacement evacuation, eliminate anti-
Answer the air in still；Being then charged with the high pure nitrogen of 0.2MPa, heating is slowly ramped to 250 DEG C, under the pressure of 1.8MPa, protects
Temperature reaction 2h, is slowly decompressed to normal pressure, and after continuing to be decompressed to 0.05MPa dehydration 1h；Blowing pelletizing obtains granular nylon type
Copolyamide (PA-4).
Prepare new type hot-melt adhesive: (fusing point is 95 DEG C, molten by 500g dimer acid type copolyamide, 340g thermoplastic polyurethane
Melt index and be 44g/10min/2.16kg/190 DEG C), 10g epoxy-functional polyolefins elastomer (epoxy functionalities is 1.5), 100g
Hydrogenated petroleum resin, 48g white carbon, 2g antioxidant BHT, put into high-speed mixer mix homogeneously；Then the material that will mix
Put in TE35 double screw extruder, extrude after blended melting, obtain this new type hot-melt adhesive.
This new type hot-melt adhesive sample is labeled as A4.
Performance test
For convenience of metal Application of composite bonding with ABS plastic or test, by each for above-mentioned A1-A4 new type hot-melt adhesive sample, respectively
Make the new-type heat-melting glued membrane that thickness is 0.10mm, with reference to No. 2790 standards of GB/T, test each new-type heat-melting film sample and exist
100 DEG C, 0.2MPa, hot pressing 30s bonding ABS/ aluminum and the peel strength of stainless 90 ° of ABS/.
Test result such as table 1 below:
Table 1: each new-type heat-melting film sample adhesion strength to ABS/ metal.
Can be seen that from upper table 1, by the adhesive strength to metal Yu ABS plastic of the new type hot-melt adhesive prepared by the present invention
Bigger, and bond damage mode major part is cohesional failure, glued membrane all has residual, explanation on metal and ABS plastic surface
This new type hot-melt adhesive has the strongest cementitiousness to metal and ABS plastic.And when reality is applied, pressing temperature is relatively low, for
100 DEG C, ABS material will not be caused damage；The pressing time is the shortest, for 30s, it is simple to constructing operation.
Claims (9)
1. a new type hot-melt adhesive, is characterised by that its raw material is constituted, by mass percentage, and including:
Nylon type copolyamide 45% ~ 50%；
Thermoplastic polyurethane 34% ~ 37%；
Epoxies compatilizer 0.3% ~ 1%；
Viscosifier 10% ~ 15%；
Filler 1% ~ 5%；
Antioxidant 0.1% ~ 0.3%；
Described nylon type copolyamide by caprolactam, nylon salt and three kinds of primary raw materials of NYLON610 salt at appropriate water and
Be polymerized under end-capping reagent stearic acid effect, and the molar percentage of described three kinds of primary raw materials be respectively 28% ~ 32%, 23% ~
28% and 42% ~ 48%；Described stearic acid and the mol ratio 1 ~ 1.2:100 of described three kinds of primary raw material sums；
The fusing point of described thermoplastic polyurethane is 80 DEG C ~ 100 DEG C, and melt index is 40 ~ 45g/10min/2.16kg/190 DEG C；
Described epoxies compatilizer is polyethylene terminal epoxy wax or epoxy-functional polyolefins elastomer.
2. new type hot-melt adhesive as claimed in claim 1, it is characterised in that: the epoxy functionalities of described polyethylene terminal epoxy wax
Being 0.75 ~ 1, the epoxy functionalities of described epoxy-functional polyolefins elastomer is 1 ~ 1.5.
