CN105836704B - A kind of hydrogen formation apparatus for chemical hydrogen manufacturing - Google Patents

A kind of hydrogen formation apparatus for chemical hydrogen manufacturing Download PDF

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Publication number
CN105836704B
CN105836704B CN201610176049.1A CN201610176049A CN105836704B CN 105836704 B CN105836704 B CN 105836704B CN 201610176049 A CN201610176049 A CN 201610176049A CN 105836704 B CN105836704 B CN 105836704B
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China
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material bin
cavity
hydrogen
condenser
formation apparatus
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CN105836704A (en
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尹诗斌
刘洋
沈培康
田植群
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Guangxi University
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Guangxi University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The present invention provides a kind of hydrogen formation apparatus for chemical hydrogen manufacturing, includes lid (1), cavity (2), material bin (4), condenser (5), it is characterised in that:There is gas outlet described lid (1) upper end, is fixed with condenser (5) and guiding gutter (9) in described cavity (2), water inlet (10) is arranged at cavity (2) bottom.The material bin (4) is circular cone structure, and material bin (4) top is provided with closure (3), and there is stomata material bin (4) upper end.Material bin (4) bottom is equipped with motor (6), and screen sweeping (7) and flabellum (8) are housed in motor (6) rotating shaft.The present invention can effectively prevent the caking of powdered reaction thing, reduce programming rate, accelerate radiating, powdered reaction thing is fully reacted, and improve the mass ratio of powdered reaction thing and water.

Description

A kind of hydrogen formation apparatus for chemical hydrogen manufacturing
Technical field
The present invention relates to a kind of hydrogen formation apparatus for chemical hydrogen manufacturing, more particularly to a kind of hydrogen for the hydrogen manufacturing that chemically reacts Gas generating means.
Background technology
Current hydrogen production process has electrolysis water, chemical reaction, photocatalysis, catalytic pyrolysis and reformation etc., but has respective The chemical hydrogen production process cost such as advantage and disadvantage, wherein electrolysis water is relatively low and application is wider.Current chemical hydrogen manufacturing reaction used is former Expect it is more, wherein application it is conveniently a kind of be to be reacted with the mixed-powder of boric acid and sodium borohydride and water, so as to make Hydrogen is obtained, but Railway Project is had in the case where reaction volume is very big:1st, easily reactant knot in course of reaction is caused Block, cause reactant fully and highly effective reaction, and then hydrogen generation efficiency can not be reduced;2nd, heating is very fast and cooling is slower;3rd, hydrogen Discharge it is not unimpeded enough.
The content of the invention
The present invention is in order to solve the shortcomings that above-mentioned chemical reaction device for producing hydrogen and deficiency, there is provided one kind can prevent reactant knot Block and heating is relatively slow, cooling is very fast, hydrogen discharge is relatively easy to hydrogen formation apparatus, and can reduce programming rate, accelerates to dissipate Heat, powdered reaction thing is fully reacted, improve the mass ratio of powdered reaction thing and water.
The present invention is taken the technical scheme to be for technical problem present in solution prior art:One kind is used for chemical hydrogen manufacturing Hydrogen formation apparatus, include lid 1, cavity 2, material bin 4, condenser 5, it is characterised in that:The described upper end of lid 1 has Gas port, condenser 5 and guiding gutter 9 is fixed with described cavity 2, the top of material bin 4 is provided with closure 3, and the bottom of cavity 2 has Water inlet 10.
The material bin 4 is circular cone structure, and there is stomata the upper end of material bin 4, and material bin 4 is fixed on chamber by condenser 5 In body 2.
The bottom hole of material bin 4, the bottom of material bin 4 are equipped with motor 6, screen sweeping 7 and flabellum are housed in the rotating shaft of motor 6 8, there is hairbrush in screen sweeping 7.
The inwall of material bin 4 is provided with wire 12, and wire 12 is connected with the motor 6 of the bottom of material bin 4.
The condenser 5 is hollow cone bench-type, inside be made up of curved surface annular array wide at the top and narrow at the bottom, material be with Heat conduction and the material of anti-corrosion function.
The cavity surrounded between described cavity 2, condenser 5 and material bin 4 is filter chamber 11, is filled in filter chamber 11 Filter material material, and have the function that to clean and dry.
There is certain space between the closure 3 and lid 1, be the buffer area of hydrogen.
The water inlet 10 is one-way conduction structure, and water can enter cavity 2 by water inlet 10, but can not be flowed from cavity 2 Go out to outside.
The invention has the advantages that:It was proved that allow powdered reactant uniformly to fall into the water, can Make reactant reaction abundant, and caused heat comparatively fast can be dispersed among water among course of reaction, reactant is reacting Cavity bottom is deposited on after complete, will not hinder continuing for reaction, and with the rise of reaction temperature, in reaction product The water contained can be also participated in reaction, efficiently solve reactant caking and reaction speed in the presence of chemical hydrogen production process The problem of causing reactant to be not sufficiently reacted soon is spent, the mass ratio of powdered reaction thing and water is improved, so as to reduce Overall quality.
Brief description of the drawings
Fig. 1 is the sectional view of the present invention.
Fig. 2, Fig. 4 are material bin chart at the bottom of of the present invention.
Fig. 3 is the outside drawing of the present invention.
Fig. 5, Fig. 6 are the structure chart of the condenser of the present invention.
Fig. 7 is the structure chart of cavity bottom of the present invention.
In figure, 1- lids;2- cavitys;3- closures;4- material bins;5- condensers;6- motors;7- screen sweepings;8- flabellums;9- Guiding gutter;10- water inlets;11- filter chambers;12- wires.
Embodiment
Below by embodiment, and with reference to accompanying drawing, technical scheme is described further, such as Fig. 1-7, one Hydrogen formation apparatus of the kind for chemical hydrogen manufacturing, has outlet comprising lid 1, cavity 2, material bin 4, condenser 5, the upper end of lid 1 Mouthful, condenser 5 and guiding gutter 9 are fixed with cavity 2, the top of material bin 4 is provided with closure 3, and water inlet is arranged at the bottom of cavity 2 10。
The material bin 4 is circular cone structure, and there is stomata (such as Fig. 1) upper end of material bin 4, and material bin 4 is consolidated by condenser 5 It is scheduled in cavity 2.
The bottom hole of material bin 4,1.0 millimeters of hole diameter, the bottom of material bin 4 are equipped with motor 6, the rotating shaft of motor 6 It is upper that screen sweeping 7 and flabellum 8 are housed, there are hairbrush, a diameter of 0.3 millimeter of hairbrush in screen sweeping 7, brush length is 2 millimeters (such as Fig. 2).
The inwall of material bin 4 is provided with wire 12, and wire 12 is connected with the motor 6 of the bottom of material bin 4.
The condenser 5 is hollow cone bench-type (such as Fig. 6, Fig. 7), and inside is by sine wave curved surface circular array wide at the top and narrow at the bottom Row composition, material is the material with heat conduction and anti-corrosion function.
The cavity surrounded between described cavity 2, condenser 5 and material bin 4 is filter chamber 11, is filled in filter chamber 11 Filter material material, have the function that to clean and dry.
There is certain space between the closure 3 and lid 1, be the buffer area of hydrogen.
The water inlet 10 is one-way conduction structure, and water can enter cavity 2 by water inlet 10, but can not be flowed from cavity 2 Go out to outside.
Material bin is filled into powdered reaction thing during use, such as sodium borohydride and the mixed-powder of boric acid, by water inlet 10, By a certain amount of water of injection in cavity 2.Rotated by external power supply motor 6, screen sweeping 7 and the concomitant rotation of flabellum 8, screen sweeping 7 Powdered reaction thing is scanned out out of material bin 4 in the lower rotation of material bin 4, and by the hole of the bottom of material bin 4, wherein flabellum 8 also function to the effect of gaseous exchange in enhancing cavity 2, and powdered reaction thing is blown into water, is also prevented from a large amount of water caused by reaction The hole of the bottom of fogbound plug thing feed bin 4.When powdered reaction thing enters in water, caused hydrogen and vapor and other gases rise Into condenser 5, most of vapor condenses in condenser 5,5 hollow cone bench-types of condenser, up-narrow and down-wide structure, gas When body circulates from the bottom up, pressure increase, easily condensation, residual gas continue to rise, and enter filter chamber 11, and filter chamber 11 will Remaining a small amount of vapor and other impurity remove, the hydrogen that more pure hydrogen then enters between closure 3 and lid 1 Buffer area, by the outlet of lid 1, it is output to outside hydrogen use device or hydrogen reception device.
Protection scope of the present invention is not limited to above-mentioned example, it is clear that those skilled in the art can be to the present invention Various changes and deformation are carried out without departing from scope and spirit of the present invention.If these changes and deformation belong to right of the present invention It is required that and its in the range of equivalent technologies, then the intent of the present invention also comprising these change and deformation.

Claims (4)

1. a kind of hydrogen formation apparatus for chemical hydrogen manufacturing, comprising lid (1), cavity (2), material bin (4), condenser (5), It is characterized in that:There is gas outlet described lid (1) upper end, and condenser (5) and guiding gutter are fixed with described cavity (2) (9), material bin (4) top is provided with closure (3), and water inlet (10) is arranged at cavity (2) bottom, and material bin (4) is frustum of a cone knot There is stomata structure, material bin (4) upper end, and material bin (4) is fixed in cavity (2) by condenser (5), and material bin (4) bottom has Hole, material bin (4) bottom are equipped with motor (6), and screen sweeping (7) and flabellum (8) be housed in motor (6) rotating shaft, hairiness in screen sweeping (7) Brush.
A kind of 2. hydrogen formation apparatus for chemical hydrogen manufacturing as claimed in claim 1, it is characterised in that the condenser (5) For hollow cone bench-type, inside is made up of curved surface annular array wide at the top and narrow at the bottom, and material is the material with heat conduction and anti-corrosion function Material.
3. a kind of hydrogen formation apparatus for chemical hydrogen manufacturing as claimed in claim 1, it is characterised in that cavity (2), condensation The cavity surrounded between device (5) and material bin (4) is filter chamber (11), filtering material is filled in filter chamber (11), and have and remove Effect that is miscellaneous and drying.
4. a kind of hydrogen formation apparatus for chemical hydrogen manufacturing as claimed in claim 1, it is characterised in that closure (3) and lid There is certain space between sub (1), be the buffer area of hydrogen.
CN201610176049.1A 2016-03-24 2016-03-24 A kind of hydrogen formation apparatus for chemical hydrogen manufacturing Active CN105836704B (en)

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Publication number Priority date Publication date Assignee Title
CN106345373B (en) * 2016-09-26 2018-09-11 齐绍诚 The reactor for generating gaseous state product is reacted with liquid reactant for solid-state reactants
CN106769162B (en) * 2017-02-20 2023-06-06 广西大学 Transmission electron microscope magnetic sample preprocessor
CN110127607A (en) * 2019-04-11 2019-08-16 江苏博赛环境科技有限公司 A kind of hydrogen formation apparatus for chemical hydrogen manufacturing
CN114259864B (en) * 2022-01-12 2022-10-18 山东宝塔新能源有限公司 Hydrogen purification device

Citations (7)

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US5817157A (en) * 1996-01-02 1998-10-06 Checketts; Jed H. Hydrogen generation system and pelletized fuel
CN1688506A (en) * 2002-08-20 2005-10-26 千年电池公司 System for hydrogen generation
CN101437750A (en) * 2006-03-06 2009-05-20 株式会社莱恩能源 Hydrogen generator and hydrogenation apparatus
CN101786603A (en) * 2010-02-24 2010-07-28 天津海蓝德能源技术发展有限公司 Device for preparing hydrogen through hydrolysis
CN102989379A (en) * 2011-09-09 2013-03-27 曲靖师范学院 Gas-solid phase reactor
CN104192796A (en) * 2014-09-04 2014-12-10 桂林浩新科技服务有限公司 Self-stirring hydrogen production device
CN204802997U (en) * 2015-05-11 2015-11-25 北京神农源生物科技发展有限公司 Clean energy production system

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JPH09113128A (en) * 1995-10-19 1997-05-02 Nippon Sanso Kk Slush hydrogen production device
FR2833863B1 (en) * 2001-12-20 2004-08-20 Air Liquide CATALYTIC REACTOR, CORRESPONDING INSTALLATION AND REACTION METHOD

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5817157A (en) * 1996-01-02 1998-10-06 Checketts; Jed H. Hydrogen generation system and pelletized fuel
CN1688506A (en) * 2002-08-20 2005-10-26 千年电池公司 System for hydrogen generation
CN101437750A (en) * 2006-03-06 2009-05-20 株式会社莱恩能源 Hydrogen generator and hydrogenation apparatus
CN101786603A (en) * 2010-02-24 2010-07-28 天津海蓝德能源技术发展有限公司 Device for preparing hydrogen through hydrolysis
CN102989379A (en) * 2011-09-09 2013-03-27 曲靖师范学院 Gas-solid phase reactor
CN104192796A (en) * 2014-09-04 2014-12-10 桂林浩新科技服务有限公司 Self-stirring hydrogen production device
CN204802997U (en) * 2015-05-11 2015-11-25 北京神农源生物科技发展有限公司 Clean energy production system

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