CN105851469A - Trace element chromium feed additive, preparation and application method thereof - Google Patents
Trace element chromium feed additive, preparation and application method thereof Download PDFInfo
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- CN105851469A CN105851469A CN201510026825.5A CN201510026825A CN105851469A CN 105851469 A CN105851469 A CN 105851469A CN 201510026825 A CN201510026825 A CN 201510026825A CN 105851469 A CN105851469 A CN 105851469A
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Abstract
The invention discloses a trace element chromium feed additive, a preparation and an application method thereof. The trace element chromium feed additive is the active chromium-containing cation exchange resin, by weight percentage, content of chromium in the cation exchange resin is 0.05-0.5%. The preparation method uses the characteristics of the exchange and absorption effects of the cation exchange resin and positive ions, trivalent chromium ions are loaded in the cation exchange resin, the cation exchange resin is a controlled/slow-release carrier with excellent performance, has controlled/slow-release effect on the loaded chromium, so that the chromium absorption utilization rate is greatly increased. The trace element chromium feed additive is added in a feed for aquatic animal, cattle, sheep, and livestock and poultry with addition amount accounting 0.1-1.0 mg/kg (by referring chromium) of total weight of the feed, can enhance animal immunity, promotes growth and increases feed utilization rate, and increases the efficacy for increasing carcass lean-meat percentage and laying rate.
Description
Technical field
The present invention relates to a kind of trace element chromium forage additive and preparation and using method.
Background technology
According to the difference of resin physical arrangement, ion exchange resin can be divided into gel-type and the big class of macroporous ion-exchange resin two.Gel type resin is the ion exchange resin of the homogeneous polymeric gel structure of a class appearance transparent, produces micropore after water suction in resin-phase, and counter ion is diffusible to enter to carry out ion exchange in the micropore that produced by absorbing water.The basic characteristics of macroreticular ion exchange resin are dry inside whole resin, wet or shrink, swelling all there is the duct more, bigger than general gel-type in water, thus surface area is big, in ion exchange process, the easy diffusion mobility of ion, exchange velocity is very fast.
Ion exchange resin is applied to the medical separation of analytical chemistry and purification pure water preparation and for a long time in the recent period for fields such as environmental conservation blood purifications.
Summary of the invention
It is an object of the invention to provide a kind of trace element chromium forage additive and preparation and using method.
Trace element chromium forage additive is a kind of cation exchange resin containing active chromium using chromic salt to be prepared from through ionic adsorption, exchange reaction with cation exchange resin, by weight percentage, chromium content in cation exchange resin is 0.05~0.5%.
The preparation method of trace element chromium forage additive, comprises the following steps:
1) cation exchange resin is placed in resin volume 1~the 0.5 of 2 times~2mol/L hydrochloric acid solution soak 2~5 hours, drain after acid solution with water rinsing to neutral;
2) it is cation exchange resin weight 0.05~the chromic salts of 0.5% by chrome content, it is pre-configured to the aqueous solution of 0.1~1.0mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 4.0~5.5, room temperature reaction 4~7 hours;
3) detecting step 2) pH value of reactant liquor, regulate with alkaline solution, making reacting liquid pH value is 6.0~7.0;Wash 2~5 times, filter or centrifuge dehydration;
4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.
The chromate used in invention can be Chlorizate chromium, chromic nitrate, chromium acetate or chromic sulfate.Alkaline solution be concentration be the aqueous solution of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate or the potassium bicarbonate of 0.5~5moL/L.
The using method of trace element chromium forage additive: in terms of chromium by account for the 0.1 of feedstuff gross weight~the additive capacity of 1.0mg/kg admix in aquatic animal, cattle, sheep, animal and fowl fodder.
The invention have the advantage that
(1) utilizing cation exchange resin can play the feature of absorption, exchange interaction with cation, loaded to by chromium in cation exchange resin, implementation is easy, and production suitable for industrialized, cost is relatively low.
(2) it is the control slow-released carrier of a kind of function admirable due to ion exchange resin, the chromium loaded is had control slow releasing function, thus substantially increases chrome uptake utilization rate.
(3) trace element chromium forage additive of the present invention is prone to mix with feedstuff, forms dispersed system, easy to use.
(4) trace element chromium forage additive obtained by the present invention has enhancing animal immunizing power, promotes growth and improves efficiency of feed utilization, improves the effect such as carcass lean meat percentage, egg fowl laying rate, applied widely.
Detailed description of the invention
Cation exchange resin includes storng-acid cation exchange resin and weak-acid cation-exchange resin.Cation exchange resin is with acid function base, including highly acid (sulfonic group ,-SO3And faintly acid (carboxylic acid group-COOH, phosphate-PO H)3H2)
Function base, the polymer that can swap with cation.According to the difference of resin physical arrangement, cation exchange resin can be gel-type or macroporous ion-exchange resin.Cation exchange resin skeleton is polystyrene or acrylic acid series.
