CN105819894A - Aqueous permeable concrete sealing and curing agent - Google Patents

Aqueous permeable concrete sealing and curing agent Download PDF

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Publication number
CN105819894A
CN105819894A CN201610146149.XA CN201610146149A CN105819894A CN 105819894 A CN105819894 A CN 105819894A CN 201610146149 A CN201610146149 A CN 201610146149A CN 105819894 A CN105819894 A CN 105819894A
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CN
China
Prior art keywords
concrete
agent
curing agent
silicate
percentage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610146149.XA
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Chinese (zh)
Inventor
沈玲
易文静
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Deligu Material Co Ltd
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Wuhan Deligu Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Deligu Material Co Ltd filed Critical Wuhan Deligu Material Co Ltd
Priority to CN201610146149.XA priority Critical patent/CN105819894A/en
Publication of CN105819894A publication Critical patent/CN105819894A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5024Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • C04B41/68Silicic acid; Silicates

Abstract

An aqueous permeable concrete sealing and curing agent is composed of the following components in percentage by weight: 75 to 95 wt% of silicate, 0.1 to 1.5 wt% of penetrating agent, 0.1 to 1.0 wt% of promoter, 0.1 to 2.5 wt% of waterproof agent, and the balance being water. The aqueous permeable concrete sealing and curing agent can be diluted by water according to the situation of concrete base material; diluted agent can be sprayed or painted on the surface of concrete structure, the active components can penetrate to a depth of 2 to 8 millimeters in concrete under the effect of promoter; the active components can react with calcium hydroxide crystals in concrete to generate calcium hydroxide hydrate gel, which can fill and enclose the pores in concrete, thus the strength and wear resistant performance of concrete pavement are largely improved, the phenomenon of ash generation and sand generation is avoided, and the anti-permeability and stain resistant properties of pavement are prominently improved.

