CN105838316A - Flame-retardant silicone sealant for hollow glass - Google Patents
Flame-retardant silicone sealant for hollow glass Download PDFInfo
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- CN105838316A CN105838316A CN201610300425.3A CN201610300425A CN105838316A CN 105838316 A CN105838316 A CN 105838316A CN 201610300425 A CN201610300425 A CN 201610300425A CN 105838316 A CN105838316 A CN 105838316A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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Abstract
The invention relates to a sealing material, in particular to a flame-retardant silicone sealant for hollow glass. The flame-retardant silicone sealant is prepared from polymethylhydrosiloxane, (6-methoxy-4-quinolyl)(5-vinyl-1-diazabicyclo[2.2.2]octane-2-yl)methanol, 3beta-hydroxypregn-5,16-diene-20-ketone, 1,1,3,3-tetramethoxypropane, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy)ethyl acrylate and the like. The flame-retardant silicone sealant for the hollow glass is good in sealing effect, high in flame-retardant rating, excellent in various mechanical properties, simple in preparation method, high in construction efficiency, long in preservation time and suitable for being applied and popularized in the field of silicon sealants for the hollow glass.
Description
Technical field
The present invention relates to a kind of encapsulant, be specifically related to a kind of double glazing flame retardant type silicone sealant.
Background technology
Double glazing is invented in 1865 by American, it it is a kind of good heat insulation, sound insulation, beautiful and applicable and the New Building Materials of building deadweight can be reduced, it is with two panels (or three) glass, use high intensity high-air-tightness compound binding agent, sheet glass and the aluminum alloy frame including desiccant are bondd, the high-effect sound-and heat-insulated glass made.The multiple performance of double glazing is superior to ordinary double-layer glass, has therefore obtained the accreditation of countries in the world, and double glazing is by two panels or divided glass is evenly spaced with effectively support and perimeter bond seals, and makes glass interlayer be formed with the glass of the dry gas compartment.
Between glass and the glass of double glazing, leave certain space.Desiccant it is filled with, to ensure the aridity of air between sheet glass in frame.Two interlamellar spacings of double glazing are generally 8mm.High-performance hollow glass is different from general ordinary insulating glass, in addition to enclosing dry air in the middle of layer glass, also in glass intermediate air layer side, outside, to be coated with particulate metal film of last layer good in thermal property.It can end the suitable energy being mapped to indoor by the sun, plays bigger effect of heat insulation.
Can be with the desiccant of adsorbed water molecule owing to also existing inside double glazing, gas is dry, and when temperature reduces, the inside of double glazing also will not produce the phenomenon of condensation, and meanwhile, the outer surface condensation point at double glazing also can raise.It is 5m/s as worked as outdoor wind speed, indoor temperature 20 DEG C, when relative humidity is 60%, 5mm glass starts condensation when outdoor temperature is 8 DEG C, and 16mm double glazing is under similarity condition, outdoor temperature is for just starting condensation when-2 DEG C, tri-layers of double glazing of 27mm just start condensation when outdoor temperature is for-11 DEG C.
The energy transmission of double glazing has three kinds of modes: radiation transmission, convection current are transmitted and conduction transmission.The sealing property of double glazing, is the key factor affecting hollow glass heat insulating performance.The most undesirable for the silicone sealant of double glazing, sealing effectiveness and flame retardant effect on the market, it is impossible to meet the demand of user.
Summary of the invention
It is an object of the invention to solve sealing effectiveness difference and the deficiency of flame retardant effect difference that above-mentioned prior art exists, it is provided that a kind of good sealing effect, the double glazing flame retardant type silicone sealant of good flame retardation effect.
nullA kind of double glazing flame retardant type silicone sealant，It is characterized in that the raw material including following weight: poly-methyl polysiloxane 45-51 part，(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7-13 part，3beta-monohydric pregnant-5,16-diene-20-ketone 11-15 part，1,1,3,3-tetramethoxy propane 25-31 part，2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4-8 part，3-(octadecane epoxide)-1,2-propylene glycol 19-27 part，Tert-butoxy trimethyl silane 30-36 part，3,4-diisopropoxy-3-cyclobutane-1,2-diketone 17-25 part，1,3-dimethyl acetone-1,3-dicarboxylate 14-20 part.
