CN105816880A - Novel medical high-molecular material and application thereof - Google Patents
Novel medical high-molecular material and application thereof Download PDFInfo
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- CN105816880A CN105816880A CN201510010945.6A CN201510010945A CN105816880A CN 105816880 A CN105816880 A CN 105816880A CN 201510010945 A CN201510010945 A CN 201510010945A CN 105816880 A CN105816880 A CN 105816880A
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Abstract
The invention relates to a novel medical high-molecular material, which is characterized in that the novel medical high-molecular material is netted compound molecules formed by carbon element atoms, hydrogen element atoms and oxygen element atoms by a bonding mode and having a spatial structure.
Description
Technical field
The invention belongs to medical macromolecular materials.
Background technology
In prior art, medical macromolecular materials have been obtained for being widely applied.Main application aspect is for artifucial limb；And the application in terms of medical high polymer adsorbent, in particular with the application of the material surface micro power that adsorbent is had, still there is wide developing space.
Summary of the invention
The purpose of the present invention is to propose to a kind of polymeric sorbent new material technology scheme utilizing material surface micro power, the blank of material for repairing application.
Present disclosure is: described medical high polymer new material is one and includes carbon atom, protium atom and oxygen element atom, the meshing adduct molecule with space structure constituted in keyed jointing (link) mode.
The preparation method is that: using the styrene-divinylbenzene polymer absorbant of network molecular structure as parent, or using vinylacetate-divinylbenzene polymer adsorbent as parent, obtained by post-crosslinking reaction.
The cellular construction of this meshing adduct molecule minimum is by including that two phenyl ring and several hydroxy combinings are constituted, and has hydrophilic and lipophilic surface is amphiphilic.Two public keys, interval can be had between two phenyl ring to constitute the mesh space between phenyl ring；Remaining key mapping of phenyl ring is by hydroxyl occupy-place, and hydroxyl can have four to eight；The vacant key mapping of phenyl ring can be taken by two phenyl ring covalency.Three public keys, interval can also be had between two phenyl ring to constitute the mesh space between phenyl ring；Remaining key mapping of phenyl ring is by hydroxyl occupy-place, and hydroxyl can have three to six；The vacant key mapping of phenyl ring can be taken by two phenyl ring covalency.Two public keys, interval can also be had between two phenyl ring to constitute the mesh space between phenyl ring；Remaining key mapping of phenyl ring by hydroxyl occupy-place, hydroxyl can have two each and every one to four；The vacant key mapping of phenyl ring can be taken by two phenyl ring covalency, or links other hydrophilic group.Multiple compound molecule cellular constructions can be constituted two or more unit compound molecule with the structural form of phenyl ring covalent linkage.Multiple-unit molecule copolymerization can be netted lineament, or netted 2-dimensional planar type structure, or three dimensional network solid type structure.
In the material molecular structure of final products, including by two and above phenyl ring and the compound of keyed jointing (link) multiple hydroxyl on the key mapping node of phenyl ring.This type of compound molecule unit can be obtained by different process routes；Wherein have and this same molecular structure, or contain and this same molecular structure division, or there is compound or the polymer of molecular structure similar with this element, broadly fall into disclosure of the present invention, all should be among the scope of the present patent application protection.
The present invention is an embodiment of inventor's earlier application patent of invention.Earlier application denomination of invention: " the nanoscale striker of intensive material surface micro power ", the applying date: on December 24th, 2014, application number: 201410813390.4.
Medical high polymer new diseases of the present invention:
Macromolecular material of the present invention has reticulated structure, there is a micro-space in reticulated structure, and this micro-space can accommodate the nuclear particle of constitution element.Placing particle by ion injection method in the framework space of reticulated structure, described particle can be uncharged neutron；Or charged proton, or include the pantogen daughter nucleus of neutron, or the atom of element.
Actually one, this space accommodates the particle reaction device that nuclear particle carries out reacting.
