CN105837047A - Leucite microcrystalline glass, preparation method and application thereof - Google Patents
Leucite microcrystalline glass, preparation method and application thereof Download PDFInfo
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- CN105837047A CN105837047A CN201610168992.8A CN201610168992A CN105837047A CN 105837047 A CN105837047 A CN 105837047A CN 201610168992 A CN201610168992 A CN 201610168992A CN 105837047 A CN105837047 A CN 105837047A
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- leucite
- devitrified glass
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- porcelain
- ball milling
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0018—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
Abstract
The invention belongs to the field of medical materials, especially to leucite microcrystalline glass and its preparation method and application. The method comprises the following steps: firstly calcining raw materials such as SiO2, Al2O3, K2O, B2O3, etc. for the first time to obtain leucite baked porcelain blocks, crushing, ball-milling by a wet method, drying and sieving to obtain leucite baked porcelain powder, tabletting the above prepared leucite baked porcelain powder and calcining so as to prepare the leucite microcrystalline glass. Grain size of leucite crystal grains in the leucite baked porcelain powder is about 1 micron. By small grain size, strength of the leucite microcrystalline glass can be effectively raised. After tabletting and calcining, the leucite microcrystalline glass has high strength and good transmittance. The invention provides a new method for preparation of the leucite microcrystalline glass.
Description
Technical field
The invention belongs to field of medical materials, particularly to a kind of leucite devitrified glass, its preparation method and should
With.
Background technology
Microcrystal glass material is just with its good biocompatibility since being applied to clinic, and extremely strong is anti-corrosion
Property and close to the advantage such as color and luster of natural teeth, become the main material being applied to treat injury of teeth.Its
Middle leucite devitrified glass has obtained extensively with its high thermal coefficient of expansion, good mechanical performance and biological property
General application.Leucite (K2O-Al2O3-4SiO2) as K2O-Al2O3-SiO2The master of system glass ceramics
Phase, Dispersed precipitate, in glass basis, directly affects the performance of matrix, has been applied to external some dentistry pottery
To improve the mechanical strength of dummy and to beautify the color and luster of dummy in porcelain products.China All-ceramic Dental Material master
Rely on external import, but owing to import All-ceramic material is expensive, greatly limit it and face
Bed application, reason is that the microcrystal glass material of domestic production is at mechanical property, thermal coefficient of expansion, color and luster etc.
Aspect is unable to reach the standard of imported material.Therefore independent research domestic dentistry microcrystal glass material is to reduce into
Originally there is important practical significance.
Leucite (K2O-Al2O3-4SiO2) as K2O-Al2O3-SiO2The principal phase of system glass ceramics, more
Dissipate and be distributed in glass basis, directly affect the performance of matrix.Tradition prepare the method for leucite have solid phase method,
Hydro-thermal method, sol-gal process, coprecipitation etc., wherein solid phase method prepares leucite devitrified glass is to use
Water quenching prepares pristine glass, then carries out crystallization crystalline substance process in sintering process, compared to additive method, Gu
Phase method have simple to operate controlled, the cycle is short, low cost and other advantages.
There is big, the highest, the leucite crystal skewness of obdurability of fragility etc. in domestic leucite devitrified glass
Shortcoming.Therefore, it is necessary to drug formulation reasonable in design, and improve by improving system of heat treatment process
Himself shortcoming so that it is intensity, fragility, light transmission and material homogeneity meet Clinical practice requirement.White pomegranate
Stone devitrified glass is currently mainly prepared through Overheating Treatment crystallize by pristine glass, will pharmaceutical raw material mixing add
Heat is melted, and shrend prepares pristine glass, and pristine glass is carried out heat treatment, makes crystal separate out and prepares leucite
Devitrified glass.Pristine glass is generally by SiO2、Al2O3、K2O、Na2O、B2O3、TiO2Form etc. component,
Wherein SiO2、Al2O3And K2O is the main body of glass composition, is mainly used to separate out leucite crystal, Na2O
It is mainly used in reducing pristine glass fusing point, TiO2As nucleating agent.
CN 1442380 A discloses a kind of dentistry devitrified glass, including the K of 15-25%2O, 20-30%'s
Al2O3, the SiO of 50-60%2, the Fe of MgO, 0.04-001% of CaO, 0.1-0.8% of 1-6%2O3With
0.04-0.1%TiO2's.The dentistry devitrified glass of this application has the physicochemical property of excellence, but preferable not enough.
