CN105839296A - Three-dimensional net structure with sound attenuation and high elasticity performance - Google Patents

Three-dimensional net structure with sound attenuation and high elasticity performance Download PDF

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Publication number
CN105839296A
CN105839296A CN201610254593.3A CN201610254593A CN105839296A CN 105839296 A CN105839296 A CN 105839296A CN 201610254593 A CN201610254593 A CN 201610254593A CN 105839296 A CN105839296 A CN 105839296A
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Prior art keywords
space network
elastomer
noise reduction
elastomeric property
accounts
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CN201610254593.3A
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CN105839296B (en
Inventor
瞿锋
瞿一锋
徐明明
胡军
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JIANGSU HESHILI NEW MATERIAL CO Ltd
Jiangyin Hechuang Elastomers New Materials Technology Co Ltd
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JIANGSU HESHILI NEW MATERIAL CO Ltd
Jiangyin Hechuang Elastomers New Materials Technology Co Ltd
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Priority to CN201610254593.3A priority Critical patent/CN105839296B/en
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/018Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the shape
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/03Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments at random
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention relates to a three-dimensional net structure with sound attenuation and high elasticity performance. The structure is made of a thermoplastic elastomer, the material hardness is in a range of 80-98 A, the density of the three-dimensional net structure is 20-100 kg/m<3>, and the structure is made of two different types of fibers including (1) hollow fibers which have the wire diameter of 0.3-2 mm and account for 40%-95% of all hole counts and (2) solid special-shaped fibers which have the wire diameter of 0.05-0.6 mm and account for 5%-60% of all hole counts. The compressive deformation durability, resilience, adaptability and sound attenuation performance of a support product are improved, so that the three-dimensional net structure has the longer service life and sound attenuation comfort when used as a buffer material.

