CN105802150A - Hydrophobic anti-leakage pbt material and preparation method thereof - Google Patents
Hydrophobic anti-leakage pbt material and preparation method thereof Download PDFInfo
- Publication number
- CN105802150A CN105802150A CN201610231194.5A CN201610231194A CN105802150A CN 105802150 A CN105802150 A CN 105802150A CN 201610231194 A CN201610231194 A CN 201610231194A CN 105802150 A CN105802150 A CN 105802150A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- powder
- weight
- zinc oxide
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a hydrophobic anti-leakage pbt material.The hydrophobic anti-leakage pbt material is prepared from, by weight, 2-3 parts of dimethylethanolamine, 1-2 parts of sodium silicate, 3-4 parts of 2-ethyl-4-methylimidazole, 70-80 parts of caprolactam, 10-13 parts of attapulgite, 1-1.4 parts of zinc acetate, 2-3 parts of gamma-aminopropyl triethoxy silane, 18-20 parts of oxalic acid, 300-370 parts of polybutylene terephthalate, 2-3 parts of 2-thiolbenzimidazole, 10-13 parts of epoxy cotton seed butyl oleate, 1-2 parts of chlorthal-dimethyl and 2-3 parts of calcium lactobionate.The hydrophobic anti-leakage pbt material has the good surface hydrophobic property, and is high in surface strength and good in stability.
Description
Technical field
The present invention relates to field of material technology, particularly relate to a kind of hydrophobic anti-leakage pbt material and preparation method thereof.
Background technology
ZnO was widely studied in the last few years as a kind of photocatalyst-type anti-biotic agent, and it generates strong oxygen under photocatalysis
The active function groups of the property changed kills antibacterial.It has nontoxic, nonirritant, good stability, and difficult decomposition under high temperature, timeliness is long
For a long time, cheap, the advantage such as aboundresources, have broad application prospects;
The common carrier being presently used for loaded optic catalyst mainly has CNT (CNTs) and activated carbon, mesoporous material, Linesless charcoal
Black and zeolites etc. can obtain the nano-particle of size uniform by load, in turn ensure that functional nano-composites simultaneously
High stability.Nano-photocatalyst/porous mineral compound system, i.e. assembles Nano semiconductor photocatalyst or loads to mineral
In the hole of material or on surface, not only solve the agglomeration traits of nano-photocatalyst granule, reduce its consumption, also simultaneously
Utilize the high-specific surface area of porous mineral, strong characterization of adsorption to realize in water or the targeting enrichment of pollutants in air, urged by light
Agent is more effectively carried out light degradation;
Therefore nano-photocatalyst/porous mineral compound system can improve the disposal efficiency of catalysis material, reduces again
Its consumption and preparation cost, accomplished to have complementary advantages, and this support type composite had both remained the character of nano-particle itself,
Closed by the interface between nano-particle and matrix simultaneously, some new assembly effects can be produced again, make whole complex
System shows as distinctive synergistic enhancing effect, thus significantly improves the functional characteristic of material, but presently used carrier is the most all deposited
In the shortcoming such as expensive, surface activity point is low, therefore, research and develop a kind of novel carrier material and be the most increasingly subject to
The attention of scholars, find a kind of cheap, surface activity is high and the novel carriers of good stability seems the most necessary;
Polyamide due to its good mechanical property, barrier property, anti-wear performance, acid-proof alkaline and good processing characteristics,
Increasingly become indispensable material as engineering plastics and non-fibre material, its application relate to auto parts and components, cord fabric,
The fields such as tyre equatorial, electronic apparatus, household supplies, consumption becomes kinds most in polyamide product.But applying
Cheng Zhong, the polar group of polyamide 6 material makes it be prone to absorb moisture, causes dry state and low temperature impact strength is low, product
Easily there is the phenomenon such as plastic deformation, serious wear in product poor stability, friction, additionally, uses as mine engineering plastics, do not possess
Antistatic property, easily produces gas explosion etc., thus affects the stability of its product size, antiwear and friction reduction property and electrically
Can, which has limited its range of application;
Attapulgite, as a kind of natural nanometer fibrous clay mineral, has 2:1 type layer chain structure, in its crystal structure
There is a large amount of pore passage structure, and have that specific surface area is big, surface activity site is many, energy of adsorption
By force, excellent biocompatibility and the chemically and thermally feature such as stability, be a kind of economical and practical carrier material, giving birth to
The aspects such as thing, environment, new material have broad application prospects;Therefore it is an object of the invention to nano-photocatalyst with recessed
Convex rod stone is effectively combined, and is the most effectively distributed in polyamide, prepares a kind of novel composite.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of hydrophobic anti-leakage pbt material and system thereof
Preparation Method.
