CN105838018A - Bakelite purline and manufacturing method thereof - Google Patents
Bakelite purline and manufacturing method thereof Download PDFInfo
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- CN105838018A CN105838018A CN201511019944.4A CN201511019944A CN105838018A CN 105838018 A CN105838018 A CN 105838018A CN 201511019944 A CN201511019944 A CN 201511019944A CN 105838018 A CN105838018 A CN 105838018A
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- parts
- bakelite
- purlin
- temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
The invention provides a bakelite purline and a manufacturing method thereof. The bakelite purline utilizes phenolic resin as a base resin and is prepared from 20-30 parts by weight of phenolic resin, 0.5-2 parts by weight of a halogen-free fire retardant, 1-3 parts by weight of carbon fibers, 50-70 parts by weight of glass fiber yarn, 4-7 parts by weight of a polyester surfacing mat, 2-8 parts by weight of a diluent, 0.5-1.5 parts by weight of a release agent and 0.5-1.5 parts by weight of a pigment through pultrusion. The bakelite purline has light weight, is safe, reliable, economic and reasonable and has a high industrialization level and good fireproof and corrosion resistant performances.
Description
Technical field
The present invention relates to building field, be specifically related to a kind of large-scale steel structure roofing or metope of being applied to
Bakelite purlin and manufacture method thereof.
Background technology
Due to steel building have with steel province, cost economic, the supply of material rapidly, simple installation and profile
The advantage such as succinct, at home and abroad obtains developing rapidly with widely used as a kind of commodity.External six
The ten's started to widely apply, and nowadays, light weight steel structure system is in the low-rise building city of non-livability
Occupying an leading position on field, its purposes is extremely wide, including cold-formed steel residence structure
(1～3 layer of villa house), the building of commercial use such as warehouse, small-sized storied office building, garage, supermarket；
Build such as Factory Building, material recovery station, automobile production Factory Building and chemical plant including manufacture and processing industry type
Deng；Also include community and public building such as school, City Hall, stadiums etc..
The First Line defendd to external world of building is made up of metope and roofing, they be also subjected to simultaneously as
The structural load effect such as wind, snow load, and these loads are passed on secondary supporting structure.Roof purline
As aggregated(particle) structure most important in steel structural roof, not only occupy the biggest in the cost of roofing system
Ratio, and play great effect.Transmitted, by metope and roofing, the load of coming by receiving, and by it
Pass to the main structure of post and crossbeam composition equably up, bear wind load, snow load and other load and incite somebody to action
It is delivered to building foundation.
In early days, China is mainly hot-rolled steel section for the purlin of roofing, but it is from great, steel quantity consumption
Many.Conventional freely-supported purlin mostly controls for amount of deflection, and intensity tends not to play one's part to the full.Later
The light gauge cold-formed steel shape of exploitation have meterial saving and high efficiency, consumption steel few, from heavy and light, to manufacture transport easy etc. excellent
Point, is used as the purlin of steel structural roof in a large number.But for some border on the sea building, steel rolling mill, smelting
Industry in the corrosive environment such as factory, chemical fertilizer factory, Aluminum oxidation workshop, chemicals workshop, mariculture
Building, metal material purlin easily corrodes, and brings puzzlement greatly to steel structural roof building.
Traditional fiberglass in the successful Application of corrosion-resistant field more than 80 years, such as chemical storage tank, ground
Lower water supply and sewerage pipeline, marine pleasure-boat, wind power facility etc., the anticorrosion of its brilliance, ageing-resistant performance obtain
Arrive extensive approval.It is although the purlin excellent anti-corrosion performance that this composite makes, lightweight,
But, it is easy to burning under the high temperature conditions, causes fracture, caves in, and cost of manufacture is high.
Therefore, how to promote roofing or the corrosion resistance of metope purlin, anti-flammability and mechanical property are to work as
The urgent needs of front architectural structural system.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of prior art, it is provided that one have lightweight, safe and reliable,
Economical rationality, speed of application are soon, industrialization manufacture degree is high and prevent fires, corrosion resistant A level is prevented fires high
Strength corrosion resistant purlin.