Description

A kind of space network with noise reduction, elastomeric property
Technical field
The present invention relates to as supporting the space network used, be specifically related to a kind of there is noise reduction and elastomeric property Space network.
Background technology
Space network belongs to the products formed of elastic construction, and using thermoplastic elastomer is that strip fibre made by raw material Dimension, ribbon fibre is curled into space multistory network structure again, and material can re-work recovery and use, and comprises a large amount of sky in structure Gap, has the most ventilative and lightweight performance, uses as supporting pad and may replace traditional thermoset polyurethane foamed cotton, no Only can reduce environmental pressure, more give the more preferable comfortableness of product.But when described space network, when compression reaction Can produce certain noise, these noises are due to the sound occurred when strip crimped fibre rubs, and use as cushion pad Time, people can be allowed to feel ear-piercing unhappy, when being especially applicable to bedding. a little sound is all likely to result in sleep discomfort, exploitation There is the space network of the elastomeric property of noise reduction, become aobvious reusing especially in actual applications.
When space network uses the softest elastomer as material, and the sound of network structure compression is the least, but Using too soft elastomer is material, then this space network supporting force is not enough, sleeps sense discomfort and Long-Time Service is prone to collapse Fall into, reduce Acceptable life.
When space network uses hollow ribbon fibre structure to replace special solid structure, can promote solid netted Structure supporting force, but because being the structure of hollow, line footpath is relatively thick again, when compression, is more easy to send bigger noise.
When space network fiber abutment is the most, the sound of network structure compression is the least, but abutment is more Many expression product densities are the highest, uncontrollable required indentation force deflection.
Summary of the invention
The technical problem to be solved provides a kind of for above-mentioned prior art and has noise reduction, elastomeric property Space network, improves and supports buckling durability, resilience and the adaptive of product and sound-deadening properties, make this space network Also have the comfortableness of noise reduction as padded coaming concurrently except having longer service life when using.
The present invention solves the technical scheme that the problems referred to above are used: a kind of have noise reduction, elastomeric property solid netted Structure, is made up of thermoplastic elastomer, and this space network density is 20~100kg/m3, by two kinds of different kenel fibers Making, two kinds of different kenel fibers are respectively
(1) doughnut: line footpath, between 0.3~2mm, accounts for the 40~95% of all silk hole count point rates;
(2) solid special fiber, line footpath, between 0.05~0.6 mm, accounts for all silk hole count point rates 5~60%.
Further, thermoplastic elastomer can be ethylene octane copolymer, thermoplastic polyurethane class elastomer, heat Plasticity polyester elastomer or the polyamide-based elastomer of thermoplasticity.
Preferably, the thickness of described space network is 15~200mm, and material hardness is between 80~98A.
Above-mentioned dimorphism state fiber space network manufacture method is, on extruder, by the heat after measuring pump measures Plasticity elastomer is depressed in spinning plate, and spinning plate has the silk hole of two kinds of different kenels, can spray doughnut after spinneret, Line footpath, between 0.3~2mm, accounts for the 40~95% of all silk holes point rate, and solid special line, line footpath between 0.05~0.6mm, Account for all silk hole count point rates 5~60%.
It is an advantage of the current invention that: doughnut plays the effect improving supporting force, makes product have elastomeric property, it is ensured that The prolongation in product service life, accounts for the 40~95% of all silk holes point rate, and weight fraction is 70~99.5%.Described solid special Fiber, owing to line footpath is relatively thin, accounts for the 5~60% of all silk hole count point rates, and weight fraction is 0.5~30%, and its quantity number is to whole Volume density impact is little.But the addition of solid special fiber, improves when minimal effect space network density Space network fiber abutment, it is sound-deadening properties that this structure has preferably compression, also improves durability of product, additionally can also Arrangement regulation and control by solid special fiber increase the sense of touch of space network.
Space network in the present invention uses doughnut and the staggered combination of solid special fiber, and its doughnut rises To the effect of raising supporting force, as reinforcing bar, play buckling durability and the supportive improving space network, and solid Heterotypic fibre part, improves space network fiber abutment, makes this structure have preferably compression sound-deadening properties, also increases Durability that space network is good and comfort level, it is ensured that the comfortableness of noise reduction and extend it simultaneously and use longevity when product uses Life.The skin composition of the present invention selects thermoplastic elastomer, can reduce space network supportive owing to hardness is the lowest, need to enter One step limits the preferred hardness scope (shore hardness as 80~98A) of thermoplastic elastomer, with reach best supportive and Longer service life.
It addition, by controlling doughnut and the ratio of solid special fiber, it is achieved that changing indentation force deflection hardly Under, adjustable go out noise reduction and there is the space network of different sense of touch, when using as buffering, support member, satisfied difference makes The use requirement of user, strengthens the adaptive of application.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the embodiment of the present invention two kinds different kenel fiber spinneret point rate.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Table 1 each embodiment materials list
In upper table, DMT/BDO is dimethyl terephthalate (DMT)/Isosorbide-5-Nitrae-dibutylene glycol, and PTMEG is polytetramethylene ether diol.
Embodiment 1
A kind of space network with noise reduction, elastomeric property, the spinneret kenel constituting structure includes doughnut and reality Heart heterotypic fibre interlocks.Doughnut and solid special filament hole count point rate are 56:44.Concrete preparation method is, A-1 raw material Send into extruder, in extruder, be heated to 230 DEG C of molten conditions, after measuring pump measures, be transported to spinneret, spinneret Infrared ray insulation is used, it is to avoid thinner solid special fiber is solidification ahead of time before staggered, and the fiber woven is 50 between water tank DEG C warm water obtains space network after dies compress is molded, by controlling pulling speed by space network density control System is at 55kg/m3, and it is 255N that its space network 40% compresses compressive hardness, and permanent set is 3.8%, and endurance is pressed repeatedly After contracting, Hardness loss leads is 25.3%.During Repeated Compression test, sound is fairly small, sound-deadening properties evaluation, is classified as excellent.
