Clean applications of the water-washing pre-treatment domestic garbage incineration flyash in road surface
Technical field
The present invention relates to a kind of clean applications of the domestic garbage incineration flyash after water-washing pre-treatment in road surface, belong to solid
Body offal treatment disposal and recycling, road paving materials and its processing technology of preparing crossing domain.
Background technology
Domestic garbage incineration flyash is the trapping thing and flue and chimney bottom of municipal solid waste incinerator flue gas purification system
The bottom ash of sedimentation.Research shows, containing poisonous and harmful substances such as dioxin and heavy metals in domestic garbage incineration flyash, because
This, China is classified as《National Hazard waste register》In HW18 class hazardous wastes, it is improper conduct oneself well put and can directly threaten around
Environment and human health, and public group event can be triggered and then influence waste incineration industry actively to develop in a healthy way.House refuse
The toxicity of flying ash and the characteristic for easily causing secondary pollution are also important original that municipal solid waste incinerator addressing is queried by the public
Cause.
Now some developed countries mainly include for the disposal technology of domestic garbage incineration flyash at present:Mine is buried, height
Temperature melting, clinker mixing disposal etc., but in view of China's national situation, investment cost of disposal and current law limitation etc., the above
Technology is not suitable for China's use at present.And the main disposal options of domestic garbage incineration flyash of domestic current include:Directly enter
Enter hazardous waste landfill landfill, chelating agent stabilize or cement solidification after enter sanitary filling field landfill, at cement kiln collaboration
Put etc., there is processing cost height in these methods, be also easy to produce the secondary pollution of environment, and land occupation resource exists rotten to equipment
The shortcomings of erosion.
Based on above reason, development environment is friendly, meet the incineration of refuse flyash disposal technology of China's economic development, from root
Change flying dust disposal actuality in sheet, the contradiction between the current waste incineration industry energy, environment, resource three is broken through, in turning into
The Major Strategic Demand of state's waste incineration industry value chain.
The content of the invention
In view of this, it is an object of the invention to provide a kind of domestic garbage incineration flyash application by after water-washing pre-treatment
In the technical scheme of road surfacing, the technical scheme realizes recycling cleaning of the domestic garbage incineration flyash in road surface should
With.
The technical scheme that the present invention takes is as follows:
1st, clean applications of the water-washing pre-treatment domestic garbage incineration flyash in road surface, by the consumer waste incineration after washing
Flying dust substitutes part miberal powder and added in asphalt, and asphalt is applied into road surface;House refuse is burnt after the washing
It is 2~5% to burn mass percent of the flying dust in asphalt mineral aggregate.
It is preferred that, the particle diameter of the domestic garbage incineration flyash is less than 1mm.
It is preferred that, flying dust weight/mass percentage composition of the particle diameter less than 75 μm is more than 75% in the domestic garbage incineration flyash,
And the domestic garbage incineration flyash mass fraction in 58~75 μm of particle size ranges is more than 70%.
It is preferred that, the asphalt is matched somebody with somebody using SMA-13 types level, SMA-16 types level is matched somebody with somebody, AC-20C types level is matched somebody with somebody, AC-
25C types level is matched somebody with somebody or ATB-25 types level is matched somebody with somebody.
It is preferred that, the water-washing pre-treatment comprises the following steps:First domestic garbage incineration flyash is dried, then will life
Incineration of refuse flyash is 1 in mass ratio with water:3~5 ratio mixes 20 under conditions of 1800~2500r/min~
30min, precipitation or standing, until moisture is filtered after supernatant clarification, after domestic garbage incineration flyash repetition washing 0~2 time
Dried in 75 DEG C of baking ovens.
It is preferred that, domestic garbage incineration flyash and water in mass ratio 1 during water-washing pre-treatment:3 mix, and flying dust washing times are
2 times, asphalt is matched somebody with somebody using SMA-13 types level, and cementitious matter uses SBS modified pitch, and water-washing pre-treatment consumer waste incineration flies
Mass percent of the ash in asphalt mineral aggregate is 4%.Now result (the TSR of indirect tensile test on frozen-thaw:Freeze-thaw split intensity
Than) it is 82.3%.
