CN105802254A - TPE (thermoplastic elastomer) based 3D printing material - Google Patents

TPE (thermoplastic elastomer) based 3D printing material Download PDF

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Publication number
CN105802254A
CN105802254A CN201610306035.7A CN201610306035A CN105802254A CN 105802254 A CN105802254 A CN 105802254A CN 201610306035 A CN201610306035 A CN 201610306035A CN 105802254 A CN105802254 A CN 105802254A
Authority
CN
China
Prior art keywords
parts
printing material
tpe
printed material
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610306035.7A
Other languages
Chinese (zh)
Inventor
肖文涛
郝同辉
赵辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Daoqin New Material Technology Co Ltd
Original Assignee
Jiangsu Daoqin New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Daoqin New Material Technology Co Ltd filed Critical Jiangsu Daoqin New Material Technology Co Ltd
Priority to CN201610306035.7A priority Critical patent/CN105802254A/en
Publication of CN105802254A publication Critical patent/CN105802254A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Toys (AREA)

Abstract

The invention discloses a TPE (thermoplastic elastomer) based 3D printing material. The 3D printing material comprises the following raw materials in parts by weight: 20-35 parts of SEBS (styrene-ethylene-butylene-styrene block copolymer), 40-70 parts of naphthenic oil, 10-25 parts of PP (polypropylene), 3-8 parts of foaming microspheres, 0.5-1.5 parts of dispersing and lubricating agent, 3-8 parts of toughening agent, 1-2.5 parts of stabilizing agent and 0.5-1 part of antioxidant. The 3D printing material has the beneficial effects that the 3D printing material has excellent plasticity, good elasticity and light mass and can meet the production requirements of various bouncing ball toys; manufactured products have long service lives and are easy to popularize.

Description

A kind of TPE base 3D printed material
Technical field
The present invention relates to novel plastic Material Field, be specifically related to a kind of TPE base 3D printed material.
Background technology
Bouncing ball is a kind of toy liked by child very much, and it is the transparent ball utilizing lactoprene to be processed into, and this colloid has good elastic force effect, has high bouncing function after touching ground.Existing bouncing ball toy is typically made up of elastic transparent sphere shell body and liquid or the gas filler being enclosed in spherical housing body, the defect of existing bouncing ball is that sealing is poor, after using a period of time, gas or liquid easily spill, and cause bouncing ball to damage and can not use.
Traditional bouncing ball processing technology also results in and reduces the service life of bouncing ball, uses 3D printing technique, bouncing ball can be made to reach seamless effect, can be greatly improved the service life of bouncing ball, but traditional material can not meet the requirement that 3D prints.
Therefore, for the problems referred to above, the present invention proposes a kind of new technical scheme.
Summary of the invention
It is an object of the invention to provide a kind of TPE base 3D printed material.
The present invention is achieved through the following technical solutions:
A kind of TPE base 3D printed material, the raw material including following parts by weight forms: SEBS20-35 part, TPE30-50 part, naphthenic oil 40-70 part, PP10-25 part, foam microspheres 3-8 part, dispersed lubricant 0.5 ~ 1.5 part, toughener 3 ~ 8 parts, stabilizer 1 ~ 2.5 part, antioxidant 0.5 ~ 1 part.
Described dispersed lubricant is calcium stearate.
Described toughener is ethylene-vinyl acetate copolymer.
Described stabilizer is barium zinc stabilizer.
Described antioxidant is antioxidant TNP.
The invention has the beneficial effects as follows: the present invention has the plasticity of excellence, good springiness, light weight, can meet the production requirement of multiple bouncing ball toy, the long product lifecycle of making, it is easy to promote.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further.
Embodiment 1
A kind of TPE base 3D printed material, the raw material including following parts by weight forms: SEBS35 part, TPE50 part, naphthenic oil 70 parts, PP25 part, foam microspheres 8 parts, dispersed lubricant 1.5 parts, toughener 8 parts, stabilizer 2.5 parts, antioxidant 1 part.
Embodiment 2
A kind of TPE base 3D printed material, the raw material including following parts by weight forms: SEBS20 part, TPE30 part, naphthenic oil 40 parts, PP10 part, foam microspheres 3 parts, dispersed lubricant 0.5 part, toughener 3 parts, stabilizer 1 part, antioxidant 0.5 part.
Embodiment 3
A kind of TPE base 3D printed material, the raw material including following parts by weight forms: SEBS30 part, TPE40 part, naphthenic oil 50 parts, PP20 part, foam microspheres 5 parts, dispersed lubricant 1 part, toughener 6 parts, stabilizer 1.8 parts, antioxidant 0.6 part.
The present invention has the plasticity of excellence, good springiness, light weight, can meet the production requirement of multiple bouncing ball toy, the long product lifecycle of making, it is easy to promote.
Although the above-mentioned detailed description of the invention to the present invention is described; but not limiting the scope of the invention; on the basis of technical scheme, those skilled in the art need not to pay various amendments or deformation that creative work can make still within protection scope of the present invention.