For solving above-mentioned technical problem, the technical scheme that the present invention takes is as follows.
The present invention provides a kind of bakelite purlin, with phenolic resin as matrix resin, by comprising following weight
The component of part is made by pultrude process, wherein, phenolic resin: 20～30 parts, halogen-free flame retardants:
0.5～2 part, carbon fiber: 1～3 part, glass fiber yarn: 50～70 parts, surface of polyester felt: 4～
7 parts, diluent: 2～8 parts, releasing agent: 0.5～1.5 part, pigment: 0.5～1.5 part.
Further, it is made up by pultrude process of the component comprising following weight portion, wherein, phenolic aldehyde
Resin: 25 parts, halogen-free flame retardants: 1 part, carbon fiber: 1.5 parts, glass fiber yarn: 60 parts,
Surface of polyester felt: 5.5 parts, diluent: 5 parts, releasing agent: 1 part, pigment: 1 part.
Further, in described pultrude process, the temperature of pultrusion die is 140～280 DEG C.
Further, described pigment is particle diameter 5～the iron sesquioxide of 15 microns, or be particle diameter 1～
The titanium dioxide of 5 microns.
Further, during described halogen-free flame retardants is aluminium hydroxide, magnesium hydroxide or poly phosphorus ammonium acid
One or more.
Additionally, the present invention also provides for a kind of method making above-mentioned bakelite purlin, comprise the steps of
Step 1) preparation of resin system material: by phenolic resin, halogen-free flame retardants, diluent, face
Material, releasing agent are blended, and the blended groove of holding is that constant temperature is to obtain resin system material；
Step 2) knit the manufacture of part in advance: carbon fiber, glass fibre are made into tubular and are impregnated with resinite
System's material, afterwards parcel surface of polyester felt be fixed to described pre-knit part by preforming tool；And
Step 3) curing molding: described pre-part of knitting is drawn in metal die cavity, carries out three sections of temperature control solidifications.
Further, step 1) in, described blended groove is remained 85 degrees Celsius.
Further, step 3) in the temperature of three sections be respectively 140～170 DEG C, 160～190 DEG C,
180～240 DEG C.
Further, the temperature of described three sections is respectively preferably 160 DEG C, 180 DEG C, 210 DEG C.
The present invention compared with prior art has the advantage that
1. the phenolic fiberglass reinforced plastics of the present invention uses common alkali-free glass fibre yarn, has carried out layer with carbon fiber
Between strengthen, and use surface of polyester felt to wrap up, its weight far below the metal purlins of same volume,
And mechanical property has reached the intensity of steel, load-bearing reaches more than 620kg；By to fabric structure
The design made reaches the uniform purpose of each side's stress, and the drawing and extruding section bar solving area of section big is the strongest
Degree height, and the problem that longitudinal strength is low, be mixed into carbon fiber in fabric simultaneously and hot strength improved
More than 50%.
2. the phenolic fiberglass reinforced plastics of the present invention uses ultra-fine magnesium hydroxide to be mixed into filler as filler, resin
Serving the effect of binding agent, its combustion heat value is less than 3MJ/kg；Produce smoke toxicity and reach ZA1；Oxygen
Index reaches more than 34；Product is made to be well positioned to meet the requirement that steel construction is fire-retardant.
Detailed description of the invention
For the disclosedest purpose, below with reference to embodiment, the present invention is described in further details.
Should be appreciated that specific embodiments described below is only used for explaining the present invention, be not intended to limit this
Bright protection domain.