It is preferred that, domestic garbage incineration flyash and water in mass ratio 1 during water-washing pre-treatment:3 mix, and flying dust washing times are
2 times, asphalt is matched somebody with somebody using AC-20C types level, and cementitious matter uses plain asphalt, water-washing pre-treatment domestic garbage incineration flyash
Mass percent in asphalt mineral aggregate is 2%.Now result (the TSR of indirect tensile test on frozen-thaw:Freeze-thaw split intensity
Than) it is 79.4%.
It is preferred that, domestic garbage incineration flyash and water in mass ratio 1 during water-washing pre-treatment:5 mix, and flying dust washing times are
3 times, asphalt is matched somebody with somebody using AC-20C types level, and cementitious matter uses plain asphalt, water-washing pre-treatment domestic garbage incineration flyash
Mass percent in asphalt mineral aggregate is 3%.Now result (the TSR of indirect tensile test on frozen-thaw:Freeze-thaw split intensity
Than) it is 77.6%.
It should be noted that the preparation method of water-washing pre-treatment domestic garbage incineration flyash asphalt mixed using heat,
Warm mix or cold-mix asphalt compound mix and stir technique;It is that dry method substitutes ore deposit that water-washing pre-treatment domestic garbage incineration flyash, which is mixed with mode,
Powder, its heating-up temperature, heat time, the same miberal powder of adding order;The transport of water-washing pre-treatment domestic garbage incineration flyash, addition,
The process such as mix and stir and be in relative air-tight state;The mixing time root of water-washing pre-treatment domestic garbage incineration flyash asphalt
The amount added according to water-washing pre-treatment domestic garbage incineration flyash accordingly extends 0~30s.
The beneficial effects of the present invention are:The domestic garbage incineration flyash asphalt that traditional asphalt curing technology is made
The soluble salt of middle high content can influence the anti-water damage ability of bituminous paving, reduce Pavement Condition, and then lead to not reality
The large dosage that border is applied to domestic garbage incineration flyash is disposed, and domestic garbage incineration flyash can not be really realized the resource on road surface
Change clean utilization.The present invention is pre-processed using washing to domestic garbage incineration flyash first, is washed consumer waste incineration off and is flown
More than 90% soluble salt in ash, is then applied to road surfacing by pretreated flying dust.The road surface pavement performance of laying is each
It is qualified that index meets Leaching Heavy Metals in code requirement, and domestic garbage incineration flyash, will not cause secondary to environment
Pollution.The present invention realizes recycling clean utilization of the domestic garbage incineration flyash in road surface in engineering, efficiently solves
Influence of the soluble salt dissolution to bituminous paving water stabilizing during domestic garbage incineration flyash is applied on road surface, it is ensured that asphalt road
The performance in face.
Embodiment
The preferred embodiments of the present invention are described in detail below.The experiment side of unreceipted actual conditions in embodiment
Method, generally according to normal condition or according to the condition proposed by manufacturer.
Domestic garbage incineration flyash used of the invention derives from Chongqing garbage burning factory, for through grate furnace formula waste incineration
The domestic garbage incineration flyash that the sack cleaner of stove is collected, domestic garbage incineration flyash carries out bioxin low temperature thermal degradation first
Processing, the optimal processing parameter of low temperature thermal degradation is as follows:
Thermal degradation temperature:400 DEG C,
Flying dust discharge temperature:≤ 150 DEG C,
The solid phase residence time:1-2h,
Atmosphere:Nitrogen atmosphere, O2Volumetric concentration≤1%,
Dechlorination active medium:CaO, mass concentration >=10%.
Xia above-mentioned process conditions the degradation rate of bioxin is up to more than 95%, and domestic garbage incineration flyash Zhong bioxin contains
Amount is reduced to below 10ng TEQ/kg;In addition, solvable salt content is 20~30% in domestic garbage incineration flyash, heavy metal contains
Amount is shown in Table 1.
Content of beary metal (butt, mg/kg) in the domestic garbage incineration flyash of table 1
Domestic garbage incineration flyash leachate Leaching of Heavy Metals concentration is shown in Table 2.