The present invention is achieved by the following technical solutions:
A kind of hydrophobic anti-leakage pbt material, it is made up of the raw material of following weight parts:
Dimethylethanolamine 2-3, sodium silicate 1-2,2-ethyl-4 Methylimidazole. 3-4, caprolactam 70-80, attapulgite 10-
13, zinc acetate 1-1.4, gamma-aminopropyl-triethoxy-silane 2-3, ethanedioic acid 18-20, polybutylene terephthalate (PBT) 300-
370,2-mercapto benzimidazole 2-3, epoxy cotton seed oil acid butyl ester 10-13, chlorine dimethyl phthalate 1-2, calcium lactobionate. 2-3.
The preparation method of a kind of described hydrophobic anti-leakage pbt material, comprises the following steps:
(1) above-mentioned sodium silicate is joined in the deionized water of its weight 6-10 times, stir, mix with attapulgite,
At 80-90 DEG C, insulated and stirred is done to water, calcines 1-2 hour at sending into 300-350 DEG C, and cooling joins the hydrochloric acid of 3-5mol/l
Middle acidifying 3-5 hour, souring temperature is 20-35 DEG C, precipitation is washed 3-4 time after filtration, is dried at 80-90 DEG C, wears into thin
Powder, obtains activation attapulgite powder;
(2) take the 16-20% of above-mentioned ethanedioic acid weight, join in the dehydrated alcohol of its weight 25-30 times, stir;
(3) above-mentioned zinc acetate is joined in its weight 70-80 times, 46-50% ethanol solution, add above-mentioned activation concavo-convex
Rod soil powder, ultrasonic 10-20 minute, drips the ethanol solution of above-mentioned ethanedioic acid, magnetic agitation 3-4 minute after dropping, sucking filtration,
Product after sucking filtration is dried 3-5 hour at 110-116 DEG C, sends in Muffle furnace, at 600-640 DEG C, calcine 1.7-2 little
Time, cooling, obtain zinc oxide load powder;
(4) above-mentioned 2-ethyl-4 Methylimidazole. is joined in the dehydrated alcohol of its weight 50-60 times, stir, add two
Methylethanolamine, adds gamma-aminopropyl-triethoxy-silane, rises high-temperature and is 30-40 DEG C, and insulated and stirred 10-16 minute obtains silicon
Alkanol liquid;
(5) joining in silanol liquid by above-mentioned zinc oxide load powder, rise high-temperature and be 80-90 DEG C, insulated and stirred 1.7-2 is little
Time, sucking filtration, precipitation is washed 2-3 time, is vacuum dried 20-30 minute at 50-60 DEG C, obtain amino modified zinc oxide load powder
Material;
(6) take the 10-16% of above-mentioned caprolactam weight, the 20-30% of residue ethanedioic acid weight, load with amino modified zinc oxide
Powder, calcium lactobionate. mix, and add the distilled water of compound weight 8-10 times, are sent in reactor, and liter high-temperature is 190-
200 DEG C, insulation reaction 3-4 hour, slowly cool to room temperature, be filtered to remove filtrate, precipitation is dried, grinds to form fine powder, obtain pre-
Poly-modified zinc oxide load powder;
(7) above-mentioned pre-polymerization modified zinc oxide load powder is mixed with remaining caprolactam, add compound weight 4-7 times
Distilled water, is sent in reactor, rises high-temperature and is 200-230 DEG C, adds remaining ethanedioic acid, insulation reaction 3-3.5 hour,
Adding above-mentioned chlorine dimethyl phthalate, stirring mixing 10-20 minute, discharging cools down, and is vacuum dried 1-2 hour at 50-60 DEG C,
Polymeric modification zinc oxide load powder;
(8) being mixed with remaining each raw material by above-mentioned polymeric modification zinc oxide load powder, high-speed stirred is uniform, sends into twin screw and squeezes
Go out machine extrusion, through tie rod, cooling, pelletizing, dried, to obtain final product.