Even if it should be noted that in a lot of patent and all comprising SiO2、Al2O3、K2O、Na2O and B2O3
Etc. component, but the trickleest change of these components may result in leucite devitrified glass performance and produces the biggest
Change.Griffith micro-crack theory is pointed out, present in material, micro-crack is under the effect of external force, meeting around
Generation stress is concentrated, and when stress reaches certain degree, crackle will extend until rupturing.Devitrified glass
Mechanical property strengthen mechanism, be widely considered to be due to leucite Dispersed precipitate in glass mutually in, in glass produce
Raw crackle will be hindered by leucite crystal when extension, and leucite separates out the most, and this obstruction is just
Can be more strong so that the intensity of devitrified glass has increased.The generally size of dialogue garnet crystal needs
Strictly control, typically require that it is smaller in size than 4 μm, so can be effectively prevented from devitrified glass
Stress is concentrated.
Devitrified glass is a kind of translucent goods, and its light transmission directly affects the attractive in appearance of tooth, by transmittance
Index may determine that the uniformity that crystal in sample separates out.Measuring the matter identifying devitrified glass of transmittance
Measurer has important practical significance.The thickness of material directly affects its optical property, the amount of crystal in material,
The uniformity of chemical characteristic, the granular size of crystal and crystal grain distribution determines the light transmission of material.
Summary of the invention
It is an object of the invention to provide a kind of nano titania catalyst, its preparation method and application, described
Nano titania catalyst material does not use any template in preparation process, and reaction condition is gentle, simple
Single efficient, there is the feature of environmental protection.
For reaching this goal of the invention, the present invention by the following technical solutions:
First aspect, the invention provides a kind of leucite devitrified glass, and quality pressed by described leucite devitrified glass
Percentage ratio includes following component:
Wherein, each constituent content sum of described leucite devitrified glass is less than 100%.
Described SiO2Can be such as 61%, 62%, 63%, 64%, 65%, 66%, 67%, 68%,
69% or 70%.
Described K2O can be such as 18%, 19% or 20%.
Described Al2O3Can be such as 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13% or 14%.
Described B2O3Can be such as 0.6%, 0.7%, 0.8%, 0.9% or 1%.
Preferably, described leucite devitrified glass includes following component by mass percentage:
Wherein, each constituent content sum of described dentistry leucite devitrified glass is less than 100%.
Second aspect, the present invention provides the preparation method of a kind of leucite devitrified glass as described in relation to the first aspect,
Comprise the steps:
(1) SiO is weighed by formula ratio2、Al2O3、K2O and B2O3, ball milling being dried after mixing;
(2) being calcined by the medicine after step (1) dried, furnace cooling carries out Crystallizing treatment, then
It is cooled to room temperature and obtains porcelain block;
(3) porcelain that step (2) obtains is pulverized soon, take slurry after ball milling and sieve after drying, obtain porcelain
Powder;
(4) porcelain powders that step (3) obtains is pressed into required size, carries out secondary clacining, prepare white pomegranate
Stone devitrified glass.
In the present invention, the leucite powder body crystallized can be analyzed detection by secondary clacining, pass through
The detection meanss such as XRD, SEM determine optimum heat treatment process parameter, and the powder choosing degree of crystallinity best enters
Row sinter molding.Conventional solid-state method leucite crystal separates out during sinter molding, controls more difficulty.
The secondary clacining method quasi-complement deficiency of conventional solid-state method, can be the most cost-effective.
Preferably, the time of step (1) described ball milling is 4-8h, such as, can be 4h, 5h, 6h, 7h
Or 8h, preferably 5-7h, more preferably 6h.
Preferably, step (3) described Calcination: Calcination process uses temperature programming, the speed of described temperature programming
For 8-15 DEG C/min, can be such as 8 DEG C/min, 9 DEG C/min, 10 DEG C/min, 11 DEG C/min, 12 DEG C/min,
13 DEG C/min, 14 DEG C/min or 15 DEG C/min, preferably 9-12 DEG C/min, more preferably 10 DEG C/min.
Preferably, the temperature of described calcining is 1300-1550 DEG C, can be such as 1300 DEG C, 1320 DEG C,
1350 DEG C, 1380 DEG C, 1400 DEG C, 1420 DEG C, 1450 DEG C, 1480 DEG C, 1500 DEG C, 1520 DEG C or 1550 DEG C,
It is preferably 1400-1500 DEG C.
