CN105860285A - Wear-resistant aging-resistant high-flame-retardant cable special for oil platform - Google Patents
Wear-resistant aging-resistant high-flame-retardant cable special for oil platform Download PDFInfo
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a wear-resistant aging-resistant high-flame-retardant cable special for an oil platform. The wear-resistant aging-resistant high-flame-retardant cable comprises a cable core and a sheath; the sheath is made of a modified ethylene propylene diene rubber composite material, wherein the modified ethylene propylene diene rubber composite material is prepared from ethylene propylene diene rubber, chlorosulfonated polyethylene rubber, high-density polyethylene, butadiene-acrylonitrile rubber, a maleic anhydride-grafted polyethylene copolymer, stearic acid, aluminum oxide, tert-butyl monoperoxymaleate, benzoyl peroxide, silicon nitride nanometer powder, spray furnace black, boron carbide, carbon monofluoride, talcum powder, calcium bentonite, molybdenum disulfide, polytetrafluoroethylene micropowder, an accelerant, glyceryl tribenzoate, triethylene glycol di-2-ethylhexoate, trioctyl trimellitate, tetra(3,5-ditert-butyl-4-hydroxyl)phenylpropionic acid pentaerythritol ester, tris(2,4-ditert-butyl phenyl)phosphite ester, a phenol amine anti-aging agent, octavinyl silsesquioxane, butadiene sulfone and a flame retardant.
Description
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of ageing-resistant high fire-retardance of oil platform Special wear-resistant
Cable.
Background technology
At present, the development and utilization to marine resources is the most constantly strengthened in countries in the world, particularly to offshore oil
Development and utilization, as the applicating history that electric power transmission and the cable used for oil platform of communication are the longest.
Owing to cable used for oil platform is arranged on the sea of circumstance complication, for a long time by sea beat, seawater corrosion and
Many X factor impacts, are susceptible to catabiosis.The performance of cable used for oil platform is carried by people at present
Go out higher requirement.Existing cable used for oil platform is during using, its wearability, ageing-resistant
Property and anti-flammability are less desirable.
Summary of the invention
The technical problem existed based on background technology, it is resistance to always that the present invention proposes a kind of oil platform Special wear-resistant
Changing high flame-retardant cable, its intensity is high, and wearability is good, and ageing-resistant performance is excellent, and has the anti-flammability of excellence
Energy.
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 20-40
Part, high density polyethylene (HDPE) 15-35 part, nitrile rubber 5-20 part, maleic anhydride grafted polyethylene copolymer 2-10
Part, stearic acid 1-3 part, aluminium oxide 1-3 part, peroxidating maleic acid tert-butyl ester 0.5-2 part, benzoyl peroxide
0.1-0.5 part, silicon nitride nano powder 4-15 part, spray carbon black 5-15 part, boron carbide 5-15 part, fluorographite
2-12 part, Pulvis Talci 2-15 part, calcium-base bentonite 1-5 part, molybdenum bisuphide 3-15 part, ptfe micropowder
2-15 part, accelerator 1-3 part, tribenzoin 3-8 part, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 0.5-2 part, partially
Benzenetricarboxylic acid three monooctyl ester 0.5-2.5 part, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.3-1
Part, three (2,4-di-tert-butyl-phenyl) phosphite ester 0.5-2 part, phenol amine age resistor 1-2.5 part, eight vinyls
Silsesquioxane 2-5 part, cyclobufene sultone 0.5-1.5 part, fire retardant 5-20 part.
Preferably, in the raw material of described modified EPT rubber composite, ethylene propylene diene rubber, chlorine sulphur
Change polyethylene rubber, high density polyethylene (HDPE), the weight ratio of nitrile rubber are 100:28-36:20-32:9-17.
