CN105820722A - Novel waterproof anti-wear coating and preparation method thereof - Google Patents

Novel waterproof anti-wear coating and preparation method thereof Download PDF

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Publication number
CN105820722A
CN105820722A CN201610286735.4A CN201610286735A CN105820722A CN 105820722 A CN105820722 A CN 105820722A CN 201610286735 A CN201610286735 A CN 201610286735A CN 105820722 A CN105820722 A CN 105820722A
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CN
China
Prior art keywords
parts
poly
resistant paint
fiberglass
granule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610286735.4A
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Chinese (zh)
Inventor
汪德发
汤新明
翟建
赵文定
余芳有
孙成芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant
Original Assignee
Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant filed Critical Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant
Priority to CN201610286735.4A priority Critical patent/CN105820722A/en
Publication of CN105820722A publication Critical patent/CN105820722A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides novel waterproof anti-wear coating and a preparation method thereof. The coating is prepared from, by weight, 11-19 parts of polyimide, 7-14 parts of polymethyl urea resin, 19-27 parts of polyethylene glycol terephthalate, 8-14 parts of chlorosulfonated polyethylene, 10-18 parts of glass fiber reinforced plastic particles, 13-19 parts of modified styrene tar, 7-11 parts of silicon carbide and 2-4 parts of curing agent. A more simplified method is adopted in the preparation method, waterproof performance and anti-wear strength are further improved, industrialized producing and processing are convenient, and application and popularization can be further conducted.