The domestic garbage incineration flyash leachate Leaching of Heavy Metals concentration (hac buffer method, mg/L) of table 2
Endanger composition |
Leaching concentration |
Be |
Do not detect |
V |
Do not detect |
Cr |
0.05 |
Mn |
3.92 |
Co |
0.10 |
Ni |
0.19 |
Cu |
3.09 |
Zn |
111.29 |
As |
Do not detect |
Se |
Do not detect |
Cd |
5.99 |
Sb |
Do not detect |
Ba |
2.55 |
Hg |
0.03 |
Tl |
Do not detect |
Pb |
1.19 |
U |
Do not detect |
Th |
Do not detect |
Ag |
Do not detect |
In the content in table, domestic garbage incineration flyash the higher heavy metal element of content include Zn, Pb, Ba, Mn,
Be also in Cu, Cr and Cd, its hac buffer method leachate Zn, Pb, Mn, Cu, Cd concentration it is higher, wherein Pb and Cd's is dense
Degree beyond《Household refuse landfill sites contamination control standard (GB16889-2008)》Specified in admission limit value.Now use this hair
Bright methods described carries out innoxious, recycling to the domestic garbage incineration flyash.
Above-mentioned domestic garbage incineration flyash is taken to carry out washing process first, water-washing process is as follows:
1), the domestic garbage incineration flyash for consolidating caking is pulverized and weighed, is then placed in 2 in 105 DEG C of baking oven
~4h is dried to constant weight, is taken out domestic garbage incineration flyash and is weighed and calculate moisture content;By the domestic garbage incineration flyash being baked
Load hermetic bag sealing, to prevent the moisture absorption again;
2) a certain amount of drying domestic garbage incineration flyash, is weighed, 3~5 times of domestic garbage incineration flyash quality of addition
Water simultaneously stirs (rotating speed 1800r/min~2500r/min) 20~30min under strong mixer;
3) after, stirring or concussion terminate, precipitation or standing 1h or so, until supernatant is no longer muddy, filter superfluous water
Point, moisture centralized collection;
4), repeat after washing 0~2 time, filter excessive moisture, dry, weigh in 75 DEG C of baking oven, counting loss rate
(i.e. soluble salt constituent content);
5) domestic garbage incineration flyash grinding, pack, mark, standby after, washing.
It is preferred that the particle diameter of domestic garbage incineration flyash is less than 1mm;Particle diameter is less than 75 μ more preferably in domestic garbage incineration flyash
M flying dust weight/mass percentage composition is more than 75%, and in the domestic garbage incineration flyash mass fraction of 58~75 μm of particle size ranges
More than 70%.
By the domestic garbage incineration flyash of water-washing pre-treatment part miberal powder will be replaced to add in asphalt, after washing
Mass percent of the domestic garbage incineration flyash in asphalt mineral aggregate is 2~5%.Mixed using heat, warm mix or cold mixing are dripped
Blue or green compound mixes and stirs technique;It is that dry method substitutes miberal powder that water-washing pre-treatment domestic garbage incineration flyash, which is mixed with mode, and it heats temperature
Degree, heat time, the same miberal powder of adding order;The transport of water-washing pre-treatment domestic garbage incineration flyash, the process such as to add, mix and stir equal
In relative air-tight state;The mixing time of water-washing pre-treatment domestic garbage incineration flyash asphalt is according to water-washing pre-treatment
The amount of domestic garbage incineration flyash addition accordingly extends 0~30s.The asphalt of acquisition is finally applied to road surface.Experiment
As a result show, by asphalt be used to laying the table on road surface, in, cutting optimal or basic unit.
It is preferred that asphalt is matched somebody with somebody using SMA-13 types level, SMA-16 types level is matched somebody with somebody, AC-20C types level is matched somebody with somebody, AC-25C types level is matched somebody with somebody
Or ATB-25 types level is matched somebody with somebody.
Several preferred concrete schemes, but the scheme not limited to this that the present invention takes is set forth below.In addition, it is necessary to explanation
Be that acid organic pitch has high surface energy, big surface-active and strong cohesive force, lived with the alkalescence that belongs to inorganic constituents
The effect of a series of physical and chemical adsorption occurs for incineration of refuse flyash, reach cladding domestic garbage incineration flyash, stable curing its
In heavy metal and its compound purpose, realize that de- " danger " of domestic garbage incineration flyash is applied.But recycling exists
During bituminous paving, the physicochemica components of domestic garbage incineration flyash have impact on the high-temperature stability of bituminous paving, anti-low-temperature cracking
Property and water resistant damage the pavement performance such as performance, wherein influence most to protrude is water stability.Therefore, in following examples emphatically
Introduce water stabilizing result of the test.