Preferably, the raw material of described modified EPT rubber composite includes by weight: EPDM
Rubber 100 parts, CSM 30-35 part, high density polyethylene (HDPE) 24-28 part, nitrile rubber 11-15
Part, maleic anhydride grafted polyethylene copolymer 5-8.5 part, stearic acid 1.6-2.1 part, aluminium oxide 1.6-2.4 part,
Peroxidating maleic acid tert-butyl ester 0.8-1.4 part, benzoyl peroxide 0.32-0.4 part, silicon nitride nano powder 8-11
Part, spray carbon black 7-10 part, boron carbide 6.5-10 part, fluorographite 5.8-8 part, Pulvis Talci 6-11 part, calcium
Base bentonite 3-3.6 part, molybdenum bisuphide 10-14 part, ptfe micropowder 5-9 part, accelerator 1.6-2.1
Part, tribenzoin 5-6.2 part, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1-1.6 part, trioctyl trimellitate (TOTM)
1.3-1.8 part, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.8-1 part, three (2,4-
Di-tert-butyl-phenyl) phosphite ester 1.1-1.6 part, phenol amine age resistor 1.3-2.1 part, eight vinyl silsesquioxanes
Alkane 3-3.8 part, cyclobufene sultone 0.9-1.2 part, fire retardant 13-16 part.
Preferably, the raw material of described modified EPT rubber composite includes by weight: EPDM
Rubber 100 parts, CSM 32 parts, high density polyethylene (HDPE) 25 parts, nitrile rubber 12 parts, Malaysia
Anhydride grafted lldpe copolymer 6 parts, stearic acid 2 parts, aluminium oxide 2.1 parts, the peroxidating maleic acid tert-butyl ester 1
Part, benzoyl peroxide 0.36 part, 10 parts of silicon nitride nano powder, spray carbon black 8.6 parts, boron carbide 7 parts,
Fluorographite 6.2 parts, Pulvis Talci 10 parts, calcium-base bentonite 3.2 parts, molybdenum bisuphide 11 parts, politef
Micropowder 8 parts, accelerator 2 parts, tribenzoin 5.3 parts, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1.2 parts, inclined benzene
Three sour three monooctyl esters 1.5 parts, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.88 part, three (2,
4-di-tert-butyl-phenyl) phosphite ester 1.45 parts, 2 parts of phenol amine age resistor, eight vinyl silsesquioxane 3.6 parts,
Cyclobufene sultone 1 part, fire retardant 14 parts.
Preferably, described silicon nitride nano powder be particle diameter be that the silicon nitride nano powder of 20-35nm, particle diameter are
The silicon nitride nano powder of 45-60nm, particle diameter are that the silicon nitride nano powder of 65-80nm is by weight
The mixture of 4-15:3-10:1-5.
Preferably, described accelerator is accelerant NOBS, accelerator TATD, accelerator T, accelerant CZ, rush
Enter one or more the mixture in agent BBP.
Preferably, described phenol amine age resistor is prepared according to following technique: add 2-first in reaction vessel
Base acrylic acid, adds thionyl chloride at 5-10 DEG C, wherein, 2-methacrylic acid and thionyl chloride mole
Ratio is 1:1.5-2, is subsequently adding hydroquinone, and stirring reaction 2-3h after being warming up to 55-60 DEG C, reaction terminates
Intermediate A is obtained by distillation；By weight 5-10 part mutual-amido two polyaniline is added 15-30 part absolute ether
In, it is passed through nitrogen after stirring, at 0 DEG C, adds 3-5 part intermediate A and 3-5 part sodium carbonate, in room temperature
Lower stirring reaction 3-5h, reaction terminate after through sucking filtration, recrystallization, be dried to obtain intermediate B；By weight will
25-40 part 4-aminodiphenylamine addition 50-100 part dehydrated alcohol stirs, is subsequently adding 10-20 part
3-pi-allyl salicylide, reacts 3-5h at 65-75 DEG C, is passed through nitrogen, is subsequently adding 25-40 after stirring
Part intermediate B and 0.3-1.2 part Ammonium persulfate., stirring reaction 2-5h, reaction is cooled to room temperature, warp after terminating
Filter, wash, be dried to obtain described phenol amine age resistor.