Description

A kind of aqueous infiltrating type concrete dense curing agent
Technical field
The present invention relates to building material technical field, a kind of aqueous infiltrating type concrete dense curing agent.
Background technology
Concrete, as a kind of widely used construction material, plays great function in modern construction engineering.But, Normal concrete is rolled over due to intrinsic deficiency, the bad or chemical attacks of constructing, fork truck in-service as earth material Pressure etc., cause whole ground produce Coarse Aggregate scatter and disappear, pit-hole, peeling or the phenomenon such as loose.For avoiding these phenomenons to occur, generally Pour the materials such as epoxy resin at concrete surface, the most both added construction cost, also improve later maintenance expense.
Occur in that concrete curing agent reaches with the density and case hardness improving xoncrete structure in recent years on market To improving concrete floor effect.At present, concrete dense curing agent mainly has two classes: a class is using resin as main component Organic polymer class, another kind of is the mineral-type with silicate as main component.Wherein mineral-type can be easily made water-based material, Without volatile organic matter, the impact on environment is little, and can receive much concern with hydrolysis product of cement chemically reactive.
Existing mattess intensity and wearability is the highest, rise ash dusting problem generally exist, developing can be effective Improve mattess abrasion resistance, avoid it to play ash dusting, improve the curing sealing agent of its impervious resistance to soiling, there is important valency Value and meaning.
Summary of the invention
It is an object of the invention to the defect for prior art, it is provided that one can be suitably used for poor mattess, can make Obtain high intensity, the aqueous infiltrating type concrete dense curing agent of high abrasion mattess.
A kind of aqueous infiltrating type concrete dense curing agent, the percentage by weight of its each component is as follows:
Further, aqueous infiltrating type concrete dense curing agent, the percentage by weight of its each component is as follows:
Described silicate is one or more in sodium silicate, potassium silicate and Lithium metasilicate.
Described penetrating agent be the one in dodecyl sodium sulfate, alkylphenol polyoxyethylene or fluorocarbon surfactant or Several.
Described accelerator is in lignosulfonates, naphthalene sulfonate, melamine, polycarboxylate, villaumite, sulfate, organic amine One or more.
Described waterproofing agent is in octyltri-ethoxysilane, octyltri-ethoxysilane aqueous emulsion, methyl silicate Plant or several.
The advantage of aqueous infiltrating type concrete dense curing agent of the present invention is: can be watered according to concrete substrate situation and make With, spraying or be brushed to concrete structural surface, active component therein penetrates into inside concrete by the effect of accelerator 2-8 millimeters deep, and react formation afwillite (C-S-H) gel with the calcium hydroxide crystals in concrete, thus fill out Fill and closed concrete pore, the intensity of mattess, abrasion resistance are significantly increased, it is to avoid ash dusting is played on ground, and It is obviously improved the impervious resistance to soiling on ground.
Detailed description of the invention
Elaborating embodiments of the invention below, the present embodiment carries out reality premised on technical solution of the present invention Execute.
Present pre-ferred embodiments discloses a kind of aqueous infiltrating type concrete dense curing agent, this concrete sealing and curing Agent includes the silicate of 75-95wt%, 0.1-1.5wt% penetrating agent, 0.1-1.0wt% accelerator, 0.1-2.5wt% waterproofing agent And the water of surplus.
Described silicate can select one or more to mix from sodium silicate, potassium silicate and Lithium metasilicate.Wherein, resultant effect And economic aspect considers, sodium silicate and potassium silicate the raising mattess that surface is rougher, dusting is more serious intensity and Wearability aspect has advantage, and Lithium metasilicate price is higher, considers according to consumption, is more suitable for basis preferably mattess.Should It is 75%-95%, preferably 85-90wt% that silicate content accounts for percentage by weight.
Described penetrating agent promotes concrete dense curing agent to permeate to inside concrete.Penetrating agent is dissolved in firming agent, makes Effective ingredient stably dispersing in firming agent, promotes that the liquid film formed permeates in concrete, accelerates and calcium hydroxide, aluminate hydrates The reaction of calcium etc., forms gel hard, that cohesive is good, and fully blocking concrete pore, makes concrete surface layer be solidified into one Individual dustless, fine and close entirety.This penetrating agent can be dodecyl sodium sulfate, alkylphenol polyoxyethylene or fluorocarbon surfactant In one or more be combined.By the stably dispersing effect of penetrating agent, active ion such as silicic acid contained in aqueous hardening dose Unreacted free ion such as calcium ion reacts generation calcium silicate hydrate to radical ion with concrete, makes in concrete free State ion participates in reaction, and intensity and the hardness of concrete are significantly increased.It is 0.1-that this penetrating agent content accounts for percentage by weight 1.5wt%, preferably 0.5-1.0wt%.
The hard water resistance property of described accelerator is preferable, can excite activity micro crystal in concrete, prevents activity micro crystal Between cohesion and conglomeration, make activity micro crystal fully dispersed, thus activity can give full play to, and accelerates calcium silicate hydrate gel Generation.Concrete active micro crystal includes the tricalcium aluminate in the materials such as slag, zeolite powder, flyash, silica flour, ferrum aluminic acid One or more of four calcium, aluminium oxide, entringite etc. are combined.Described accelerator can be lignosulfonates, naphthalene sulfonate, close One or more in amine, polycarboxylate, villaumite, sulfate, organic amine are combined.This accelerator content accounts for percentage by weight 0.1-1.0wt%, preferably 0.5-0.8wt%.
Described waterproofing agent has good penetrant crystalline, it is achieved " anti-capillary effect ", forms excellent water-repellent layer, shape Become thin polymer film to produce blocking effect, thus improve that concrete is dust-proof, water repellent ability, effectively inhibit water, oil and other The intrusion of corrosive substance.This waterproofing agent can be octyltri-ethoxysilane, octyltri-ethoxysilane aqueous emulsion, methane-siliconic acid One or more in salt are combined.It is 0.1-2.5wt%, preferably 0.5-1.5wt% that this waterproofing agent content accounts for percentage by weight.
The surplus of described aqueous infiltrating type concrete dense curing agent is water, and accounting for percentage by weight is 0-24.3wt%.
Embodiment one:
In aqueous infiltrating type concrete dense curing agent of the present invention, silicate is main component, and this silicate is sodium silicate, Accounting for percentage by weight is 90%;It is 0.5% that penetrating agent accounts for percentage by weight, and penetrating agent uses dodecyl sodium sulfate;Accelerator Accounting for percentage by weight is 0.5%, and accelerator uses class organic amine;Waterproofing agent accounts for percentage by weight 0.8%, and waterproofing agent uses octyl group Triethoxysilane aqueous emulsion;Water is surplus, accounts for percentage by weight 8.2%.
This aqueous curing sealing agent coats after be watered dilution at 1: 4, is soaked in concrete surface, after reaching 4 hours, removes Remaining material, dries, fine-grinding and polishing.After treatment, the abrasion resistance of mattess, impervious resistance to soiling, glossiness all have Increase substantially.
Table 1 is the performance parameter of the concrete through the coating of aqueous infiltrating type concrete dense curing agent.
The performance parameter of table 1 embodiment one
Embodiment two
In aqueous infiltrating type concrete dense curing agent of the present invention, silicate is main component, and this silicate is Lithium metasilicate, Accounting for percentage by weight is 85%;It is 0.5% that penetrating agent accounts for percentage by weight, and penetrating agent uses fluorocarbon surfactant;Accelerator Accounting for percentage by weight is 1.0%, and accelerator uses sulfate;Waterproofing agent accounts for percentage by weight 1.0%, and waterproofing agent uses methyl silicon Hydrochlorate;Water is surplus, accounts for percentage by weight 12.5%.
This aqueous curing sealing agent coats after be watered dilution at 1: 4, is soaked in concrete surface, after reaching 4 hours, removes Remaining material, dries, fine-grinding and polishing.After treatment, the abrasion resistance of mattess, impervious resistance to soiling, glossiness all have Increase substantially.
Table 2 is the performance parameter of the concrete through the coating of aqueous infiltrating type concrete dense curing agent.
The performance parameter of table 2 embodiment two
Aqueous infiltrating type concrete dense curing agent of the present invention is occurred by the composition in the most effectively infiltration and concrete Chemical reaction, makes each composition of concrete be solidified into a firm entity, and is filled with the pore of concrete, obtains a nothing The entirety that dirt is fine and close, thus improve the wearability of concrete, compactness and impermeability.This aqueous infiltrating type concrete sealing and curing Agent be a kind of nontoxic, do not fire, water-based material that penetration is strong, easy to use, sealing and curing is respond well, increases the strong of concrete Degree and wearability, increase the service life, and can resist the erosion of the chemical substance such as water and general acid, alkali, salt.Through this aqueous infiltrating Normal concrete ground after type concrete dense curing agent processes can form the ground that approximation marble is the same.

