CN105860561A - High-quality luminescent wood-plastic photo frame and preparation method - Google Patents
High-quality luminescent wood-plastic photo frame and preparation method Download PDFInfo
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- CN105860561A CN105860561A CN201610268415.6A CN201610268415A CN105860561A CN 105860561 A CN105860561 A CN 105860561A CN 201610268415 A CN201610268415 A CN 201610268415A CN 105860561 A CN105860561 A CN 105860561A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention discloses a high-quality luminescent wood-plastic photo frame and a preparation method. The high-quality luminescent wood-plastic photo frame consists of the following materials in percentage by weight: 30-60% of plastic, 20-50% of wood powder, 5-10% of a silane coupling agent, 3-5% of a lubricant, 2-4% of a luminous material, 4-7% of an antioxidant, 1-4% of a preservative and 2-5% of an impact-resistant modifier M-61. According to the high-quality luminescent wood-plastic photo frame, the impact-resistant modifier is added into the formula, so that the processing performance of wood plastic is improved, and the impact resistance can be improved; the added long-afterglow energy storage and luminescent material enables people to pay attention to the photo frame in a dark environment, so that loss due to failure of seeing is avoided, and therefore, the life of people is convenient; a sodium hydroxide solution is used for soaking, so that low-molecule impurities such as part of pectin, lignin and hemicelluloses in plant fibers can be dissolved, and holes are formed in the surface; and impurities on the surfaces of the fibers are removed, and the surfaces of the fibers are rough, so that bonding capacity between the fibers and the resin interface is strengthened, and therefore, the obtained photo frame material is relatively good in mechanical property, and has tensile strength up to 28Mpa.
Description
Technical field
The present invention relates to photo frame Material Field, be specifically related to a kind of high-quality luminescent wood-plastic photo frame and system
Preparation Method.
Background technology
Photo frame industry is the industry with long history, and it is mainly used in four location, limit of photograph,
And strengthen the aesthetic property of photo, it is also possible to prevent photograph variable color to turn to be yellow.Along with materials industry not
Disconnected progressive, the photo frame that increasing high-quality is attractive in appearance commercially emerges in an endless stream, especially in indoor
Decoration industry occupies very important status.
Wooden and plastics are the two big materials that photo frame is conventional, and wooden is a kind of ancient natural material
Material, can make photo frame more have texture, but the heaviest, and the easy moisture absorption is easily damaged by worms, and the later stage protects
Managing cumbersome, the use of timber depends on a large amount of felling of trees, so for the Nature
Protection is also disadvantageous.Plastics are with monomer as raw material, are synthesized by addition polymerization or polycondensation reaction
Macromolecular compound, its flexible cheap, light, resistance to chemical attack, but aging resistance
Poor performance, changeableness, it is not easily decomposed.Therefore, people both combine on the basis of advantage,
Developing one and be called the material of " wood is moulded ", it is to be polymerized by wood powder or the wood fiber and thermoplasticity
Thing is combined, and formed by melt-processed molding has new structure and Good All-around Property
New material, is widely used in the industries such as house ornamentation, building, packed and transported.The Wood-plastic material system of using
The photo frame obtained has life-span length, Anti-moth-eating, water absorption is little, ageing-resistant, have the advantages such as woodiness touch.
Constantly promoting of photo frame material can not make it be entirely free of meaningless damage, especially puts
Platform photo frame is not often noted by people under dark surrounds, it is easy to is touched down and damages on the ground
Bad, it is necessary for therefore manufacturing a kind of high-quality luminescent wood-plastic photo frame.
Summary of the invention
The invention provides a kind of high-quality luminescent wood-plastic photo frame and preparation method, both ensure that photo frame
Quality and outward appearance, it can be made again the most luminous, it is to avoid unnecessary damage.
In order to realize object above, the present invention is practiced by the following technical programs:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: plastics
30-60%, wood powder 20-50%, silane coupler 5-10%, lubricant 3-5%, Noctilucent material
2-4%, antioxidant 4-7%, preservative 1-4%, impact resistance modification agent M-612-5%.
Preferably, described plastics are polyethylene, polypropylene, polyurethane, polrvinyl chloride, benzene second
One or more in alkene-acrylonitrile-butadiene copolymer, polymethyl methacrylate.
Preferably, the particle diameter of described plastics and wood powder is 50-75 mesh.
Preferably, described lubricant is stearic acid, butyl stearate, natural paraffin wax, microlite
One or more in wax, Tissuemat E.