Preferably, the double glazing flame retardant type silicone sealant prepared including the raw material of following weight has a more preferable effect: poly-methyl polysiloxane 48 parts, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7 parts, 3beta-monohydric pregnant-5, 16-diene-20-ketone 15 parts, 1, 1, 3, 3-tetramethoxy propane 28 parts, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4 parts, 3-(octadecane epoxide)-1, 2-propylene glycol 27 parts, tert-butoxy trimethyl silane 33 parts, 3, 4-diisopropoxy-3-cyclobutane-1, 2-diketone 17 parts, 1, 3-dimethyl acetone-1,3-dicarboxylate 20 parts.
Further, in order to obtain effect more preferable double glazing flame retardant type silicone sealant, described double glazing flame retardant type silicone sealant also includes the raw material of following weight: 5-methylol phendioxin, 3-dioxolanes 11-15 part, 1-chloro-3-ethoxy-2-propanol 5-9 part, and (S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z, 4E)-pentadienoic acid 8-16 part.
Preferably, double glazing flame retardant type silicone sealant, its parts by weight of raw materials proportioning is: 5-methylol phendioxin, 3-dioxolanes 13 parts, 1-chloro-3-ethoxy-2-propanol 5 parts, and (S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z, 4E)-pentadienoic acid 16 parts.
The preparation method of the present invention: in high-speed dispersing kettle, add poly-methyl polysiloxane, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol, 3beta-monohydric pregnant-5,16-diene-20-ketone, carry out high speed dispersion, evacuation, obtains its mixture；1,1,3,3-tetramethoxy propane, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester is added so that it is with mixture reaction above, evacuation 15 minutes after 10 minutes；Add 3-(octadecane epoxide)-1,2-propylene glycol, tert-butoxy trimethyl silane, wait to be uniformly dispersed, evacuation, adds 3,4-diisopropoxy-3-cyclobutane-1 after 20 minutes, 2-diketone, 1,3-dimethyl acetone-1,3-dicarboxylate, after reacting 30 minutes, i.e. obtains required double glazing flame retardant type silicone sealant.
This double glazing flame retardant type silicone sealant, good sealing effect, flame retardant rating is high, various good mechanical performance, and preparation method is simple, and efficiency of construction is efficient, and the holding time is longer, is suitable to popularization and application in double glazing silicone sealant field.
Detailed description of the invention
The detailed description of the invention of the present invention given below, is used for being further described the present invention.In the present invention, if no special instructions, each raw material all by working substance content be in terms of 100%.
In following example, raw material introduction:
Poly-methyl polysiloxane, CAS accession number is: 9004-73-3；
(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol, CAS accession number is: 130-95-0；
3beta-monohydric pregnant-5,16-diene-20-ketone, CAS accession number is: 1162-53-4；
1,1,3,3-tetramethoxy propane, CAS accession number is: 102-52-3；
2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester, CAS accession number is: 16432-81-8；
3-(octadecane epoxide)-1,2-PD, CAS accession number is: 544-62-7；
Tert-butoxy trimethyl silane, CAS accession number is: 13058-24-7；
3,4-diisopropoxy-3-cyclobutane-1,2-diketone, CAS accession number is: 61699-62-5；
1,3-dimethyl acetone-1,3-dicarboxylate, CAS accession number is: 1830-54-2；
5-methylol phendioxin, 3-dioxolanes, CAS accession number is: 495-76-1；
1-chloro-3-ethoxy-2-propanol, CAS accession number is: 4151-98-8；
(S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-bases)-3-methyl-(2Z, 4E)-pentadienoic acid, CAS accession number is: 21293-29-8.
