CN105833640A - Cage washing dust collector used in building and working method thereof - Google Patents
Cage washing dust collector used in building and working method thereof Download PDFInfo
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- CN105833640A CN105833640A CN201610224471.XA CN201610224471A CN105833640A CN 105833640 A CN105833640 A CN 105833640A CN 201610224471 A CN201610224471 A CN 201610224471A CN 105833640 A CN105833640 A CN 105833640A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F216/10—Carbocyclic compounds
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Abstract
The invention discloses a cage washing dust collector used in building and a working method thereof. The dust collector comprises a dusty gas inlet, a dust chamber, a clean gas outlet, a water-sending system, a clean-water reservoir, a sewage discharge pipe, a cesspool, an air dust density detector, a holder, and a control system. The dusty gas enters the dust chamber from the bottom through the dusty gas inlet, and the water-sending system sends clear water to the dust chamber. The clear gas treated by the dust chamber is discharged from the dust chamber through the clean gas outlet, and the sewage is discharged into the cesspool through the sewage discharge pipe. The cage washing dust collector used in building and the working method thereof have novel and reasonable structure, have high gas suspension dust removal rate, and have wide range of application.
Description
Technical field
The invention belongs to architectural engineering device, be specifically related to a kind of cage for building and clean dust arrester and method of work thereof.
Background technology
Environmental conservation has become the focus that common people pay close attention to, and the cry of the spring tide of economic globalization and solution Global Environmental Problems makes
Environment is day by day close with the relation of trade, and international organization has formulated a series of technical standard being intended to protect environment.How to prevent and treat big
Gas pollutes, pure air environment is also the problem that people constantly study.The particularly building dedusting of China, in building construction process
Substantial amounts of dust can be produced, severe contamination atmospheric environment.Trickle coal dust in these air, the most a diameter of 2.5~6
The floating dust of μm has high risks to health.It not only can be in pulmonary deposition, it is also possible to be directly entered blood arrival human body each
Position.Various noxious substance also can be adhered in powder dust particle surface, and it once enters human body, will cause various respiratory system disease,
Harm will be bigger.Therefore, control the discharge of the fine solid particle of dust the most a diameter of 2.5~6 μm, be that China administers greatly
Gas pollutes, the Important Action of pure air environment.
China is since the tentative discharge standard announcing 13 kinds of materials for the first time in 1973, and each industrial department is made the most in succession
Determine the dust emission standard of the industry.Such as, the discharge standard of boiler for building be according to atmospheric environmental standards one, two,
Three class areas determine, the standard (GB3841-83) of nineteen eighty-three be respectively 200,400,600mg/Nm3, 1992
The standard (GB13271 1) announced is respectively 200 for installation before 1 day August in 1992,300,400mg/Nm3,
Install after August 1 be then respectively 100,250,350mg/Nm3.Obviously to reach new standard and be accomplished by using higher
The cleaner of efficiency.
Tiny dust is big to harm relatively coarse granule, and therefore since the seventies, each state all focuses on research fine powder
The big art of control of dirt (commonly referred to microgranule), and propose many corresponding technical measures.At U.S.'s pure air in 1992
Clearly proposing in method to classify the dust (PM10) less than l0 μm, its standard area and non-standard area are to draw by PM10
Point.In non-standard area, moderate requirement is up to standard before the end of the year 1994, more serious requirement is up to standard at the bottom of calendar year 2001.
The toxicity dust produced in construction is maximum to harm, and before nineteen ninety, NESHAPS is only to 7 kinds of poisonous dirts
Thing dye defines standard, including: hydrargyrum, quilt, asbestos, arsenic etc..But in the pure air method of 1990, propose 189 kinds
Toxic pollutant (many of which is solid-state dust), just has 37 kinds more than in the emission of boiler the most for building.1988
The total amount of the U.S.'s these toxic pollutants discharge is more than 2,400,000,000 pounds.At present these poisonous substances are not yet formulated standard, pure air method
Require in 1 year, complete the work of the standard formulation to these poisonous substances by stages and in groups, and before not formulating, require reduction by 9000, right
Dust requires reduction by 96%.
Existing common building dust removal process equipment has: mechanical type building cleaner unit, gravity building cleaner unit, inertia building are removed
Dirt device, whirlwind building separator, filtering type building cleaner unit, pocket type building cleaner unit, granular layer building cleaner unit, electric precipitation
Device, wet type building cleaner unit, gravity building spray jet scrubber, impact water bath building cleaner unit, efficient venturi tube duster etc..
Under prior art conditions, the increase of the equipment construction cost and operating cost that process building air-borne dust will become must
So, existing traditional handicraft, that processing method has technological process is long, controls complexity, takes up an area big, the shortcomings such as processing cost is high.
Summary of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of cage for building to clean dust arrester, including:
Dusty gas import 1, dirt pocket 2, clean gas outlet 3, send water system 4, clear water reserviors 5, effluent outfall 6, sewage
Pond 7, air-borne dust concentration detector 8, support 9, control system 10;Described support 9 top is provided with dirt pocket 2, described
Dusty gas import 1 is positioned at dirt pocket 2 sidewall bottom position, and described clean gas outlet 3 is positioned at dirt pocket 2 tip position,
It is provided with effluent outfall 6 bottom described dirt pocket 2, bottom described effluent outfall 6, is provided with cesspool 7, described dirt pocket 2
And being provided with water system 4 of sending between clear water reserviors 5, described dirt pocket 2 is outside is provided with air-borne dust concentration detector 8, described support
Control system 10 it is provided with below 9;
Electromagnetic valve in described dusty gas import 1 is connected with control system 10 polygon control survey;
Electromagnetic valve in described clean gas outlet 3 is connected with control system 10 polygon control survey;
The described water pump that send in water system 4, water flow meter, electromagnetic valve are connected with control system 10 polygon control survey;
Electromagnetic valve on described effluent outfall 6 is connected with control system 10 polygon control survey;
Described air-borne dust concentration detector 8 is connected with control system 10 polygon control survey.
