CN105820399A - Wood and rubber composite floor used for train and preparing method thereof - Google Patents
Wood and rubber composite floor used for train and preparing method thereof Download PDFInfo
- Publication number
- CN105820399A CN105820399A CN201610297708.7A CN201610297708A CN105820399A CN 105820399 A CN105820399 A CN 105820399A CN 201610297708 A CN201610297708 A CN 201610297708A CN 105820399 A CN105820399 A CN 105820399A
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- parts
- wood
- wood shavings
- train
- timber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a wood and rubber composite floor used for a train. The wood and rubber composite floor is prepared from, by weight, 10-11 parts of an isocyanate tackiness agent, 0.5-0.6 part of acetone, 35-38 parts of wood shavings, 62-66 parts of waste rubber particles, 5-6 parts of lithium perchlorate, 4-5 parts of nano polytetrafluoroethylene, 5-6 parts of trifluoroethyl acrylate, 6-7 parts of dodecafluoroheptyl methacrylate, 60-70 parts of ethyl acetate, 0.4-0.5 part of dicumyl peroxide, 90-100 parts of 9-10% salpeter solution, 90-100 parts of a urea saturated solution, 0.7-0.9 part of hexafluoroacetylacetone, 1.1-1.3 parts of nano magnesium hydrate, 0.3-0.4 part of methyltin mercaptide and 1.2-1.4 parts of glass powder. The tackiness agent is modified with hexafluoroacetylacetone, nano magnesium hydrate, methyltin mercaptide and glass powder, and the prepared floor is resistant to skidding and moisture and excellent in mechanical property, flame retardance and weather resistance.
Description
Technical field
The present invention relates to rubber floor covering technical field, particularly relate to a kind of train timber rubber laminated floor and preparation thereof
Method.
Background technology
Timber-rubber composite is the class functional material being the most just suggested, and has good preventing
The performance such as water, anticorrosion, mothproof, antistatic, sound insulating and absorbing, damping shock absorption, heat-insulation and heat-preservation, can serve as interior decoration decoration material
Material, sound-insulation and sound-absorbing material, damping shock absorption material, heat-insulating heat-preserving material, comprehensively embody efficiently the utilizing of timber, junked tire
The pollution-free value recycled and improve the aspects such as forestry products added value, development prospect is boundless.But at present about timber-
The research of rubber composite, also in the starting stage, not yet forms industrialization product.In order to timber-rubber composite is entered
Row further investigation, by consulting substantial amounts of document, completes the design of its cork biomimetic features, with artificial forest wood, woodwork
Industrial wood waste and waste tyre particle are raw material, be prepared for timber-rubber composite and on affect its performance main because of
Son is studied;The quiet mechanism of timber-rubber composite is disclosed, to it quiet by the method for experimental modal analysis
Application in floor has carried out exploratory study.Flooring method and performance, economic benefit are analyzed, and to floor
Quiet performance test methods has done preliminary study.This research draws following main research conclusion: 1) at timber-rubber composite
Cork biomimetic features in, timber is equivalent to cork cell wall substance, plays support, filling effect, mainly provides physical mechanics
Performance, is the intensity unit in structure;Rubber is equivalent to the closed gas in cork lumen, plays the effect of spring-like,
It it is the vibration absorption unit in structure;Adhesive is equivalent to the suberin in cork cell wall to a certain extent, primarily serves structure list
Cementation between unit.2) affecting laws of timber-rubber composite performance is mainly had by preparation technology: wood/rubber mass
Amount comparison material property impact is the most notable.Along with the reduction of wood/rubber quality ratio, rubber grain consumption increases, the resistance to suction of material
Hydroexpansivity can strengthen, and internal bond strength reduces, and MOR and elastic modelling quantity reduce, and natural frequency declines, and damping ratio raises,
Strike note reduces, and strike note improved values increases.Timber form is notable to Effect of Materials.Flat wood shavings and fiber is used to obtain