Preferably, described phenol amine age resistor is prepared according to following technique: add 2-first in reaction vessel
Base acrylic acid, adds thionyl chloride at 8 DEG C, and wherein, 2-methacrylic acid with the mol ratio of thionyl chloride is
1:1.7, is subsequently adding hydroquinone, and after being warming up to 58 DEG C, stirring reaction 2.6h, reacts after terminating through distilling
To intermediate A；By weight 8 parts of mutual-amido two polyanilines are added in 21 parts of absolute ethers, logical after stirring
Enter nitrogen, at 0 DEG C, add 4.2 parts of intermediate A and 4 parts of sodium carbonate, be stirred at room temperature reaction 3.8h, instead
Through sucking filtration, recrystallization after should terminating, it is dried to obtain intermediate B；By weight by 35 parts of 4-aminodiphenylamines
Add in 85 parts of dehydrated alcohol and stir, be subsequently adding 16 parts of 3-pi-allyl salicylides, after stirring
React 4h at 70 DEG C, be passed through nitrogen, be subsequently adding 38 parts of intermediate B and 0.9 part of Ammonium persulfate., stirring reaction
3.5h, reaction is cooled to room temperature, through filtering, wash, be dried to obtain described phenol amine age resistor after terminating；?
In the preparation process of phenol amine age resistor, with 2-methacrylic acid and thionyl chloride as raw material, reacted by control
Condition, make hydroxyl in 2-methacrylic acid there occurs reaction with the chlorine in thionyl chloride, obtained in the middle of
Body A；After intermediate A is mixed with mutual-amido two polyaniline, the chlorine in intermediate A and primary in mutual-amido two polyaniline
Amine there occurs reaction, thus 2-methacrylic acid and mutual-amido two polyaniline are combined as a whole and have obtained intermediate B；
After 4-aminodiphenylamine is mixed with 3-pi-allyl salicylide, the primary amine in 4-aminodiphenylamine and 3-alkene
Aldehyde radical in propyl group salicylide there occurs reaction, thus by the primary amine in 4-aminodiphenylamine and 3-pi-allyl
Salicylide is combined as a whole, and after adding intermedium B, double bond therein there occurs instead with the double bond in intermediate B
Should, thus by 2-methacrylic acid, mutual-amido two polyaniline, 4-aminodiphenylamine and 3-pi-allyl salicylide
It is combined as a whole, in addition system, is uniformly dispersed in system, and does not migrates, significantly improve multiple
The resistance to ag(e)ing of condensation material.
Preferably, described fire retardant is that red phosphorus, Firebrake ZB, aluminium titanates, cerium oxide, triphenyl phosphate are by weight
Amount is than the mixture for 1-5:3-8:2-6:1-5:4-15.
Modified EPT rubber composite of the present invention can be combined according to conventional ethylene propylene diene rubber
Material preparation process is prepared from.
The ageing-resistant high flame-retardant cable of oil platform Special wear-resistant of the present invention is rubber combined with modified EPT
Material is sheath material, thus the character of modified EPT rubber composite has been incorporated in cable,
The cable strength obtained is high, and wearability is good, and ageing-resistant performance is excellent, and has the fire resistance of excellence；Tool
Body ground, in modified EPT rubber composite, with ethylene propylene diene rubber as major ingredient, and adds chlorine
It is modified by sulfonated polyethylene rubber, high density polyethylene (HDPE) and nitrile rubber, and four connect at maleic anhydride
Under the compatibilization of branch polyethylene and ethylene copolymers, after mixing in the ratio in the present invention, the compatibility is good, and performance is assisted
With, significantly improve wearability and the ozone weather-proof, resistance to of composite and resist corona resistant, and reducing it
Water absorption, meanwhile, improves the density of composite, hot strength and scale of hardness and reveals cooperative effect, and
The thermostability of blend compounds is the most stable；With aluminium oxide, the peroxidating maleic acid tert-butyl ester, benzoyl peroxide and rush
Enter agent and coordinate the vulcanizing system as system, it is achieved that the co-vulcanization of system, increase the sulfuric of system simultaneously
The change time, give the excellent processing safety of Blend rubber so as to get vulcanizate have preferable thermostability and
Compression set；In boron carbide addition system, coordinate with aluminium oxide, promote glue to a certain extent
The vulcanization reaction of material, further increases processing fluidity and the goods reliability of composite, simultaneously and nitrogen
SiClx nano powder, spray carbon black, fluorographite, Pulvis Talci, calcium-base bentonite, molybdenum bisuphide, polytetrafluoro
Ethylene micropowder coordinate be effectively increased the hot strength of composite, hardness, modulus of compressibility, Static stiffness and
Friction and wear behavior and heat stability；Four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester, three
(2,4-di-tert-butyl-phenyl) phosphite ester, phenol amine age resistor coordinate in addition system, have synergism,
Significantly improve the ageing-resistant performance of composite.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 40 parts,
High density polyethylene (HDPE) 15 parts, nitrile rubber 20 parts, maleic anhydride grafted polyethylene copolymer 2 parts, stearic acid 3
Part, aluminium oxide 1 part, the peroxidating maleic acid tert-butyl ester 2 parts, benzoyl peroxide 0.1 part, silicon nitride nano powder
15 parts, spray carbon black 5 parts, boron carbide 15 parts, fluorographite 2 parts, Pulvis Talci 15 parts, calcium-base bentonite 1 part,
Molybdenum bisuphide 15 parts, ptfe micropowder 2 parts, accelerator 3 parts, tribenzoin 3 parts, 2,2'-ethylenedioxybis(ethanol).