The molecular configuration of macromolecular material of the present invention, including phenyl ring and the hydroxyl being connected on phenyl ring site.When using as adsorbent, show as hydroxyl and there is hydrophilic and phenyl ring has lipophilic amphiphilic.In practice, when material of the present invention is prepared as nano_scale particle, the amphiphatic attribute in surface can make it freely navigate within electron cloud field between atom, can break through blood brain barrier in human body.In clinic, under the induction of human-body biological electric field, driven by raw electric current, implement to penetrate for all kinds of focus materials, make its cell tissue avalanche, reach therapeutic purposes.This is an aspect of the possessed function of macromolecular material of the present invention.Another aspect, material of the present invention or resin absorption agent carrier, the mesh space structure of material itself can be as a carrier loading material particle.Take technological means, it can be made completely to carry uncharged neutron and pass electron cloud field, enter atomic nucleus district.Or, it can be made to carry the atom of element, or atomic nucleus in advance, through another electron cloud field, enter another atomic nucleus district.When neutron and nucleus collision, or atomic nucleus with nucleus collision time, atomic nucleus will be caused change, i.e. initiation: or nuclear fission or the nuclear reaction of nuclear fusion.Before, initiated core reaction needs huge startup energy, and its effect mainly overcomes the barrier of atomic nucleus peripheral electron cloud field, makes the neutron of external source and atomic nucleus come in contact (shock)；That is a kind of strength breakthrough mode applied with external force.And material of the present invention has the amphiphilic attribute in surface, it navigates within electron cloud field is the intensive micro power utilizing material surface.With the difference that strength breakthrough mode has essence.The startup of nuclear reaction is that the equilibrium state making atomic nucleus internal forces is unbalance owing to the neutron in atomic nucleus or proton quantity change, and destroys certain gravitation barrier in pantogen daughter nucleus；Make in atomic nucleus combinations of substances naturally-occurring avalanche, or restructuring polymerization, and thus discharge huge atomic energy.The interior space of material network structure of the present invention can accommodate the particle of atomic core levels, allow in the liquid electric field that nanoscale microsphere of the present invention cruises at one, particles of material of the present invention, with the micro power on its amphiphilic surface, can navigate within the electron cloud field outside atomic nucleus with the particle in carrying structure.Have two kinds it can happen that, Yi Zhongshi: the neutron that carries (or proton, or atomic nucleus) deviates from cancellated space, comes in contact (shock) with the atomic nucleus touched in electron cloud field；Another kind is: in the liquid electric field allowing nanoscale microsphere of the present invention to cruise, and there is also the driving force ordering about particle concentration balance.Rich free neutron (or atomic nucleus) in liquid electric field, is ordered about space in the network structure entering low-level neutron concentration, comes in contact (shock) with neutron (or atomic nucleus) therebetween by equilibrant；In the case of two kinds, nuclear reaction all can thus occur.Owing to these nuclear reactions are to occur in material molecule of the present invention nano level reticulated structure space, and occur between the particle that number is few, it is possible to achieve control.
Embodiments of the invention:
One of embodiment, the environment used is placed among the solution under electric field or emulsion: the nanoscale medical high polymer new material of the present invention carries neutron, it is in the uranium 235 of nano_scale particle, or nano_scale particle 239, or nano_scale particle beryllium or beryllium alloy, or both wherein, or three, or among four solution put altogether or emulsion, induced by potential difference in electric field, cruise under the ordering about of electric current, enter in above-mentioned substance electron cloud field, overflow cancellated space can directly contact with above-mentioned substance atomic nucleus or clash into, or atomic nucleus enters in network structure space, directly contact with neutron or clash into, initiated core fission reaction.
The two of embodiment, the environment used is placed among the solution under electric field or emulsion: the nanoscale medical high polymer new material of the present invention carries neutron, be in nano_scale particle liquid deuterium atom, nano_scale particle liquid tritium atom or nano_scale particle liquid deuterate lithium atom or with wherein the two or the solution of three's atomic mixture or emulsion among, induced by potential difference in electric field, cruise under the ordering about of electric current, entering in above-mentioned substance electron cloud field, overflowing cancellated space can directly contact with the atomic nucleus in above-mentioned substance or clash into；Or atomic nucleus enters in network structure space, directly contacts with neutron or clashes into, initiated core fusion reaction.
The three of embodiment, the environment used is placed among the solution under electric field or emulsion: what the nanoscale new material of the present invention carried is nano_scale particle uranium 235, or nano_scale particle 239, or nano_scale particle beryllium or nano_scale particle beryllium alloy, or during mixture microgranule that wherein the two or three or four put altogether；Controlled electrical field is rich in free neutron in solution or emulsion, in a liquid under the ordering about of particle concentration equilibrium driving force, can enter in the reticulated structure of the present invention being in neutron low concentration level, contact with atomic nucleus or clash into, initiated core fission reaction.
The four of embodiment, the environment used is placed among the solution under electric field or emulsion: the nanoscale new material of the present invention carries nano_scale particle D-atom or nano_scale particle tritium atom or nano_scale particle lithium deuteride atom, or wherein the two or three's mixture atomic time；Being rich in free neutron in solution or emulsion in controlled electrical field, in a liquid under the ordering about of particle concentration equilibrant, free neutron can enter in the reticulated structure of the present invention being in neutron low concentration level, contacts with atomic nucleus or clashes into, initiated core fusion reaction.
The nanoscale molecular of material of the present invention can be induced by potential difference in the electric field, and cruises under electric current orders about.During electric field avalanche (power failure), stop mobile.Therefore, above-described embodiment manually can be implemented in the electric field of relation control at one.
The prominent substantive distinguishing features that the present invention is had is that the molecular configuration of new material of the present invention has cancellated space；Can be as carrying the carrier of particle, such as, the nano_scale particle of new material can carry neutron, under the induction of electric field, is ordered about movement by electric current.The most still the most identical with present invention material carrier.
Another prominent substantive distinguishing features of the present invention is that new material of the present invention has amphiphilic surface characteristic, and its nano_scale particle can free in and out the electron cloud field of molecule.
3rd the prominent substantive distinguishing features of the present invention is, new material of the present invention can provide nuclear fission or the reaction condition of nuclear fusion for nuclear reaction, become Micro Core reactor in nano level mesh space.