Preferably, described Noctilucent material is long-afterglow energy-accumulating luminescent material.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
The method have the benefit that and inventive formulation adds impact resistance modification agent, not only improve
The processing characteristics that wood is moulded, and can improve its resistance to impact；The long-afterglow energy-accumulating added is sent out
Luminescent material, makes people also it will be noted that photo frame in the environment of pitch-dark, it is to avoid to make because can't see
The loss become, facilitates the life of people；Soak with sodium hydroxide solution and can make in Plant fiber
The low molecule impurity such as part pectin, lignin and hemicellulose be dissolved and in formation hole, surface
Hole, the impurity of fiber surface is removed, and fiber surface becomes coarse, makes fiber and resin boundary surface
Between adhesive power strengthen, the photo frame material mechanical performance obtained is relatively good, and its bending strength can
Reach 28Mpa.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot
Close the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched
State, it is clear that described embodiment is a part of embodiment of the present invention rather than whole realities
Execute example.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation
The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: polypropylene
30%, wood powder 45%, silane coupler 8%, stearic acid 5%, long-afterglow energy-accumulating luminescent material
2%, antioxidant 4%, preservative 1%, impact resistance modification agent M-615%.
The particle diameter of above-mentioned plastics and wood powder is 50-75 mesh.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
Embodiment 2:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: styrene
-acrylonitrile-butadiene copolymer 60%, wood powder 20%, silane coupler 5%, microcrystalline wax
3%, long-afterglow energy-accumulating luminescent material 3%, antioxidant 4%, preservative 2%, impact resistance modifies
Agent M-613%.
The particle diameter of above-mentioned plastics and wood powder is 50-75 mesh.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
Embodiment 3:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: poly-methyl
Acrylic acid methyl ester. 20%, polyethylene 20%, wood powder 40%, silane coupler 6%, natural stone
Wax 3%, long-afterglow energy-accumulating luminescent material 3%, antioxidant 4%, preservative 1%, impact resistance
Modification agent M-613%.
The particle diameter of above-mentioned plastics and wood powder is 50-75 mesh.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
Embodiment 4:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: polychlorostyrene second
Alkene 50%, wood powder 20%, silane coupler 8%, stearic acid 2%, butyl stearate 2%,
Long-afterglow energy-accumulating luminescent material 4%, antioxidant 7%, preservative 4%, impact resistance modification agent
M-613%.
The particle diameter of above-mentioned plastics and wood powder is 50-75 mesh.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
Embodiment 5:
A kind of high-quality luminescent wood-plastic photo frame, is made up of the material of following weight percents: poly-methyl
Acrylic acid methyl ester. 43%, wood powder 30%, silane coupler 5%, Tissuemat E 3%, long remaining
Brightness energy-saving luminous material 4%, antioxidant 6%, preservative 4%, impact resistance modification agent M-615%.
The particle diameter of above-mentioned plastics and wood powder is 50-75 mesh.
The preparation method of high-quality luminescent wood-plastic photo frame, comprises the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
It should be noted that in this article, the relational terms of such as first and second or the like is only
Only it is used for separating an entity or operation with another entity or operating space, and not necessarily
Require or imply and there is the relation of any this reality or suitable between these entities or operation
Sequence.And, term " includes ", " comprising " or its any other variant are intended to non-exclusive
Comprising, so that include the process of a series of key element, method, article or equipment not of property
Only include those key elements, but also include other key elements being not expressly set out, or also wrap
Include the key element intrinsic for this process, method, article or equipment.There is no more restriction
In the case of, statement " including ... " key element limited, it is not excluded that described in including
The process of key element, method, article or equipment there is also other identical element.
Above example only in order to technical scheme to be described, is not intended to limit；Although
With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art
It is understood that the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent；And these amendments or replacement, not
The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a high-quality luminescent wood-plastic photo frame, it is characterised in that by following weight percents
Material forms: plastics 30-60%, wood powder 20-50%, silane coupler 5-10%, lubricant
3-5%, Noctilucent material 2-4%, antioxidant 4-7%, preservative 1-4%, impact resistance modification agent
M-612-5%.
2. high-quality luminescent wood-plastic photo frame as claimed in claim 1, it is characterised in that described
Plastics are polyethylene, polypropylene, polyurethane, polrvinyl chloride, styrene-acrylonitrile-butadiene
One or more in copolymer, polymethyl methacrylate.
3. high-quality luminescent wood-plastic photo frame as claimed in claim 1, it is characterised in that described
The particle diameter of plastics and wood powder is 50-75 mesh.