3. the preparation method of a new type hot-melt adhesive, it is characterised in that comprise the steps:
(1) prepare nylon type copolyamide, by mole meter, weigh the caprolactam of 28% ~ 32%, the nylon of 23% ~ 28%
66 salt and three kinds of primary raw materials of NYLON610 salt of 42% ~ 48%, and appropriate stearic acid and water, put in reactor,
First lead to the air that nitrogen evacuation eliminates in reactor, be re-filled with high pure nitrogen and open stirring, be to slowly warm up to 250 DEG C,
Insulation reaction 2h under 1.8MPa pressure, is the most slowly decompressed to normal pressure, and continues to be decompressed to 0.05MPa dehydration 1h, then blowing
Obtain；
(2) by mass percentage, above-mentioned nylon type copolyamide 45% ~ 50%, thermoplastic polyurethane 34% ~ 37%, epoxy are weighed
Class compatilizer 0.3% ~ 1%, viscosifier 10% ~ 15%, filler 1% ~ 5%, and antioxidant 0.1% ~ 0.3%, put into the most mixed
Mix homogeneously in conjunction machine；
(3) by the material after above-mentioned mix homogeneously, put in screw extruder, blended melted after extrude, obtain Novel hot
Melten gel.
4. the preparation method of new type hot-melt adhesive as claimed in claim 3, it is characterised in that: in described step (1), described tristearin
The addition of acid is 1 ~ 1.2:100 with the mol ratio of described three kinds of primary raw material addition sums.
5. the preparation method of new type hot-melt adhesive as claimed in claim 3, it is characterised in that: in affiliated step (2), described thermoplastic
The fusing point of property polyurethane is 80 DEG C ~ 100 DEG C, and melt index is 40 ~ 45g/10min/2.16kg/190 DEG C；Described epoxies is compatible
Agent is polyethylene terminal epoxy wax or epoxy-functional polyolefins elastomer.
6. the preparation method of new type hot-melt adhesive as claimed in claim 5, it is characterised in that: described polyethylene terminal epoxy wax
Epoxy functionalities is 0.75 ~ 1, and the epoxy functionalities of described epoxy-functional polyolefins elastomer is 1 ~ 1.5.
7. a new-type heat-melting glued membrane, it is characterised in that: with the new type hot-melt adhesive described in any one of claim 1 ~ 2 as raw material,
Prepare after being coated by casting machine or heat seeling coating equipment after melted.
8. new-type heat-melting glued membrane as claimed in claim 7, it is characterised in that: the thickness of described new-type heat-melting glued membrane is 0.1mm.
9. a new type hot-melt adhesive nethike embrane, it is characterised in that: it is former with the new type hot-melt adhesive described in any one of claim 1 ~ 2
Material, is prepared by melt-out spinning web-forming equipment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610273342.XA CN105860917B (en) | 2016-04-28 | 2016-04-28 | A kind of hot melt adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610273342.XA CN105860917B (en) | 2016-04-28 | 2016-04-28 | A kind of hot melt adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105860917A true CN105860917A (en) | 2016-08-17 |
| CN105860917B CN105860917B (en) | 2018-11-30 |
Family
ID=56629471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610273342.XA Active CN105860917B (en) | 2016-04-28 | 2016-04-28 | A kind of hot melt adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105860917B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841355A (en) * | 2018-07-19 | 2018-11-20 | 佛山陵朝新材料有限公司 | A kind of preparation method of composite polyamide hot melt adhesive |
| CN113978049A (en) * | 2021-09-28 | 2022-01-28 | 读布科技(杭州)有限公司 | Preparation process of ethnic style fabric |
| CN115093822A (en) * | 2022-07-18 | 2022-09-23 | 广州市嘉雁粘合剂有限公司 | Hot melt adhesive for laminating household appliance panels and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766413A (en) * | 2012-08-20 | 2012-11-07 | 天津博苑高新材料有限公司 | Integrated circuit (IC) card packaging special hot melting adhesive tape and preparation method thereof |
| CN104927741A (en) * | 2015-06-17 | 2015-09-23 | 南通和和塑胶新材料有限公司 | Novel flame-retarding hot-melt adhesive film and preparation method thereof |
| CN105349088A (en) * | 2015-12-21 | 2016-02-24 | 上海天洋热熔粘接材料股份有限公司 | Novel hot-melt adhesive and preparation method thereof |
-
2016