Two tricaprylates 2 parts, trioctyl trimellitate (TOTM) 0.5 part, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid seasons
Doutrate 1 part, three (2,4-di-tert-butyl-phenyl) phosphite ester 0.5 part, 2.5 parts of phenol amine age resistor, eight
Vinyl silsesquioxane 2 parts, cyclobufene sultone 1.5 parts, fire retardant 5 parts.
Embodiment 2
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 20 parts,
High density polyethylene (HDPE) 35 parts, nitrile rubber 5 parts, maleic anhydride grafted polyethylene copolymer 10 part, stearic acid 1
Part, aluminium oxide 3 parts, the peroxidating maleic acid tert-butyl ester 0.5 part, benzoyl peroxide 0.5 part, silicon nitride nano
4 parts of powder, spray carbon black 15 parts, boron carbide 5 parts, fluorographite 12 parts, Pulvis Talci 2 parts, calcium-base bentonite 5
Part, molybdenum bisuphide 3 parts, ptfe micropowder 15 parts, accelerator 1 part, tribenzoin 8 parts, three
Glycol two tricaprylate 0.5 part, trioctyl trimellitate (TOTM) 2.5 parts, four (3,5-di-t-butyl-4-hydroxyl) benzene
Propionate 0.3 part, three (2,4-di-tert-butyl-phenyl) phosphite ester 2 parts, 1 part of phenol amine age resistor,
Eight vinyl silsesquioxanes 5 parts, cyclobufene sultone 0.5 part, fire retardant 20 parts.
Embodiment 3
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 35 parts,
High density polyethylene (HDPE) 24 parts, nitrile rubber 15 parts, maleic anhydride grafted polyethylene copolymer 8.5 parts, stearic acid
1.6 parts, aluminium oxide 2.4 parts, the peroxidating maleic acid tert-butyl ester 0.8 part, benzoyl peroxide 0.4 part, nitridation
Silicon nano power 11 parts, spray carbon black 7 parts, boron carbide 10 parts, fluorographite 5.8 parts, Pulvis Talci 11 parts, calcium
Base bentonite 3 parts, molybdenum bisuphide 14 parts, ptfe micropowder 5 parts, accelerant NOBS 0.5 part, promotion
Agent TATD 0.8 part, accelerator T 0.5 part, accelerant CZ 0.1 part, accelerant B BP 0.2 part, glycerol three
Benzoate 5 parts, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1.6 parts, trioctyl trimellitate (TOTM) 1.3 parts, four (3,5-bis-uncles
Butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 1 part, three (2,4-di-tert-butyl-phenyl) phosphite ester 1.1 parts,
2.1 parts of phenol amine age resistor, eight vinyl silsesquioxane 3 parts, cyclobufene sultone 1.2 parts, fire retardant 13 parts；
Wherein, described silicon nitride nano powder be particle diameter be the silicon nitride nano powder of 35nm, particle diameter be the nitrogen of 45nm
SiClx nano powder, particle diameter are that the silicon nitride nano powder of 80nm is by weight the mixture for 4:10:1；
Described phenol amine age resistor is prepared according to following technique: add 2-methacrylic acid in reaction vessel,
Adding thionyl chloride at 5 DEG C, wherein, 2-methacrylic acid is 1:2 with the mol ratio of thionyl chloride, then
Adding hydroquinone, stirring reaction 3h after being warming up to 55 DEG C, reaction obtains intermediate A through distillation after terminating；Press
5 parts of mutual-amido two polyanilines are added in 30 parts of absolute ethers by weight portion, are passed through nitrogen, at 0 DEG C after stirring
3 parts of intermediate A of lower addition and 5 parts of sodium carbonate, be stirred at room temperature reaction 3h, react after terminating through sucking filtration, weight
Crystallize, be dried to obtain intermediate B；By weight 40 parts of 4-aminodiphenylamines are added in 50 parts of dehydrated alcohol
Stir, be subsequently adding 20 parts of 3-pi-allyl salicylides, at 65 DEG C, react 5h after stirring, be passed through
Nitrogen, is subsequently adding 25 parts of intermediate B and 1.2 parts of Ammonium persulfate .s, stirring reaction 2h, and reaction cools down after terminating
To room temperature, through filtering, wash, be dried to obtain described phenol amine age resistor；
Described fire retardant is that red phosphorus, Firebrake ZB, aluminium titanates, cerium oxide, triphenyl phosphate are by weight
The mixture of 5:3:6:5:4.