The invention have the advantage that first attapulgite is calcined and acidification by the present invention, attapulgite can be increased
The silicone hydroxyl group on stone surface, gives attapulgite surface more negative charge, increases its absorbability to metal cation,
By the attapulgite in-situ precipitate of absorption Zn2+ ion is obtained presoma, obtain ZnO/ attapulgite composite wood by calcination
Material, with attapulgite as carrier, can improve the dispersibility of ZnO nanoparticle, it is thus achieved that have the composite of high antibacterial activity,
Attapulgite as layer chain silicate clay, the advantages such as tool specific surface area is big and lateral reactivity site is many, load nano-ZnO
After, considerably increasing the contact area of ZnO and microorganism, high adsorption activity based on attapulgite, antibacterial can be by antibacterial material
Material absorption is forming enrichment about so that ZnO nano granule is easier to directly contact with antibacterial, thus plays its antibacterial characteristics
Cause inactivation of bacteria, then this composite is participated in the pre-polymerization process of caprolactam, utilize caprolactam open-loop products
Aminocaproic acid reacts with the amino of composite material surface, makes composite material surface be grafted a certain amount of polyamide prepolymer aggressiveness, at it
Surface forms one layer of strong boundary layer;Participate in the polymerization process of polyamide the most again, due to the polyamides of composite material surface grafting
Amine performed polymer can participate in the ring-opening polymerisation of caprolactam, therefore, it is possible to form " micronetwork " structure with masterbatch as core, enters
And add intensity and the toughness of polyamide substrate material, and, beneficially composite is in the dispersion of polyamide substrate material;
The material of the present invention has good hydrophobic properties of the surface, and surface strength is high, good stability.
Detailed description of the invention
A kind of hydrophobic anti-leakage pbt material, it is made up of the raw material of following weight parts:
Dimethylethanolamine 2, sodium silicate 1,2 ethylmethylimidazolium 3, caprolactam 70, attapulgite 10, zinc acetate 1, γ ammonia third
Ethyl triethoxy silicane alkane 2, ethanedioic acid 18, polybutylene terephthalate (PBT) 300,2 mercapto benzimidazole 2, epoxy cotton seed oil
Acid butyl ester 10, chlorine dimethyl phthalate 1, calcium lactobionate. 2.
The preparation method of a kind of described hydrophobic anti-leakage pbt material, comprises the following steps:
(1) above-mentioned sodium silicate is joined in the deionized water of its weight 6 times, stir, mix with attapulgite, at 80 DEG C
Lower insulated and stirred is done to water, calcines 1 hour at sending into 300 DEG C, and cooling joins in the hydrochloric acid of 3mol/l and is acidified 3 hours, acidifying
Temperature is 20 DEG C, precipitation is washed 3 times after filtration, is dried, wears into fine powder, obtain activation attapulgite powder at 80 DEG C;
(2) take the 16% of above-mentioned ethanedioic acid weight, join in the dehydrated alcohol of its weight 25 times, stir;
(3) above-mentioned zinc acetate is joined in its weight 70 times, the ethanol solution of 46%, adds above-mentioned activation attapulgite powder,
Ultrasonic 10 minutes, dripping the ethanol solution of above-mentioned ethanedioic acid, magnetic agitation 3 minutes after dropping, sucking filtration, by the product after sucking filtration
Thing is dried 3 hours at 110 DEG C, sends in Muffle furnace, calcines 1.7 hours at 600 DEG C, cooling, obtains zinc oxide load powder;
(4) above-mentioned 2 ethylmethylimidazolium are joined in the dehydrated alcohol of its weight 50 times, stir, add dimethyl second
Hydramine, adds γ aminopropyl triethoxysilane, and rising high-temperature is 30 DEG C, and insulated and stirred 10 minutes obtains silanol liquid;
(5) joining in silanol liquid by above-mentioned zinc oxide load powder, rising high-temperature is 80 DEG C, and insulated and stirred 1.7 hours is taken out
Filter, washes precipitation 2 times, is vacuum dried 20 minutes at 50 DEG C, obtains amino modified zinc oxide load powder;
(6) take above-mentioned caprolactam weight 10%, residue ethanedioic acid weight 20%, with amino modified zinc oxide load powder,
Calcium lactobionate. mixes, and adds the distilled water of compound weight 8 times, is sent in reactor, and rising high-temperature is 190 DEG C, and insulation is anti-
Answer 3 hours, slowly cool to room temperature, be filtered to remove filtrate, precipitation is dried, grinds to form fine powder, obtain pre-polymerization modified zinc oxide and bear
Carry powder;
(7) above-mentioned pre-polymerization modified zinc oxide load powder is mixed with remaining caprolactam, add the steaming of compound weight 4 times
Distilled water, is sent in reactor, and rising high-temperature is 200 DEG C, adds remaining ethanedioic acid, insulation reaction 3 hours, adds above-mentioned chlorine
Dimethyl phthalate, stirring mixing 10 minutes, discharging cools down, and is vacuum dried 1 hour at 50 DEG C, obtains the load of polymeric modification zinc oxide
Powder;
(8) being mixed with remaining each raw material by above-mentioned polymeric modification zinc oxide load powder, high-speed stirred is uniform, sends into twin screw and squeezes
Go out machine extrusion, through tie rod, cooling, pelletizing, dried, to obtain final product.