Preferably, the time of described calcining is 0.8-3h, can be such as 0.8h, 0.9h, 1h, 1.2h,
1.3h, 1.5h, 1.6h, 1.8h, 2h, 2.2h, 2.3h, 2.5h, 2.8h or 3h, preferably 1-2h,
More preferably 1h.
Preferably, the temperature of the furnace cooling described in step (2) is 700-850 DEG C, can be such as 700 DEG C,
720 DEG C, 750 DEG C, 760 DEG C, 780 DEG C, 800 DEG C, 820 DEG C, 830 DEG C or 850 DEG C, preferably 750-820 DEG C.
Preferably, described Ball-milling Time is 8-15h, can be such as 8h, 9h, 10h, 11h, 12h,
13h, 14h or 15h, preferably 10-13h, more preferably 12h.
Preferably, the sieve of described mistake is 100-400 mesh, can be such as 100 mesh, 120 mesh, 130 mesh,
150 mesh, 180 mesh, 200 mesh, 220 mesh, 230 mesh, 250 mesh, 260 mesh, 280 mesh, 300 mesh, 320
Mesh, 350 mesh, 360 mesh or 400 mesh, preferably 150-300 mesh, more preferably 200 mesh.
Preferably, step (4) described secondary clacining calcination process uses temperature programming, described temperature programming
Speed is 8-15 DEG C/min, can be such as 8 DEG C/min, 9 DEG C/min, 10 DEG C/min, 11 DEG C/min, 12 DEG C
/ min, 13 DEG C/min, 14 DEG C/min or 15 DEG C/min, preferably 9-12 DEG C/min, more preferably 10 DEG C
/min。
Preferably, the temperature of described secondary clacining is 900-1200 DEG C, can be such as 900 DEG C, 920 DEG C,
950℃、980℃、1000℃、1020℃、1050℃、1080℃、1100℃、1120℃、1150℃、
1180 DEG C or 1200 DEG C, preferably 1000-1200 DEG C, more preferably 1150 DEG C.
Preferably, the preparation method of described leucite devitrified glass comprises the steps:
(1) SiO is weighed by formula ratio2、Al2O3、K2O and B2O3, after mixing, ball milling 6h is placed in being dried
Case is dried process;
(2) putting in corundum crucible after step (1) dried is calcined, be warming up to 10 DEG C/min
1400-1500 DEG C, melted isothermal holding 1h, cool to 800-900 DEG C with the furnace and carry out Crystallizing treatment, be incubated 2-4h,
It is cooled to room temperature and obtains porcelain block;
(3) being pulverized soon by the porcelain that step (2) obtains, using dehydrated alcohol is ball-milling medium ball milling 12h,
Take slurry dried mistake 200 mesh sieve after ball milling, obtain porcelain powders;
(4) porcelain powders that step (3) obtains is pressed into required size, carries out secondary clacining, with 10 DEG C/min
It is warming up to 1150 DEG C, is incubated 1h, prepare leucite devitrified glass.
The third aspect, the present invention provides a kind of leucite devitrified glass as described in relation to the first aspect in terms of dentistry
Application.
Compared with prior art, the method have the advantages that
(1) present invention adjustment by formula, just obtains with leucite as precipitated phase after first calcining
Porcelain powders, and the size of leucite crystal is tiny, about 1 μm;
(2) present invention is strong by the three-point bending resistance recording leucite devitrified glass sample after tabletting secondary clacining
Degree has reached 100-130MPa, and microhardness reaches 460-520HV, and light-transmission coefficient is 0.7-0.9cm-1, and
Sample has good light transmission, has taken into account attractive in appearance and mechanical property.
Accompanying drawing explanation
Fig. 1 is the XRD figure preparing leucite devitrified glass porcelain powders in embodiment 1;
Fig. 2 is the SEM figure preparing leucite devitrified glass porcelain powders in embodiment 1;
Fig. 3 is the XRD figure preparing leucite devitrified glass porcelain powders in embodiment 2;
Fig. 4 is the SEM figure preparing leucite devitrified glass porcelain powders in embodiment 2;
Fig. 5 is the XRD figure preparing leucite devitrified glass porcelain powders in embodiment 3;
Fig. 6 is the SEM figure preparing leucite devitrified glass porcelain powders in embodiment 3;
Fig. 7 is the XRD figure preparing leucite devitrified glass porcelain powders in embodiment 4;
Fig. 8 is the SEM figure preparing leucite devitrified glass porcelain powders in embodiment 4;
Fig. 9 is the XRD figure preparing leucite devitrified glass porcelain powders in embodiment 5;
Figure 10 is the SEM figure preparing leucite devitrified glass porcelain powders in embodiment 5.
Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.Those skilled in the art should
This understands, the only help of described embodiment understands the present invention, is not construed as the concrete restriction to the present invention.
Experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, the most commercially obtain.
Embodiment 1
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1400 DEG C of insulation 1h with 10 DEG C/min,
Cool to 1100 DEG C of insulation 2h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
XRD and the SEM result of leucite devitrified glass prepared by the present embodiment is as shown in Figure 1-2.
Embodiment 2
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1400 DEG C of insulation 1h with 10 DEG C/min,
Cool to 1000 DEG C of insulation 4h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
XRD and the SEM result of leucite devitrified glass prepared by the present embodiment is as shown in Figure 3-4.
Embodiment 3
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1450 DEG C of insulation 1h with 10 DEG C/min,
Cool to 900 DEG C of insulation 3h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
XRD and the SEM result of leucite devitrified glass prepared by the present embodiment is as seen in figs. 5-6.
Embodiment 4
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1500 DEG C of insulation 1h with 10 DEG C/min,
Cool to 900 DEG C of insulation 3h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
XRD and the SEM result of leucite devitrified glass prepared by the present embodiment is as Figure 7-8.
Embodiment 5
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1500 DEG C of insulation 1h with 10 DEG C/min,
Cool to 1050 DEG C of insulation 2h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
XRD and the SEM result of leucite devitrified glass prepared by the present embodiment is as shown in figs. 9-10.
Comparative example 1
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1500 DEG C of insulation 1h with 10 DEG C/min,
Cool to 1050 DEG C of insulation 2h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, after 1150 DEG C of calcinings, prepare leucite devitrified glass.
Comparative example 2
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1500 DEG C of insulation 1h with 10 DEG C/min,
Cool to 900 DEG C of insulation 3h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, prepare leucite devitrified glass.
Comparative example 3
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1500 DEG C of insulation 1h with 10 DEG C/min,
Cool to 900 DEG C of insulation 3h with the furnace, be cooled to 800 DEG C of insulation 2h, be finally cooled to room temperature and obtain white pomegranate
Stone porcelain block, using dehydrated alcohol is to cross 200 mesh sieves after medium ball milling is dried, and obtains leucite devitrified glass
Porcelain powders, tabletting, prepare leucite devitrified glass.
Comparative example 4
Described leucite devitrified glass includes following component by mass percentage:
Weighing medicine by drug formulation, ball milling is calcined after drying, is warming up to 1600 DEG C of insulation 1h with 10 DEG C/min,
Cool to 1100 DEG C of insulation 4h with the furnace, be finally cooled to room temperature and obtain leucite porcelain block, use dehydrated alcohol
Crossing 200 mesh sieves after drying for medium ball milling, obtain leucite devitrified glass porcelain powders, tabletting, at 1250 DEG C
Leucite devitrified glass is prepared after calcining.
Performance test and sign:
The leucite devitrified glass preparing embodiment 1-5 and comparative example 1-5 carries out performance test, method of testing
As follows:
Test result is as shown in table 1:
Table 1
As it can be seen from table 1 the three-point bending resistance intensity of the garnet devitrified glass sample in embodiment 1-5 reaches
100-130MPa, microhardness reaches 460-520HV, and light-transmission coefficient is 0.7-0.9cm-1, all it is substantially better than
Comparative example 1-4, it is seen then that and sample has good light transmission, has taken into account attractive in appearance and mechanical property.
Applicant states, the present invention illustrates the process of the present invention by above-described embodiment, but the present invention is also
It is not limited to above-mentioned processing step, does not i.e. mean that the present invention has to rely on above-mentioned processing step and could implement.
Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to former selected by the present invention
The equivalence of material is replaced and the interpolation of auxiliary element, concrete way choice etc., all falls within the protection model of the present invention
Within the scope of enclosing and disclosing.
Claims (10)
1. a leucite devitrified glass, it is characterised in that described leucite devitrified glass is by mass percentage
Including following component:
Wherein, each constituent content sum of described leucite devitrified glass is less than 100%.
Leucite devitrified glass the most according to claim 1, it is characterised in that described leucite crystallite
Glass includes following component by mass percentage:
Wherein, each constituent content sum of described dentistry leucite devitrified glass is less than 100%.
3. the preparation method of a leucite devitrified glass as claimed in claim 1 or 2, it is characterised in that
Comprise the steps:
(1) SiO is weighed by formula ratio2、Al2O3、K2O and B2O3, ball milling being dried after mixing;
(2) being calcined by the medicine after step (1) dried, furnace cooling carries out Crystallizing treatment,
It is cooled to room temperature and obtains porcelain block;
(3) porcelain that step (2) obtains is pulverized soon, take slurry after ball milling and sieve after drying, baked
Porcelain powder;
(4) porcelain powders that step (3) obtains is pressed into required size, carries out secondary clacining, prepare white
Garnet devitrified glass.
Preparation method the most according to claim 3, it is characterised in that step (1) described ball milling
Time is 4-8h, preferably 5-7h, more preferably 6h.
5. according to the preparation method described in claim 3 or 4, it is characterised in that step is forged described in (3)
Burning calcination process and use temperature programming, the speed of described temperature programming is 8-15 DEG C/min, preferably 9-12 DEG C
/ min, more preferably 10 DEG C/min;
Preferably, the temperature of described calcining is 1300-1550 DEG C, preferably 1400-1500 DEG C;
Preferably, the time of described calcining is 0.8-3h, preferably 1-2h, more preferably 1h.
6. according to the preparation method according to any one of claim 3-5, it is characterised in that step (2) institute
The temperature of the furnace cooling stated is 700-850 DEG C, preferably 750-820 DEG C;
Preferably, the time of described Crystallizing treatment is 1-5h, preferably 2-4h.
7. according to the preparation method according to any one of claim 3-6, it is characterised in that during described ball milling
Between be 8-15h, preferably 10-13h, more preferably 12h;
Preferably, the sieve of described mistake is 100-400 mesh, preferably 150-300 mesh, more preferably 200
Mesh.
8. according to the preparation method according to any one of claim 3-7, it is characterised in that step (4) institute
Stating secondary clacining calcination process and use temperature programming, the speed of described temperature programming is 8-15 DEG C/min, preferably
For 9-12 DEG C/min, more preferably 10 DEG C/min;
Preferably, the temperature of described secondary clacining is 900-1200 DEG C, preferably 1000-1200 DEG C, further
It is preferably 1150 DEG C.
9. according to the preparation method according to any one of claim 3-8, it is characterised in that include walking as follows
Rapid:
(1) SiO is weighed by formula ratio2、Al2O3、K2O and B2O3, after mixing, ball milling 6h is placed in being dried
Case is dried process;
(2) putting in corundum crucible after step (1) dried is calcined, be warming up to 10 DEG C/min
1400-1500 DEG C, melted isothermal holding 1h, cool to 800-900 DEG C with the furnace and carry out Crystallizing treatment, be incubated 2-4h,
It is cooled to room temperature and obtains porcelain block;
(3) being pulverized soon by the porcelain that step (2) obtains, using dehydrated alcohol is ball-milling medium ball milling 12h,
Take slurry dried mistake 200 mesh sieve after ball milling, obtain porcelain powders;
(4) porcelain powders that step (3) obtains is pressed into required size, carries out secondary clacining, with 10 DEG C
/ min is warming up to 1150 DEG C, is incubated 1h, prepares leucite devitrified glass.
10. a leucite devitrified glass as claimed in claim 1 or 2 application in terms of dentistry.
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CN103910489A (en) * | 2012-12-29 | 2014-07-09 | 中国科学院过程工程研究所 | Glass used as dental veneering porcelain, preparation method and application thereof |
WO2014207244A1 (en) * | 2013-06-28 | 2014-12-31 | Queen Mary And Westfield College University Of London | Leucite glass ceramics |
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2016
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US6527846B1 (en) * | 1998-08-17 | 2003-03-04 | Chemichl Ag | Glass-ceramic material for dental restoration and method for producing same |
US6342302B1 (en) * | 1998-11-13 | 2002-01-29 | Degussa Ag | Ceramic dental restoration |
CN103910489A (en) * | 2012-12-29 | 2014-07-09 | 中国科学院过程工程研究所 | Glass used as dental veneering porcelain, preparation method and application thereof |
WO2014207244A1 (en) * | 2013-06-28 | 2014-12-31 | Queen Mary And Westfield College University Of London | Leucite glass ceramics |
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