Further, described dirt pocket 2 includes: bucket type sewage chamber 2-1, bottom dividing plate 2-2, " S " type dedusting plate 2-3,
Upper partition 2-4, water drenches system 2-5, water-stop sheet 2-6, air exhauster 2-7, dust degradation capability detector 2-8;Described bucket type
Sewage chamber 2-1 is positioned at described dirt pocket 2 least significant end position, and described bucket type sewage chamber 2-1 is pyramidal structure, and cross section is rectangle,
Described bucket type sewage chamber 2-1 cross section is upwards gradually increased;Described " S " type dedusting plate 2-3 is positioned in described dirt pocket 2 inside
Between position, described " S " type dedusting plate 2-3 level is spaced substantially equidistant, quantity be no less than 5 pieces, adjacent " S " type dedusting plate 2-
3 spacing 5~30cm, described " S " type dedusting plate 2-3 and described dirt pocket 2 inwall seamless welding;Described " S " type dedusting
The upper and lower two ends of plate 2-3 are respectively welded upper partition 2-4 and bottom dividing plate 2-2, described upper partition 2-4 and bottom dividing plate 2-2
Structure size is the most identical, and upper partition 2-4 and bottom dividing plate 2-2 surface distributed leaking hole, and pore diameter range value is 5~10mm,
Described upper partition 2-4 and bottom dividing plate 2-2 and described dirt pocket 2 inwall seamless welding;Described water drenches system 2-5 and is positioned at institute
Stating upper partition 2-4 top position, described water drenches system 2-5 away from described upper partition 2-4 surface 5~20cm;Described water proof
Plate 2-6 be positioned at described water drench system 2-5 top position, described water-stop sheet 2-6 away from described water drench system 2-5 upper surface 5~
20cm, described water-stop sheet 2-6 are corrosion resistant plate bending 60~90 ° of structures, described water-stop sheet 2-6 and described dirt pocket 2 inwall
Seamless welding, described water-stop sheet 2-6 level is spaced substantially equidistant, quantity be no less than 8 pieces, adjacent water-stop sheet 2-6 spacing 5~
20cm;Described air exhauster 2-7 is positioned at described water-stop sheet 2-6 top position, described air exhauster 2-7 and control system 10 wire
Control to connect;Described dust degradation capability detector 2-8 is positioned in described " S " type dedusting plate layer 2-3, and described dust is degraded
Capacity detector 2-8 is connected with control system 10 polygon control survey.
Further, described " S " type dedusting plate 2-3 includes: " S " bent plate 2-3-1, dedusting ball 2-3-2;Described " S "
Bent plate 2-3-1 is serpentine structure, and described " S " bent plate 2-3-1 is made up of multi-section circular arc shape corrosion resistant plate, thickness of slab 1~5mm,
Described " S " bent plate 2-3-1 surface distributed substantial amounts of dedusting ball 2-3-2, described dedusting ball 2-3-2 a diameter of 5~20mm.
Further, described water drenches system 2-5 and includes: water inlet main 2-5-1, distributive pipe 2-5-2, water sprays a 2-5-3;
Described water inlet main 2-5-1 one end is connected with the described outfan sending water system 4, the other end and described distributive pipe 2-5-2 phase
Connection, described distributive pipe 2-5-2 is " mesh " shape structure, and water that the arm of described distributive pipe 2-5-2 is uniformly arranged sprays
Head 2-5-3, the distance sprayed between a 2-5-3 that borders on the river mutually is 5cm~20cm, and it is cone-shaped structure that described water sprays a 2-5-3,
Described water sprays the surface of a 2-5-3 and is thick with substantial amounts of micropore, a diameter of 5nm~100nm of micropore.
Further, described dedusting ball 2-3-2 is by macromolecular material pressing mold molding, the constituent of dedusting ball 2-3-2 and system
Make process as follows:
One, dedusting ball 2-3-2 constituent:
Count by weight, ethyl thloylyllate 55~105 parts, ethylene glycol monoethyl ether acetate (EGEEA) 18~33 parts,
2,3,4-trifluoronitrobenzenes 11~24 parts, 5-fluoro-2-nitro-trifluoromethyl toluene 20~85 parts, 4-acetylamino dimethyl phthalate
15~40 parts, o aminophenylacetic acid 50~120 parts, concentration is N-(the S-trityl mercaptoacetyl of 55ppm~115ppm
Base) alanyl glycylglycine 50~100 parts, mercaptoacetyl three glycyl-N-hydroxysuccinimide ester 20~95 parts,
N-(2-mercapto radical propionyl group)-glycine 60~150 parts, cross-linking agent 30~75 parts, methyl butenol 10~30 parts, 4-(2,6,6-
3-methyl cyclohexanol thiazolinyl-1-base)-3-butene-2-ol 40~120 parts, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-2-
Crotonaldehyde 25~55 parts, 4-(2,6,6 trimethyl-1-cyclohexene-1-base)-3-butene-2-ol acetas 10~30 parts;
Described cross-linking agent is any one in the only ether of diethylene glycol, polyacrylamide gel, polyacrylamide hydrophilic gel (PAHG);
Two, the manufacture process of dedusting ball 2-3-2, comprises the steps of
1st step: add ultra-pure water 200~700 parts that electrical conductivity is 0.3 μ S/cm~0.8 μ S/cm in a kettle., start reaction
Agitator in still, rotating speed is 85rpm~130rpm, starts heat pump, makes reactor temperature rise to 60 DEG C~75 DEG C;
Being sequentially added into ethyl thloylyllate, ethylene glycol monoethyl ether acetate (EGEEA), 2,3,4-trifluoronitrobenzenes, stirring is to completely
Dissolving, regulation pH value is 4.0~9.5, and agitator speed is adjusted to 140rpm~195rpm, and temperature is 65 DEG C~75 DEG C,
Esterification 5~10 hours;
2nd step: take 5-fluoro-2-nitro-trifluoromethyl toluene, 4-acetylamino dimethyl phthalate, powder diameter is 300~800 mesh;