The present invention provides a kind of bakelite purlin, by comprising the component of following weight portion by pultrude process system
Becoming, pultrusion die temperature is 140～280 DEG C:
In an embodiment of the present invention, described phenolic resin is common thermoplastic phenolic resin.Described
Halogen-free flame retardants can be ultra-fine aluminium hydrate powder or magnesium hydroxide powder, it is also possible to for poly phosphorus ammonium
Acid；Or the compound system of these fire retardants.Described carbon fiber is that the carbon of general T 300 series level is fine
Dimension, can be domestic carbon fiber, as Jiangsu perseverance god, in the T300 level produced of multiple Condor serial；Also
Can be the T300 level series carbon fiber of import, such as the product of the productions such as toray, east nation.Institute
Stating glass fiber yarn is common alkali-free glass fibre yarn.The polyester that described polyester continuous felt is commercially available is continuous
Felt.Described diluent is industry conventional thinner, such as ethanol.Described phenolic resin is commercially available established practice
Phenolic resin, such as the phenolic resin (viscous brown of Changshu Southeast Plastic Co., Ltd.'s model NR9450
Liquid is suitable for pultrusion).Described releasing agent is industry conventional release agent, such as industrial paraffin.Described
Pigment is particle diameter 5～the iron sesquioxide of 15 microns, or the titanium dioxide of particle diameter 1～5 microns is i.e.
Titanium dioxide etc..
Additionally, the present invention also provides for a kind of method manufacturing above-mentioned bakelite purlin:
1. the preparation of resin system: first by phenolic resin, halogen-free flame retardants, diluent, pigment, de-
Mould agent is blended, and blended groove is constant temperature, and temperature is maintained at 85 degree, makes resin material both keep fine
Mobility counter will not give birth to cross-linking reaction again.
Knit part manufacture the most in advance: above-mentioned carbon fiber, glass fibre are made into tubular by loom, are impregnated with
Wrap up surface of polyester felt after resin material to be shaped by preforming tool.
3. curing molding: above-mentioned pre-part of knitting is drawn in metal die cavity, carries out three sections of temperature controls and solidifies, and three
The temperature of section is respectively 140～170 DEG C, 160～190 DEG C, 180～240 DEG C.Metal die afterbody is adopted
Take caterpillar-tractor section bar is pulled.
Embodiment 1
A kind of bakelite purlin, is made up by pultrude process of the component comprising following weight portion, pultrusion mould
Tool temperature is 140～280 DEG C:
Its preparation method is: the most first by phenolic resin, ultra-fine magnesium hydroxide, diluent,
Releasing agent, titanium dioxide are poured in stirred autoclave and are blended, and after mix homogeneously, are transferred to groove is blended.
Blended groove is constant temperature, and temperature is maintained at about 85 DEG C.At this temperature, resin system has well
Mobility, the crosslinking curing temperature of resin system is at about 190 DEG C simultaneously, far below its cross-linking reaction,
Its working life is long.
By above-mentioned carbon fiber, that glass fibre is made into, by loom, the tubular that thickness is 4.5 millimeters thick is pre-
Knit part, this pre-part of knitting is blended groove by the constant temperature equipped with resin, is filled by extruding after being impregnated with resin
Put, by unnecessary resin extruded.Then surface of polyester felt is wrapped up on part pre-the knitting being impregnated with resin, then
Shaped by preforming tool.
Pre-part of knitting after above-mentioned sizing is drawn in metal die cavity, carries out three sections of temperature control solidifications.The temperature of three sections
Degree is respectively 140 DEG C, 160 DEG C, 180 DEG C, is respectively 1 minute, 2 minutes and 1 point hardening time
Clock.Metal die afterbody takes caterpillar-tractor to draw section bar, and cools down, thus makes
Obtain bakelite purlin.
Embodiment 2
A kind of bakelite purlin, is made up by pultrude process of the component comprising following weight portion, pultrusion mould
Tool temperature is 140～280 DEG C:
Its preparation method is: the most first by phenolic resin, ultra-fine magnesium hydroxide, diluent,
Releasing agent, titanium dioxide are poured in stirred autoclave and are blended, and after mix homogeneously, are transferred to groove is blended.
Blended groove is constant temperature, and temperature is maintained at about 85 DEG C.At this temperature, resin system has well
Mobility, the crosslinking curing temperature of resin system is at about 190 DEG C simultaneously, far below its cross-linking reaction,
Its working life is long.