Performance test:
Hot strength is 96.6MPa;
Notch impact strength (KJ/m2) 10.16;
Vertical combustion (1.6mm) FV-O;
The zinc oxide load powder wherein prepared is O.lg/L to colibacillary minimum inhibitory concentration.
Claims (2)
1. a hydrophobic anti-leakage pbt material, it is characterised in that it is made up of the raw material of following weight parts:
Dimethylethanolamine 2-3, sodium silicate 1-2,2-ethyl-4 Methylimidazole. 3-4, caprolactam 70-80, attapulgite 10-
13, zinc acetate 1-1.4, gamma-aminopropyl-triethoxy-silane 2-3, ethanedioic acid 18-20, polybutylene terephthalate (PBT) 300-
370,2-mercapto benzimidazole 2-3, epoxy cotton seed oil acid butyl ester 10-13, chlorine dimethyl phthalate 1-2, calcium lactobionate. 2-3.
2. the preparation method of a hydrophobic anti-leakage pbt material as claimed in claim 1, it is characterised in that include following step
Rapid:
(1) above-mentioned sodium silicate is joined in the deionized water of its weight 6-10 times, stir, mix with attapulgite,
At 80-90 DEG C, insulated and stirred is done to water, calcines 1-2 hour at sending into 300-350 DEG C, and cooling joins the hydrochloric acid of 3-5mol/l
Middle acidifying 3-5 hour, souring temperature is 20-35 DEG C, precipitation is washed 3-4 time after filtration, is dried at 80-90 DEG C, wears into thin
Powder, obtains activation attapulgite powder;
(2) take the 16-20% of above-mentioned ethanedioic acid weight, join in the dehydrated alcohol of its weight 25-30 times, stir;
(3) above-mentioned zinc acetate is joined in its weight 70-80 times, 46-50% ethanol solution, add above-mentioned activation concavo-convex
Rod soil powder, ultrasonic 10-20 minute, drips the ethanol solution of above-mentioned ethanedioic acid, magnetic agitation 3-4 minute after dropping, sucking filtration,
Product after sucking filtration is dried 3-5 hour at 110-116 DEG C, sends in Muffle furnace, at 600-640 DEG C, calcine 1.7-2 little
Time, cooling, obtain zinc oxide load powder;
(4) above-mentioned 2-ethyl-4 Methylimidazole. is joined in the dehydrated alcohol of its weight 50-60 times, stir, add two
Methylethanolamine, adds gamma-aminopropyl-triethoxy-silane, rises high-temperature and is 30-40 DEG C, and insulated and stirred 10-16 minute obtains silicon
Alkanol liquid;
(5) joining in silanol liquid by above-mentioned zinc oxide load powder, rise high-temperature and be 80-90 DEG C, insulated and stirred 1.7-2 is little
Time, sucking filtration, precipitation is washed 2-3 time, is vacuum dried 20-30 minute at 50-60 DEG C, obtain amino modified zinc oxide load powder
Material;
(6) take the 10-16% of above-mentioned caprolactam weight, the 20-30% of residue ethanedioic acid weight, load with amino modified zinc oxide
Powder, calcium lactobionate. mix, and add the distilled water of compound weight 8-10 times, are sent in reactor, and liter high-temperature is 190-
200 DEG C, insulation reaction 3-4 hour, slowly cool to room temperature, be filtered to remove filtrate, precipitation is dried, grinds to form fine powder, obtain pre-
Poly-modified zinc oxide load powder;
(7) above-mentioned pre-polymerization modified zinc oxide load powder is mixed with remaining caprolactam, add compound weight 4-7 times
Distilled water, is sent in reactor, rises high-temperature and is 200-230 DEG C, adds remaining ethanedioic acid, insulation reaction 3-3.5 hour,
Adding above-mentioned chlorine dimethyl phthalate, stirring mixing 10-20 minute, discharging cools down, and is vacuum dried 1-2 hour at 50-60 DEG C,
Polymeric modification zinc oxide load powder;
(8) being mixed with remaining each raw material by above-mentioned polymeric modification zinc oxide load powder, high-speed stirred is uniform, sends into twin screw and squeezes
Go out machine extrusion, through tie rod, cooling, pelletizing, dried, to obtain final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610231194.5A CN105802150A (en) | 2016-04-14 | 2016-04-14 | Hydrophobic anti-leakage pbt material and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610231194.5A CN105802150A (en) | 2016-04-14 | 2016-04-14 | Hydrophobic anti-leakage pbt material and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105802150A true CN105802150A (en) | 2016-07-27 |