Description

A kind of new waterproof wear-resistant paint and preparation method thereof
Technical field
The present invention relates to coating manufacture field, be specifically related to a kind of new waterproof wear-resistant paint and Preparation method.
Background technology
Along with the most social development, people also get over for the requirement of the living standard of self Come the highest, and the most scientific and technical development, the application of high-abrasive material is the most increasingly paid attention to, special Do not relate to some artificial satellites, spacecraft, bullet train, suffered high velocity air, Mechanical friction impact is relatively big, is vulnerable to effect of attrition, reduces the service life of material, material list Face needs painting to add one layer of high-abrasive material.
But for the most of wear-resistant paint occurred currently on the market, all can not effectively make Get a promotion in water resistance and wear-resisting intensity so that carrying out wearability lifting the most simultaneously Meanwhile, reduce the lifting of water resistance, cause causing while reality is applied one fixing Ring, it is impossible to be further generalized and apply.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of new waterproof wear-resistant paint and Preparation method so that water resistance and the anti-wear performance of coating promote further.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 11-19 part, Poly-MU resin 7-14 part, polyethylene terephthalate 19-27 part, the poly-second of chlorosulfonation Alkene 8-14 part, fiberglass granule 10-18 part, modified phenylethylene tar 13-19 part, carborundum 7-11 part, firming agent 2-4 part.
Preferably, the components by weight percent of raw material is: polyimides 12-17 part, poly-MU resin 9-14 part, polyethylene terephthalate 21-23 part, chlorosulfonated polyethylene 9-14 part, glass Glass steel particles 13-17 part, modified phenylethylene tar 16-19 part, carborundum 8-10 part, solidification Agent 3-4 part.
Preferably, the components by weight percent of raw material is: polyimides 13 parts, poly-MU resin 12 Part, polyethylene terephthalate 22 parts, chlorosulfonated polyethylene 11 parts, fiberglass granule 13 parts, 17 parts of modified phenylethylene tar, carborundum 9 parts, 3 parts of firming agent.
Preferably, described firming agent is by epoxide addition polyamines, aliphatic cyclic amine, the weight of aromatic amine Amount part is combined in 4:3:3 ratio.
The preparation method of described new waterproof wear-resistant paint, operating procedure is as follows:
1) by poly-for raw material MU resin, polyethylene terephthalate, chlorosulfonated polyethylene, Fiberglass granule, modified phenylethylene tar stir mixing by weight, control reaction temperature and are 20-30 DEG C, the response time is 60-70min;
2) in step 1) operation on the basis of, chilling temperature is to 5-10 DEG C, then to reactant liquor Middle continuation adds polyimides, fiberglass granule, carborundum, firming agent stirring, raises reaction Temperature is 35-43 DEG C, and the response time controls as 50-90min, and controls stir speed (S.S.) and be 100-200r/min, reaction terminates to room temperature, to obtain final product.
Preferably, described step 1) middle control stir speed (S.S.) 200-300r/min.
The invention provides a kind of new waterproof wear-resistant paint and preparation method thereof, by raw material The fiberglass granule of interpolation, carborundum, it is possible to effectively strengthen the roughness of coating surface, and become This is relatively low, can carry out further genralrlization application, and high containing heteroaromatic in the molecule of polyimides Molecular compound, heat stability is high, and tension force and plasticity are strong, and water resistance is good.And preparation The preparation technology that method is the most traditional, more simplifies, and does not destroys the composition of its component so that property Can be more, it is simple to industrialized production and processing, further genralrlization application can be carried out.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot Close embodiments of the invention, the technical scheme in the embodiment of the present invention is carried out clearly and completely Describe.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 13 parts, poly- MU resin 12 parts, polyethylene terephthalate 22 parts, chlorosulfonated polyethylene 11 parts, Fiberglass granule 13 parts, 17 parts of modified phenylethylene tar, carborundum 9 parts, 3 parts of firming agent.
Embodiment 2:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 11 parts, poly- MU resin 7 parts, polyethylene terephthalate 19 parts, chlorosulfonated polyethylene 13 parts, Fiberglass granule 18 parts, 19 parts of modified phenylethylene tar, carborundum 11 parts, 2 parts of firming agent.
Embodiment 3:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 12 parts, poly- MU resin 9 parts, polyethylene terephthalate 21 parts, chlorosulfonated polyethylene 14 parts, Fiberglass granule 17 parts, 16 parts of modified phenylethylene tar, carborundum 7 parts, 4 parts of firming agent.
Embodiment 4:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 19 parts, poly- MU resin 14 parts, polyethylene terephthalate 23 parts, chlorosulfonated polyethylene 9 parts, Fiberglass granule 10 parts, 13 parts of modified phenylethylene tar, carborundum 10 parts, 2 parts of firming agent.
Embodiment 5:
A kind of new waterproof wear-resistant paint, the components by weight percent of raw material is: polyimides 17 parts, poly- MU resin 14 parts, polyethylene terephthalate 27 parts, chlorosulfonated polyethylene 8 parts, Fiberglass granule 10 parts, 13 parts of modified phenylethylene tar, carborundum 8 parts, 3 parts of firming agent.
The preparation method of new waterproof wear-resistant paint, operating procedure is as follows:
1) by poly-for raw material MU resin, polyethylene terephthalate, chlorosulfonated polyethylene, Fiberglass granule, modified phenylethylene tar stir mixing by weight, control reaction temperature and are 20-30 DEG C, the response time is 60-70min;
2) in step 1) operation on the basis of, chilling temperature is to 5-10 DEG C, then to reactant liquor Middle continuation adds polyimides, fiberglass granule, carborundum, firming agent stirring, raises reaction Temperature is 35-43 DEG C, and the response time controls as 50-90min, and controls stir speed (S.S.) and be 100-200r/min, reaction terminates to room temperature, to obtain final product.
Step 1) middle control stir speed (S.S.) 200-300r/min.
Above example only in order to technical scheme to be described, is not intended to limit;Although With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art It is understood that the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent;And these amendments or replacement, not The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a new waterproof wear-resistant paint, it is characterised in that the components by weight percent of raw material is: poly- Acid imide 11-19 part, poly-MU resin 7-14 part, polyethylene terephthalate 19-27 Part, chlorosulfonated polyethylene 8-14 part, fiberglass granule 10-18 part, modified phenylethylene tar 13-19 Part, carborundum 7-11 part, firming agent 2-4 part.
2. new waterproof wear-resistant paint as claimed in claim 1, it is characterised in that raw material Components by weight percent is: polyimides 12-17 part, poly-MU resin 9-14 part, poly-terephthaldehyde Acid glycol ester 21-23 part, chlorosulfonated polyethylene 9-14 part, fiberglass granule 13-17 part, Modified phenylethylene tar 16-19 part, carborundum 8-10 part, firming agent 3-4 part.
3. new waterproof wear-resistant paint as claimed in claim 2, it is characterised in that raw material Components by weight percent is: polyimides 13 parts, poly-MU resin 12 parts, poly terephthalic acid second Diol ester 22 parts, chlorosulfonated polyethylene 11 parts, fiberglass granule 13 parts, modified phenylethylene are burnt Oil 17 parts, carborundum 9 parts, 3 parts of firming agent.
4. new waterproof wear-resistant paint as claimed in claim 1, it is characterised in that described Firming agent by epoxide addition polyamines, aliphatic cyclic amine, aromatic amine weight portion in 4:3:3 ratio group Close.
5. the preparation side of the new waterproof wear-resistant paint as described in claim 1-4 any of which item Method, it is characterised in that operating procedure is as follows:
1) by poly-for raw material MU resin, polyethylene terephthalate, chlorosulfonated polyethylene, Fiberglass granule, modified phenylethylene tar stir mixing by weight, control reaction temperature and are 20-30 DEG C, the response time is 60-70min;
2) in step 1) operation on the basis of, chilling temperature is to 5-10 DEG C, then to reactant liquor Middle continuation adds polyimides, fiberglass granule, carborundum, firming agent stirring, raises reaction Temperature is 35-43 DEG C, and the response time controls as 50-90min, and controls stir speed (S.S.) and be 100-200r/min, reaction terminates to room temperature, to obtain final product.
6. the preparation method of new waterproof wear-resistant paint as claimed in claim 5, its feature exists In, described step 1) middle control stir speed (S.S.) 200-300r/min.
CN201610286735.4A 2016-04-28 2016-04-28 Novel waterproof anti-wear coating and preparation method thereof Pending CN105820722A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610286735.4A CN105820722A (en) 2016-04-28 2016-04-28 Novel waterproof anti-wear coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610286735.4A CN105820722A (en) 2016-04-28 2016-04-28 Novel waterproof anti-wear coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105820722A true CN105820722A (en) 2016-08-03

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Application Number Title Priority Date Filing Date
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602129A (en) * 2013-11-16 2014-02-26 王爽 Wear-resistant coating
CN103992667A (en) * 2014-05-16 2014-08-20 吴江市英力达塑料包装有限公司 Environment-friendly paint and preparation method thereof
CN104059337A (en) * 2014-06-26 2014-09-24 青岛博洋生物技术有限公司 Environment-friendly type waterproof material and preparation method thereof
CN105199600A (en) * 2015-10-23 2015-12-30 山东华特知新化工有限公司 Non-cured rubber asphalt waterproof coating as well as preparation method and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602129A (en) * 2013-11-16 2014-02-26 王爽 Wear-resistant coating
CN103992667A (en) * 2014-05-16 2014-08-20 吴江市英力达塑料包装有限公司 Environment-friendly paint and preparation method thereof
CN104059337A (en) * 2014-06-26 2014-09-24 青岛博洋生物技术有限公司 Environment-friendly type waterproof material and preparation method thereof
CN105199600A (en) * 2015-10-23 2015-12-30 山东华特知新化工有限公司 Non-cured rubber asphalt waterproof coating as well as preparation method and application thereof

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Application publication date: 20160803

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