Embodiment 1
When in water-washing process, the mass ratio of flying dust and water is 1:3, when washing times are 2 times, with SMA-13 types level with being
Example, water intaking wash after domestic garbage incineration flyash substitute part miberal powder, using SBS modified pitch and necessarily match coarse aggregate,
Fine aggregate, miberal powder and lignin fibre, using the mixing that technique carries out compound of mixing and stirring of hot-mix asphalt mixture, obtain water
Wash pretreatment domestic garbage incineration flyash asphalt.Wherein the heating-up temperature of water-washing pre-treatment domestic garbage incineration flyash,
Heating-up temperature and heat time of the heat time with miberal powder.Water-washing pre-treatment domestic garbage incineration flyash is added simultaneously with miberal powder,
And duration of mixing extension 15s after addition.Water-washing pre-treatment is lived in water-washing pre-treatment domestic garbage incineration flyash asphalt
The mass percent of mineral aggregate shared by incineration of refuse flyash is 4%, now result (the TSR of indirect tensile test on frozen-thaw:Freeze-thaw split intensity
Than) it is 82.3%, meet《Standard specification for construction and acceptance of highway asphalt pavement》(JTG F40-2004) Asphalt Mixture, which will reach, to be split
Resistance to spalling is than the regulation not less than 80%.
Embodiment 2
When in water-washing process, the mass ratio of flying dust and water is 1:3, when washing times are 2 times, with AC-20C types level with being
Example, the domestic garbage incineration flyash after water intaking is washed substitutes part miberal powder, uses SK 70# pitches and the coarse aggregate necessarily matched, thin
Gather materials and miberal powder, using the mixing that technique carries out compound of mixing and stirring of hot-mix asphalt mixture, obtain water-washing pre-treatment life
Incineration of refuse flyash asphalt.The wherein heating-up temperature of water-washing pre-treatment domestic garbage incineration flyash, heat time same ore deposit
The heating-up temperature of powder and heat time.Water-washing pre-treatment domestic garbage incineration flyash is added simultaneously with miberal powder, and mix after addition
Time lengthening 10s.Water-washing pre-treatment domestic garbage incineration flyash in water-washing pre-treatment domestic garbage incineration flyash asphalt
The mass percent of shared mineral aggregate is 2%, now result (the TSR of indirect tensile test on frozen-thaw:Freeze-thaw split strength ratio) it is 79.4%,
Meet《Standard specification for construction and acceptance of highway asphalt pavement》(JTG F40-2004) Asphalt Mixture will reach that Ratio of split strength is not small
In 75% regulation.
Embodiment 3
When in water-washing process, the mass ratio of flying dust and water is 1:5, when washing times are 3 times, with AC-20C types level with being
Example, using SK 70# pitches, and the coarse aggregate, fine aggregate and miberal powder necessarily matched, using mixing and stirring for hot-mix asphalt mixture
Technique carries out the mixing of compound, obtains water-washing pre-treatment domestic garbage incineration flyash asphalt.Wherein water-washing pre-treatment
Heating-up temperature and heat time of the heating-up temperature, heat time of domestic garbage incineration flyash with miberal powder.Water-washing pre-treatment is lived
Incineration of refuse flyash is added simultaneously with miberal powder, and duration of mixing extension 12s after addition.Water-washing pre-treatment domestic garbage incineration flyash
The mass percent of mineral aggregate shared by water-washing pre-treatment domestic garbage incineration flyash is 3% in asphalt, now freeze-thaw split
Result (the TSR of experiment:Freeze-thaw split strength ratio) it is 77.6%, meet《Standard specification for construction and acceptance of highway asphalt pavement》(JTG
F40-2004) Asphalt Mixture will reach the regulation that Ratio of split strength is not less than 75%.
It should be noted that the code requirement that the proportioning of each raw material of Asphalt Mixture of the present invention is matched somebody with somebody by corresponding stage adds
Plus, prepare the data that the condition of asphalt do not provide and carried out by this area usual operating conditions, the noun in the present invention
Term is understood by this area conventional sense.
Finally illustrate, preferred embodiment above is merely illustrative of the technical solution of the present invention and unrestricted, although logical
Cross above preferred embodiment the present invention is described in detail, it is to be understood by those skilled in the art that can be
Various changes are made to it in form and in details, without departing from claims of the present invention limited range.