Embodiment 2
Concrete preparation method is similar to Example 1, and heating-up temperature is set to 210 DEG C of molten conditions, is transported to spray through measuring pump Filament plate, uses infrared ray insulation between spinneret to water tank, it is to avoid thinner solid special fiber is solidification ahead of time before staggered, weaves Fiber in 20 DEG C of cold water through dies compress be molded after obtain space network, by control pulling speed by solid netted Density of texture controls at 73kg/m3, and it is 234N that its space network 40% compresses compressive hardness, and compression set rate is 4.8%, after endurance Repeated Compression, Hardness loss leads is 34.1%.During Repeated Compression test, sound is fairly small, sound-deadening properties evaluation, It is classified as excellent.
Comparative example 1
A kind of space network with elastomeric property, the spinneret constituting structure is doughnut kenel, is sent by A-1 raw material Enter extruder, be heated to 230 DEG C of molten conditions in extruder, be transported to spinneret through measuring pump, adopt between spinneret to water tank Infrared ray is incubated, and the fiber woven obtains space network in 50 DEG C of warm water after dies compress is molded, and is led by control Draw speed by space network density domination at 53kg/m3, it is 244N that its space network 40% compresses compressive hardness, pressure Compression permanent deformation rate is 4.4%, and after endurance Repeated Compression, Hardness loss leads is 29.6%.During Repeated Compression test, sound is bigger. Sound-deadening properties evaluation, is classified as bad.
Comparative example 2
Concrete preparation method is similar to comparative example 1, and selection A-2 is material, obtains space network, led by control after shaping Drawing speed by space network density domination at 71kg/m3, it is 232N that its space network 40% compresses compressive hardness, pressure Compression permanent deformation rate is 5.1%, and after endurance Repeated Compression, Hardness loss leads is 36.6%.During Repeated Compression test, sound-deadening properties comment Valency, is classified as still may be used.But material hardness is relatively low.
Comparative example 3
Concrete preparation method is similar to comparative example 1, and selection B-1 is material, obtains space network, led by control after shaping Drawing speed by space network density domination at 51kg/m3, it is 151N that its space network 40% compresses compressive hardness, pressure Compression permanent deformation rate is 5.1%, and after endurance Repeated Compression, Hardness loss leads is 34.6%.During Repeated Compression test, sound is less. Sound-deadening properties evaluation, is classified as excellent.This material is owing to using hardness relatively low, therefore has sound-deadening properties, but also because hardness is low, 40% Compression compressive hardness is that support force is not enough.And Hardness loss leads higher after endurance Repeated Compression, unfavorable durable use.
Comparative example 4
Concrete preparation method is similar to comparative example 1, and selection B-2 is material, obtains space network, led by control after shaping Drawing speed by space network density domination at 71kg/m3, it is 132N compression that its space network 40% compresses compressive hardness Permanent set is 6.2%, and after endurance Repeated Compression, Hardness loss leads is 44.3%.During Repeated Compression test, sound is less.Disappear Sound is evaluated, and is classified as excellent.This material is owing to using hardness relatively low, therefore has sound-deadening properties, but also because hardness is low, 40% compression Compressive hardness support force is not enough.And Hardness loss leads higher after endurance Repeated Compression, use the most durable.
Concrete method of testing is as follows:
1, line footpath: extract fiber from space network out, use 20 times of light microscope blend proportion ruler measurement diameters, at random Extract 5 fibers to average.
2, thickness: use pachometer to measure product thickness, randomly select 5 samples and average.
3, density: product is put into baking oven, baking oven is set to 80 DEG C of * 3hr, it is ensured that after moisture removal, measures the length of product Wide height calculates volume, and weighs with the precision balance of three after being accurate to decimal point, calculates density afterwards.
4,40% indentation force deflection test: under 23 DEG C of steady temperatures, be placed in by product between upper and lower two platens, in test speed Under degree 100mm/min, being compressed to strain 40%, the downward compressed products of upper platen, the load measuring gauge of upper end is i.e. experienced pressure, and is incited somebody to action Pressure is converted into voltage signal and is defeated by display parsing, force value is shown on screen simultaneously, tests and average for three times.
5, compression set rate: under 23 DEG C of steady temperatures, 50% compress variation, after 22 hours, observe product extensive The change of thickness after multiple.Thickness * 100% before compression set amount=(thickness difference before and after product test)/product test, tests three Secondary average.
6, endurance Repeated Compression Hardness loss leads: under 23 DEG C of steady temperatures, and product is put into Repeated Compression test On the lower platform of instrument, with compression stress 750N, the frequency Repeated Compression product of 70 times per minute, after reaching 80,000 times, evaluate the property of product Energy.Endurance Repeated Compression Hardness loss leads=(before and after product test, hardness power is poor)/product test before hardness power * 100%, test Average for three times.
7, sound-deadening properties evaluation is compressed: by space network continued compression, 3 different testers sound is disappeared Sound is evaluated, and is classified as excellent, Shang Ke, bad 3 grades.
8, silk hole count divides rate: with the solid hole count of spinneret with hollow hole count is relevant, calculates space network and also can obtain Go out, take the sample of 5cm*5cm*1cm thickness, the abutment of doughnut with solid special fiber is taken apart, calculate hollow respectively Fiber and the quantity of solid special fiber.
Fiber count/(the doughnut number+solid special fiber count) that silk hole count point rate=be intended to calculates
Test result is shown in Table 2
The performance comparison of table 2 embodiment 1 to 2 and comparative example 1 to 4
In addition to the implementation, other embodiment, all employing equivalents or equivalence substitute mode have been present invention additionally comprises The technical scheme formed, all should fall within the scope of the hereto appended claims.

