CN105839181B - 具有优化的材料组成的多晶金刚石结构 - Google Patents
具有优化的材料组成的多晶金刚石结构 Download PDFInfo
- Publication number
- CN105839181B CN105839181B CN201610145112.5A CN201610145112A CN105839181B CN 105839181 B CN105839181 B CN 105839181B CN 201610145112 A CN201610145112 A CN 201610145112A CN 105839181 B CN105839181 B CN 105839181B
- Authority
- CN
- China
- Prior art keywords
- diamond
- grain size
- volume
- volume fraction
- working face
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/02—Elements
- C30B29/04—Diamond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
- B22F3/15—Hot isostatic pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
- B24D3/10—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements for porous or cellular structure, e.g. for use with diamonds as abrasives
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B28/00—Production of homogeneous polycrystalline material with defined structure
- C30B28/02—Production of homogeneous polycrystalline material with defined structure directly from the solid state
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
- E21B10/56—Button-type inserts
- E21B10/567—Button-type inserts with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
- C22C2026/005—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds being borides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
- C22C2026/006—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds being carbides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
- C22C2026/007—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds being nitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
- C22C2026/008—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds other than carbides, borides or nitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2204/00—End product comprising different layers, coatings or parts of cermet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249954—With chemically effective material or specified gas other than air, N, or carbon dioxide in void-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249961—With gradual property change within a component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Earth Drilling (AREA)
- Carbon And Carbon Compounds (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Percussive Tools And Related Accessories (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/954,403 US8689912B2 (en) | 2010-11-24 | 2010-11-24 | Polycrystalline diamond constructions having optimized material composition |
| US12/954,403 | 2010-11-24 | ||
| CN201180056837.2A CN103379974B (zh) | 2010-11-24 | 2011-11-23 | 具有优化的材料组成的多晶金刚石结构 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180056837.2A Division CN103379974B (zh) | 2010-11-24 | 2011-11-23 | 具有优化的材料组成的多晶金刚石结构 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105839181A CN105839181A (zh) | 2016-08-10 |
| CN105839181B true CN105839181B (zh) | 2019-04-19 |
Family
ID=45319397
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610145112.5A Active CN105839181B (zh) | 2010-11-24 | 2011-11-23 | 具有优化的材料组成的多晶金刚石结构 |
| CN201180056837.2A Active CN103379974B (zh) | 2010-11-24 | 2011-11-23 | 具有优化的材料组成的多晶金刚石结构 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180056837.2A Active CN103379974B (zh) | 2010-11-24 | 2011-11-23 | 具有优化的材料组成的多晶金刚石结构 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US8689912B2 (https=) |
| JP (2) | JP6317109B2 (https=) |
| CN (2) | CN105839181B (https=) |
| GB (1) | GB2498882A (https=) |
| WO (1) | WO2012071515A2 (https=) |
| ZA (1) | ZA201303382B (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9593577B2 (en) * | 2012-09-28 | 2017-03-14 | Element Six Gmbh | Pick tool having a super-hard planar strike surface |
| US9475176B2 (en) | 2012-11-15 | 2016-10-25 | Smith International, Inc. | Sintering of thick solid carbonate-based PCD for drilling application |
| US10315175B2 (en) | 2012-11-15 | 2019-06-11 | Smith International, Inc. | Method of making carbonate PCD and sintering carbonate PCD on carbide substrate |