Adding o aminophenylacetic acid mix homogeneously, be laid in pallet, tiling thickness is 20mm~50mm, and employing dosage is
4.0kGy~8.5kGy, energy are the alpha ray irradiation 50 of 7.0MeV~10MeV~80 minutes, and the β of Isodose
X ray irradiation x 30~55 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in N-(S-trityl mercaptoacetyl) alanyl glycylglycine,
Adding reactor, agitator speed is 60rpm~95rpm, and temperature is 70 DEG C~85 DEG C, starts vacuum pump and makes the true of reactor
Reciprocal of duty cycle reaches-0.10MPa~-0.35MPa, keeps this state response 6~20 hours;Pressure release is also passed through nitrogen, in making reactor
Pressure is 0.10~0.30MPa, and insulation stands 11~20 hours;Agitator speed is promoted to 100rpm~210rpm, simultaneously
Reactor pressure release is to 0MPa;Be sequentially added into mercaptoacetyl three glycyl-N-hydroxysuccinimide ester, N-(2-mercapto radical propionyl group)-
After glycine is completely dissolved, add cross-linking agent stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 6.5~9.5,
Insulation stands 5~9 hours;
4th step: when agitator speed is 140rpm~180rpm, is sequentially added into methyl butenol, 4-(2,6,6-3-methyl cyclohexanols
Thiazolinyl-1-base)-3-butene-2-ol, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-crotonic aldehyde and 4-(2,6,6 front threes
Base-1-cyclohexene-1-base)-3-butene-2-ol acetas, promote reactor pressure so that it is reach 0.55MPa~0.95MPa, temperature
Degree is 160 DEG C~190 DEG C, polyreaction 6~15 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to
25 DEG C~45 DEG C, discharging, enter molding press and can be prepared by dedusting ball 2-3-2.
The invention also discloses a kind of cage for building and clean the minimizing technology of dust arrester, the method includes following
Step:
1st step: control system 10 starts the electromagnetic valve in dusty gas import 1 and inputted by dusty gas in dirt pocket 2, and gas exists
Taking the lead in dirt pocket 2 rising in " S " type dedusting plate layer 2-3, the dust in gas is adsorbed by dedusting ball 2-3-2, this time control
System 10 processed starts send water system 4, drenches system 2-5 by water and supplies water in " S " type dedusting plate layer 2-3, and clear water is with " S "
Type dedusting plate 2-3 surface flows downward, and forms water membrane on " S " type dedusting plate 2-3 surface, and moisture film stops powder in gas
The dust of absorption on dedusting ball 2-3-2 is also rinsed well by the rising of dirt, and the sewage after flushing discharges into sewage through effluent outfall 6
In pond 7, now control system 10 start air exhauster 2-7 by " S " type dedusting plate 2-3 process after clean gas be drawn up,
Water-stop sheet 2-6 blocks the rising of current, and clean gas is finally by clean gas outlet 3 discharge dirt pocket 2;
2nd step: meanwhile, the absorption degradation ability of dust suspension is monitored by dust degradation capability detector 2-8 in real time, when
When the absorption degradation ability of dust suspension is less than 35%~45%, dust degradation capability detector 2-8 sends to control system 10
Feedback signal, prompting staff changes " S " type dedusting plate 2-3;
3rd step: the air-borne dust concentration detector 8 outside position dirt pocket 2, carries out actual time safety to the dust suspension content in air
Monitoring, setting air dust concentration detector 8 is when gas suspension dust content concentration is more than 30mg/m3~120mg/m3Time,
Air-borne dust concentration detector 8 sends signal to control system 10, the electricity that control system 10 will start in dusty gas import 1
Magnet valve, the electromagnetic valve in clean gas outlet 3, send the water pump in water system 4, water flow meter, electromagnetic valve, effluent outfall
Electromagnetic valve on 6, air exhauster 2-7 so that whole system is started working.
A kind of cage for building disclosed in patent of the present invention cleans dust arrester and method of work thereof, has an advantage in that:
(1) this device uses " S " type dedusting plate isolation dust granules, and dust removal efficiency is high;
(2) this apparatus structure is reasonable in design compact, and integrated level is high;
(3) this device dedusting ball uses macromolecular material to prepare, and dust purification rate promotes notable.
One of the present invention cage for building cleans dust arrester and method of work novel and reasonable structure, gas suspension
Dust clearance is high, and the scope of application is wide.
Accompanying drawing explanation
The one cage for building that Fig. 1 is heretofore described cleans dust arrester schematic diagram.
Fig. 2 is heretofore described dirt pocket internal structure schematic diagram.
Fig. 3 is heretofore described " S " type dedusting plate schematic diagram.
Fig. 4 is that heretofore described water drenches system schematic.
Fig. 5 is the fuel gas and dust gross decontamination rate graph of a relation of dedusting ball of the present invention and reference examples.
In figure 1 above~Fig. 4, dusty gas import 1, dirt pocket 2, bucket type sewage chamber 2-1, bottom dividing plate 2-2, " S "
Type dedusting plate 2-3, " S " bent plate 2-3-1, dedusting ball 2-3-2, upper partition 2-4, water drenches system 2-5, main 2-5-1 of intaking,
Distributive pipe 2-5-2, water sprays a 2-5-3, water-stop sheet 2-6, air exhauster 2-7, dust degradation capability detector 2-8, clean gas
Body outlet 3, send water system 4, clear water reserviors 5, effluent outfall 6, cesspool 7, air-borne dust concentration detector 8, support
9, control system 10.
