CN105818322B - A kind of manufacturing process of electric toothbrush housings - Google Patents

A kind of manufacturing process of electric toothbrush housings Download PDF

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Publication number
CN105818322B
CN105818322B CN201610259314.2A CN201610259314A CN105818322B CN 105818322 B CN105818322 B CN 105818322B CN 201610259314 A CN201610259314 A CN 201610259314A CN 105818322 B CN105818322 B CN 105818322B
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layer
decorative article
transparent
parts
transparent decorative
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CN105818322A (en
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严佑春
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Guangdong Luoman Intelligent Technology Co Ltd
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Guangdong Luoman Intelligent Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/51One specific pretreatment, e.g. phosphatation, chromatation, in combination with one specific coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • B05D7/534Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/361Removing material for deburring or mechanical trimming
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08Oxides
    • C23C14/086Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/20Aqueous dispersion or solution
    • B05D2401/21Mixture of organic solvent and water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00Acrylic polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Brushes (AREA)

Abstract

The present invention relates to electric toothbrush manufacturing process, and in particular to a kind of manufacturing process of electric toothbrush housings includes the following steps: that (1) sprays: in the front of transparent decorative article or back side spraying shading light oil reservoir;(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving;(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article;(4) it is molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle;(5) assemble: by transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article is bonded with the transparent flexible glue layer.This technique realizes processing risk spreading, reduces the cost depletions that processing mistake causes, realizes recessive illumination effect, lighting effects homogeneous soft.

Description

A kind of manufacturing process of electric toothbrush housings
Technical field
The present invention relates to electric toothbrush manufacturing process, and in particular to a kind of manufacturing process of electric toothbrush housings.
Background technique
In the prior art, because electric toothbrush is there are many mode, for the convenience of the users, general electric toothbrush all can be in hand Indication panel is set on handle, and existing power toothbrush handle is traditionally arranged to be simple indicator light mode, directly in plastic handle On several holes are provided are put into LED lamp bead and fill transparency material, then in lamp hole subscript explanatory notes word, consumer is allowed to feel thick System is made excessively, does not appeal to refined taste, and it is dominant luminous (i.e. not luminous also to clearly see using text that there are also fraction electric toothbrushes Text) form, however the cooked mode of essentially integral type easily causes whole branch if process goes wrong or careless mistake Electronic brush is scrapped, dangerous.
Summary of the invention
The purpose of the present invention is being directed to above-mentioned deficiency in the prior art, a kind of processing risk spreading, recessive luminous is provided Electric toothbrush housings manufacturing process.
The purpose of the present invention is achieved through the following technical solutions:
A kind of manufacturing process of electric toothbrush housings, electric toothbrush housings are equipped with transparent decorative article, the manufacturing process packet Include following steps:
(1) it sprays: spraying shading light oil reservoir in the front of the transparent decorative article or the back side;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article;
(4) it is molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer fitting.
The manufacture of electric toothbrush housings is divided into two parts, first is that spray-laser carving-plating to transparent decorative article, two It is to be molded to power toothbrush handle, then the two is assembled together again, realize processing risk spreading, it is wrong reduces processing Misquote the cost depletions of hair;The shading for non-light display area domain is realized by spraying-laser carving, and laser laser carving portrays exquisiteness, convex The aesthetic feeling of aobvious electric toothbrush housings, and the metal layer or metal oxide layer being electroplated stop the entrance of ambient, realize hidden Property shine, the figure or text of laser carving only can be just seen clearly that when toothbrush handle light source luminescent, more can be consumer Bring pleasantly surprised, the transparent flexible glue layer of injection molding is conducive to the assembly of transparent decorative article, and the light that transparent flexible glue layer can issue light source It is scattered reduction, keeps lighting effects more evenly soft.
It wherein, further include that step S1 air brushing and/or step S2 spray gloss oil after the step (3),
The step S1 air brushing is partial region or whole region air brushing on the metal layer or metal oxide layer Text or pattern;
The step S2 spraying gloss oil is one layer of UV water-based gloss oil of front spraying in the transparent decorative article.Step S1 spray The figure translucidus drawn is extremely strong, has substantially no effect on the illumination effect of electric toothbrush housings, and increases the color of electric toothbrush housings Coloured silk sense;And shell feel can be enhanced in the UV water-based gloss oil of step S2 spraying, protects interior metal layer or metal oxide layer not Corroded, and electric toothbrush has the apparatus directly contacted as with body cavity, face, security requirement is high, and aqueous UV Gloss oil toxicity is minimum, can be with effective protection human health.
