CN105839024A - Heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for garbage power station fire grate and preparing method of heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material - Google Patents

Heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for garbage power station fire grate and preparing method of heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material Download PDF

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Publication number
CN105839024A
CN105839024A CN201610299057.5A CN201610299057A CN105839024A CN 105839024 A CN105839024 A CN 105839024A CN 201610299057 A CN201610299057 A CN 201610299057A CN 105839024 A CN105839024 A CN 105839024A
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resistant
alloy material
stainless steel
corrosion
heat
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CN201610299057.5A
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Inventor
颜银喜
周牧
肖学山
张玉刚
李钧
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Taizhou Jindongfang Special Steel Manufacturing Co Ltd
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Taizhou Jindongfang Special Steel Manufacturing Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention relates to a heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for a garbage power station fire grate. The alloy material comprises, by mass percent, 0.15%-0.45% of C, 23.0%-28.0% of Cr, 4.0%-6.0% of Ni, 0.5%-1.0% of Mo, 0.2%-2.0% of Al, 0.1%-0.4% of N, smaller than or equal to 1.0% of Mn, smaller than or equal to 1.5% of Si, smaller than or equal to 0.03% of P, smaller than or equal to 0.03% of S, smaller than or equal to 0.6% of C+N, and the balance Fe and inevitable impurities. The invention further relates to a preparing method of the heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for the garbage power station fire grate. A traditional conventional melting technology method is adopted for the alloy material, after burdening melting is conducted, pouring forming is performed, and solid dissolving of 1,000 DEG C to 1,200 DEG C and aging treatment of 700 DEG C to 900 DEG C are conducted. The heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material and the preparing method have the beneficial effects that nitride forming elements are added in duplex stainless steel resistant to chlorine ion corrosion at the same time, a large number of carbohydrates and nitrogenous compounds are separated out to increase the abrasion resistance of the duplex stainless steel casting alloy material under the condition that corrosion-resistant permission is met, the combination is optimized to ensure that the material has good heat resistance, abrasion resistance and corrosion resistance, and the using requirements under the specific severe environment are met.