Detailed description of the invention
The one cage for building provided the present invention below in conjunction with the accompanying drawings cleans dust arrester and is further described.
As it is shown in figure 1, be the schematic diagram of the cage a kind of for building cleaning dust arrester that the present invention provides.Figure is found out,
Including dusty gas import 1, dirt pocket 2, clean gas outlet 3, send water system 4, clear water reserviors 5, effluent outfall 6,
Cesspool 7, air-borne dust concentration detector 8, support 9, control system 10;Described support 9 surface is provided with dirt pocket 2,
Described dusty gas import 1 is positioned at dirt pocket 2 sidewall bottom position, and described clean gas outlet 3 is positioned at position, dirt pocket 2 top
Put, be provided with effluent outfall 6 bottom described dirt pocket 2, bottom described effluent outfall 6, be provided with cesspool 7, described dedusting
Being provided with water system 4 of sending between room 2 and clear water reserviors 5, described dirt pocket 2 is outside is provided with air-borne dust concentration detector 8, described
Control system 10 it is provided with below support 9;
Electromagnetic valve in described dusty gas import 1 is connected with control system 10 polygon control survey;
Electromagnetic valve in described clean gas outlet 3 is connected with control system 10 polygon control survey;
The described water pump that send in water system 4, water flow meter, electromagnetic valve are connected with control system 10 polygon control survey;
Electromagnetic valve on described effluent outfall 6 is connected with control system 10 polygon control survey;
Described air-borne dust concentration detector 8 is connected with control system 10 polygon control survey.
As in figure 2 it is shown, be heretofore described dirt pocket internal structure schematic diagram.Find out from Fig. 2 or Fig. 1, institute
Stating dirt pocket 2 to include: bucket type sewage chamber 2-1, bottom dividing plate 2-2, " S " type dedusting plate 2-3, upper partition 2-4, water drenches
System 2-5, water-stop sheet 2-6, air exhauster 2-7, dust degradation capability detector 2-8;Described bucket type sewage chamber 2-1 is positioned at institute
Stating dirt pocket 2 least significant end position, described bucket type sewage chamber 2-1 is pyramidal structure, and cross section is rectangle, described bucket type sewage chamber 2-
1 cross section is upwards gradually increased;Described " S " type dedusting plate 2-3 is positioned at described dirt pocket 2 bosom position, described " S "
Type dedusting plate 2-3 level is spaced substantially equidistant, and quantity is no less than 5 pieces, adjacent " S " type dedusting plate 2-3 spacing 5~30cm,
Described " S " type dedusting plate 2-3 and described dirt pocket 2 inwall seamless welding;Described " S " type dedusting plate 2-3 divides at upper and lower two ends
It is not welded with upper partition 2-4 and bottom dividing plate 2-2, described upper partition 2-4 and bottom dividing plate 2-2 structure size the most identical,
Upper partition 2-4 and bottom dividing plate 2-2 surface distributed leaking hole, and pore diameter range value is 5~10mm, described upper partition 2-
4 and bottom dividing plate 2-2 with described dirt pocket 2 inwall seamless welding;Described water drenches system 2-5 and is positioned at described upper partition 2-4
Top position, described water drenches system 2-5 away from described upper partition 2-4 surface 5~20cm;Described water-stop sheet 2-6 is positioned at described
Water drenches system 2-5 top position, and described water-stop sheet 2-6 drenches system 2-5 upper surface 5~20cm, described water-stop sheet away from described water
2-6 is corrosion resistant plate bending 60~90 ° of structures, described water-stop sheet 2-6 and described dirt pocket 2 inwall seamless welding, described every
Water plate 2-6 level is spaced substantially equidistant, and quantity is no less than 8 pieces, adjacent water-stop sheet 2-6 spacing 5~20cm;Described air exhauster 2-
7 are positioned at described water-stop sheet 2-6 top position, and described air exhauster 2-7 is connected with control system 10 polygon control survey;Described dust drops
Solve capacity detector 2-8 to be positioned in described " S " type dedusting plate layer 2-3, described dust degradation capability detector 2-8 and control system
10 polygon control survey of uniting connect.
As it is shown on figure 3, be heretofore described " S " type dedusting plate schematic diagram.Finding out in figure, described " S " type removes
Dirt plate 2-3 includes: " S " bent plate 2-3-1, dedusting ball 2-3-2;Described " S " bent plate 2-3-1 is serpentine structure, described " S "
Bent plate 2-3-1 is made up of multi-section circular arc shape corrosion resistant plate, thickness of slab 1~5mm, and described " S " bent plate 2-3-1 surface distributed greatly
The dedusting ball 2-3-2, described dedusting ball 2-3-2 a diameter of 5~20mm of amount.
As shown in Figure 4, it is that heretofore described water drenches system schematic.Finding out in figure, described water drenches system 2-5 and includes:
Water inlet main 2-5-1, distributive pipe 2-5-2, water sprays a 2-5-3;Water system 4 is sent with described in described water inlet main 2-5-1 one end
Outfan be connected, the other end is connected with described distributive pipe 2-5-2, and described distributive pipe 2-5-2 is " mesh " shape structure,
Water of uniformly arranging on the arm of described distributive pipe 2-5-2 sprays a 2-5-3, and the distance sprayed between a 2-5-3 that borders on the river mutually is
5cm~20cm, it is cone-shaped structure that described water sprays a 2-5-3, and described water sprays the surface of a 2-5-3 and is thick with substantial amounts of
Micropore, a diameter of 5nm~100nm of micropore.