Claims (5)

1. a TPE base 3D printed material, it is characterized in that: include that the raw material of following parts by weight forms: SEBS20-35 part, TPE30-50 part, naphthenic oil 40-70 part, PP10-25 part, foam microspheres 3-8 part, dispersed lubricant 0.5 ~ 1.5 part, toughener 3 ~ 8 parts, stabilizer 1 ~ 2.5 part, antioxidant 0.5 ~ 1 part.
A kind of TPE base 3D printed material, it is characterised in that: described dispersed lubricant is calcium stearate.
A kind of TPE base 3D printed material, it is characterised in that: described toughener is ethylene-vinyl acetate copolymer.
A kind of TPE base 3D printed material, it is characterised in that: described stabilizer is barium zinc stabilizer.
A kind of TPE base 3D printed material, it is characterised in that: described antioxidant is antioxidant TNP.
CN201610306035.7A 2016-05-10 2016-05-10 TPE (thermoplastic elastomer) based 3D printing material Pending CN105802254A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610306035.7A CN105802254A (en) 2016-05-10 2016-05-10 TPE (thermoplastic elastomer) based 3D printing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610306035.7A CN105802254A (en) 2016-05-10 2016-05-10 TPE (thermoplastic elastomer) based 3D printing material

Publications (1)

Publication Number Publication Date
CN105802254A true CN105802254A (en) 2016-07-27

Family

ID=56456729

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610306035.7A Pending CN105802254A (en) 2016-05-10 2016-05-10 TPE (thermoplastic elastomer) based 3D printing material

Country Status (1)

Country Link
CN (1) CN105802254A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862673A (en) * 2019-12-03 2020-03-06 诺思贝瑞新材料科技(苏州)有限公司 Foaming thermoplastic elastomer material for 3D printing and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292850A (en) * 2014-08-20 2015-01-21 青岛尤尼科技有限公司 Three dimensional (3D) printing-based flexible material and preparation method thereof
CN104672616A (en) * 2015-03-16 2015-06-03 深圳市光华伟业实业有限公司 Woody 3D printing line
CN105218939A (en) * 2015-11-05 2016-01-06 中国科学院福建物质结构研究所 A kind of foamable 3D printed material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292850A (en) * 2014-08-20 2015-01-21 青岛尤尼科技有限公司 Three dimensional (3D) printing-based flexible material and preparation method thereof
CN104672616A (en) * 2015-03-16 2015-06-03 深圳市光华伟业实业有限公司 Woody 3D printing line
CN105218939A (en) * 2015-11-05 2016-01-06 中国科学院福建物质结构研究所 A kind of foamable 3D printed material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862673A (en) * 2019-12-03 2020-03-06 诺思贝瑞新材料科技(苏州)有限公司 Foaming thermoplastic elastomer material for 3D printing and preparation method thereof

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Application publication date: 20160727