Preferably physical and mechanical property, material prepared by c-type wood shavings have relatively low natural frequency and strike note, higher damping ratio and
Strike note improved values.Extremely significantly (2 h water sucting thickness are swollen on the impact of timber-rubber composite physical and mechanical property for resin added
Except swollen rate), the impact on vibration and acoustical behavior is the most notable.The density shadow to physical and mechanical property, vibration and acoustical behavior
Ring all highly significants.The target density of timber-rubber composite can obtain the most comprehensive in the range of 0.8 ~ 1.0 g/cm3
Performance.Wood/between rubber quality ratio and resin added, density and the reciprocal action between pressing time to physical and mechanical property, shake
Dynamic and acoustical behavior all has a significant impact.Therefore, when adjusting process parameter, reciprocal action should be taken into account.3) have good
The preferred process parameter of good damping noise reduction performance: timber form: c-type wood shavings;Waste tyre particle particle diameter: 2 ~ 3 mm;Wood/rubber
Mass ratio: 40/60;Resin added: 6%;Target density: 0.8 g/cm3;Pressing time: 4 min;Platen temperature: 140 DEG C.Use
The main performance of timber-rubber composite prepared by this optimization technique is as follows: density: 0.78 g/cm3;2 h water sucting thickness are swollen
Swollen rate: 3.12%;Internal bond strength: 1.1 MPa;MOR: 3.8 MPa;Elastic modelling quantity: 342 MPa;Natural frequency: 17.4
Hz;Damping ratio: 0.15;Strike note: 76.5 dB (A);Strike note improved values: 15.5 dB (A).4) timber-rubber composite
Quiet mechanism: the existence of a large amount of rubber grains so that timber-rubber composite has relatively low natural frequency and higher
Damping ratio.Under impact loading, owing to timber-rubber composite each order frequency spacing is less, easily produces resonance, make
The function obtaining the rubber grain damping energy-absorbing in material is not fully exerted, the shock-absorbing denoising function raising that material is overall;Meanwhile,
Higher damping ratio can accelerate the decay of vibration, and energy dissipates relatively big in transmittance process, reduces and dissipates with acoustic energy form
Energy, play damping noise reduction effect.5) use strike note and two parameter indexs of strike note improved values to floor quietness energy
It is evaluated, it is proposed that a kind of quiet performance test methods in floor free falling sphere impingement method, designs and made a set of phase
The test system answered.Experiment proves, the floor of different quiet performances can be made and quantitatively commenting accurately by free falling sphere impingement method
Valency, has that required test specimen is few, it is fast and convenient to test, result feature accurately.6) new with timber-rubber composite as base material
Type mute floor board (WRC mute floor board), is designed by different structures, it is possible to obtain good quiet performance and physical mechanics property
Energy.
But wood shavings easily absorb water, cause floor dilatancy, and wood shavings are different from the character of rubber, poor compatibility,
Adhesion strength is the highest, and durability is bad, is easily damaged, and soundproof effect is general.And other aspect performances on floor also need
To improve further, such as thermostability, environmental-protecting performance, antistatic behaviour, resilience, heat stability, anti-flammability, anti-radiation, tough
Property, tensile strength, dimensional stability, pollution resistance, Scratch Resistance.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of train timber rubber laminated floor and
Its preparation method.
The present invention is achieved by the following technical solutions:
A kind of train timber rubber laminated floor, is prepared by the raw materials in: isocyanate adhesive 10-11, third
Ketone 0.5-0.6, wood wool 35-38, waste and old rubber particle 62-66, lithium perchlorate 5-6, nanometer polytetrafluoroethylcomposite 4-5, acrylic acid
Trifluoro ethyl ester 5-6, dodecafluoroheptyl methacrylate 6-7, ethyl acetate 60-70, dicumyl peroxide 0.4-0.5,9-10% nitre
Acid solution 90-100, urea saturated solution 90-100, hexafluoroacetylacetone 0.7-0.9, nano-sized magnesium hydroxide 1.1-1.3, mercaptan
Methyl stannum 0.3-0.4, glass dust 1.2-1.4.