| US9273724B1 (en) * | 2012-12-11 | 2016-03-01 | Bruce Diamond Corporation | Thrust bearing pad having metallic substrate |
| GB201223530D0 (en) * | 2012-12-31 | 2013-02-13 | Element Six Abrasives Sa | A cutter element for rock removal applications |
| GB201321991D0 (en) * | 2013-12-12 | 2014-01-29 | Element Six Abrasives Sa | A polycrystalline super hard construction and a method of making same |
| GB201404782D0 (en) * | 2014-03-18 | 2014-04-30 | Element Six Abrasives Sa | Superhard constructions & methods of making same |
| US11014157B2 (en) | 2014-12-17 | 2021-05-25 | Schlumberger Technology Corporation | Solid PCD with transition layers to accelerate full leaching of catalyst |
| US10711331B2 (en) | 2015-04-28 | 2020-07-14 | Halliburton Energy Services, Inc. | Polycrystalline diamond compact with gradient interfacial layer |
| CN104832101B (zh) * | 2015-05-15 | 2018-07-03 | 中国水利水电第十工程局有限公司 | 双基材型切削元件及具有该切削元件的潜孔锤钻头 |
| CN104847277A (zh) * | 2015-05-15 | 2015-08-19 | 中国水利水电第十工程局有限公司 | 潜孔锤用聚晶金刚石多点切割钻头 |
| KR102020014B1 (ko) * | 2015-05-28 | 2019-09-09 | 핼리버튼 에너지 서비시즈 인코퍼레이티드 | 다결정 다이아몬드 공구를 제조하는 재료 편석 유도 방법 |
| WO2017075626A1 (en) * | 2015-10-30 | 2017-05-04 | Smith International, Inc. | Eruption minimization in thermally stable pcd products |
| RU2018125628A (ru) * | 2015-12-16 | 2020-01-16 | Даймонд Инновейшнз, Инк. | Поликристаллические алмазные шарошки с добавкой некаталитического материала и способы их изготовления |
| CN108884707B (zh) * | 2016-03-16 | 2021-08-24 | 戴蒙得创新股份有限公司 | 包含具有不同特性的环形区域的多晶金刚石体 |
| CN108057894B (zh) * | 2017-12-12 | 2019-11-15 | 鑫京瑞钨钢(厦门)有限公司 | 一种梯度硬质合金圆棒 |
| WO2019219906A1 (en) * | 2018-05-18 | 2019-11-21 | Element Six (Uk) Limited | Polycrystalline diamond cutter element and earth boring tool |
| CN110860693A (zh) * | 2019-11-28 | 2020-03-06 | 中国有色桂林矿产地质研究院有限公司 | 一种中空结构的超硬材料聚晶多层复合片及其制备方法 |
| TWI899117B (zh) * | 2019-12-11 | 2025-10-01 | 美商戴蒙創新公司 | 多晶鑽石複合片;胚料、切刀與包括其之切割工具;及製造方法 |
| EP4157570A1 (en) * | 2020-06-02 | 2023-04-05 | Saudi Arabian Oil Company | Producing catalyst-free pdc cutters |
| US12024470B2 (en) | 2021-02-08 | 2024-07-02 | Saudi Arabian Oil Company | Fabrication of downhole drilling tools |
| CN113968736B (zh) * | 2021-12-01 | 2022-12-30 | 西南交通大学 | 一种碲触媒的多晶金刚石烧结体及其制备方法 |
| CN119866260A (zh) * | 2022-09-30 | 2025-04-22 | 山高刀具公司 | 用于粉末注射模制部件的模制工具组件和方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86103664A (zh) * | 1985-04-29 | 1987-02-04 | 史密斯国际公司 | 改进的复合多晶态金刚石压坯 |
| EP1760165A2 (en) * | 2005-08-03 | 2007-03-07 | Smith International, Inc. | Polycrystalline Diamond Composite Construction Comprising Thermally Stable Diamond Volume |
| CN101646527A (zh) * | 2007-01-26 | 2010-02-10 | 戴蒙得创新股份有限公司 | 等级钻削刀具 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224380A (en) * | 1978-03-28 | 1980-09-23 | General Electric Company | Temperature resistant abrasive compact and method for making same |
| US4303442A (en) | 1978-08-26 | 1981-12-01 | Sumitomo Electric Industries, Ltd. | Diamond sintered body and the method for producing the same |
| US4333986A (en) | 1979-06-11 | 1982-06-08 | Sumitomo Electric Industries, Ltd. | Diamond sintered compact wherein crystal particles are uniformly orientated in a particular direction and a method for producing the same |
| JPS5747771A (en) | 1980-09-06 | 1982-03-18 | Sumitomo Electric Industries | Sintered body for linedrawing dice and manufacture |
| JPS57175775A (en) * | 1981-04-20 | 1982-10-28 | Showa Denko Kk | Diamond sintered body |
| SE457537B (sv) | 1981-09-04 | 1989-01-09 | Sumitomo Electric Industries | Diamantpresskropp foer ett verktyg samt saett att framstaella densamma |
| US4525178A (en) | 1984-04-16 | 1985-06-25 | Megadiamond Industries, Inc. | Composite polycrystalline diamond |
| DE3583567D1 (de) | 1984-09-08 | 1991-08-29 | Sumitomo Electric Industries | Gesinterter werkzeugkoerper aus diamant und verfahren zu seiner herstellung. |