Wherein, the UV water-based gloss oil is made of the raw material of following parts by weight:
30-50 parts of prepolymer
30-90 parts of monomer
4-6 parts of photoinitiator
1-2 parts of damage resistant auxiliary agent
Organic-silicon-modified levelling agent 1-2 parts
1-2 parts of silane coupling agent
10-20 parts of solvent
Wherein, the prepolymer be aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer extremely Few one kind, the monomer are at least two of TPGDA, EOEOEA, PO3-TMPTA, PEGDA, and the photoinitiator is light-initiated At least two of agent 184,907,1173, the scratch resistance auxiliary agent are at least one of organic wax, polyethylene micropowder, the solvent The mixture mixed for water with ethyl alcohol with arbitrary proportion
UV water-based gloss oil of the invention has scratch resistance, and adhesive force is strong, minimum to human toxicity, is present invention process The preferred embodiment of the power toothbrush handle gloss oil prepared.This formula prepolymer determines the main character after gloss oil solidifies, The main function that monomer plays is the viscosity for adjusting this formula system, is adjusted to gloss oil property, and prepolymer and monomer need The adhesive force of this formula gloss oil could preferably be strengthened by carrying out certain limited proportion, while scratch resistance auxiliary agent is added and enhances light The scratch resistance of oil, the defects of preventing the sharp objects such as nail from leaving scratch under gloss oil.
Further, the prepolymer is oligomeric by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate Object is mixed by weight the ratio of 1-3:1, and the monomer is by TPGDA, PO3- TMPTA and PEGDA are by weight 2:3:1's Ratio mixes, and the weight ratio of the monomer and prepolymer is 1.5:1, the photoinitiator by photoinitiator 184,907, The ratio of 1173 1:1:1 by weight mixes, and the solvent is made of water and ethyl alcohol by weight the ratio mixing of 1:1.
Light oil reservoir after aqueous polyurethane acrylate oligomer solidifies with respect to waterborne epoxy acrylate oligomer has Better flexibility, wearability, water resistance, but the ability to cure of epoxy resin is stronger, in conjunction with the advantage and electric tooth of the two The demand of brush handle is 1-3:1 to the preferred mixed proportion that the selection of prepolymer is made, and more preferably ratio is 2:1; TPGDA and PO3- TMPTA contains propoxyl group, increases the flexibility of gloss oil after solidifying, PO3- TMPTA ability to cure is strong, and TPGDA pairs It is good in the adjustment effect of viscosity, and PEGDA has good hydrophily, by constantly testing adjustment, obtained TPGDA, PO3- TMPTA and PEGDA has the gloss oil of this formula more excellent by weight the preferred hybrid plan of the ratio mixing of 2:3:1 Different performance;And different photoinitiators has the absorption of different wave length strong and weak ultraviolet light, due to the output of ultraviolet lamp Energy is easy to be influenced by temperature, therefore photoinitiator 184,907,1173 mixes light by weight the ratio of 1:1:1 and draws Hair agent has good absorbability for the ultraviolet lamp of a certain range wavelength;And suitable ethyl alcohol is added in water to be promoted The dissolution of prepolymer and monomer etc., but ethyl alcohol addition is excessively difficult to control, the mixing of water and ethyl alcohol due to its volatility It is preferably in a proportion of 1:1.
Wherein, step (1) the shading light oil reservoir is black gloss oil, and the black gloss oil is sprayed on the transparent decorative article The back side.
Black light oil reservoir good shading effect, the back side for being sprayed on transparent decorative article are advantageous in that: subsequent laser carving step It is be easy to cause the uneven of spray-coating surface, if electricity consumption is plated on the rough back side, metal layer or metal oxide thickness Degree is easy unevenness, and shaded effect is inconsistent, and to make plating, uniformly then electroplating time needs to increase, and the metal layer of hollow part Or metal oxide layer thickness is excessive, the light that light source issues is difficult to penetrate, and be easy to cause and shows unclear phenomenon;Secondly, laser carving, It is electroplated and separates the linking that front and back sides operation is conducive to process, save the production time.
Wherein, the black gloss oil is made of the raw material of following parts by weight: 10-50 parts of black gloss oil stoste, diluent 100-150 parts, 2-10 parts of polyurethane levelling agent, 2-5 parts of silane coupling agent.Black gloss oil adhesive force after allotment is stronger, Shaded effect is more evenly.
Wherein, the laser carving speed of step (2) laser carving is 500-1500mm/s, and laser carving power is 10-60W.Laser carving speed Degree, which is higher than the easy engraving unevenness of 1500mm/s, causes light transmittance inconsistent, influences translucent effect, too lower than 500mm/s working efficiency It is low, it is not easy to produce;Laser carving power will affect depth, evenness, speed of engraving etc., and laser laser carving will lead to fever, consider The heat resistance of each material layer, laser carving power setting are preferred embodiment in 10-60W.