Embodiment 4
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 30 parts,
High density polyethylene (HDPE) 28 parts, nitrile rubber 15 parts, maleic anhydride grafted polyethylene copolymer 5 parts, stearic acid 2.1
Part, aluminium oxide 1.6 parts, the peroxidating maleic acid tert-butyl ester 1.4 parts, benzoyl peroxide 0.32 part, silicon nitride
Nano powder 8 parts, spray carbon black 10 parts, boron carbide 6.5 parts, fluorographite 8 parts, Pulvis Talci 6 parts, calcio are swollen
3.6 parts of profit soil, molybdenum bisuphide 10 parts, ptfe micropowder 9 parts, accelerator TATD 0.5 part, accelerator T
0.2 part, accelerant CZ 0.9 part, tribenzoin 6.2 parts, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1 part, inclined benzene
Three sour three monooctyl esters 1.8 parts, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.8 part, three (2,
4-di-tert-butyl-phenyl) phosphite ester 1.6 parts, 1.3 parts of phenol amine age resistor, eight vinyl silsesquioxanes 3.8
Part, cyclobufene sultone 0.9 part, fire retardant 16 parts；
Wherein, described silicon nitride nano powder be particle diameter be the silicon nitride nano powder of 20nm, particle diameter be the nitrogen of 60nm
SiClx nano powder, particle diameter are that the silicon nitride nano powder of 65nm is by weight the mixture for 15:3:5；
Described phenol amine age resistor is prepared according to following technique: add 2-methacrylic acid in reaction vessel,
Adding thionyl chloride at 10 DEG C, wherein, 2-methacrylic acid is 1:1.5 with the mol ratio of thionyl chloride, so
Rear addition hydroquinone, stirring reaction 2h after being warming up to 60 DEG C, reaction obtains intermediate A through distillation after terminating；
By weight 10 parts of mutual-amido two polyanilines are added in 15 parts of absolute ethers, be passed through nitrogen after stirring, at 0 DEG C
5 parts of intermediate A of lower addition and 3 parts of sodium carbonate, be stirred at room temperature reaction 5h, react after terminating through sucking filtration, weight
Crystallize, be dried to obtain intermediate B；By weight 25 parts of 4-aminodiphenylamines are added 100 parts of dehydrated alcohol
In stir, be subsequently adding 10 parts of 3-pi-allyl salicylides, at 75 DEG C, after stirring, react 3h, logical
Entering nitrogen, be subsequently adding 40 parts of intermediate B and 0.3 part of Ammonium persulfate., stirring reaction 5h, reaction is cold after terminating
But to room temperature, through filtering, wash, be dried to obtain described phenol amine age resistor；
Described fire retardant is that red phosphorus, Firebrake ZB, aluminium titanates, cerium oxide, triphenyl phosphate are by weight
The mixture of 1:8:2:1:15.