Description

A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials and system thereof Preparation Method
Technical field
The present invention relates to the fire grate heat-resistant antifriction erosion two phase stainless steel casting of a kind of garbage power station Alloy material, the invention still further relates to a kind of garbage power station fire grate heat-resistant antifriction and loses two-phase stainless The preparation method of steel cast alloy materials, belongs to steel alloy material technical field.
Background technology
Two phase stainless steel cast steel occupies the heaviest in the development and application field of wear-and corrosion-resistant cast steel The effect wanted, especially in the field such as petrochemical industry and ocean engineering.
Along with the development in city is increasing, the process of house refuse becomes the most serious.At present The process of domestic waste mainly uses landfill and burning electricity generation.Waste incineration and generating electricity is according to burning Burn the technology that stove is different, be broadly divided into circulating fluidized bed incinerator and two kinds of skills of grate incinerator Art.Rubbish is directly burned by grate furnace technology, and the requirement to rubbish quality and composition is relatively low, Pre-treatment is simple, and flying dust amount is few, technology maturation, is the major technique that uses at present of developed country. Fire grate in grate incinerator technology is the Chief consumable accessory of this technology, is chronically at height Temperature, wash away with in high chloride ion corrosive environment, quite a few producer uses heat-resisting at present Austenite material, through the running of certain time, fire grate abrasion and excessive corrosion, is easily caused stove Row's fracture, shutdown can cause equipment breakdown not in time.For this, exploitation is a kind of high temperature resistant, wear-resisting same Time anti-chlorine ion corrosion new material be that this technology develops one of problem encountered further, as What resolves the relation improved between the service life of fire grate and rational manufacturing cost is this Bright original intention place.
The present invention is through the design of scientific research personnel and repetition test, by laboratory advanced instrument thing Reason simulation casting production also combines enterprise's scene trial-production checking, has fully probed into heat-resistant antifriction erosion double Alloys producing behavior in phase stainless cast steel part, optimize cast steel material formula, and establish with Its most supporting Technology for Heating Processing, forms the heat-resistant antifriction erosion of complete material and technology one Two phase stainless steel steel-casting manufacturing technology.
Summary of the invention
It is an object of the invention to provide a kind of high performance-price ratio, 650-950 DEG C of temperature range Inside there is two phase stainless steel cast steel material formula and the preparation side thereof of good wear and corrosion behavior Method.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel casting of the present invention is closed Gold copper-base alloy, this alloy material has following composition and mass percent: C:0.15-0.45, Cr:23.0-28.0, Ni:4.0-6.0, Mo:0.5-1.0, Al:0.2-2.0, N:0.1-0.4, Mn≤1.0, Si≤1.5, P≤0.03, S≤0.03, and meet C+N≤0.6, surplus is Fe With inevitable impurity, in this composition range, the solid solution structure of steel is ferrite and austenite.
The content of this alloy material austenite is 40-60%, and room temperature tensile intensity is 500-700 MPa, percentage elongation is more than 20%.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials Preparation method, this alloy material uses the smelting process that tradition is conventional, after dispensing melting, Cast molding, then through the solid solution of 1000-1200 DEG C and the Ageing Treatment of 700-900 DEG C.
The invention have the advantage that the reason of this heat-resistant antifriction corrosive-resisting double-phase stainless steel is: resistance to The two phase stainless steel of chloride ion corrosion is simultaneously introduced nitride forming element such as Al etc., full Under conditions of the anti-corrosion license of foot, in 650-950 DEG C uses temperature range, separate out the nitridation of a large amount of carbon Compound increases its wearability, and it is excellent heat-resisting resistance to that their optimum organization guarantees that this material has Mill corrosion resistance, meets the use requirement under specific severe rugged environment.
Detailed description of the invention
Embodiment 1
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel casting of the present invention is closed Gold copper-base alloy, this alloy material has following composition and a mass percent:
In this composition range, the solid solution structure of steel is ferrite and austenite, this alloy material Ovshinsky The content of body is 40%, and room temperature tensile intensity is 500MPa, and percentage elongation is more than 20%.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials Preparation method, this alloy material uses the smelting process that tradition is conventional, after dispensing melting, Cast molding, then through the solid solution of 1000 DEG C and the Ageing Treatment of 700 DEG C.
The invention have the advantage that the reason of this heat-resistant antifriction corrosive-resisting double-phase stainless steel is: resistance to The two phase stainless steel of chloride ion corrosion is simultaneously introduced nitride forming element such as Al etc., full Under conditions of the anti-corrosion license of foot, in 650 DEG C use temperature range, separate out a large amount of carboritride Increasing its wearability, it is resistance to that their optimum organization guarantees that this material has excellent heat-resistant antifriction Erosion property, meets the use requirement under specific severe rugged environment.
Embodiment 2
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel casting of the present invention is closed Gold copper-base alloy, this alloy material has following composition and a mass percent:
In this composition range, the solid solution structure of steel is ferrite and austenite, this alloy material Ovshinsky The content of body is 48%, and room temperature tensile intensity is 580MPa, and percentage elongation is more than 20%.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials Preparation method, this alloy material uses the smelting process that tradition is conventional, after dispensing melting, Cast molding, then through the solid solution of 1080 DEG C and the Ageing Treatment of 780 DEG C.
The invention have the advantage that the reason of this heat-resistant antifriction corrosive-resisting double-phase stainless steel is: resistance to The two phase stainless steel of chloride ion corrosion is simultaneously introduced nitride forming element such as Al etc., full Under conditions of the anti-corrosion license of foot, in 750 DEG C use temperature range, separate out a large amount of carboritride Increasing its wearability, it is resistance to that their optimum organization guarantees that this material has excellent heat-resistant antifriction Erosion property, meets the use requirement under specific severe rugged environment.
Embodiment 3
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel casting of the present invention is closed Gold copper-base alloy, this alloy material has following composition and a mass percent:
In this composition range, the solid solution structure of steel is ferrite and austenite, this alloy material Ovshinsky The content of body is 55%, and room temperature tensile intensity is 650MPa, and percentage elongation is more than 20%.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials Preparation method, this alloy material uses the smelting process that tradition is conventional, after dispensing melting, Cast molding, then through the solid solution of 1150 DEG C and the Ageing Treatment of 850 DEG C.
The invention have the advantage that the reason of this heat-resistant antifriction corrosive-resisting double-phase stainless steel is: resistance to The two phase stainless steel of chloride ion corrosion is simultaneously introduced nitride forming element such as Al etc., full Under conditions of the anti-corrosion license of foot, in 850 DEG C use temperature range, separate out a large amount of carboritride Increasing its wearability, it is resistance to that their optimum organization guarantees that this material has excellent heat-resistant antifriction Erosion property, meets the use requirement under specific severe rugged environment.
Embodiment 4
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel casting of the present invention is closed Gold copper-base alloy, this alloy material has following composition and a mass percent:
In this composition range, the solid solution structure of steel is ferrite and austenite, this alloy material Ovshinsky The content of body is 60%, and room temperature tensile intensity is 700MPa, and percentage elongation is more than 20%.
A kind of garbage power station fire grate heat-resistant antifriction erosion two phase stainless steel cast alloy materials Preparation method, this alloy material uses the smelting process that tradition is conventional, after dispensing melting, Cast molding, then through the solid solution of 1200 DEG C and the Ageing Treatment of 900 DEG C.
The invention have the advantage that the reason of this heat-resistant antifriction corrosive-resisting double-phase stainless steel is: resistance to The two phase stainless steel of chloride ion corrosion is simultaneously introduced nitride forming element such as Al etc., full Under conditions of the anti-corrosion license of foot, in 950 DEG C use temperature range, separate out a large amount of carboritride Increasing its wearability, it is resistance to that their optimum organization guarantees that this material has excellent heat-resistant antifriction Erosion property, meets the use requirement under specific severe rugged environment.