4. high-quality luminescent wood-plastic photo frame as claimed in claim 1, it is characterised in that described
Lubricant is in stearic acid, butyl stearate, natural paraffin wax, microcrystalline wax, Tissuemat E
One or more.
5. high-quality luminescent wood-plastic photo frame as claimed in claim 1, it is characterised in that described
Noctilucent material is long-afterglow energy-accumulating luminescent material.
6. the preparation side of the high-quality luminescent wood-plastic photo frame as described in claim 1-5 is arbitrary
Method, it is characterised in that comprise the following steps:
(1) wood powder pretreatment: wood powder first soaks with the sodium hydroxide solution that concentration is 5%, a section
It is dried after time；Again wood powder is soaked in dissolved with in the acetone soln of silane coupler, constantly stirs
Mix, the most standby；
(2) batch mixing: the wood powder processed, plastics are added single screw rod together with other auxiliary agent
Extruder, obtains Wood-plastic mix material premix material, control temperature and be 145-160 DEG C, in order to make
Batch mixing is uniform, repeatable operation 3 times；
(3) hot-forming: to add the premix to be covered with the photo frame mold of polytetrafluoroethylene film
In, set furnace temperature, controlling firing rate is 6 DEG C/minute, is warming up to 150 DEG C and is incubated 40-60min,
It is forced into 6-13Mpa, makes scattered premix pellet clinkering become closely knit phase frame material, in constant voltage
Under the conditions of naturally cool to room temperature with furnace temperature, obtain wood plastic composite.
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| CN201610268415.6A CN105860561A (en) | 2016-04-25 | 2016-04-25 | High-quality luminescent wood-plastic photo frame and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610268415.6A CN105860561A (en) | 2016-04-25 | 2016-04-25 | High-quality luminescent wood-plastic photo frame and preparation method |
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| CN201610268415.6A Pending CN105860561A (en) | 2016-04-25 | 2016-04-25 | High-quality luminescent wood-plastic photo frame and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633979A (en) * | 2016-12-05 | 2017-05-10 | 钦州市钦南区生产力促进中心 | Wood-plastic composite material and preparation method thereof |
| CN109467954A (en) * | 2018-10-24 | 2019-03-15 | 江阴市江威工艺包装材料有限公司 | A kind of wood powder plastic composite and the method using material manufacture pet toy |
| CN110903584A (en) * | 2019-12-20 | 2020-03-24 | 孙爱芬 | Environment-friendly wood-plastic material and preparation method thereof |
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| CN101074307A (en) * | 2006-05-16 | 2007-11-21 | 谷广强 | Luminescent plastic products |
| CN102031003A (en) * | 2009-09-28 | 2011-04-27 | 莊丽 | Fluorescent wood-plastic and bamboo-plastic new material |
| CN102702602A (en) * | 2012-06-07 | 2012-10-03 | 天津聚贤达科技有限公司 | Novel wood-plastic composite material |
| CN104151808A (en) * | 2014-09-01 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Luminous injection molding material |
| CN104231426A (en) * | 2013-06-24 | 2014-12-24 | 黑龙江鑫达企业集团有限公司 | Polypropylene self-luminescent material and preparation method thereof |
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2016
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074307A (en) * | 2006-05-16 | 2007-11-21 | 谷广强 | Luminescent plastic products |
| CN102031003A (en) * | 2009-09-28 | 2011-04-27 | 莊丽 | Fluorescent wood-plastic and bamboo-plastic new material |
| CN102702602A (en) * | 2012-06-07 | 2012-10-03 | 天津聚贤达科技有限公司 | Novel wood-plastic composite material |
| CN104231426A (en) * | 2013-06-24 | 2014-12-24 | 黑龙江鑫达企业集团有限公司 | Polypropylene self-luminescent material and preparation method thereof |
| CN104151808A (en) * | 2014-09-01 | 2014-11-19 | 苏州卓越工程塑料有限公司 | Luminous injection molding material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633979A (en) * | 2016-12-05 | 2017-05-10 | 钦州市钦南区生产力促进中心 | Wood-plastic composite material and preparation method thereof |
| CN109467954A (en) * | 2018-10-24 | 2019-03-15 | 江阴市江威工艺包装材料有限公司 | A kind of wood powder plastic composite and the method using material manufacture pet toy |
| CN110903584A (en) * | 2019-12-20 | 2020-03-24 | 孙爱芬 | Environment-friendly wood-plastic material and preparation method thereof |
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Application publication date: 20160817 |