Claims (6)

1. having a space network for noise reduction, elastomeric property, be made up of thermoplastic elastomer, material hardness is between 80 ~98A, it is characterised in that: this space network density is 20~100kg/m3, it is made up of two kinds of different kenel fibers, two kinds Different kenel fibers are respectively
(1) doughnut: line footpath, between 0.3~2mm, accounts for the 40~95% of all silk hole count point rates;
(2) solid special fiber, line footpath, between 0.05~0.6 mm, accounts for all silk hole count point rates 5~60%.
The space network with noise reduction, elastomeric property the most according to claim 1, it is characterised in that: described heat Plasticity elastomer can be ethylene octane copolymer, thermoplastic polyurethane class elastomer, thermoplasticity polyester elastomer Or the polyamide-based elastomer of thermoplasticity.
The space network with noise reduction, elastomeric property the most according to claim 1 and 2, it is characterised in that: described vertical The cancellated thickness of body is 15~200mm.
4. the manufacture method of a space network with noise reduction, elastomeric property, it is characterised in that: on extruder, will Thermoplastic elastomer after measuring pump measures is depressed in spinning plate, and spinning plate has the silk hole of two kinds of different kenels, spinneret After can spray doughnut, line footpath, between 0.3~2mm, accounts for the 40~95% of all silk holes point rate, and solid special line, Line footpath, between 0.05~0.6mm, accounts for all silk hole count point rates 5~60%.
The manufacture method of the space network with noise reduction, elastomeric property the most according to claim 4, its feature exists Can be that ethylene octane copolymer, thermoplastic polyurethane class elastomer, thermoplasticity gather in: described thermoplastic elastomer Esters elastomer or the polyamide-based elastomer of thermoplasticity.
The manufacture method of the space network with noise reduction, elastomeric property the most according to claim 4, its feature exists In: the thickness of described space network is 15~200mm.
CN201610254593.3A 2016-04-22 2016-04-22 A kind of space network with noise reduction, elastomeric property Active CN105839296B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113022056A (en) * 2021-03-26 2021-06-25 佛山市酷纤高分子家居用品科技有限公司 Light elastic net structure
CN113930900A (en) * 2021-10-29 2022-01-14 延锋国际座椅系统有限公司 Thermoplastic fiber net structure and automotive interior part

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2525107Y (en) * 2002-02-10 2002-12-11 北京神州瑞琪环保科技有限公司 Stereo net material
US20050176326A1 (en) * 2004-01-30 2005-08-11 Bond Eric B. Shaped fiber fabrics
US20050227563A1 (en) * 2004-01-30 2005-10-13 Bond Eric B Shaped fiber fabrics
CN201506866U (en) * 2009-09-18 2010-06-16 辛婷芬 Special-shaped hole spinneret plate
CN104562731A (en) * 2015-01-08 2015-04-29 江阴和创弹性体新材料科技有限公司 Three-dimensional mesh structure with high elasticity
EP2955259A1 (en) * 2014-06-13 2015-12-16 J.H. Ziegler GmbH Auxiliary composite material flow nonwoven fabric

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2525107Y (en) * 2002-02-10 2002-12-11 北京神州瑞琪环保科技有限公司 Stereo net material
US20050176326A1 (en) * 2004-01-30 2005-08-11 Bond Eric B. Shaped fiber fabrics
US20050227563A1 (en) * 2004-01-30 2005-10-13 Bond Eric B Shaped fiber fabrics
CN201506866U (en) * 2009-09-18 2010-06-16 辛婷芬 Special-shaped hole spinneret plate
EP2955259A1 (en) * 2014-06-13 2015-12-16 J.H. Ziegler GmbH Auxiliary composite material flow nonwoven fabric
CN104562731A (en) * 2015-01-08 2015-04-29 江阴和创弹性体新材料科技有限公司 Three-dimensional mesh structure with high elasticity

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113022056A (en) * 2021-03-26 2021-06-25 佛山市酷纤高分子家居用品科技有限公司 Light elastic net structure
CN113930900A (en) * 2021-10-29 2022-01-14 延锋国际座椅系统有限公司 Thermoplastic fiber net structure and automotive interior part

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