A kind of cage for building of the present invention cleans the work process of dust arrester:
1st step: control system 10 starts the electromagnetic valve in dusty gas import 1 and inputted by dusty gas in dirt pocket 2, and gas exists
Taking the lead in dirt pocket 2 rising in " S " type dedusting plate layer 2-3, the dust in gas is adsorbed by dedusting ball 2-3-2, this time control
System 10 processed starts send water system 4, drenches system 2-5 by water and supplies water in " S " type dedusting plate layer 2-3, and clear water is with " S "
Type dedusting plate 2-3 surface flows downward, and forms water membrane on " S " type dedusting plate 2-3 surface, and moisture film stops powder in gas
The dust of absorption on dedusting ball 2-3-2 is also rinsed well by the rising of dirt, and the sewage after flushing discharges into sewage through effluent outfall 6
In pond 7, now control system 10 start air exhauster 2-7 by " S " type dedusting plate 2-3 process after clean gas be drawn up,
Water-stop sheet 2-6 blocks the rising of current, and clean gas is finally by clean gas outlet 3 discharge dirt pocket 2;
2nd step: meanwhile, the absorption degradation ability of dust suspension is monitored by dust degradation capability detector 2-8 in real time, when
When the absorption degradation ability of dust suspension is less than 35%~45%, dust degradation capability detector 2-8 sends to control system 10
Feedback signal, prompting staff changes " S " type dedusting plate 2-3;
3rd step: the air-borne dust concentration detector 8 outside position dirt pocket 2, carries out actual time safety to the dust suspension content in air
Monitoring, setting air dust concentration detector 8 is when gas suspension dust content concentration is more than 30mg/m3~120mg/m3Time,
Air-borne dust concentration detector 8 sends signal to control system 10, the electricity that control system 10 will start in dusty gas import 1
Magnet valve, the electromagnetic valve in clean gas outlet 3, send the water pump in water system 4, water flow meter, electromagnetic valve, effluent outfall
Electromagnetic valve on 6, air exhauster 2-7 so that whole system is started working.
One of the present invention cage for building cleans dust arrester and method of work novel and reasonable structure, gas suspension
Dust clearance is high, and the scope of application is wide.
The following is the embodiment of the manufacture process of dedusting ball 2-3-2 of the present invention, embodiment is to further illustrate this
Bright content, but should not be construed as limitation of the present invention.Without departing from the spirit and substance of the case in the present invention, to the present invention
Amendment that method, step or condition are made and replacement, belong to the scope of the present invention.
If not specializing, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
According to following steps manufacture dedusting ball 2-3-2 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 200 parts that electrical conductivity is 0.3 μ S/cm in a kettle., start agitator in reactor, rotating speed
For 85rpm, start heat pump, make reactor temperature rise to 60 DEG C;It is sequentially added into ethyl thloylyllate 55 parts, second
2-ethoxyethanol acetate (EGEEA) 18 parts, 2,3,4-trifluoronitrobenzenes 11 parts, stirring is to being completely dissolved, and regulation pH value is
4.0, agitator speed is adjusted to 140rpm, temperature is 65 DEG C, esterification 5 hours;
2nd step: taking 5-fluoro-2-nitro-trifluoromethyl toluene 20 parts, 4-acetylamino dimethyl phthalate 15 parts, powder diameter is
300 mesh;Adding 50 parts of mix homogeneously of o aminophenylacetic acid, be laid in pallet, tiling thickness is 20mm, and employing dosage is
4.0kGy, energy are the alpha ray irradiation 50 minutes of 7.0MeV, and the β x ray irradiation x of Isodose 30 minutes;
3rd step: to be dissolved in N-(the S-trityl mercaptoacetyl) alanyl that concentration is 55ppm sweet for the mixed-powder processed through the 2nd step
In aminoacyl glycine 50 parts, adding reactor, agitator speed is 60rpm, and temperature is 70 DEG C, starts vacuum pump and makes reaction
The vacuum of still reaches-0.10MPa, keeps this state response 6 hours;Pressure release is also passed through nitrogen, makes the reacting kettle inner pressure be
0.10MPa, insulation stands 11 hours;Agitator speed is promoted to 100rpm, simultaneous reactions still pressure release to 0MPa;Add successively
Entering mercaptoacetyl three glycyl-N-hydroxysuccinimide ester 20 parts, N-(2-mercapto radical propionyl group)-glycine 60 parts is completely dissolved
After, add cross-linking agent 30 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 6.5, and insulation stands 5 hours;
4th step: when agitator speed is 140rpm, is sequentially added into methyl butenol 10 parts, 4-(2,6,6-3-methyl cyclohexanol thiazolinyls-
1-yl)-3-butene-2-ol 40 parts, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-crotonic aldehyde 25 parts, 4-(2,6,6
Trimethyl-1-cyclohexene-1-base)-3-butene-2-ol acetas 10 parts, promote reactor pressure so that it is reach 0.55MPa, temperature
Degree is 160 DEG C, polyreaction 6 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 25 DEG C, discharging,
Enter molding press and can be prepared by dedusting ball 2-3-2.
Described cross-linking agent is the only ether of diethylene glycol.