Wherein, the metal layer or metal oxide layer of the step (3) be tin layers, the tin layers with a thickness of 1-5 μm.Tin The brightness of layer is high, and metal-like is strong, and the thickness of tin layers is lower than 1 μm, and shaded effect is too poor, and thickness is higher than 5 μm, then cannot be effective Stop ambient, realizes that recessiveness shines, therefore the thickness control of tin layers is more appropriate at 1-5 μm.
Wherein, the evaporating temperature of step (3) plating is 1000-1500 DEG C, air pressure 0.01-0.03Pa.Evaporation temperature Degree, air pressure are the important parameter for controlling metal layer or metal oxide layer consistency, purity, deposition rate, adhesive force etc., evaporation Temperature is lower than 1000 DEG C, then deposits too slow, and coating effects are too poor, and temperature is higher than 1500 DEG C, then be lost can energy it is too many, increase at This;Air pressure is lower than 0.01Pa, then the equipment cost needed is excessively high, and air pressure is higher than 0.03Pa, then plated film is easy to be mixed into impurity or gold Category aoxidizes, and coating effects are poor.
Wherein, the flexible glue layer of the step (4) is rubber, silica gel, PU or PVC.The transparent decorative article is ABS, PC, AS And one of SAN.Flexible glue layer is preferable using colourless transparent material or milky trnaslucent materials, flexible glue layer and see-through look Gadget can use suitable material layer according to the mechanical performance of different materials.
Wherein, side of the transparent decorative article of the step (5) by 3M glue bond or with the clamping of electric toothbrush housings shell Formula is assemblied on the transparent flexible glue layer.3M glue bond is secured, high resilience, and snap fit replacement easy to disassemble, in conjunction with not The same market demand, can be selected more assembly modes.
Beneficial effects of the present invention: 1, risk spreading, two individual components of first separate machined reassemble together, serious forgiveness Height reduces production cost;2, the recessiveness for realizing product shines, and in order to which product brings feeling of freshness, attracts consumer, promotes electronic The application of toothbrush product;3, transparent decorative article can bring clean feeling rich in metal-like for consumer;4, method and step letter It is single, it is easy to accomplish, it can effectively push electric toothbrush housings manufacturing technology;5, it is kept on improving on gloss oil formula, for electric tooth The specific demand of brush handle is made with high-flexibility, scratch-resistant, new gloss oil formula;6, laser carving technology of the present invention and gloss oil The combination of innovation keeps the light of imaging solidifying without dissipating, and the pattern definition that laser carving carves out is high.
Specific embodiment
The invention will be further described with the following Examples.
Embodiment 1
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) spray: in the front spraying shading light oil reservoir of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 10 parts of black gloss oil stoste, 100 parts of diluent, polyurethane levelling agent 2 Part, 2 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 500mm/s, laser carving power are 10W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 1 μm, the evaporating temperature of plating is 1000 DEG C, air pressure 0.01Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are rubber Glue;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer passes through 3M glue bond.
Embodiment 2
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 50 parts of black gloss oil stoste, 150 parts of diluent, polyurethane levelling agent 10 parts, 5 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 1500mm/s, laser carving power are 60W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 5 μm, the evaporating temperature of plating is 1500 DEG C, air pressure 0.03Pa;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article.
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are silicon Glue;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer passes through 3M glue bond.
Embodiment 3
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 30 parts of black gloss oil stoste, 125 parts of diluent, polyurethane levelling agent 6 Part, 3.5 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 1000mm/s, laser carving power are 35W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 3 μm, the evaporating temperature of plating is 1250 DEG C, air pressure 0.02Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are PU;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer passes through 3M glue bond.
Wherein, the water-based UV gloss oil of the step (S2) is made of the raw material of following parts by weight:
40 parts of prepolymer
60 parts of monomer
5 parts of photoinitiator
1.5 parts of damage resistant auxiliary agent
1.5 parts of organic-silicon-modified levelling agent
1.5 parts of silane coupling agent
15 parts of solvent
The prepolymer by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer by weight The ratio of 2:1 mixes, and the monomer is by TPGDA, PO3- TMPTA and PEGDA by weight 2:3:1 ratio mixing and At ratio of the photoinitiator by photoinitiator 184,907,1173 by weight 1:1:1 mixes, and the scratch resistance helps Agent is organic wax, and the solvent is made of water and ethyl alcohol by weight the ratio mixing of 1:1.