- 2016-04-28 CN CN201610273342.XA patent/CN105860917B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766413A (en) * | 2012-08-20 | 2012-11-07 | 天津博苑高新材料有限公司 | Integrated circuit (IC) card packaging special hot melting adhesive tape and preparation method thereof |
| CN104927741A (en) * | 2015-06-17 | 2015-09-23 | 南通和和塑胶新材料有限公司 | Novel flame-retarding hot-melt adhesive film and preparation method thereof |
| CN105349088A (en) * | 2015-12-21 | 2016-02-24 | 上海天洋热熔粘接材料股份有限公司 | Novel hot-melt adhesive and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841355A (en) * | 2018-07-19 | 2018-11-20 | 佛山陵朝新材料有限公司 | A kind of preparation method of composite polyamide hot melt adhesive |
| CN113978049A (en) * | 2021-09-28 | 2022-01-28 | 读布科技(杭州)有限公司 | Preparation process of ethnic style fabric |
| CN115093822A (en) * | 2022-07-18 | 2022-09-23 | 广州市嘉雁粘合剂有限公司 | Hot melt adhesive for laminating household appliance panels and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105860917B (en) | 2018-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105733495B (en) | A kind of new type hot-melt adhesive and preparation method thereof | |
| CN105349088B (en) | A kind of PUR and preparation method thereof | |
| CN101864259B (en) | SIS (Styrene-Isoprene-Styrene) hot melt adhesive for car light adhesion and preparation method thereof | |
| CN101307214B (en) | Hot-fusible adhesive and method for preparing same | |
| CN105860917A (en) | Novel hot-melt adhesive and preparation method thereof | |
| CN104804659A (en) | Hot melt rubber film for adhering metal and non-polar material and preparation method of hot melt rubber film | |
| CN101265402B (en) | Water-proof sealing adhesive tape and its preparation method | |
| CN107099265B (en) | A kind of Hot melt adhesive for automobile interior trim part and preparation method thereof | |
| CN105733494B (en) | A kind of hot melt adhesive and preparation method thereof | |
| CN105111971A (en) | Compound type EVA (ethylene vinyl acetate copolymer) hot glue and preparation method thereof | |
| CN113512377B (en) | High-viscosity weather-resistant hot melt adhesive and preparation method thereof | |
| CN109096951A (en) | A kind of furniture edge sealing glue and preparation method thereof | |
| CN109082000A (en) | A kind of composite of water-proof coiled material and preparation method thereof of in situ reactive compatibilization synthesis | |
| CN111171750A (en) | Hot melt adhesive film for automotive interior ceiling and production method thereof | |
| CN116218466A (en) | Environment-friendly odorless edge sealing hot melt adhesive and preparation method thereof | |
| CN112300733B (en) | Hot melt adhesive for refrigerator sealing and preparation method thereof | |
| JPH1046121A (en) | Hot-melt adhesive for polypropylene | |
| JPH0649291A (en) | Hot melt composition | |
| JPS5968385A (en) | Hot-melt adhesive | |
| US3625933A (en) | De khotinsky cement | |
| JPS612778A (en) | Hot-melt adhesive | |
| JPS6045672B2 (en) | hot melt adhesive composition | |
| JPS629274B2 (en) | ||
| CN114262582A (en) | High-temperature-resistant EVA hot-melt adhesive film and preparation process thereof | |
| CN114574128A (en) | Composite adhesive for protective clothing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 201802 Shanghai City, Jiading District Hui Ping Lu Nanxiang Town, No. 505 Patentee after: SHANGHAI TIANYANG HOT MELT ADHESIVE Co.,Ltd. Patentee after: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee after: Kunshan Tianyang New Material Co.,Ltd. Address before: 201802 Shanghai City, Jiading District Hui Ping Lu Nanxiang Town, No. 505 Patentee before: SHANGHAI TIANYANG HOT MELT ADHESIVE Co.,Ltd. Patentee before: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee before: KUNSHAN TIANYANG HOT MELT ADHESIVE Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 201802 Shanghai City, Jiading District Hui Ping Lu Nanxiang Town, No. 505 Patentee after: Tianyang New Material (Shanghai) Technology Co.,Ltd. Patentee after: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee after: Kunshan Tianyang New Material Co.,Ltd. Address before: 201802 Shanghai City, Jiading District Hui Ping Lu Nanxiang Town, No. 505 Patentee before: SHANGHAI TIANYANG HOT MELT ADHESIVE Co.,Ltd. Patentee before: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee before: Kunshan Tianyang New Material Co.,Ltd. |