Embodiment 2
According to following steps manufacture dedusting ball 2-3-2 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 700 parts that electrical conductivity is 0.8 μ S/cm in a kettle., start agitator in reactor, rotating speed
For 130rpm, start heat pump, make reactor temperature rise to 75 DEG C;It is sequentially added into ethyl thloylyllate 105 parts,
Ethylene glycol monoethyl ether acetate (EGEEA) 33 parts, 2,3,4-trifluoronitrobenzenes 24 parts, stirring, to being completely dissolved, regulates pH value
Being 9.5, agitator speed is adjusted to 195rpm, temperature is 75 DEG C, esterification 10 hours;
2nd step: taking 5-fluoro-2-nitro-trifluoromethyl toluene 85 parts, 4-acetylamino dimethyl phthalate 40 parts, powder diameter is
800 mesh;Adding 120 parts of mix homogeneously of o aminophenylacetic acid, be laid in pallet, tiling thickness is 50mm, uses dosage
For alpha ray irradiation that 8.5kGy, energy are 10MeV 80 minutes, and the β x ray irradiation x of Isodose 55 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in N-(the S-trityl mercaptoacetyl) alanyl that concentration is 115ppm
In glycylglycine 100 parts, adding reactor, agitator speed is 95rpm, and temperature is 85 DEG C, starts vacuum pump and makes instead
The vacuum answering still reaches-0.35MPa, keeps this state response 20 hours;Pressure release is also passed through nitrogen, makes reacting kettle inner pressure
For 0.30MPa, insulation stands 20 hours;Agitator speed is promoted to 210rpm, simultaneous reactions still pressure release to 0MPa;Depend on
Secondary addition mercaptoacetyl three glycyl-N-hydroxysuccinimide ester 95 parts, N-(2-mercapto radical propionyl group)-glycine 150 parts is complete
After dissolving, add cross-linking agent 75 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 9.5, is incubated standing 9
Hour;
4th step: when agitator speed is 180rpm, is sequentially added into methyl butenol 30 parts, 4-(2,6,6-3-methyl cyclohexanol thiazolinyls-
1-yl)-3-butene-2-ol 120 parts, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-crotonic aldehyde 55 parts, 4-
(2,6,6 trimethyl-1-cyclohexene-1-base)-3-butene-2-ol acetas 30 parts, promotes reactor pressure so that it is reach 0.95MPa,
Temperature is 190 DEG C, polyreaction 15 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 45 DEG C, goes out
Material, enters molding press and can be prepared by dedusting ball 2-3-2.
Described cross-linking agent is polyacrylamide hydrophilic gel (PAHG).
Embodiment 3
According to following steps manufacture dedusting ball 2-3-2 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 245 parts that electrical conductivity is 0.38 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 89rpm, starts heat pump, makes reactor temperature rise to 68 DEG C;It is sequentially added into ethyl thloylyllate 78 parts,
Ethylene glycol monoethyl ether acetate (EGEEA) 22 parts, 2,3,4-trifluoronitrobenzenes 21 parts, stirring, to being completely dissolved, regulates pH value
Being 5.55, agitator speed is adjusted to 165pm, temperature is 69 DEG C, esterification 9 hours;
2nd step: taking 5-fluoro-2-nitro-trifluoromethyl toluene 45 parts, 4-acetylamino dimethyl phthalate 35 parts, powder diameter is
398 mesh;Adding 111 parts of mix homogeneously of o aminophenylacetic acid, be laid in pallet, tiling thickness is 45mm, uses dosage
For alpha ray irradiation that 4.78kGy, energy are 7.78MeV 78 minutes, and the β x ray irradiation x of Isodose 51 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in N-(the S-trityl mercaptoacetyl) alanyl that concentration is 111ppm
In glycylglycine 87 parts, adding reactor, agitator speed is 87rpm, and temperature is 79 DEG C, starts vacuum pump and makes instead
The vacuum answering still reaches-0.178MPa, keeps this state response 18 hours;Pressure release is also passed through nitrogen, makes reacting kettle inner pressure
For 0.145MPa, insulation stands 19 hours;Agitator speed is promoted to 178rpm, simultaneous reactions still pressure release to 0MPa;Depend on
Secondary addition mercaptoacetyl three glycyl-N-hydroxysuccinimide ester 45 parts, N-(2-mercapto radical propionyl group)-glycine 78 parts is complete
After dissolving, add cross-linking agent 65 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 6.55, and insulation stands
5.9 hour;
4th step: when agitator speed is 171rpm, is sequentially added into methyl butenol 28 parts, 4-(2,6,6-3-methyl cyclohexanol thiazolinyls-
1-yl)-3-butene-2-ol 114 parts, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-crotonic aldehyde 41 parts, 4-
(2,6,6 trimethyl-1-cyclohexene-1-base)-3-butene-2-ol acetas 25 parts, promotes reactor pressure so that it is reach
0.5595MPa, temperature is 169 DEG C, polyreaction 6.15 hours;After having reacted, reacting kettle inner pressure is down to 0MPa,
It is cooled to 25.45 DEG C, discharging, enter molding press and can be prepared by dedusting ball 2-3-2.
Described cross-linking agent is polyacrylamide gel.
Reference examples
Reference examples is the dedusting ball processing procedure for fuel gas and dust of certain brand commercially available.
Embodiment 4
Dedusting ball described in dedusting ball 2-3-2 embodiment 1~3 prepared and reference examples is used for the processing procedure of fuel gas and dust.
Process terminate after character to fuel gas and dust respectively, and the impact on fuel gas and dust parameters detects, result such as table 1 institute
Show.
Table 1 is the performance parameter in the processing procedure of fuel gas and dust of the dedusting ball described in embodiment 1~3 and reference examples
Impact, as seen from Table 1, dedusting ball 2-3-2 of the present invention, its catalytic polymerization degree, catalysis strength enhancing rate, catalysis are produced
Amount enhancing rate, dust removal efficiency are above the product that prior art produces.
Additionally, as it is shown in figure 5, be the fuel gas and dust gross decontamination rate graph of a relation of dedusting ball of the present invention and reference examples.Figure
In find out, macromolecular material the dedusting ball 2-3-2 material manufactured is evenly distributed, and material surface is long-pending relatively big with volume ratio, surface
Good dispersion, the concentration relative comparison example of dispersible carrier free in continuous phase is high.Use the dedusting ball 2-3-2 of the present invention, make
The total inversion quantity of fuel gas and dust is assembled agglomerating little, forms the precipitation body of dispersed structure, macromolecular material the dedusting ball 2-3-2 manufactured
Fuel gas and dust had good catalytic;Using dedusting ball 2-3-2 of the present invention, it is the most excellent to fuel gas and dust gross decontamination rate
In existing product.