Claims (6)

1. an aqueous infiltrating type concrete dense curing agent, it is characterised in that the percentage by weight of its each component is as follows:
2. firming agent as claimed in claim 1, it is characterised in that the percentage by weight of its each component is as follows:
3. firming agent as claimed in claim 1 or 2, it is characterised in that: described silicate is sodium silicate, potassium silicate and Lithium metasilicate In one or more.
4. firming agent as claimed in claim 1 or 2, it is characterised in that: described penetrating agent is dodecyl sodium sulfate, alkyl phenol One or more in polyoxyethylene ether or fluorocarbon surfactant.
5. firming agent as claimed in claim 1 or 2, it is characterised in that: described accelerator is lignosulfonates, LOMAR PWA EINECS 246-676-2 One or more in salt, melamine, polycarboxylate, villaumite, sulfate, organic amine.
6. firming agent as claimed in claim 1 or 2, it is characterised in that: described waterproofing agent is octyltri-ethoxysilane, octyl group One or more in triethoxysilane aqueous emulsion, methyl silicate.
CN201610146149.XA 2016-03-12 2016-03-12 Aqueous permeable concrete sealing and curing agent Pending CN105819894A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610146149.XA CN105819894A (en) 2016-03-12 2016-03-12 Aqueous permeable concrete sealing and curing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610146149.XA CN105819894A (en) 2016-03-12 2016-03-12 Aqueous permeable concrete sealing and curing agent

Publications (1)

Publication Number Publication Date
CN105819894A true CN105819894A (en) 2016-08-03