The preparation method of described train timber rubber laminated floor, comprises the following steps:
(1) wood wool is pulverized, dry to over dry, put in 9-10% salpeter solution, process 20-23 minute at 96-100 DEG C, mistake
Filter, then soak 60-70 minute with urea saturated solution, filter, be dried, obtain swelling wood shavings;
(2) by nanometer polytetrafluoroethylcomposite, acrylic acid trifluoro ethyl ester, lithium perchlorate, dodecafluoroheptyl methacrylate, ethyl acetate
Mixing, is heated to 60-70 DEG C, adds swelling wood shavings, adds dicumyl peroxide, stirring reaction 30-40 minute, is dried and goes
Except ethyl acetate, obtain modified wood shavings;
(3) isocyanate adhesive is mixed homogeneously with acetone, add hexafluoroacetylacetone, nano-sized magnesium hydroxide, mercaptan first
Ji Xi, glass dust mix homogeneously, obtain modified adhesive;
(4) modification wood shavings, modified adhesive are mixed homogeneously with other surplus stocks, carry out plate blank paving, then at 1.0-
Carrying out precompressed 30-40s under 1.2MPa, then 140-150 DEG C, hot pressing molding in 8-9 minute under 3.5-3.8MPa, room temperature is placed
24-26 hour, then carry out sanding, to obtain final product.
The invention have the advantage that wood shavings are carried out by the present invention swelling rear dry, obtain the structure of porosity and looseness, re-use and receive
Rice politef, acrylic acid trifluoro ethyl ester, dodecafluoroheptyl methacrylate are modified, in the inside of wood shavings and surface shape
Become water-fast organic layer, improve toughness and the compatibility with adhesive, improve adhesion strength, improve wood shavings simultaneously
Toughness, more preferably, sound-absorbing effect is more preferable, and durability is more preferable for the elasticity of the rubber composite obtained;Also use perchloric acid simultaneously
Lithium, improves the electric conductivity of wood shavings, and then improves the antistatic property on floor.By using hexafluoroacetylacetone, nanometer hydrogen
Adhesive is modified by magnesium oxide, thiol methyl tin, glass dust, improves the thermostability of adhesive, anti-flammability and wearability,
The floor, anti-skidding, moistureproof prepared, and there is the mechanical property of excellence, fire resistance, weather resistance, it is adaptable to train floor
Lay.
Detailed description of the invention
A kind of train timber rubber laminated floor, is made up of the raw material of following weight portion (kilogram): isocyanates is gluing
Agent 10, acetone 0.5, wood wool 35, waste and old rubber particle 62, lithium perchlorate 5, nanometer polytetrafluoroethylcomposite 4, acrylic acid trifluoro ethyl ester
5, dodecafluoroheptyl methacrylate 6, ethyl acetate 60, dicumyl peroxide 0.4,9% salpeter solution 90, urea saturated solution
90, hexafluoroacetylacetone 0.7, nano-sized magnesium hydroxide 1.1, thiol methyl tin 0.3, glass dust 1.2.
The preparation method of described train timber rubber laminated floor, comprises the following steps:
(1) wood wool is pulverized, dry to over dry, put in 9% salpeter solution, process 20 minutes at 96 DEG C, filter, then with urinating
Element saturated solution soaks 60 minutes, filters, and is dried, obtains swelling wood shavings;
(2) by nanometer polytetrafluoroethylcomposite, acrylic acid trifluoro ethyl ester, lithium perchlorate, dodecafluoroheptyl methacrylate, ethyl acetate
Mixing, is heated to 60 DEG C, adds swelling wood shavings, adds dicumyl peroxide, stirring reaction 30 minutes, is dried and removes acetic acid
Ethyl ester, obtains modified wood shavings;
(3) isocyanate adhesive is mixed homogeneously with acetone, add hexafluoroacetylacetone, nano-sized magnesium hydroxide, mercaptan first
Ji Xi, glass dust mix homogeneously, obtain modified adhesive;
(4) modification wood shavings, modified adhesive are mixed homogeneously with other surplus stocks, carry out plate blank paving, then at 1.0MPa
Under carry out precompressed 30s, then 140 DEG C, hot pressing molding in 8 minutes under 3.5MPa, room temperature is placed 24 hours, then is carried out sanding, i.e.
?.
The density on this embodiment floor is 0.84g/cm3, 2h thickness swelling rate is 1.9%, and MOR is
3.7MPa, interior bonding strength is 1.86MPa, and elastic modelling quantity is 415MPa, and strike note is 67.2dB (A), and strike note sound insulation improves
Value is 18.9dB (A).