Claims (6)
1. cage for building cleans a dust arrester, including: dusty gas import (1), dirt pocket (2), clean gas exports
(3), water system (4), clear water reserviors (5), effluent outfall (6), cesspool (7), air-borne dust concentration detector are sent
(8), support (9), control system (10);It is characterized in that, described support (9) top is provided with dirt pocket (2), described
Dusty gas import (1) is positioned at dirt pocket (2) sidewall bottom position, and described clean gas outlet (3) is positioned at dirt pocket (2)
Tip position, described dirt pocket (2) bottom is provided with effluent outfall (6), and described effluent outfall (6) bottom is provided with sewage
Pond (7), is provided with water system (4) of sending between described dirt pocket (2) and clear water reserviors (5), described dirt pocket (2) is outside to be set
Air dust concentration detector (8), described support (9) lower section is had to be provided with control system (10);
Electromagnetic valve on described dusty gas import (1) is connected with control system (10) polygon control survey;
Electromagnetic valve on described clean gas outlet (3) is connected with control system (10) polygon control survey;
The described water pump that send in water system (4), water flow meter, electromagnetic valve are connected with control system (10) polygon control survey;
Electromagnetic valve on described effluent outfall (6) is connected with control system (10) polygon control survey;
Described air-borne dust concentration detector (8) is connected with control system (10) polygon control survey.
One the most according to claim 1 cage for building cleans dust arrester, it is characterised in that described dirt pocket (2) wraps
Including: bucket type sewage chamber (2-1), bottom dividing plate (2-2), " S " type dedusting plate (2-3), upper partition (2-4), water drenches system
System (2-5), water-stop sheet (2-6), air exhauster (2-7), dust degradation capability detector (2-8);Described bucket type sewage chamber
(2-1) being positioned at described dirt pocket (2) least significant end position, described bucket type sewage chamber (2-1) is pyramidal structure, and cross section is square
Shape, described bucket type sewage chamber (2-1) cross section is upwards gradually increased;Described " S " type dedusting plate (2-3) is positioned at described dedusting
Room (2) bosom position, described " S " type dedusting plate (2-3) level is spaced substantially equidistant, and quantity is no less than 5 pieces, phase
Adjacent " S " type dedusting plate (2-3) spacing 5~30cm, described " S " type dedusting plate (2-3) is interior with described dirt pocket (2)
Wall seamless welds;Described " S " type dedusting plate (2-3) is respectively welded upper partition (2-4) and bottom dividing plate in two ends up and down
(2-2), described upper partition (2-4) and bottom dividing plate (2-2) structure size are the most identical, upper partition (2-4) and bottom
Dividing plate (2-2) surface distributed leaking hole, and pore diameter range value is 5~10mm, described upper partition (2-4) and bottom dividing plate
(2-2) with described dirt pocket (2) inwall seamless welding;Described water drenches system (2-5) and is positioned at described upper partition (2-4)
Top position, described water drenches system (2-5) away from described upper partition (2-4) surface 5~20cm;Described water-stop sheet (2-6)
Be positioned at described water drench system (2-5) top position, described water-stop sheet (2-6) away from described water drench system (2-5) upper surface 5~
20cm, described water-stop sheet (2-6) is corrosion resistant plate bending 60~90 ° of structures, described water-stop sheet (2-6) and described dirt pocket
(2) inwall seamless welding, described water-stop sheet (2-6) level is spaced substantially equidistant, and quantity is no less than 8 pieces, adjacent water-stop sheet
(2-6) spacing 5~20cm;Described air exhauster (2-7) is positioned at described water-stop sheet (2-6) top position, described air exhauster
(2-7) it is connected with control system (10) polygon control survey;Described dust degradation capability detector (2-8) is positioned at described " S "
In type dedusting plate (2-3) layer, described dust degradation capability detector (2-8) is connected with control system (10) polygon control survey.
One the most according to claim 2 cage for building cleans dust arrester, it is characterised in that described " S " type dedusting plate
(2-3) including: " S " bent plate (2-3-1), dedusting ball (2-3-2);Described " S " bent plate (2-3-1) is serpentine structure,
Described " S " bent plate (2-3-1) is made up of multi-section circular arc shape corrosion resistant plate, thickness of slab 1~5mm, described " S " bent plate (2-3-
1) surface distributed substantial amounts of dedusting ball (2-3-2), described dedusting ball (2-3-2) a diameter of 5~20mm.
One the most according to claim 2 cage for building cleans dust arrester, it is characterised in that described water drenches system (2-5)
Including: water inlet main (2-5-1), distributive pipe (2-5-2), water sprays head (2-5-3);Described water inlet main (2-5-1)
End is connected with the described outfan sending water system (4), and the other end is connected with described distributive pipe (2-5-2), described point of water
Pipe (2-5-2) is " mesh " shape structure, and water that the arm of described distributive pipe (2-5-2) is uniformly arranged sprays head (2-5-3),
The distance sprayed between head (2-5-3) that borders on the river mutually is 5cm~20cm, and it is cone-shaped structure that described water sprays head (2-5-3),
Described water sprays the surface of head (2-5-3) and is thick with substantial amounts of micropore, a diameter of 5nm~100nm of micropore.