Embodiment 1
Weigh the raw material of following weight: poly-methyl polysiloxane 45kg, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 13kg, 3beta-monohydric pregnant-5, 16-diene-20-ketone 13kg, 1, 1, 3, 3-tetramethoxy propane 25kg, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 8kg, 3-(octadecane epoxide)-1, 2-propylene glycol 23kg, tert-butoxy trimethyl silane 30kg, 3, 4-diisopropoxy-3-cyclobutane-1, 2-diketone 25kg, 1, 3-dimethyl acetone-1,3-dicarboxylate 17kg.
The present embodiment double glazing preparation method of flame retardant type silicone sealant: in high-speed dispersing kettle, add poly-methyl polysiloxane, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol, 3beta-monohydric pregnant-5,16-diene-20-ketone, carry out high speed dispersion, evacuation, obtains its mixture；1,1,3,3-tetramethoxy propane, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester is added so that it is with mixture reaction above, evacuation 15 minutes after 10 minutes；Add 3-(octadecane epoxide)-1,2-propylene glycol, tert-butoxy trimethyl silane, wait to be uniformly dispersed, evacuation, adds 3,4-diisopropoxy-3-cyclobutane-1 after 20 minutes, 2-diketone, 1,3-dimethyl acetone-1,3-dicarboxylate, after reacting 30 minutes, i.e. obtains required double glazing flame retardant type silicone sealant.
Embodiment 2
Weigh the raw material of following weight: poly-methyl polysiloxane 48kg, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7kg, 3beta-monohydric pregnant-5, 16-diene-20-ketone 15kg, 1, 1, 3, 3-tetramethoxy propane 28kg, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4kg, 3-(octadecane epoxide)-1, 2-propylene glycol 27kg, tert-butoxy trimethyl silane 33kg, 3, 4-diisopropoxy-3-cyclobutane-1, 2-diketone 17kg, 1, 3-dimethyl acetone-1,3-dicarboxylate 20kg.
The present embodiment double glazing by the preparation method of flame retardant type silicone sealant with embodiment 1.
Embodiment 3
Weigh the raw material of following weight: poly-methyl polysiloxane 51kg, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 10kg, 3beta-monohydric pregnant-5, 16-diene-20-ketone 11kg, 1, 1, 3, 3-tetramethoxy propane 31kg, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 6kg, 3-(octadecane epoxide)-1, 2-propylene glycol 19kg, tert-butoxy trimethyl silane 36kg, 3, 4-diisopropoxy-3-cyclobutane-1, 2-diketone 21kg, 1, 3-dimethyl acetone-1,3-dicarboxylate 14kg.
The present embodiment double glazing by the preparation method of flame retardant type silicone sealant with embodiment 1.
Embodiment 4
nullWeigh the raw material of following weight: poly-methyl polysiloxane 48kg，(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7kg，3beta-monohydric pregnant-5,16-diene-20-ketone 15kg，1,1,3,3-tetramethoxy propane 28kg，2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4kg，3-(octadecane epoxide)-1,2-propylene glycol 27kg，Tert-butoxy trimethyl silane 33kg，3,4-diisopropoxy-3-cyclobutane-1,2-diketone 17kg，1,3-dimethyl acetone-1,3-dicarboxylate 20kg，5-methylol phendioxin,3-dioxolanes 11kg，1-chloro-3-ethoxy-2-propanol 9kg，(S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z,4E)-pentadienoic acid 12kg.
The present embodiment double glazing preparation method of flame retardant type silicone sealant: in high-speed dispersing kettle, add poly-methyl polysiloxane, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol, 3beta-monohydric pregnant-5,16-diene-20-ketone, carry out high speed dispersion, evacuation, obtains its mixture；1,1,3,3-tetramethoxy propane, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester is added so that it is with mixture reaction above, evacuation 15 minutes after 10 minutes；Add 3-(octadecane epoxide)-1,2-propylene glycol, tert-butoxy trimethyl silane, wait to be uniformly dispersed, evacuation, 3 are added after 20 minutes, 4-diisopropoxy-3-cyclobutane-1,2-diketone, 1,3-dimethyl acetone-1,3-dicarboxylate, 5-methylol phendioxin, 3-dioxolanes, 1-chloro-3-ethoxy-2-propanol, (S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z, 4E)-pentadienoic acid, after reacting 30 minutes, i.e. obtains required double glazing flame retardant type silicone sealant.