Claims (2)
1. a train timber rubber laminated floor, it is characterised in that: it is prepared by the raw materials in: isocyanate glue
Stick 10-11, acetone 0.5-0.6, wood wool 35-38, waste and old rubber particle 62-66, lithium perchlorate 5-6, nanometer polytetrafluoroethyl-ne
Alkene 4-5, acrylic acid trifluoro ethyl ester 5-6, dodecafluoroheptyl methacrylate 6-7, ethyl acetate 60-70, dicumyl peroxide
0.4-0.5,9-10% salpeter solution 90-100, urea saturated solution 90-100, hexafluoroacetylacetone 0.7-0.9, nanometer hydroxide
Magnesium 1.1-1.3, thiol methyl tin 0.3-0.4, glass dust 1.2-1.4.
The preparation method of train timber rubber laminated floor the most according to claim 1, it is characterised in that include following step
Rapid:
(1) wood wool is pulverized, dry to over dry, put in 9-10% salpeter solution, process 20-23 minute at 96-100 DEG C, mistake
Filter, then soak 60-70 minute with urea saturated solution, filter, be dried, obtain swelling wood shavings;
(2) by nanometer polytetrafluoroethylcomposite, acrylic acid trifluoro ethyl ester, lithium perchlorate, dodecafluoroheptyl methacrylate, ethyl acetate
Mixing, is heated to 60-70 DEG C, adds swelling wood shavings, adds dicumyl peroxide, stirring reaction 30-40 minute, is dried and goes
Except ethyl acetate, obtain modified wood shavings;
(3) isocyanate adhesive is mixed homogeneously with acetone, add hexafluoroacetylacetone, nano-sized magnesium hydroxide, mercaptan first
Ji Xi, glass dust mix homogeneously, obtain modified adhesive;
(4) modification wood shavings, modified adhesive are mixed homogeneously with other surplus stocks, carry out plate blank paving, then at 1.0-
Carrying out precompressed 30-40s under 1.2MPa, then 140-150 DEG C, hot pressing molding in 8-9 minute under 3.5-3.8MPa, room temperature is placed
24-26 hour, then carry out sanding, to obtain final product.
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CN201610297708.7A CN105820399A (en) | 2016-05-06 | 2016-05-06 | Wood and rubber composite floor used for train and preparing method thereof |
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CN201610297708.7A CN105820399A (en) | 2016-05-06 | 2016-05-06 | Wood and rubber composite floor used for train and preparing method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106182319A (en) * | 2016-07-15 | 2016-12-07 | 志邦厨柜股份有限公司 | A kind of easily processing graphite nanometer aluminium powder electromagnetic shielding medium density fibre board (MDF) and preparation method thereof |
CN107540904A (en) * | 2017-08-07 | 2018-01-05 | 安徽温禾新材料科技股份有限公司 | A kind of modified rubber powder Wood composite material for mute floor board and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
CN103173028A (en) * | 2013-03-22 | 2013-06-26 | 武汉天佑橡胶制品有限公司 | Wood powder and rubber composite material capable of replacing wood |
-
2016
- 2016-05-06 CN CN201610297708.7A patent/CN105820399A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
CN103173028A (en) * | 2013-03-22 | 2013-06-26 | 武汉天佑橡胶制品有限公司 | Wood powder and rubber composite material capable of replacing wood |
Non-Patent Citations (1)
Title |
---|
孙伟圣: "木材-橡胶复合材料及其在静音地板中的应用研究", 《中国博士学位论文全文数据库工程科技I辑(月刊)》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106182319A (en) * | 2016-07-15 | 2016-12-07 | 志邦厨柜股份有限公司 | A kind of easily processing graphite nanometer aluminium powder electromagnetic shielding medium density fibre board (MDF) and preparation method thereof |
CN107540904A (en) * | 2017-08-07 | 2018-01-05 | 安徽温禾新材料科技股份有限公司 | A kind of modified rubber powder Wood composite material for mute floor board and preparation method thereof |
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Application publication date: 20160803 |
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