Embodiment 1
1) by 001 × 7 commercially available strongly acidic styrene type cation exchange resin, (this product is equivalent to U.S. Amberrlite IR-120 Dowex-50, West Germany Lewatit-100, Japan DiaonSK-1), it is placed in 0.5mol/L hydrochloric acid solution isopyknic with resin to soak 5 hours, the most neutral with water rinsing after draining acid solution;
2) by the Chlorizate chromium that chrome content is cation exchange resin weight 0.05%, be pre-configured to the aqueous solution of 0.1mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 4.0, room temperature reaction 4 hours;
3) detecting step 2) pH value of reactant liquor, with the sodium hydrate aqueous solution regulation that concentration is 0.5moL/L, making reacting liquid pH value is 6.0;Wash 2 times, filtering means dehydration;
4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.By weight percentage, chromium content in cation exchange resin is 0.05%.
Embodiment 2
1) by commercially available 001 × 12/14/16 strongly acidic styrene type cation exchange resin, (this product is equivalent to the U.S.: Amberlite IR-132, IR-130, IR-124), the 2mol/L hydrochloric acid solution being placed in resin volume 2 times soaks 2 hours, the most neutral with water rinsing after draining acid solution;
2) by the chromic nitrate that chrome content is cation exchange resin weight 0.5%, be pre-configured to the aqueous solution of 1.0mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 5.5, room temperature reaction 7 hours;
3) detecting step 2) pH value of reactant liquor, with the potassium hydroxide aqueous solution regulation that concentration is 5moL/L, making reacting liquid pH value is 7.0;Wash 5 times, centrifuge dehydration;
4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.By weight percentage, chromium content in cation exchange resin is 0.5%.
Embodiment 3
1) by commercially available D001 macropore strong acid polystyrene cation conversion resin, (this product is equivalent to the U.S.: Amberlite200, West Germany: Lewaitet-SP120), the 1mol/L hydrochloric acid solution being placed in resin volume 1.5 times soaks 3 hours, the most neutral with water rinsing after draining acid solution;
2) by the chromium acetate that chrome content is cation exchange resin weight 0.1%, be pre-configured to the aqueous solution of 0.5mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 5.0, room temperature reaction 6 hours;
3) detecting step 2) pH value of reactant liquor, with the aqueous sodium carbonate regulation that concentration is 1moL/L, making reactant liquor pH value is 6.5;Wash 3 times, filtering means dehydration;
4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.By weight percentage, chromium content in cation exchange resin is 0.1%.
Embodiment 4
1) by commercially available D113 macropore acidulous acrylic acid's cation exchanger resin, (this product is equivalent to Germany LewatitCNP-80, U.S. AmberliteIRC-84), the 0.5mol/L hydrochloric acid solution being placed in resin volume 2 times soaks 5 hours, the most neutral with water rinsing after draining acid solution;
2) by the chromic sulfate that chrome content is cation exchange resin weight 0.3%, be pre-configured to the aqueous solution of 0.2mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 5.0, room temperature reaction 7 hours;
3) detecting step 2) pH value of reactant liquor, regulate with the sodium bicarbonate aqueous solution of 5moL/L, making reacting liquid pH value is 7.0;Wash 5 times, centrifuge dehydration;
4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.By weight percentage, chromium content in cation exchange resin is 0.3%.
Claims (2)
1. a trace element chromium forage additive and preparation and using method, it is characterized in that, it is a kind of cation exchange resin containing active chromium using chromic salt to be prepared from through ionic adsorption, exchange reaction with cation exchange resin, by weight percentage, chromium content in cation exchange resin is 0.05~0.5%, described chromic salts is Chlorizate chromium, chromic nitrate, chromium acetate or chromic sulfate, tool
Preparation step is as follows: 1) cation exchange resin is placed in resin volume 1~the 0.5 of 2 times~2mol/L hydrochloric acid solution soak 2~5 hours, put
The most neutral with water rinsing after acid solution to the greatest extent;2) it is cation exchange resin weight 0.05~the chromic salts of 0.5% by chrome content, it is pre-configured to the aqueous solution of 0.1~1.0mol/L, be slowly added to step 1 with stirring) resin in, the pH value detecting and regulating reactant liquor is 4.0~5.5, room temperature reaction 4~7 hours;3) detecting step 2) pH value of reactant liquor, regulate with alkaline solution, making reacting liquid pH value is 6.0~7.0;Wash 2~5 times, filter or centrifuge dehydration;4) by step 3) filter cake of gained dries at less than 70 DEG C, pulverizes, and obtains trace element chromium forage additive.
One the most according to claim 1 contains trace element chromium forage additive, it is characterised in that described alkaline solution be concentration be the aqueous solution of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate or the potassium bicarbonate of 0.5~5mol/L.
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CN201510026825.5A CN105851469A (en) | 2015-01-20 | 2015-01-20 | Trace element chromium feed additive, preparation and application method thereof |
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