Embodiment 5
A kind of ageing-resistant high flame-retardant cable of oil platform Special wear-resistant that the present invention proposes, including cable core and sheath；
Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT rubber
The raw material of composite includes by weight: ethylene propylene diene rubber 100 parts, CSM 32 parts,
High density polyethylene (HDPE) 25 parts, nitrile rubber 12 parts, maleic anhydride grafted polyethylene copolymer 6 parts, stearic acid 2
Part, aluminium oxide 2.1 parts, the peroxidating maleic acid tert-butyl ester 1 part, benzoyl peroxide 0.36 part, silicon nitride are received
10 parts of rice flour, spray carbon black 8.6 parts, boron carbide 7 parts, fluorographite 6.2 parts, Pulvis Talci 10 parts, calcio are swollen
3.2 parts of profit soil, molybdenum bisuphide 11 parts, ptfe micropowder 8 parts, accelerant NOBS 2 parts, glycerol triphen
Formic acid esters 5.3 parts, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1.2 parts, trioctyl trimellitate (TOTM) 1.5 parts, four (3,5-bis-uncles
Butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.88 part, three (2,4-di-tert-butyl-phenyl) phosphite ester 1.45
Part, 2 parts of phenol amine age resistor, eight vinyl silsesquioxane 3.6 parts, cyclobufene sultone 1 part, fire retardant 14 parts；
Wherein, described silicon nitride nano powder be particle diameter be the silicon nitride nano powder of 30nm, particle diameter be the nitrogen of 55nm
SiClx nano powder, particle diameter are that the silicon nitride nano powder of 70nm is by weight the mixture for 10:8:3；
Described phenol amine age resistor is prepared according to following technique: add 2-methacrylic acid in reaction vessel,
Adding thionyl chloride at 8 DEG C, wherein, 2-methacrylic acid is 1:1.7 with the mol ratio of thionyl chloride, so
Rear addition hydroquinone, stirring reaction 2.6h after being warming up to 58 DEG C, reaction obtains intermediate A through distillation after terminating；
By weight 8 parts of mutual-amido two polyanilines are added in 21 parts of absolute ethers, be passed through nitrogen after stirring, at 0 DEG C
4.2 parts of intermediate A of lower addition and 4 parts of sodium carbonate, be stirred at room temperature reaction 3.8h, reaction terminate after through sucking filtration,
Recrystallization, it is dried to obtain intermediate B；By weight 35 parts of 4-aminodiphenylamines are added 85 parts of dehydrated alcohol
In stir, be subsequently adding 16 parts of 3-pi-allyl salicylides, at 70 DEG C, after stirring, react 4h, logical
Entering nitrogen, be subsequently adding 38 parts of intermediate B and 0.9 part of Ammonium persulfate., stirring reaction 3.5h, after reaction terminates
It is cooled to room temperature, through filtering, wash, be dried to obtain described phenol amine age resistor；
Described fire retardant is that red phosphorus, Firebrake ZB, aluminium titanates, cerium oxide, triphenyl phosphate are by weight
The mixture of 3:7:5:4:11.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (9)
1. the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant, it is characterised in that include cable core and protect
Set；Wherein, described sheath uses modified EPT rubber composite to make, described modified EPT
The raw material of rubber composite includes by weight: ethylene propylene diene rubber 100 parts, CSM
20-40 part, high density polyethylene (HDPE) 15-35 part, nitrile rubber 5-20 part, maleic anhydride grafted polyethylene copolymerization
Thing 2-10 part, stearic acid 1-3 part, aluminium oxide 1-3 part, peroxidating maleic acid tert-butyl ester 0.5-2 part, peroxidating
Benzoyl 0.1-0.5 part, silicon nitride nano powder 4-15 part, spray carbon black 5-15 part, boron carbide 5-15 part, fluorine
Graphite 2-12 part, Pulvis Talci 2-15 part, calcium-base bentonite 1-5 part, molybdenum bisuphide 3-15 part, polytetrafluoroethyl-ne
Alkene micropowder 2-15 part, accelerator 1-3 part, tribenzoin 3-8 part, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 0.5-2
Part, trioctyl trimellitate (TOTM) 0.5-2.5 part, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester
0.3-1 part, three (2,4-di-tert-butyl-phenyl) phosphite ester 0.5-2 part, phenol amine age resistor 1-2.5 part, eight
Vinyl silsesquioxane 2-5 part, cyclobufene sultone 0.5-1.5 part, fire retardant 5-20 part.
The ageing-resistant high flame-retardant cable of oil platform Special wear-resistant the most according to claim 1, it is characterised in that
In the raw material of described modified EPT rubber composite, ethylene propylene diene rubber, CSM,
High density polyethylene (HDPE), the weight ratio of nitrile rubber are 100:28-36:20-32:9-17.