Embodiment 4
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 20 parts of black gloss oil stoste, 120 parts of diluent, polyurethane levelling agent 4 Part, 3 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 800mm/s, laser carving power are 30W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 2 μm, the evaporating temperature of plating is 1100 DEG C, and air pressure is 0.015Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are PVC;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer passes through 3M glue bond.
Wherein, the water-based UV gloss oil of the step (S2) is made of the raw material of following parts by weight:
50 parts of prepolymer
50 parts of monomer
4 parts of photoinitiator
1 part of damage resistant auxiliary agent
1 part of organic-silicon-modified levelling agent
1 part of silane coupling agent
10 parts of solvent
Wherein, the prepolymer is aqueous polyurethane acrylate oligomer, and the monomer is by TPGDA, EOEOEA by weight The ratio than 3:1 to be measured to mix, ratio of the photoinitiator by photoinitiator 184,907 by weight 2:1 mixes, The scratch resistance auxiliary agent is polyethylene micropowder, and the solvent is water.
Embodiment 5
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 40 parts of black gloss oil stoste, 140 parts of diluent, polyurethane levelling agent 8 Part, 4 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 1400mm/s, laser carving power are 55W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 4 μm, the evaporating temperature of plating is 1400 DEG C, and air pressure is 0.025Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are rubber Glue;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer fitting, the transparent decorative article and electric toothbrush housings shell are clamped.
Wherein, the water-based UV gloss oil of the step (S2) is made of the raw material of following parts by weight:
30 parts of prepolymer
30 parts of monomer
6 parts of photoinitiator
2 parts of damage resistant auxiliary agent
2 parts of organic-silicon-modified levelling agent
2 parts of silane coupling agent
20 parts of solvent
Wherein, the prepolymer is waterborne epoxy acrylate oligomer, and the monomer is by PO3-TMPTA, PEGDA by weight The ratio than 1:2 of measuring mixes, the photoinitiator by photoinitiator 907,1173 by weight the ratio mixing of 1:2 and At, the scratch resistance auxiliary agent is mixed by organic wax, polyethylene micropowder by weight the ratio of 1:1, the solvent by water with Ethyl alcohol is mixed by weight the ratio of 7:3.
Embodiment 6
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil, institute It states black gloss oil to be made of the raw material of following parts by weight: 25 parts of black gloss oil stoste, 130 parts of diluent, polyurethane levelling agent 7 Part, 2.5 parts of silane coupling agent;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 850mm/s, laser carving power are 45W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 2.5 μm, the evaporating temperature of plating is 1300 DEG C, and air pressure is 0.02Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are silicon Glue;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer fitting, the transparent decorative article and electric toothbrush housings shell are clamped.
Wherein, the water-based UV gloss oil of the step (S2) is made of the raw material of following parts by weight:
40 parts of prepolymer
80 parts of monomer
4.5 parts of photoinitiator
1.8 parts of damage resistant auxiliary agent
1.2 parts of organic-silicon-modified levelling agent
1.6 parts of silane coupling agent
17 parts of solvent
Wherein, the prepolymer is by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer by weight The ratio than 1:1 of measuring mixes, the monomer by TPGDA, EOEOEA, PEGDA by weight the ratio mixing of 3:2:1 and At the photoinitiator is that photoinitiator 184,907,1173 is mixed by weight the ratio of 1:2:1, and the scratch resistance helps Agent is mixed by organic wax, polyethylene micropowder by weight the ratio of 4:6, and the solvent is by water and ethyl alcohol by weight 3:7 Ratio mix.
Embodiment 7
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 1350mm/s, laser carving power are 48W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 1-5 μm, the evaporating temperature of plating is 1150 DEG C, and air pressure is 0.01Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are PU;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer fitting, the transparent decorative article and electric toothbrush housings shell are clamped.
Wherein, the water-based UV gloss oil of the step (5) is made of the raw material of following parts by weight:
35 parts of prepolymer
75 parts of monomer
4.5 parts of photoinitiator
1.2 parts of damage resistant auxiliary agent
1.6 parts of organic-silicon-modified levelling agent
1.9 parts of silane coupling agent
18 parts of solvent
Wherein, the prepolymer is by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer by weight It measures the ratio than 3:1 to mix, the monomer is mixed by EOEOEA, PO3-TMPTA, PEGDA by weight the ratio of 2:2:1 It forms, the photoinitiator is that photoinitiator 184,1173 is mixed in the ratio of 4:1, and the scratch resistance auxiliary agent is organic Wax, the solvent are mixed by water and ethyl alcohol by weight the ratio of 6:5.