Claims (3)

1. fire grate heat-resistant antifriction in garbage power station loses a two phase stainless steel cast alloy materials, and its feature exists In: this alloy material there is following composition and mass percent: C:0.15-0.45, Cr:23.0-28.0, Ni:4.0-6.0, Mo:0.5-1.0, Al:0.2-2.0, N:0.1-0.4, Mn≤1.0, Si≤1.5, P≤0.03, S≤0.03, and meet C+N≤0.6, surplus is Fe and inevitable impurity, and in this composition range, steel consolidates Histolytica is ferrite and austenite.
A kind of garbage power station the most according to claim 1 fire grate heat-resistant antifriction erosion two phase stainless steel casting Make alloy material, it is characterised in that: the content of this alloy material austenite is 40-60%, room temperature tensile intensity For 500-700MPa, percentage elongation is more than 20%.
A kind of garbage power station the most according to claim 1 fire grate heat-resistant antifriction erosion two phase stainless steel casting Make the preparation method of alloy material, it is characterised in that: this alloy material uses the smelting technology side that tradition is conventional Method, after dispensing melting, cast molding, then at the solid solution of 1000-1200 DEG C and the timeliness of 700-900 DEG C Reason.
CN201610299057.5A 2016-05-06 2016-05-06 Heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for garbage power station fire grate and preparing method of heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material Pending CN105839024A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107245648A (en) * 2017-06-02 2017-10-13 江阴国润机械有限公司 High-temperature wearable fire grate segment and its casting mold and pouring technology
CN107254641A (en) * 2017-06-02 2017-10-17 江阴国润机械有限公司 High temperature oxidation resisting fire grate segment and its casting mold and pouring technology
CN111850388A (en) * 2019-04-26 2020-10-30 沈阳铸造研究所有限公司 Low-induction high-wear-resistance corrosion-resistant alloy for nuclear power station and preparation method and application thereof
CN113293335A (en) * 2021-07-27 2021-08-24 科华控股股份有限公司 Low-nickel precipitation hardening austenitic heat-resistant steel material and application thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107245648A (en) * 2017-06-02 2017-10-13 江阴国润机械有限公司 High-temperature wearable fire grate segment and its casting mold and pouring technology
CN107254641A (en) * 2017-06-02 2017-10-17 江阴国润机械有限公司 High temperature oxidation resisting fire grate segment and its casting mold and pouring technology
CN107254641B (en) * 2017-06-02 2019-03-19 江阴国润机械有限公司 High temperature oxidation resisting fire grate segment and its casting mold and pouring technology
CN111850388A (en) * 2019-04-26 2020-10-30 沈阳铸造研究所有限公司 Low-induction high-wear-resistance corrosion-resistant alloy for nuclear power station and preparation method and application thereof
CN111850388B (en) * 2019-04-26 2022-02-15 沈阳铸造研究所有限公司 Low-induction high-wear-resistance corrosion-resistant alloy for nuclear power station and preparation method and application thereof
CN113293335A (en) * 2021-07-27 2021-08-24 科华控股股份有限公司 Low-nickel precipitation hardening austenitic heat-resistant steel material and application thereof

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Application publication date: 20160810