Embodiment 5
nullWeigh the raw material of following weight: poly-methyl polysiloxane 48kg，(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7kg，3beta-monohydric pregnant-5,16-diene-20-ketone 15kg，1,1,3,3-tetramethoxy propane 28kg，2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4kg，3-(octadecane epoxide)-1,2-propylene glycol 27kg，Tert-butoxy trimethyl silane 33kg，3,4-diisopropoxy-3-cyclobutane-1,2-diketone 17kg，1,3-dimethyl acetone-1,3-dicarboxylate 20kg，5-methylol phendioxin,3-dioxolanes 13kg，1-chloro-3-ethoxy-2-propanol 5kg，(S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z,4E)-pentadienoic acid 16kg.
The present embodiment double glazing by the preparation method of flame retardant type silicone sealant with embodiment 4.
Embodiment 6
nullWeigh the raw material of following weight: poly-methyl polysiloxane 48kg，(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7kg，3beta-monohydric pregnant-5,16-diene-20-ketone 15kg，1,1,3,3-tetramethoxy propane 28kg，2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4kg，3-(octadecane epoxide)-1,2-propylene glycol 27kg，Tert-butoxy trimethyl silane 33kg，3,4-diisopropoxy-3-cyclobutane-1,2-diketone 17kg，1,3-dimethyl acetone-1,3-dicarboxylate 20kg，5-methylol phendioxin,3-dioxolanes 15kg，1-chloro-3-ethoxy-2-propanol 7kg，(S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-base)-3-methyl-(2Z,4E)-pentadienoic acid 8kg.
The present embodiment double glazing by the preparation method of flame retardant type silicone sealant with embodiment 4.
Properties of product test result
Doing properties of product test with regard to this double glazing flame retardant type silicone sealant below, details is shown in Table 1.
Table 1: properties of product test result
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Surface drying time (min) | 13 | 11 | 12 | 10 | 8 | 9 |
| Hot strength (MPa) | 0.90 | 0.97 | 0.94 | 0.99 | 1.07 | 1.03 |
| Elongation at break (%) | 425 | 450 | 440 | 460 | 485 | 475 |
| The storage phase (moon) | 12 | 12 | 12 | 12 | 12 | 12 |
| Fire-retardant rank | V0 | V0 | V0 | V0 | V0 | V0 |
As can be seen from the above table, this double glazing flame retardant type silicone sealant surface drying time is shorter, shortens the waiting time；Hot strength is relatively strong, has higher elongation at break, and it is longer to store the time, and fire-retardant rank has reached highest standard.Wherein, the double glazing flame retardant type silicone sealant best performance of embodiment 5 is different, and surface drying time has reached 8min, and hot strength is 1.07MPa, and elongation at break is 485, and the storage phase is 12 months, and fire-retardant rank is V0.
Claims (4)
- null1. a double glazing flame retardant type silicone sealant，It is characterized in that including the raw material of following weight: poly-methyl polysiloxane 45-51 part，(6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7-13 part，3beta-monohydric pregnant-5,16-diene-20-ketone 11-15 part，1,1,3,3-tetramethoxy propane 25-31 part，2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4-8 part，3-(octadecane epoxide)-1,2-propylene glycol 19-27 part，Tert-butoxy trimethyl silane 30-36 part，3,4-diisopropoxy-3-cyclobutane-1,2-diketone 17-25 part，1,3-dimethyl acetone-1,3-dicarboxylate 14-20 part.
- 2. double glazing flame retardant type silicone sealant as claimed in claim 1, it is characterized in that including the raw material of following weight: poly-methyl polysiloxane 48 parts, (6-methoxyl group-4-quinolyl) (5-vinyl-1-azabicyclo [2.2.2] octane-2-base) methanol 7 parts, 3beta-monohydric pregnant-5, 16-diene-20-ketone 15 parts, 1, 1, 3, 3-tetramethoxy propane 28 parts, 2-acrylic acid 2-(4-benzoyl-3-hydroxyphenoxy) ethyl ester 4 parts, 3-(octadecane epoxide)-1, 2-propylene glycol 27 parts, tert-butoxy trimethyl silane 33 parts, 3, 4-diisopropoxy-3-cyclobutane-1, 2-diketone 17 parts, 1, 3-dimethyl acetone-1,3-dicarboxylate 20 parts.