Embodiment 8
A kind of manufacturing process of electric toothbrush housings of the present embodiment, includes the following steps:
(1) it sprays: spraying shading light oil reservoir at the back side of transparent decorative article, the shading light oil reservoir is black gloss oil;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving, the laser carving speed of laser laser carving are 900mm/s, laser carving power are 30W;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article, metal layer Or metal oxide layer is tin layers, the tin layers with a thickness of 1-5 μm, the evaporating temperature of plating is 1330 DEG C, and air pressure is 0.03Pa;
(S1) air brushing: partial region or whole region air brushing text or figure on the metal layer or metal oxide layer Case;
(S2) gloss oil is sprayed: in one layer of UV water-based gloss oil of front spraying of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on the source region of power toothbrush handle, the transparent flexible glue layer are PVC;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with The transparent flexible glue layer fitting, the transparent decorative article and electric toothbrush housings shell are clamped.
Wherein, the water-based UV gloss oil of the step (5) is made of the raw material of following parts by weight:
45 parts of prepolymer
40 parts of monomer
5.8 parts of photoinitiator
1.7 parts of damage resistant auxiliary agent
1.3 parts of organic-silicon-modified levelling agent
1.4 parts of silane coupling agent
12 parts of solvent
Wherein, the prepolymer is by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer by weight It measures the ratio than 1:2 to mix, the monomer is by TPGDA, EOEOEA, PO3-TMPTA, PEGDA by weight 1:1:1:1's Ratio mixes, and ratio of the photoinitiator by photoinitiator 184,907,1173 by weight 1:2:1 mixes, institute It states scratch resistance auxiliary agent and is mixed by organic wax, polyethylene micropowder by weight the ratio of 2:3, the solvent is pressed by water and ethyl alcohol The ratio of weight ratio 8:3 mixes.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention Matter and range.

Claims (3)

1. a kind of manufacturing process of electric toothbrush housings, it is characterised in that: electric toothbrush housings are equipped with transparent decorative article, the system Technique is made to include the following steps:
(1) it sprays: spraying shading light oil reservoir in the front of the transparent decorative article or the back side;
(2) laser carving: shape needed for being gone out shading light oil reservoir hollow out using laser laser carving;
(3) it is electroplated: in one layer of metal layer of front vacuum plating or metal oxide layer of the transparent decorative article;
(4) be molded: the injection moulded clear flexible glue layer on power toothbrush handle shell, the electric toothbrush shell is interior to be equipped with for irradiating The light source of transparent flexible glue layer;
(5) assemble: by the transparent decorative article assembly on the transparent flexible glue layer, the back side of the transparent decorative article with it is described Transparent flexible glue layer fitting, is made the electric toothbrush housings;
Wherein, step (1) the shading light oil reservoir is black gloss oil, and the black gloss oil is sprayed on the back of the transparent decorative article Face, the black gloss oil are made of the raw material of following parts by weight: 10-50 parts of black gloss oil stoste, 100-150 parts of diluent, 2-10 parts of polyurethane levelling agent, 2-5 parts of silane coupling agent;
Wherein, the laser carving speed of step (2) laser carving is 500-1500mm/s, and laser carving power is 10-60W;
Wherein, the metal layer or metal oxide layer of the step (3) be tin layers, the tin layers with a thickness of 1-5 μm;
It further include that step S1 air brushing and step S2 spray gloss oil after the step (3),
The step S1 air brushing is partial region or whole region air brushing text on the metal layer or metal oxide layer Or pattern;
The step S2 spraying gloss oil is one layer of UV water-based gloss oil of front spraying in the transparent decorative article;
Wherein, the UV water-based gloss oil is made of the raw material of following parts by weight:
The prepolymer is by aqueous polyurethane acrylate oligomer and waterborne epoxy acrylate oligomer by weight 1-3:1 Ratio mix, the monomer is mixed by TPGDA, PO3-TMPTA and PEGDA by weight the ratio of 2:3:1, institute The weight ratio for stating monomer and prepolymer is 1.5:1, and the photoinitiator is by photoinitiator 184,907,1173 by weight 1:1:1 Ratio mix, ratio mixing of the solvent by water and ethyl alcohol by weight 1:1 forms.
2. a kind of manufacturing process of electric toothbrush housings according to claim 1, it is characterised in that: the step (4) Transparent flexible glue layer is rubber, silica gel, PU or PVC.
3. a kind of manufacturing process of electric toothbrush housings according to claim 1, it is characterised in that: the step (5) Transparent decorative article is assemblied on the transparent flexible glue layer by way of 3M glue bond or with the clamping of electric toothbrush housings shell.
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