By above-mentioned carbon fiber, that glass fibre is made into, by loom, the tubular that thickness is 4.5 millimeters thick is pre-
Knit part, this pre-part of knitting is blended groove by the constant temperature equipped with resin, is filled by extruding after being impregnated with resin
Put, by unnecessary resin extruded.Then surface of polyester felt is wrapped up on part pre-the knitting being impregnated with resin, then
Shaped by preforming tool.
Pre-part of knitting after above-mentioned sizing is drawn in metal die cavity, carries out three sections of temperature control solidifications.The temperature of three sections
Degree is respectively 170 DEG C, 190 DEG C, 240 DEG C, is respectively 1 minute, 2 minutes and 1 point hardening time
Clock.Metal die afterbody takes caterpillar-tractor to draw section bar, and cools down, thus makes
Obtain bakelite purlin.
Embodiment 3
A kind of bakelite purlin, is made up by pultrude process of the component comprising following weight portion, pultrusion mould
Tool temperature is 140～280 DEG C:
Its preparation method is: the most first by phenolic resin, ultra-fine magnesium hydroxide, diluent,
Releasing agent, titanium dioxide are poured in stirred autoclave and are blended, and after mix homogeneously, are transferred to groove is blended.
Blended groove is constant temperature, and temperature is maintained at about 85 DEG C.At this temperature, resin system has well
Mobility, the crosslinking curing temperature of resin system is at about 190 DEG C simultaneously, far below its cross-linking reaction,
Its working life is long.
By above-mentioned carbon fiber, that glass fibre is made into, by loom, the tubular that thickness is 4.5 millimeters thick is pre-
Knit part, this pre-part of knitting is blended groove by the constant temperature equipped with resin, is filled by extruding after being impregnated with resin
Put, by unnecessary resin extruded.Then surface of polyester felt is wrapped up on part pre-the knitting being impregnated with resin, then
Shaped by preforming tool.
Pre-part of knitting after above-mentioned sizing is drawn in metal die cavity, carries out three sections of temperature control solidifications.The temperature of three sections
Degree is respectively 160 DEG C, 180 DEG C, 210 DEG C, is respectively 1 minute, 2 minutes and 1 point hardening time
Clock.Metal die afterbody takes caterpillar-tractor to draw section bar, and cools down, thus makes
Obtain bakelite purlin.
Tests prove that, the phenolic resin frp bakelite purlin that the present invention provides, its performance and specification
As follows:
Load-carrying properties: (degree of disturbing under span 6000mm, load 6000N) 31.6mm；Outward appearance:
Day shaped sections；Buckling strength: 1098MPa；Buckling elastic modelling quantity 4.03 × 104MPa；
Transverse bending strength: 147.8MPa；Hardness Barcol: 67.2；Fire-protection rating: A level is prevented fires.
Embodiment described above only have expressed embodiments of the present invention, and it describes more concrete and detailed
Carefully, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that, it is right
For those of ordinary skill in the art, without departing from the inventive concept of the premise, it is also possible to do
Going out some deformation and improvement, these broadly fall into protection scope of the present invention.Therefore, patent of the present invention
Protection domain should be as the criterion with claims.
Claims (9)
1. a bakelite purlin, with phenolic resin as matrix resin, it is characterised in that following by comprising
The component of weight portion is made by pultrude process, wherein, phenolic resin: 20～30 parts, halogen-free flameproof
Agent: 0.5～2 part, carbon fiber: 1～3 part, glass fiber yarn: 50～70 parts, surface of polyester felt:
4～7 parts, diluent: 2～8 parts, releasing agent: 0.5～1.5 part, pigment: 0.5～1.5 part.
Bakelite purlin the most according to claim 1, it is characterised in that by comprising following weight portion
Component made by pultrude process, wherein, phenolic resin: 25 parts, halogen-free flame retardants: 1 part,
Carbon fiber: 1.5 parts, glass fiber yarn: 60 parts, surface of polyester felt: 5.5 parts, diluent: 5
Part, releasing agent: 1 part, pigment: 1 part.