The present invention is significantly progressive to be, nano_scale particle of the present invention can free in and out the electron cloud field between material molecule, directly contacts with atomic nucleus for neutron or clashes into offer condition；Realize atomic energy release, without using device complicated in prior art, save the preposition energy starting nuclear reaction, and required complexity and costly equipment.
Claims (10)
1. a medical high polymer new material, it is characterised in that: described medical high polymer new material is a meshing adduct molecule with space structure including that carbon atom, protium atom and oxygen element atom are constituted in keyed jointing mode；The minimum cellular construction of this meshing adduct molecule is by including that two phenyl ring and some hydroxy combinings are constituted, and has hydrophilic and lipophilic amphiphilic.
2. a kind of medical high polymer new material as claimed in claim 1, it is characterised in that: there are two public keys, the mesh space between the phenyl ring of interval between two phenyl ring；Remaining key mapping of phenyl ring is by hydroxyl occupy-place, and hydroxyl can have four to eight；Or, between two phenyl ring, have three public keys, the mesh space between the phenyl ring of interval；Remaining key mapping of phenyl ring is by hydroxyl occupy-place, and hydroxyl can have three to six；Or, between two phenyl ring, have four public keys, the mesh space between the phenyl ring of interval；Remaining key mapping of phenyl ring is by hydroxyl occupy-place, and hydroxyl can have two to four；The vacant key mapping of phenyl ring can be taken by two phenyl ring covalency, or links other hydrophilic group.
3. a kind of medical high polymer new material as claimed in claim 1 or 2, it is characterised in that: multiple compound molecule cellular constructions can be constituted two or more unit compound molecule with the structural form of phenyl ring covalent linkage.
4. a kind of medical high polymer new material as claimed in claim 3, it is characterised in that: multiple-unit molecular compound can be netted lineament, or netted two dimension aspect type structure, or three dimensional network solid type structure.
The preparation method of a kind of medical high polymer new material the most as claimed in claim 1 or 2, it is characterised in that: using the styrene-divinylbenzene polymer absorbant of network molecular structure as parent, obtained by post-crosslinking reaction.
The preparation method of a kind of medical high polymer new material the most as claimed in claim 1 or 2, it is characterised in that: using the vinylacetate-divinylbenzene polymer adsorbent of network molecular structure as parent, obtained by post-crosslinking reaction.
7. a kind of medical high polymer new diseases as claimed in claim 1, it is characterised in that: space in the net of new material nanoscale microsphere reticulated structure, place and carry particle by particle method for implanting, described particle can be uncharged neutron；Or include the pantogen daughter nucleus of neutron.
8. a kind of medical high polymer new diseases as claimed in claim 7, it is characterized in that: space in the net of new material nanoscale microsphere reticulated structure, placing and carry particle by particle method for implanting, described particle is uranium 235, or 239, or beryllium or beryllium alloy；Or wherein the two, or three, or four put altogether.
9. a kind of medical high polymer new diseases as claimed in claim 7, it is characterized in that: space in the net of new material nanoscale microsphere reticulated structure, placed by particle method for implanting and carry particle, described particle is deuterium, or tritium, or lithium deuteride, or wherein the two, or three puts the most altogether.
10. a kind of medical high polymer new diseases as described in claim 7 or 8 or 9, it is characterized in that, the environment used is placed among electric field: the period of the day from 11 p.m. to 1 a.m in described nanoscale medical high polymer new material carries, be in electric field is the uranium 235 of nano_scale particle, or nano_scale particle 239, or nano_scale particle beryllium or beryllium alloy, or wherein the two, or three, or four solution put altogether or emulsions；Or, be in electric field is nano_scale particle liquid deuterium, nano_scale particle liquid tritium or nano_scale particle liquid lithium deuteride, or wherein the two or the liquefied mixture of three；Or, the microgranule carried at described nanoscale medical high polymer new material is nanoscale uranium 235, or nano_scale particle 239, or nano_scale particle beryllium or nano_scale particle beryllium alloy, or wherein the two, or three, or four put altogether mixture microgranule time；Or in described nanoscale medical high polymer new material, carry nano_scale particle liquid deuterium, nano_scale particle liquid tritium or nano_scale particle liquid lithium deuteride, or wherein when the two or three's liquefied mixture, be in electric field is the solution containing rich free neutron or emulsion.
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| CN101088598A (en) * | 2006-06-12 | 2007-12-19 | 天津协成昌国际贸易有限公司 | Prepn and product of adsorbing material |
| CN101543764A (en) * | 2009-04-30 | 2009-09-30 | 南京大学 | Hydrophobic carbonyl modified superhigh crosslinked adsorption resin as well as synthetic method and application thereof |
| EP2564923A1 (en) * | 2010-04-28 | 2013-03-06 | Hitachi High-Technologies Corporation | Adsorbent and method for producing same |
| CN103483487A (en) * | 2013-08-01 | 2014-01-01 | 于杰 | Novel structure product, preparation method and use of styrenic resin |
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Application publication date: 20160803 |