| EP0181979B1 (en) | 1984-11-21 | 1989-03-15 | Sumitomo Electric Industries Limited | High hardness sintered compact and process for producing the same |
| JPH0437650A (ja) * | 1990-06-04 | 1992-02-07 | Exxon Res & Eng Co | 耐破壊性ダイヤモンド及びダイヤモンド複合物品の加工方法 |
| US7396505B2 (en) * | 1994-08-12 | 2008-07-08 | Diamicron, Inc. | Use of CoCrMo to augment biocompatibility in polycrystalline diamond compacts |
| US7396501B2 (en) * | 1994-08-12 | 2008-07-08 | Diamicron, Inc. | Use of gradient layers and stress modifiers to fabricate composite constructs |
| JP4954429B2 (ja) * | 2000-09-20 | 2012-06-13 | キャムコ、インターナショナル、(ユーケイ)、リミテッド | 触媒物質を枯渇させた表面を有する多結晶ダイヤモンド |
| GB2464864B (en) * | 2004-09-21 | 2010-08-04 | Smith International | Thermally stable diamond polycrystalline diamond constructions |
| US7726421B2 (en) * | 2005-10-12 | 2010-06-01 | Smith International, Inc. | Diamond-bonded bodies and compacts with improved thermal stability and mechanical strength |
| US8627904B2 (en) | 2007-10-04 | 2014-01-14 | Smith International, Inc. | Thermally stable polycrystalline diamond material with gradient structure |
| US9297211B2 (en) * | 2007-12-17 | 2016-03-29 | Smith International, Inc. | Polycrystalline diamond construction with controlled gradient metal content |
| GB2467570B (en) * | 2009-02-09 | 2012-09-19 | Reedhycalog Uk Ltd | Cutting element |
| US8567531B2 (en) | 2009-05-20 | 2013-10-29 | Smith International, Inc. | Cutting elements, methods for manufacturing such cutting elements, and tools incorporating such cutting elements |
| WO2011017582A2 (en) | 2009-08-07 | 2011-02-10 | Smith International, Inc. | Functionally graded polycrystalline diamond insert |
| US8857541B2 (en) * | 2009-08-07 | 2014-10-14 | Smith International, Inc. | Diamond transition layer construction with improved thickness ratio |
| US20110036643A1 (en) | 2009-08-07 | 2011-02-17 | Belnap J Daniel | Thermally stable polycrystalline diamond constructions |
| US8277722B2 (en) * | 2009-09-29 | 2012-10-02 | Baker Hughes Incorporated | Production of reduced catalyst PDC via gradient driven reactivity |
| WO2012021821A2 (en) * | 2010-08-13 | 2012-02-16 | Baker Hughes Incorporated | Cutting elements including nanoparticles in at least one portion thereof, earth-boring tools including such cutting elements, and ralted methods |
-
2010
- 2010-11-24 US US12/954,403 patent/US8689912B2/en active Active
-
2011
- 2011-11-23 CN CN201610145112.5A patent/CN105839181B/zh active Active
- 2011-11-23 CN CN201180056837.2A patent/CN103379974B/zh active Active
- 2011-11-23 GB GB201305929A patent/GB2498882A/en not_active Withdrawn
- 2011-11-23 JP JP2013541047A patent/JP6317109B2/ja active Active
- 2011-11-23 WO PCT/US2011/062047 patent/WO2012071515A2/en not_active Ceased
-
2013
- 2013-05-09 ZA ZA201303382A patent/ZA201303382B/en unknown
-
2014
- 2014-04-07 US US14/247,224 patent/US10173299B2/en active Active
-
2016
- 2016-12-26 JP JP2016251581A patent/JP2017141507A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86103664A (zh) * | 1985-04-29 | 1987-02-04 | 史密斯国际公司 | 改进的复合多晶态金刚石压坯 |
| EP1760165A2 (en) * | 2005-08-03 | 2007-03-07 | Smith International, Inc. | Polycrystalline Diamond Composite Construction Comprising Thermally Stable Diamond Volume |
| CN101646527A (zh) * | 2007-01-26 | 2010-02-10 | 戴蒙得创新股份有限公司 | 等级钻削刀具 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB201305929D0 (en) | 2013-05-15 |
| JP2014505162A (ja) | 2014-02-27 |
| US20140215927A1 (en) | 2014-08-07 |
| CN103379974B (zh) | 2016-04-13 |
| WO2012071515A2 (en) | 2012-05-31 |
| JP6317109B2 (ja) | 2018-05-09 |
| ZA201303382B (en) | 2020-11-25 |
| JP2017141507A (ja) | 2017-08-17 |
| WO2012071515A3 (en) | 2012-11-15 |
| CN105839181A (zh) | 2016-08-10 |
| CN103379974A (zh) | 2013-10-30 |
| US20120125696A1 (en) | 2012-05-24 |
| US8689912B2 (en) | 2014-04-08 |
| US10173299B2 (en) | 2019-01-08 |
| GB2498882A (en) | 2013-07-31 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |