CN105833815A - Low/normal temperature photoreactor - Google Patents
Low/normal temperature photoreactor Download PDFInfo
- Publication number
- CN105833815A CN105833815A CN201510020992.9A CN201510020992A CN105833815A CN 105833815 A CN105833815 A CN 105833815A CN 201510020992 A CN201510020992 A CN 201510020992A CN 105833815 A CN105833815 A CN 105833815A
- Authority
- CN
- China
- Prior art keywords
- photoreactor
- heat radiation
- photoreaction
- integral type
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006243 chemical reaction Methods 0.000 claims abstract description 56
- 230000005855 radiation Effects 0.000 claims abstract description 45
- 238000003756 stirring Methods 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 239000012530 fluid Substances 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 230000009514 concussion Effects 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 10
- 230000017525 heat dissipation Effects 0.000 abstract 1
- 238000013461 design Methods 0.000 description 5
- 230000004907 flux Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000003504 photosensitizing agent Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910004613 CdTe Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention belongs to the technical field of photoreaction, and particularly relates to a low/normal temperature photoreactor, which comprises: the integrated supporting and radiating module comprises a liquid cooling module and is used for carrying out liquid cooling radiation on the LED light source; the stirring and adjusting device is used for adjusting the light intensity of the LED light source; the light reaction container is arranged above the stirring and adjusting device through the integrated supporting and heat dissipation module; the light reaction container performs light reaction under the irradiation of the LED light source, and the reaction temperature is adjusted through the liquid cooling module. The low/normal temperature photoreactor of the invention is widely suitable for small-dose photochemical synthesis reaction.
Description
Technical field
The present invention relates to a kind of Photoreactor, particularly relate to one and be widely used in low dose of photochemical
Learn synthetic reaction and the low/normal-temperature light reactor of high flux screening.
Background technology
Photochemical syntheses reaction directly utilizes light radiation as energy source, overcomes reaction gesture
Build, generate product via excited state species；Different from thermal chemical reaction, photochemical reaction is direct
Construct target compound structure, it is possible to be greatly simplified synthetic reaction step, embody efficient, former
Subeconomy and eco-friendly modern concepts, become what current Synthetic Organic Chemistry was enlivened the most
One of research field.
At present, photochemical syntheses reaction mainly uses with relatively large lamps such as halogen lamp, mercury lamp, xenon lamps
Has the Photoreactor as light source, owing to needing to use the radiator structure of transparent material, these light
Structure of reactor is complicated, relatively costly and is only applicable to heavy dose of photochemical syntheses reaction,
There is presently no the Photoreactor being specifically designed to the reaction of laboratory small photochemical syntheses.
Summary of the invention
The present invention provides a kind of Photoreactor, the most applicable to solve Photoreactor of the prior art
Technical problem in heavy dose of photochemical syntheses reaction.
For solving above-mentioned technical problem, the present invention provides a kind of low/normal-temperature light reactor, including:
LED light source, integral type support heat radiation module, stirring and adjusting means and photoreaction container,
Described integral type supports heat radiation module and includes liquid cooled module, for carrying out described LED light source
Liquid-cooling heat radiation；Described stirring and adjusting means are for regulating the light intensity of described LED light source；Institute
State photoreaction container and be arranged on described stirring and regulation by described integral type support heat radiation module
The top of device；Described photoreaction container carries out photoreaction under the irradiation of described LED light source,
And regulate reaction temperature by described liquid cooled module, carry out low-temp reaction and/or normal-temperature reaction；
Described Photoreactor uses when low-temp reaction and the identical replaceable light of normal-temperature reaction
Reaction vessel.
Further, described integral type supports heat radiation module by rustless steel, copper, aluminum manufacture.
Further, described liquid cooled module includes condensed fluid inlet hole, condensed fluid flow pipe and cold
Lime set is portalled, and described liquid cooled module portals cold with outer loop by condensed fluid inlet hole and condensed fluid
Solidifying device is connected.
Further, described integral type supports heat radiation module and includes guiding groove, and described photoreaction is held
Device is inserted by described guiding groove and supports heat radiation module with described integral type and fits tightly.
Further, described photoreaction container includes seal washer, for holding in described photoreaction
When device inserts described integral type support heat radiation module, the steam in air is stoped to enter described one
Formula supports heat radiation module and condenses therein.
Further, described photoreaction container is partially coated with shading more than described seal washer
Japanning.
Further, described LED light source includes LED array and connects with described LED array
The driving power supply connect, described LED array is arranged on described integral type and supports in heat radiation module.
Further, described LED array is vertical LED array or horizontal LED array.
Further, described stirring and adjusting means use magnetic agitation or machinery concussion.
Further, the photoreaction that described photoreaction container is carried out is low-temp reaction and/or often
Temperature reaction.Therefore, the present invention is directed to the light for the reaction of laboratory small photochemical syntheses
Reactor, to meet the core demand of photochemical syntheses repercussion study the following aspects: the highest
Flux: permutation and combination or a series of condition to numerous reactants are screened, and need to enter simultaneously
The multiple parallel reactions of row；2. low dose of: simultaneously the most cost-effective during screening；The highest light intensity:
Improve photoreaction speed, save the response time；4. Single wavelength: use the light of specific wavelength to select
Property excite specific photosensitizer, reduce side reaction.
Accompanying drawing explanation
Fig. 1: embodiment of the present invention Photoreactor structural representation；
Fig. 2: embodiment of the present invention integral type supports heat radiation module cut-away view；
Fig. 3: embodiment of the present invention photoreaction container supports the installation on heat radiation module in integral type
Schematic diagram；
Wherein, 1, integral type supports heat radiation module；1a, guiding groove；1b, condensed fluid portal；
1c, condensed fluid inlet hole；2, stirring and adjusting means；2a, switch；2b, display lamp；2c、
Adjusting knob；3, photoreaction container；3a, seal washer；3b, japanning shading light part；3c、
Standard interface；4, LED chip.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot
Close the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear,
Be fully described by, it is clear that described embodiment be a part of embodiment of the present invention rather than
Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not having
Make the every other embodiment obtained under creative work premise, broadly fall into present invention protection
Scope.
Seeing Fig. 1, the embodiment of the present invention provides a kind of Photoreactor, including: LED light source,
Integral type supports heat radiation module 1, stirring and adjusting means 2 and photoreaction container 3, integral type
Support heat radiation module 1 and include liquid cooled module, for LED light source is carried out liquid-cooling heat radiation；Stir
Mix and adjusting means 2 is for regulating the light intensity of LED light source and stirring or impact strength；Light is anti-
Answer container 3 to support heat radiation module 1 by integral type and be arranged on the upper of stirring and adjusting means 2
Side；Photoreaction container 3 carries out photoreaction under the irradiation of LED light source, and by liquid chill
Block regulation reaction temperature, carries out low-temp reaction and/or normal-temperature reaction；Described Photoreactor exists
Use and normal-temperature reaction identical replaceable photoreaction container during low-temp reaction.
In embodiments of the present invention, the low-temp reaction temperature range of Photoreactor is at-80 DEG C～4 DEG C
Between, normal-temperature reaction is typically at 23 DEG C ± about 5 DEG C.
Wherein, integral type support heat radiation module 1 can be had heat radiation by rustless steel, copper, aluminum etc.
The metal material of performance is made, and preferably can use aluminium manufacture, although the aluminum alloy heat coefficient of expansion
Relatively big, but heat conduction is good, it is easy to processing, relative low price, it is highly suitable as support and dissipates
Hot material.Form as in figure 2 it is shown, integral type supports heat radiation module 1 by multiple block combiner, interior
Portion leaves wiring groove and installing hole.Integral type supports the liquid cooled module internal structure of heat radiation module 1
Have condensed fluid flow pipe, by condensed fluid portal 1b and condensed fluid inlet hole 1c cold with outer loop
Solidifying device is connected, and this condenser system, on the one hand for the heat radiation of LED light source, on the other hand also may be used
From outside regulation and control photoreaction container 3 temperature, operation interval be 80 DEG C to room temperature.Further, liquid
Chill block can select different condensed fluid according to different reaction conditions with reaction temperature.Often
Can adopt during temperature reaction and use water as condensed fluid, the aqueous solution of alcohol or alcohol during low-temp reaction, can be used to make
For condensed fluid.Therefore, the photoreaction container in the embodiment of the present invention can be widely used in low temperature
And/or under normal temperature condition.
As it is shown on figure 3, integral type supports heat radiation module 1 may be configured with perforation and guiding groove 1a, many
Individual interchangeable photoreaction container 3 can be inserted by guiding groove 1a and support with integral type dissipating
Thermal module 1 fits tightly so that therebetween can heat-shift to greatest extent.It addition,
Integral type is supported and can be engaged by seal washer 3a between heat radiation module 1 and photoreaction container 3,
So can effectively stop the steam in air to enter integral type and support heat radiation module internal condensation,
Avoid LED light source short circuit.It addition, photoreaction container 3 can in the part of more than seal washer 3a
To scribble shading japanning, form japanning shading light part 3b, to avoid photoreaction container 3 using
During cause light pollution.
LED light source can include LED array and the driving power supply being connected with LED array,
LED chip 4 in LED array can be arranged on integral type and support in heat radiation module 1, by electricity
Line is connected formation loop with stirring and adjusting means 2.It is arranged on integral type in LED chip 4 to support
Time on heat radiation module 1, will also pass through waterproof package simultaneously and process, to improve the resistance to of Photoreactor
Degree for a long time.LED chip 4 in the LED array of the embodiment of the present invention can use vertical or horizontal battle array
Row.In vertical LED array, integral type supports heat radiation module 1 and aluminium can be preferably used,
In horizontal LED array integral type support heat radiation module 1 can be preferably used steel and with stirring and
The upper surface (upper surface is support system) of adjusting means 2 blends.The embodiment of the present invention
Drive power supply different because of the connection quantity of LED chip, use current control mode, exchange input
Support 110～220V, 50～60Hz civil power, the integral waterproofing standard of the embodiment of the present invention meets
IP65 degree of protection.
Stirring and adjusting means 2 can use magnetic agitation or machinery concussion, can by switch 2a,
Display lamp 2b, adjusting knob 2c switch, indicate, regulate mixing speed, and pass through current intensity
Regulate and control the luminous intensity of LED chip 4.
The photoreaction container 3 of the embodiment of the present invention can use Pyrex glass or quartz to make, can
For having the standard interface 3c such as #14/20, #19/22, #24/29, #24/40, screw socket, smallmouth
Straight type test tube.
In magnetic agitation mode, according to the arrangement principle of symmetrical expression photoreaction container 3, for vertical
Photoreaction container 3 arrangement of formula LED array optimum can be 1,2 × 1,2 × 2,4 × 1,4 × 2；
Horizontal LED array is set according to the effective coverage of magnetic agitation and the symmetry of photoreaction container 3
Putting, the arrangement of peak optimization reaction container can be 4 multi pack modes, 7 multi pack modes, or 12 multi packs
Etc. mode.In machinery concussion mode, the arrangement of photoreaction container 3 can be m × n rectangle
Array, and match with horizontal LED array.Plastic lens can be installed additional for horizontal LED array
Sheet optically focused module (can promote light utilization efficiency about 10～15%).
The embodiment of the present invention uses high-power LED light source to tie with stirring and adjusting means 2 phase
Close, it is adaptable to the photochemical syntheses reaction of low dose of type and high flux screening, its cost is relatively low,
Easy heat radiation, taking up room little, and the embodiment of the present invention is further introduced into liquid-cooling heat radiation mode,
In many aspects there is important improvement:
The most open global design without casing, ultimate attainment miniaturization, portable, save space.This
Photoreactor size involved by invention is far smaller than the most various commercially available Photoreactor, such as Fig. 1
Shown in, model machine a size of 20cm × 15cm × 16cm (L × W × H), and including
Portion is fully integrated required power supply and adapter, connects civil power and can use, if selected further
Select the greater compactness of commercially available magnetic stirring apparatus of size, can miniaturization further.
2. using modular unitary design, meet technical grade standard, integrated level is high, becomes
This is low.Wherein, integral type support heat radiation module 1 be industrial processes aluminium sheet radiator, stir and
Adjusting means 2 has been further introduced into LED on the basis of commercially available small magnetic agitator and has controlled electricity
Source, photoreaction container 3 is the straight type test tube with standard interface, and LED chip 4 is commercially available Gao Gong
Rate LED sheet, contains ultraviolet, visible, the various wavelength of near-infrared, and all parts all can be according to
Industrial standard carries out waterproof and dampproof process.
3. for photochemical syntheses repercussion study small, high flux, high light intensity, unicast
Long core demand.Use multiple straight type test tube parallel reaction, can be simultaneously to numerous reactants
Permutation and combination or a series of condition are screened；The cumulative volume of type reaction solution is 5～20
ML, saves reagent cost；Unit volume reaction solution by optical energy density high (seeing table 1),
Photoreaction speed is fast, saves the response time；Specific wavelength LED can be chosen and used up during illumination
Quick dose of coupling, farthest reduces the generation of side reaction.
4. make the straight type test tube of apparatus standard interface as replaceable photoreaction container, low cost
Honest and clean, and conveniently carry out various chemosynthesis standard operations or the process such as anhydrous, anaerobic.
5. support housing liquid cold temperature control design so that low-temp reaction as normal-temperature reaction,
Identical replaceable photoreaction container can be used, it is not necessary to use custom-designed sandwich
Transparent reaction container, enters light intensity simultaneously and keeps constant, so can be substantially reduced low-temp reaction
Cost, simplification operating procedure；Overcome in existing cryogenic technique and can only enter light from bottom or middle part,
Realize high intensity of illumination；The design using waterproof guiding groove to match with seal washer, successfully solves
The problem that certainly under open environment, steam easily condenses on low-temperature components.
6. support heat radiation module and have employed totally enclosed unitary design, photoreaction container part
Outer surface has carried out japanning shading treatment, has carried out global optimization, make in terms of preventing light pollution
Obtain Photoreactor can use in open environment easily.
A kind of use for laboratory miniaturization LED involved in the present invention is low/normal-temperature light reactor with make
Comparing with the Photoreactor of halogen lamp, mercury lamp, xenon lamp etc., comprehensive advantage is obvious；At a class acyl group
Transport reaction (reaction 1, Org.Lett.2014,16,5968), a class intersection dehydrogenation coupling reaction
(reaction 2, J.Am.Chem.Soc.2013,135,19052) and class Photocatalyzed Hydrogen Production reaction are (anti-
Answer 3, J.Am.Chem.Soc.2014,136,8261) comparative result in is as shown in table 1.This
LED light reactor light intensity under the conditions of Single wavelength is much larger than solar simulator AM 1.5
(100mW/cm2) standard, the optical energy density that unit volume reaction solution accepts is big, it is possible to big
Shorten greatly the response time.Photosensitizer is obvious with selected optical source wavelength matching effect, as in reaction 3
In using CdTe quantum as photosensitizer time, to absorb spectral coverage reaction efficiency high, in weak suction strong
Receive spectral coverage reaction efficiency low, even do not react, show rational wavelength dependency.
The LED light reactor of table 1. present invention and halogen lamp, mercury lamp, the comparison of xenon lamp reactor:
Remarks:[1]Newport company Model 842-PE portable light energy meter is used to measure；[2]Typical case is anti-
The cumulative volume answering solution is 10mL；[3]Series of parallel experiment reaches the result of same reaction degree.
The above is only the preferred embodiment of the present invention, it is noted that lead for this technology
For the those of ordinary skill in territory, on the premise of without departing from the technology of the present invention principle, it is also possible to
Making some improvement and replacement, these improve and replace and also should be regarded as protection scope of the present invention.
Claims (9)
1. a Photoreactor, it is characterised in that including: LED light source, integral type support
Heat radiation module, stirring and adjusting means and photoreaction container, described integral type supports heat radiation module
Including liquid cooled module, for described LED light source is carried out liquid-cooling heat radiation；Described stirring and tune
Regulating device is for regulating the light intensity of described LED light source；Described photoreaction container passes through described one
Body formula supports heat radiation module and is arranged on the top of described stirring and adjusting means；Described photoreaction is held
Device carries out photoreaction under the irradiation of described LED light source, and is regulated by described liquid cooled module
Reaction temperature, carries out low-temp reaction and/or normal-temperature reaction；Described Photoreactor is anti-at low temperature
Seasonable use and the identical replaceable photoreaction container of normal-temperature reaction.
2. Photoreactor as claimed in claim 1, it is characterised in that described integral type is propped up
Support heat radiation module is by rustless steel, copper, aluminum manufacture.
3. Photoreactor as claimed in claim 1, it is characterised in that described liquid cooled module
Portalling including condensed fluid inlet hole, condensed fluid flow pipe and condensed fluid, described liquid cooled module passes through
Condensed fluid inlet hole is portalled with condensed fluid and is connected with outer loop condensing unit.
4. Photoreactor as claimed in claim 1, it is characterised in that described integral type is propped up
Support heat radiation module include guiding groove, described photoreaction container inserted by described guiding groove and with institute
State integral type support heat radiation module to fit tightly.
5. Photoreactor as claimed in claim 1, it is characterised in that described photoreaction is held
Device includes seal washer, supports heat radiation mould for inserting described integral type at described photoreaction container
During group, stop the steam in air to enter described integral type and support heat radiation module and coagulate therein
Knot.
6. Photoreactor as claimed in claim 5, it is characterised in that described photoreaction is held
The device shading that is partially coated with more than described seal washer is painted.
7. Photoreactor as claimed in claim 1, it is characterised in that described LED light source
Including LED array and the driving power supply that is connected with described LED array, described LED array
It is arranged on described integral type to support in heat radiation module.
8. Photoreactor as claimed in claim 7, it is characterised in that described LED array
For vertical LED array or horizontal LED array.
9. Photoreactor as claimed in claim 1, it is characterised in that described stirring and tune
Regulating device uses magnetic agitation or machinery concussion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510020992.9A CN105833815A (en) | 2015-01-15 | 2015-01-15 | Low/normal temperature photoreactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510020992.9A CN105833815A (en) | 2015-01-15 | 2015-01-15 | Low/normal temperature photoreactor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105833815A true CN105833815A (en) | 2016-08-10 |
Family
ID=56580048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510020992.9A Pending CN105833815A (en) | 2015-01-15 | 2015-01-15 | Low/normal temperature photoreactor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105833815A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108126640A (en) * | 2018-01-23 | 2018-06-08 | 北京缔森科技发展有限公司 | A kind of bottom illuminated high temperature and pressure photochemical reaction kettle |
| WO2022127926A1 (en) * | 2020-12-19 | 2022-06-23 | 北京大学 | Liquid phase synthesis assisted system |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4905856B2 (en) * | 2007-03-29 | 2012-03-28 | 東京電力株式会社 | Photocatalytic reactor |
| CN202188707U (en) * | 2011-05-24 | 2012-04-11 | 石页 | Water-filling type wavy ice box |
| CN202709589U (en) * | 2012-03-28 | 2013-01-30 | 王文斌 | Novel ice box |
| CN203148138U (en) * | 2013-03-07 | 2013-08-21 | 戴仁德 | Wave ice box |
| CN103357364A (en) * | 2012-03-27 | 2013-10-23 | 中国科学院理化技术研究所 | Photoreactor |
| CN103752360A (en) * | 2013-12-30 | 2014-04-30 | 西安天隆科技有限公司 | Thermal module for biochemical reaction |
| CN204522959U (en) * | 2015-01-15 | 2015-08-05 | 中国科学院理化技术研究所 | Low/normal temperature photoreactor |
-
2015
- 2015-01-15 CN CN201510020992.9A patent/CN105833815A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4905856B2 (en) * | 2007-03-29 | 2012-03-28 | 東京電力株式会社 | Photocatalytic reactor |
| CN202188707U (en) * | 2011-05-24 | 2012-04-11 | 石页 | Water-filling type wavy ice box |
| CN103357364A (en) * | 2012-03-27 | 2013-10-23 | 中国科学院理化技术研究所 | Photoreactor |
| CN202709589U (en) * | 2012-03-28 | 2013-01-30 | 王文斌 | Novel ice box |
| CN203148138U (en) * | 2013-03-07 | 2013-08-21 | 戴仁德 | Wave ice box |
| CN103752360A (en) * | 2013-12-30 | 2014-04-30 | 西安天隆科技有限公司 | Thermal module for biochemical reaction |
| CN204522959U (en) * | 2015-01-15 | 2015-08-05 | 中国科学院理化技术研究所 | Low/normal temperature photoreactor |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108126640A (en) * | 2018-01-23 | 2018-06-08 | 北京缔森科技发展有限公司 | A kind of bottom illuminated high temperature and pressure photochemical reaction kettle |
| WO2022127926A1 (en) * | 2020-12-19 | 2022-06-23 | 北京大学 | Liquid phase synthesis assisted system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103357364B (en) | Photoreactor | |
| CN107741468B (en) | Magneto-optic thermal synergistic catalyst evaluation device | |
| CN107032442B (en) | Solar energy utilization system integrating photovoltaic power generation and photocatalytic water purification | |
| CN105344299A (en) | LED light source photochemical reaction instrument | |
| CN206626444U (en) | A kind of high-power LED lamp of high efficiency and heat radiation | |
| CN102518971A (en) | Ultraviolet light emitting diode light source | |
| CN105833815A (en) | Low/normal temperature photoreactor | |
| CN204522959U (en) | Low/normal temperature photoreactor | |
| CN202884865U (en) | Ultraviolet light emitting diode lamp holder and cold water heat-radiating ultraviolet light emitting diode lamp adopting same | |
| US9181177B2 (en) | Method of producing cycloalkanone oxime | |
| CN102285638B (en) | Visible light catalytic hydrogen production reactor | |
| JP2012149055A (en) | Method for producing cycloalkanone oxime | |
| CN208634943U (en) | A kind of LED street lamp lamps and lanterns of high efficiency and heat radiation | |
| CN202501224U (en) | Ultraviolet light emitting diode (UV LED) light source | |
| CN204503051U (en) | A kind of photocatalytic hydrogen production by water decomposition device | |
| CN202070335U (en) | Photochlorination reaction device | |
| CN201147688Y (en) | Actinic chemistry reactor using LED as light source | |
| CN202561604U (en) | Water-flow heat conduction type high-power light-emitting diode (LED) plant growth lighting device | |
| CN105251426A (en) | LED light source photochemical reaction instrument | |
| CN205910496U (en) | UV-LED light source box for UV-LED resistance welding exposure machine | |
| CN103288593B (en) | Device and method for producing sodium methoxide through recompression of mechanical steam | |
| CN102705795A (en) | Water flow heat conduction method and high-power light emitting diode (LED) plant growth illumination device | |
| CN205146206U (en) | LED light source photochemical reaction appearance | |
| CN211630717U (en) | Singlechip control box cooling system | |
| CN207483859U (en) | Organic electro-synthesis device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160810 |
|
| RJ01 | Rejection of invention patent application after publication |