Bakelite purlin the most according to claim 1 and 2, it is characterised in that described pultrude process
The temperature of middle pultrusion die is 140～280 DEG C.
Bakelite purlin the most according to claim 1 and 2, it is characterised in that described pigment is
Particle diameter 5～the iron sesquioxide of 15 microns, or be particle diameter 1～the titanium dioxide of 5 microns.
Bakelite purlin the most according to claim 1 and 2, it is characterised in that described Halogen hinders
Combustion agent is one or more in aluminium hydroxide, magnesium hydroxide or poly phosphorus ammonium acid.
6. the method manufacturing bakelite purlin as claimed in claim 1, it is characterised in that comprise
Following steps:
Step 1) preparation of resin system material: by phenolic resin, halogen-free flame retardants, diluent, face
Material, releasing agent are blended, and the blended groove of holding is that constant temperature is to obtain resin system material；
Step 2) knit the manufacture of part in advance: carbon fiber, glass fibre are made into tubular and are impregnated with resinite
System's material, afterwards parcel surface of polyester felt be fixed to described pre-knit part by preforming tool；And
Step 3) curing molding: described pre-part of knitting is drawn in metal die cavity, carries out three sections of temperature control solidifications.
Method the most according to claim 6, it is characterised in that step 1) in, by described common
Mixed groove remains 85 degrees Celsius.
Method the most according to claim 6, it is characterised in that step 3) in the temperature of three sections
It is respectively 140～170 DEG C, 160～190 DEG C, 180～240 DEG C.
Manufacture method the most according to claim 8, it is characterised in that the temperature of described three sections is divided
Not You Xuanwei 160 DEG C, 180 DEG C, 210 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511019944.4A CN105838018A (en) | 2015-12-31 | 2015-12-31 | Bakelite purline and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511019944.4A CN105838018A (en) | 2015-12-31 | 2015-12-31 | Bakelite purline and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105838018A true CN105838018A (en) | 2016-08-10 |
Family
ID=56580388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511019944.4A Pending CN105838018A (en) | 2015-12-31 | 2015-12-31 | Bakelite purline and manufacturing method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649105A (en) * | 2009-09-22 | 2010-02-17 | 中格复合材料（南通）有限公司 | Phenolic glass reinforced plastic grille |
| CN102198730A (en) * | 2011-04-21 | 2011-09-28 | 北京玻钢院复合材料有限公司 | Pultrusion process and pultrusion device of phenolic resin composite |
| CN102490378A (en) * | 2011-12-19 | 2012-06-13 | 中格复合材料（南通）有限公司 | Production method of the phenolic glassfiber reinforced plastic sectional material |
| CN103589127A (en) * | 2012-08-15 | 2014-02-19 | 上海杰事杰新材料(集团)股份有限公司 | High-transverse-strength pultrusion structural sheet material and manufacturing method thereof |
-
2015
- 2015-12-31 CN CN201511019944.4A patent/CN105838018A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649105A (en) * | 2009-09-22 | 2010-02-17 | 中格复合材料（南通）有限公司 | Phenolic glass reinforced plastic grille |
| CN102198730A (en) * | 2011-04-21 | 2011-09-28 | 北京玻钢院复合材料有限公司 | Pultrusion process and pultrusion device of phenolic resin composite |
| CN102490378A (en) * | 2011-12-19 | 2012-06-13 | 中格复合材料（南通）有限公司 | Production method of the phenolic glassfiber reinforced plastic sectional material |
| CN103589127A (en) * | 2012-08-15 | 2014-02-19 | 上海杰事杰新材料(集团)股份有限公司 | High-transverse-strength pultrusion structural sheet material and manufacturing method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 于东明等: "《合成树脂与塑料性能手册》", 31 May 2011, 机械工业出版社 * |
| 史才军等: "《高性能土木工程材料-科学理论与应用》", 31 January 2012, 重庆大学出版社 * |
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Application publication date: 20160810 |