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517874A (en) * 2016-11-02 2017-03-22 常州市鼎升环保科技有限公司 Preparation method of high-abrasion-resistance concrete seal solidification agent
CN106565278A (en) * 2016-11-04 2017-04-19 浙江省建筑科学设计研究院有限公司 High-permeability concrete sealed waterproofing agent and preparation method thereof
CN107915498A (en) * 2017-11-21 2018-04-17 重庆奥福精细陶瓷有限公司 A kind of low thermal expansion major diameter honeycomb ceramic carrier and preparation method thereof
CN108002800A (en) * 2017-12-22 2018-05-08 枞阳县三金颜料有限责任公司 A kind of nano-organosilicon waterproofing agent
CN108218321A (en) * 2018-02-01 2018-06-29 温州市东海建筑安装工程有限公司 Civil material curing agent and preparation method
CN108373341A (en) * 2018-02-10 2018-08-07 唐林元 A kind of preparation method of osmosis type bi-component concrete dense curing agent
CN109534852A (en) * 2018-12-29 2019-03-29 华砂砂浆有限责任公司 A kind of osmosis type liquid hardening agent and preparation method thereof
CN110066137A (en) * 2019-06-19 2019-07-30 林振喜 A kind of not inverse decomposition concrete curing agent and preparation method thereof
CN113072322A (en) * 2021-04-30 2021-07-06 北京固斯特国际化工有限公司 Concrete anti-permeability waterproof additive and application thereof
CN113912369A (en) * 2021-09-28 2022-01-11 德爱威(中国)有限公司 Ultrahigh wear-resistant sealing curing agent and preparation method thereof
CN113912375A (en) * 2021-11-22 2022-01-11 安徽大学绿色产业创新研究院 Compact ceramic coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503347A (en) * 2011-11-10 2012-06-20 上海三瑞化学有限公司 Lithium-based concrete sealing solidifying agent
CN102815885A (en) * 2011-06-08 2012-12-12 东莞市斯博锐高分子建筑材料科技有限公司 Improved liquid concrete seal curing agent
CN103755381A (en) * 2014-01-10 2014-04-30 陆天献 Nano color concrete sealing and curing agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102815885A (en) * 2011-06-08 2012-12-12 东莞市斯博锐高分子建筑材料科技有限公司 Improved liquid concrete seal curing agent
CN102503347A (en) * 2011-11-10 2012-06-20 上海三瑞化学有限公司 Lithium-based concrete sealing solidifying agent
CN103755381A (en) * 2014-01-10 2014-04-30 陆天献 Nano color concrete sealing and curing agent

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106517874A (en) * 2016-11-02 2017-03-22 常州市鼎升环保科技有限公司 Preparation method of high-abrasion-resistance concrete seal solidification agent
CN106565278A (en) * 2016-11-04 2017-04-19 浙江省建筑科学设计研究院有限公司 High-permeability concrete sealed waterproofing agent and preparation method thereof
CN107915498B (en) * 2017-11-21 2020-04-21 重庆奥福精细陶瓷有限公司 Low-thermal-expansion large-diameter honeycomb ceramic carrier and preparation method thereof
CN107915498A (en) * 2017-11-21 2018-04-17 重庆奥福精细陶瓷有限公司 A kind of low thermal expansion major diameter honeycomb ceramic carrier and preparation method thereof
CN108002800A (en) * 2017-12-22 2018-05-08 枞阳县三金颜料有限责任公司 A kind of nano-organosilicon waterproofing agent
CN108218321A (en) * 2018-02-01 2018-06-29 温州市东海建筑安装工程有限公司 Civil material curing agent and preparation method
CN108373341A (en) * 2018-02-10 2018-08-07 唐林元 A kind of preparation method of osmosis type bi-component concrete dense curing agent
CN109534852A (en) * 2018-12-29 2019-03-29 华砂砂浆有限责任公司 A kind of osmosis type liquid hardening agent and preparation method thereof
CN110066137A (en) * 2019-06-19 2019-07-30 林振喜 A kind of not inverse decomposition concrete curing agent and preparation method thereof
CN113072322A (en) * 2021-04-30 2021-07-06 北京固斯特国际化工有限公司 Concrete anti-permeability waterproof additive and application thereof
CN113912369A (en) * 2021-09-28 2022-01-11 德爱威(中国)有限公司 Ultrahigh wear-resistant sealing curing agent and preparation method thereof
CN113912369B (en) * 2021-09-28 2022-06-03 德爱威(中国)有限公司 Ultrahigh wear-resistant sealing curing agent and preparation method thereof
CN113912375A (en) * 2021-11-22 2022-01-11 安徽大学绿色产业创新研究院 Compact ceramic coating

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Application publication date: 20160803