Family
ID=56460137
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610231194.5A Pending CN105802150A (en) | 2016-04-14 | 2016-04-14 | Hydrophobic anti-leakage pbt material and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105802150A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101444717A (en) * | 2008-12-05 | 2009-06-03 | 江苏工业学院 | Method for preparing concavo-convex rod soil/zinc oxide nanometer composite material |
CN102952327A (en) * | 2011-08-25 | 2013-03-06 | 上海杰事杰新材料(集团)股份有限公司 | Resin composite material and its preparation method and use |
CN104448299A (en) * | 2013-09-24 | 2015-03-25 | 骏马化纤股份有限公司 | In-situ-polymerized halogen-free flame-retardant nylon 6/attapulgite nano composite material and preparation method thereof |
-
2016
- 2016-04-14 CN CN201610231194.5A patent/CN105802150A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101444717A (en) * | 2008-12-05 | 2009-06-03 | 江苏工业学院 | Method for preparing concavo-convex rod soil/zinc oxide nanometer composite material |
CN102952327A (en) * | 2011-08-25 | 2013-03-06 | 上海杰事杰新材料(集团)股份有限公司 | Resin composite material and its preparation method and use |
CN104448299A (en) * | 2013-09-24 | 2015-03-25 | 骏马化纤股份有限公司 | In-situ-polymerized halogen-free flame-retardant nylon 6/attapulgite nano composite material and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105860452A (en) | Antimicrobial pbt material and preparation method thereof | |
Yuan et al. | Multi-component design and in-situ synthesis of visible-light-driven SnO2/g-C3N4/diatomite composite for high-efficient photoreduction of Cr (VI) with the aid of citric acid | |
CN108855011B (en) | Composite material with adsorption-visible light catalytic degradation synergistic effect and application thereof | |
Ye et al. | Interfacial engineering of vacancy-rich nitrogen-doped FexOy@ MoS2 Co-catalytic carbonaceous beads mediated non-radicals for fast catalytic oxidation | |
CN102585309B (en) | Method for preparing high-dispersion white carbon black/rubber nano composite material | |
CN105148966B (en) | Carbon quantum dot grafted hydroxyapatite photocatalysis material preparation method | |
CN104031651A (en) | Passivation improver for heavy metal pollution farmland and using method thereof | |
El Messaoudi et al. | A comparative review of the adsorption and photocatalytic degradation of tetracycline in aquatic environment by g-C3N4-based materials | |
CN108126718B (en) | In2S3/BiPO4Preparation method and application of heterojunction photocatalyst | |
CN105107477A (en) | Hyperbranched polymer/clay mineral hybrid material and preparation method thereof | |
CN105778440A (en) | Environment-friendly pbt material and preparing method thereof | |
CN105838043A (en) | Attapulgite-modified pbt material and preparation method thereof | |
Tang et al. | Fabrication and application of chitosan-based biomass composites with fire safety, water treatment and antibacterial properties | |
CN105778441A (en) | Heat-preservation pbt material and preparing method thereof | |
Qiu et al. | Controllable synthesis of carbon dots@ CaCO3 composites: tunable morphology, UV absorption properties, and application as an ultraviolet absorber | |
CN106955677A (en) | It is a kind of based on ion liquid modified egg shell/acticarbon and preparation method thereof | |
CN103806088B (en) | Method for preparing calcium carbonate whisker by taking triethanolamine as aid | |
CN105860448A (en) | Pbt material for automobile exterior part and preparing method thereof | |
CN101058678B (en) | Large interlamellar spacing and high activity modified calcium-base montmorillonite and preparation method thereof | |
CN105860454A (en) | Anti-oxidant pbt material and preparation method thereof | |
CN105802150A (en) | Hydrophobic anti-leakage pbt material and preparation method thereof | |
CN105778437A (en) | Composite silicon modified pbt material and preparing method thereof | |
CN105802148A (en) | Pbt material and preparation method thereof | |
CN105778438A (en) | Stable type pbt material and preparation method thereof | |
CN105860451A (en) | Antistatic pbt material and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160727 |