One the most according to claim 3 cage for building cleans dust arrester, it is characterised in that described dedusting ball (2-3-2)
By macromolecular material pressing mold molding, constituent and the manufacture process of dedusting ball (2-3-2) are as follows:
One, dedusting ball (2-3-2) constituent:
Count by weight, ethyl thloylyllate 55~105 parts, ethylene glycol monoethyl ether acetate (EGEEA) 18~33 parts,
2,3,4-trifluoronitrobenzenes 11~24 parts, 5-fluoro-2-nitro-trifluoromethyl toluene 20~85 parts, 4-acetylamino dimethyl phthalate
15~40 parts, o aminophenylacetic acid 50~120 parts, concentration is N-(the S-trityl mercaptoacetyl of 55ppm~115ppm
Base) alanyl glycylglycine 50~100 parts, mercaptoacetyl three glycyl-N-hydroxysuccinimide ester 20~95 parts,
N-(2-mercapto radical propionyl group)-glycine 60~150 parts, cross-linking agent 30~75 parts, methyl butenol 10~30 parts, 4-(2,6,6-
3-methyl cyclohexanol thiazolinyl-1-base)-3-butene-2-ol 40~120 parts, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-2-
Crotonaldehyde 25~55 parts, 4-(2,6,6 trimethyl-1-cyclohexene-1-base)-3-butene-2-ol acetas 10~30 parts;
Described cross-linking agent is any one in the only ether of diethylene glycol, polyacrylamide gel, polyacrylamide hydrophilic gel (PAHG);
Two, the manufacture process of dedusting ball (2-3-2), comprises the steps of
1st step: add ultra-pure water 200~700 parts that electrical conductivity is 0.3 μ S/cm~0.8 μ S/cm in a kettle., start reaction
Agitator in still, rotating speed is 85rpm~130rpm, starts heat pump, makes reactor temperature rise to 60 DEG C~75 DEG C;
Being sequentially added into ethyl thloylyllate, ethylene glycol monoethyl ether acetate (EGEEA), 2,3,4-trifluoronitrobenzenes, stirring is to completely
Dissolving, regulation pH value is 4.0~9.5, and agitator speed is adjusted to 140rpm~195rpm, and temperature is 65 DEG C~75 DEG C,
Esterification 5~10 hours;
2nd step: take 5-fluoro-2-nitro-trifluoromethyl toluene, 4-acetylamino dimethyl phthalate, powder diameter is 300~800 mesh;
Adding o aminophenylacetic acid mix homogeneously, be laid in pallet, tiling thickness is 20mm~50mm, and employing dosage is
4.0kGy~8.5kGy, energy are the alpha ray irradiation 50 of 7.0MeV~10MeV~80 minutes, and the β of Isodose
X ray irradiation x 30~55 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in N-(S-trityl mercaptoacetyl) alanyl glycylglycine,
Adding reactor, agitator speed is 60rpm~95rpm, and temperature is 70 DEG C~85 DEG C, starts vacuum pump and makes the true of reactor
Reciprocal of duty cycle reaches-0.10MPa~-0.35MPa, keeps this state response 6~20 hours;Pressure release is also passed through nitrogen, in making reactor
Pressure is 0.10~0.30MPa, and insulation stands 11~20 hours;Agitator speed is promoted to 100rpm~210rpm, simultaneously
Reactor pressure release is to 0MPa;Be sequentially added into mercaptoacetyl three glycyl-N-hydroxysuccinimide ester, N-(2-mercapto radical propionyl group)-
After glycine is completely dissolved, add cross-linking agent stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 6.5~9.5,
Insulation stands 5~9 hours;
4th step: when agitator speed is 140rpm~180rpm, is sequentially added into methyl butenol, 4-(2,6,6-3-methyl cyclohexanols
Thiazolinyl-1-base)-3-butene-2-ol, 2,3-dimethyl-4-(2,6,6-trimethyl-1-cyclohexene-1-base)-crotonic aldehyde and 4-(2,6,6 front threes
Base-1-cyclohexene-1-base)-3-butene-2-ol acetas, promote reactor pressure so that it is reach 0.55MPa~0.95MPa, temperature
Degree is 160 DEG C~190 DEG C, polyreaction 6~15 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to
25 DEG C~45 DEG C, discharging, enter molding press and can be prepared by dedusting ball (2-3-2).
6. a cage for building cleans the minimizing technology of dust arrester, it is characterised in that the method includes following step:
1st step: control system (10) starts the electromagnetic valve in dusty gas import (1) and inputted by dusty gas in dirt pocket (2),
Gas takes the lead in rising in " S " type dedusting plate (2-3) layer in dirt pocket (2), and the dust in gas is by dedusting ball (2-3-
2) absorption, now control system (10) startup is sent water system (4), is drenched system (2-5) to " S " type dedusting plate by water
(2-3) supplying water in layer, clear water flows downward with " S " type dedusting plate (2-3) surface, at " S " type dedusting plate (2-3) table
Face forms water membrane, and moisture film stops the rising of dust in gas and rinsed well by the dust of upper for dedusting ball (2-3-2) absorption,
Sewage after flushing is in effluent outfall (6) discharges into cesspool (7), and now control system (10) starts air exhauster (2-
7) clean gas after being processed by " S " type dedusting plate (2-3) is drawn up, and water-stop sheet (2-6) blocks the rising of current,
Clean gas discharges dirt pocket (2) finally by clean gas outlet (3);
2nd step: meanwhile, the absorption degradation ability of dust suspension monitored by dust degradation capability detector (2-8) in real time,
When the absorption degradation ability of dust suspension is less than 35%~45%, dust degradation capability detector (2-8) is to control system
(10) sending feedback signal, prompting staff changes " S " type dedusting plate (2-3);
3rd step: the air-borne dust concentration detector (8) that position dirt pocket (2) is outside, carries out reality to the dust suspension content in air
Time safety monitoring, setting air dust concentration detector (8) is when gas suspension dust content concentration is more than 30mg/m3~
120mg/m3Time, air-borne dust concentration detector (8) sends signal to control system (10), and control system (10) will open
Electromagnetic valve in dynamic dusty gas import (1), the electromagnetic valve in clean gas outlet (3), send the water pump in water system (4),
Water flow meter, electromagnetic valve, the electromagnetic valve on effluent outfall (6), air exhauster (2-7) so that whole system starts work
Make.
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CN110026035A (en) * | 2019-04-30 | 2019-07-19 | 江苏同庆安全科技有限公司 | A kind of wet process polishing dust remover and its treatment process with explosion prevention function |
CN114484695A (en) * | 2022-01-21 | 2022-05-13 | 杭州人安检测科技有限公司 | Chemical plant dust detection equipment |
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