- 3. double glazing flame retardant type silicone sealant as claimed in claim 1 or 2, characterized by further comprising the raw material of following weight: 5-methylol phendioxin, 3-dioxolanes 11-15 part, 1-chloro-3-ethoxy-2-propanol 5-9 part, (S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-bases)-3-methyl-(2Z, 4E)-pentadienoic acid 8-16 part.
- 4. double glazing flame retardant type silicone sealant as claimed in claim 3, it is characterized in that including the raw material of following weight: 5-methylol phendioxin, 3-dioxolanes 13 parts, 1-chloro-3-ethoxy-2-propanol 5 parts, (S)-5-(1-hydroxyl-4-oxo-2,6,6-trimethyl-2-cyclohexene-1-bases)-3-methyl-(2Z, 4E)-pentadienoic acid 16 parts.
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| CN201610300425.3A CN105838316A (en) | 2016-05-06 | 2016-05-06 | Flame-retardant silicone sealant for hollow glass |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105713553A (en) * | 2016-05-06 | 2016-06-29 | 烟台图文马克化工科技有限公司 | Silicone sealant for aluminum alloy doors/windows |
| WO2024056569A1 (en) * | 2022-09-14 | 2024-03-21 | Merck Patent Gmbh | Composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865476A (en) * | 2014-03-28 | 2014-06-18 | 烟台德邦先进硅材料有限公司 | Organic silicon solid insulated crystal for low-power light-emitting diode (LED) encapsulated by surface mount technology (SMT) |
| CN104610905A (en) * | 2014-12-30 | 2015-05-13 | 福建瑞森化工有限公司 | High-voltage-insulation sealing adhesive |
| CN104893304A (en) * | 2015-05-05 | 2015-09-09 | 浙江凌志精细化工有限公司 | Soft-hard co-extrusion composite silicone rubber strip |
| CN105062410A (en) * | 2015-09-09 | 2015-11-18 | 蓝星（成都）新材料有限公司 | Flame-retardant organic silicon sealant for LED packaging and preparation method of flame-retardant organic silicon sealant |
| CN105111750A (en) * | 2015-09-09 | 2015-12-02 | 蓝星（成都）新材料有限公司 | Organosilicon sealant for LED (light-emitting diode) packaging |
-
2016
- 2016-05-06 CN CN201610300425.3A patent/CN105838316A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865476A (en) * | 2014-03-28 | 2014-06-18 | 烟台德邦先进硅材料有限公司 | Organic silicon solid insulated crystal for low-power light-emitting diode (LED) encapsulated by surface mount technology (SMT) |
| CN104610905A (en) * | 2014-12-30 | 2015-05-13 | 福建瑞森化工有限公司 | High-voltage-insulation sealing adhesive |
| CN104893304A (en) * | 2015-05-05 | 2015-09-09 | 浙江凌志精细化工有限公司 | Soft-hard co-extrusion composite silicone rubber strip |
| CN105062410A (en) * | 2015-09-09 | 2015-11-18 | 蓝星（成都）新材料有限公司 | Flame-retardant organic silicon sealant for LED packaging and preparation method of flame-retardant organic silicon sealant |
| CN105111750A (en) * | 2015-09-09 | 2015-12-02 | 蓝星（成都）新材料有限公司 | Organosilicon sealant for LED (light-emitting diode) packaging |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105713553A (en) * | 2016-05-06 | 2016-06-29 | 烟台图文马克化工科技有限公司 | Silicone sealant for aluminum alloy doors/windows |
| WO2024056569A1 (en) * | 2022-09-14 | 2024-03-21 | Merck Patent Gmbh | Composition |
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