The ageing-resistant high flame-retardant cable of oil platform Special wear-resistant the most according to claim 1 or claim 2, its feature exists
In, the raw material of described modified EPT rubber composite includes by weight: ethylene propylene diene rubber 100
Part, CSM 30-35 part, high density polyethylene (HDPE) 24-28 part, nitrile rubber 11-15 part, horse
Maleic anhydride grafted polyethylene and ethylene copolymers 5-8.5 part, stearic acid 1.6-2.1 part, aluminium oxide 1.6-2.4 part, peroxide
Change maleic acid tert-butyl ester 0.8-1.4 part, benzoyl peroxide 0.32-0.4 part, silicon nitride nano powder 8-11 part,
Spray carbon black 7-10 part, boron carbide 6.5-10 part, fluorographite 5.8-8 part, Pulvis Talci 6-11 part, calcio are swollen
Profit soil 3-3.6 part, molybdenum bisuphide 10-14 part, ptfe micropowder 5-9 part, accelerator 1.6-2.1 part,
Tribenzoin 5-6.2 part, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1-1.6 part, trioctyl trimellitate (TOTM) 1.3-1.8
Part, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.8-1 part, three (2,4-di-t-butyls
Phenyl) phosphite ester 1.1-1.6 part, phenol amine age resistor 1.3-2.1 part, eight vinyl silsesquioxane 3-3.8
Part, cyclobufene sultone 0.9-1.2 part, fire retardant 13-16 part.
4. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-3,
It is characterized in that, the raw material of described modified EPT rubber composite includes by weight: EPDM
Rubber 100 parts, CSM 32 parts, high density polyethylene (HDPE) 25 parts, nitrile rubber 12 parts, Malaysia
Anhydride grafted lldpe copolymer 6 parts, stearic acid 2 parts, aluminium oxide 2.1 parts, the peroxidating maleic acid tert-butyl ester 1
Part, benzoyl peroxide 0.36 part, 10 parts of silicon nitride nano powder, spray carbon black 8.6 parts, boron carbide 7 parts,
Fluorographite 6.2 parts, Pulvis Talci 10 parts, calcium-base bentonite 3.2 parts, molybdenum bisuphide 11 parts, politef
Micropowder 8 parts, accelerator 2 parts, tribenzoin 5.3 parts, 2,2'-ethylenedioxybis(ethanol). two tricaprylate 1.2 parts, inclined benzene
Three sour three monooctyl esters 1.5 parts, four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester 0.88 part, three (2,
4-di-tert-butyl-phenyl) phosphite ester 1.45 parts, 2 parts of phenol amine age resistor, eight vinyl silsesquioxanes 3.6
Part, cyclobufene sultone 1 part, fire retardant 14 parts.
5. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-4,
It is characterized in that, described silicon nitride nano powder be particle diameter be that the silicon nitride nano powder of 20-35nm, particle diameter are
The silicon nitride nano powder of 45-60nm, particle diameter are that the silicon nitride nano powder of 65-80nm is by weight
The mixture of 4-15:3-10:1-5.
6. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-5,
It is characterized in that, described accelerator is accelerant NOBS, accelerator TATD, accelerator T, accelerant CZ, rush
Enter one or more the mixture in agent BBP.
7. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-6,
It is characterized in that, described phenol amine age resistor is prepared according to following technique: add 2-first in reaction vessel
Base acrylic acid, adds thionyl chloride at 5-10 DEG C, wherein, 2-methacrylic acid and thionyl chloride mole
Ratio is 1:1.5-2, is subsequently adding hydroquinone, and stirring reaction 2-3h after being warming up to 55-60 DEG C, reaction terminates
Intermediate A is obtained by distillation；By weight 5-10 part mutual-amido two polyaniline is added 15-30 part absolute ether
In, it is passed through nitrogen after stirring, at 0 DEG C, adds 3-5 part intermediate A and 3-5 part sodium carbonate, in room temperature
Lower stirring reaction 3-5h, reaction terminate after through sucking filtration, recrystallization, be dried to obtain intermediate B；By weight will
25-40 part 4-aminodiphenylamine addition 50-100 part dehydrated alcohol stirs, is subsequently adding 10-20 part
3-pi-allyl salicylide, reacts 3-5h at 65-75 DEG C, is passed through nitrogen, is subsequently adding 25-40 after stirring
Part intermediate B and 0.3-1.2 part Ammonium persulfate., stirring reaction 2-5h, reaction is cooled to room temperature, warp after terminating
Filter, wash, be dried to obtain described phenol amine age resistor.
8. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-7,
It is characterized in that, described phenol amine age resistor is prepared according to following technique: add 2-first in reaction vessel
Base acrylic acid, adds thionyl chloride at 8 DEG C, and wherein, 2-methacrylic acid with the mol ratio of thionyl chloride is
1:1.7, is subsequently adding hydroquinone, and after being warming up to 58 DEG C, stirring reaction 2.6h, reacts after terminating through distilling
To intermediate A；By weight 8 parts of mutual-amido two polyanilines are added in 21 parts of absolute ethers, logical after stirring
Enter nitrogen, at 0 DEG C, add 4.2 parts of intermediate A and 4 parts of sodium carbonate, be stirred at room temperature reaction 3.8h, instead
Through sucking filtration, recrystallization after should terminating, it is dried to obtain intermediate B；By weight by 35 parts of 4-aminodiphenylamines
Add in 85 parts of dehydrated alcohol and stir, be subsequently adding 16 parts of 3-pi-allyl salicylides, after stirring
React 4h at 70 DEG C, be passed through nitrogen, be subsequently adding 38 parts of intermediate B and 0.9 part of Ammonium persulfate., stirring reaction
3.5h, reaction is cooled to room temperature, through filtering, wash, be dried to obtain described phenol amine age resistor after terminating.
9. according to the ageing-resistant high flame-retardant cable of oil platform Special wear-resistant according to any one of claim 1-8,
It is characterized in that, described fire retardant is that red phosphorus, Firebrake ZB, aluminium titanates, cerium oxide, triphenyl phosphate are by weight
Amount is than the mixture for 1-5:3-8:2-6:1-5:4-15.
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| CN201610280784.7A CN105860285A (en) | 2016-04-29 | 2016-04-29 | Wear-resistant aging-resistant high-flame-retardant cable special for oil platform |
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| CN201610280784.7A CN105860285A (en) | 2016-04-29 | 2016-04-29 | Wear-resistant aging-resistant high-flame-retardant cable special for oil platform |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206718A (en) * | 2018-09-29 | 2019-01-15 | 安徽兆拓新能源科技有限公司 | A kind of anti-aging CABLE MATERIALS of photovoltaic apparatus high tenacity |
| CN110885481A (en) * | 2019-11-27 | 2020-03-17 | 上海捷赢密封技术有限公司 | High-temperature wear-resistant sealing ring and preparation method thereof |
| CN112037969A (en) * | 2020-08-27 | 2020-12-04 | 远东电缆有限公司 | Aluminum alloy cable for new energy automobile and production process |
| CN115214172A (en) * | 2022-06-24 | 2022-10-21 | 江阴市斯强传动科技有限公司 | Low-resistance high-wear-resistance temperature-resistant light conveying belt and manufacturing method thereof |
-
2016
- 2016-04-29 CN CN201610280784.7A patent/CN105860285A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206718A (en) * | 2018-09-29 | 2019-01-15 | 安徽兆拓新能源科技有限公司 | A kind of anti-aging CABLE MATERIALS of photovoltaic apparatus high tenacity |
| CN110885481A (en) * | 2019-11-27 | 2020-03-17 | 上海捷赢密封技术有限公司 | High-temperature wear-resistant sealing ring and preparation method thereof |
| CN112037969A (en) * | 2020-08-27 | 2020-12-04 | 远东电缆有限公司 | Aluminum alloy cable for new energy automobile and production process |
| CN115214172A (en) * | 2022-06-24 | 2022-10-21 | 江阴市斯强传动科技有限公司 | Low-resistance high-wear-resistance temperature-resistant light conveying belt and manufacturing method thereof |
| CN115214172B (en) * | 2022-06-24 | 2023-12-08 | 江阴市斯强传动科技有限公司 | Low-resistance high-wear-resistance temperature-resistant light conveyor belt and manufacturing method thereof |
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Application publication date: 20160817 |